Restricted accessMoreSectionsView PDF ToolsAdd to favoritesDownload CitationsTrack Citations ShareShare onFacebookTwitterLinked InRedditEmail Cite this article Romo-Uribe Angel 2001Smectic–like order in the log–rolling flow of thermotropic random copolymers. A time–resolved wide–angle X–ray scattering studyProc. R. Soc. Lond. A.4571327–1342http://doi.org/10.1098/rspa.2000.0720SectionRestricted accessResearch articleSmectic–like order in the log–rolling flow of thermotropic random copolymers. A time–resolved wide–angle X–ray scattering study Angel Romo-Uribe Angel Romo-Uribe Ticona, Celanese AG, 86 Morris Avenue, Summit, NJ 07901, USA () Google Scholar Find this author on PubMed Search for more papers by this author Angel Romo-Uribe Angel Romo-Uribe Ticona, Celanese AG, 86 Morris Avenue, Summit, NJ 07901, USA () Google Scholar Find this author on PubMed Search for more papers by this author Published:08 June 2001https://doi.org/10.1098/rspa.2000.0720AbstractUnder a suitable combination of molecular weight, temperature and shear rate thermotropic random copolymers display macromolecular orientation orthogonal to the flow direction and along the vorticity axis; Romo–Uribe & Windle have called this a ‘log–rolling’ flow. Time–resolved wide–angle X–ray scattering has enabled the detection of a 002 meridional reflection as the orthogonal orientation develops from the non–oriented molten phase. Therefore, similar sequences of the random copolymer self–assemble during the log–rolling flow, giving rise to a smectic–like phase. After cessation of shear, neither the molecular sequence assemblage is lost nor is macromolecular orientation relaxation observed. Furthermore, applying shear to macromolecules that are already orthogonal to the velocity axis disrupts the chain register due to the macromolecular disorientation prior to the transition to the flow–aligning regime. Strikingly, after cessation of shear, the macromolecules recoil towards the orthogonal orientation and the molecular sequence assembly is re–established. The smectic–like order is therefore the mechanism that stabilizes the log–rolling flow. Previous ArticleNext Article VIEW FULL TEXT DOWNLOAD PDF FiguresRelatedReferencesDetailsCited by Romo-Uribe A (2022) Wide-angle X-ray diffraction and small-angle X-ray scattering studies of elastomer blends and composites Elastomer Blends and Composites, 10.1016/B978-0-323-85832-8.00010-9, (209-242), . Parisi D, Seo J, Schaake R, Rhoades A and Colby R (2021) Shear-induced nematic phase in entangled rod-like PEEK melts, Progress in Polymer Science, 10.1016/j.progpolymsci.2020.101323, 112, (101323), Online publication date: 1-Jan-2021. Romo-Uribe A (2021) Sequence segregation in the melt and viscoelasticity of thermotropic liquid crystalline polymer. A rheo-X-ray scattering study, Polymer, 10.1016/j.polymer.2020.123315, 213, (123315), Online publication date: 1-Jan-2021. Romo-Uribe A (2020) Scattering and Other Miscellanies Techniques for the Characterization of Shape Memory Polymers Shape Memory Polymers, Blends and Composites, 10.1007/978-981-13-8574-2_12, (269-309), . Reyes-Mayer A, Alvarado-Tenorio B, Romo-Uribe A, Benavente R, Jaffe M and Molina-Ocampo A (2015) Nanostructure reorganization in a thermotropic copolyester. A simultaneous WAXS and SAXS study, Polymers for Advanced Technologies, 10.1002/pat.3708, 27:6, (748-758), Online publication date: 1-Jun-2016. Romo-Uribe A (2007) Molecular orientation in sheared molten thermotropic random copolyester, Rheologica Acta, 10.1007/s00397-007-0192-9, 46:9, (1139-1152), Online publication date: 1-Dec-2007. Rendon S, Burghardt W and Bubeck R (2007) Orientation dynamics in commercial thermotropic liquid crystalline polymers in transient shear flows, Rheologica Acta, 10.1007/s00397-007-0177-8, 46:7, (945-956), Online publication date: 1-Aug-2007. This Issue08 June 2001Volume 457Issue 2010 Article InformationDOI:https://doi.org/10.1098/rspa.2000.0720Published by:Royal SocietyPrint ISSN:1364-5021Online ISSN:1471-2946History: Published online08/06/2001Published in print08/06/2001 License: Citations and impact Keywordstime–resolved X–ray scatteringthermotropic random copolymersnematic and smectic polymersmolecular sequence self–assemblymacromolecular orientation and relaxationlog–rolling and flow–aligning flow
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