Pore wetting induced by surfactants and salt scaling is a major obstacle to the industrial application of membrane distillation (MD). Identifying the transition of wetting stages and achieving early monitoring of pore wetting are crucial for wetting control. Herein, we made a pioneering attempt to use ultrasonic time-domain reflectometry (UTDR) technique to non-invasively detect the pore wetting in a direct contact MD, and explain the UTDR waveform with the help of optical coherence tomography (OCT) imaging. The results showed that the water–vapor interface had a strong reflection to ultrasound (reflection coefficient = 0.9995), while the water-membrane and water-scaling layer interfaces showed relatively weak reflection. Therefore, UTDR could effectively detect the movement of water–vapor interface with the low interference from the signals generated by the membrane and scaling layer. For the surfactant-induced wetting, the occurrence of wetting could be successfully detected by the right-shift in phase and the reduction in amplitude of the UTDR waveform. Moreover, the wetting depth could be accurately calculated by the time of flight (ToF) and ultrasonic velocity. For scaling-induced wetting, the waveform slightly shifted to the left at the beginning due to the growth of scaling layer, then to the right because the left-shift was surpassed by the right-shift of the waveform caused by pore wetting. Both for the surfactant- and scaling-induced wetting, the variation of the UTDR waveform was sensitive to wetting dynamics, and the right-shift of phase and the reduction in amplitude of the waveform could act as early monitoring signals to the occurrence of wetting.
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