In an endeavour to understand the various contributions to the spin scattering of conduction electrons in aluminium, the conduction-electron spin resonance linewidths of polycrystalline, pure and dilute alloy foils of aluminium have been measured in reflection at 42.5 MHz, 9.27 GHz and 20.9 GHz, over the temperature range 4.2-100K. From these linewidths the phonon spin scattering contribution at 42.5 MHz and 9.27 GHz is obtained and is found to be proportional to the phonon contribution to the resistivity scattering. At 42.5 MHz and below 25K a temperature dependence proportional to T2 is recorded, indicative of an electron-electron scattering process. The probability of a spin flip when an electron collides with the surface is also calculated from measurements of the linewidth at 42.5 MHz, and is found to agree with earlier measurements. At higher frequencies there are other contributions to the linewidth which may be attributed either to the complex Fermi surface of aluminium or to the breakdown of motional narrowing by the conduction electrons of the g anisotropy over the Fermi surface. In pure samples, one contribution is found at low temperatures and is linearly dependent on both the observational frequency and the resistivity scattering time. A second contribution, which is also linearly dependent on the frequency but independent of temperature, is reported as well. Finally, at the highest frequencies used or at high impurity levels an extra contribution to the temperature dependence is found, which is evident even at temperatures as high as 100K where motional narrowing is expected to be complete.
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