The flexural-torsional buckling behaviour and resistances of pin-ended hot-rolled stainless steel angle section columns have been studied in the present paper, based on laboratory testing and numerical modelling. The testing programme adopted four hot-rolled stainless steel angle sections and included initial global and torsional geometric imperfection measurements and twelve pin-ended column tests. The key obtained test results, including the failure loads and deformations at the failure loads, the load–mid-height lateral deflection curves and failure modes, were fully reported and discussed. Strong interaction between flexural-torsional buckling about the major principal axis and flexural buckling about the minor principal axis was observed for each pin-ended hot-rolled stainless steel angle section column specimen during and upon testing. The testing programme was followed by a numerical modelling programme; finite element models were developed and validated against the test results, and afterwards used to perform parametric studies to generate further numerical data over a wide range of cross-section dimensions and member lengths. On the basis of the experimentally and numerically obtained data, the accuracy of the codified design methods, as adopted in Europe, America and Australia/New Zealand, and a recently proposed DSM-based design approach for pin-ended hot-rolled stainless steel angle section columns susceptible to flexural-torsional buckling, were evaluated. Overall, it may be concluded that (i) all the three considered design codes result in conservative flexural-torsional buckling resistance predictions, (ii) the current European code leads to more accurate resistance predictions for pin-ended columns with non-slender hot-rolled stainless steel angle sections, but a lower degree of design accuracy for pin-ended columns with slender hot-rolled stainless steel angle sections, in comparison with the American specification and Australian/New Zealand standard, and (iii) the DSM-based design approach yields substantially improved resistance predictions, due to the rational consideration of the length-dependent characteristic of flexural-torsional buckling and the interaction of flexural-torsional buckling with minor-axis flexural buckling, but with many predictions lying on the unsafe side.