Flexural Strength Research Articles

MECHANICAL PROPERTIES AND MICROSTRUCTURE OF CONCRETE INCORPORATING SYNTHETIC ZEOLITE

The effect of natural and synthetic zeolite on the microstructure of cement matrix and mechanical properties of concretes was studied in the article. Results show that the addition of these pozzolanic materials results in the increase both compressive and flexural strength after 28 days of hardening. The concrete incorporating 10 mass.% of synthetic zeolite Na-P1 characterizes the highest compressive and flexural strength that reaches 53.5 and 7.8 MPa and exceeds the strength of reference concrete by 18 and 24%, respectively. This increase is the result of the improvement of the concrete on the microstructural level due to the formation of the additional amount of fibre-like crystals of hydrosilicates in the non-clinker part of the cement matrix providing its self-reinforcement.

Synchronously strengthening and plasticizing of unsaturated polyester resin based on styrene-maleic anhydride oligomer

To synchronously strength and plasticize unsaturated polyester resin (UPR), maleic anhydride were directly added in the unsaturated polyester resin solution and form the styrene-maleic anhydride oligomer (SMAO) without initiation. The creating SMAO cross link with UPR by curing reaction, and the prepared UPR resin exhibit higher tensile, elongation, bending strength and higher impact strength simultaneously, 0.45, 0.36, 0.76 and 0.12 times than UPR matrix, SMAO-UPR exhibits obvious plastic fracture characteristics; The DSC result indicates that the curing degree of SMAO-UPR is 96.55% which is 1.45% lower than that of UPR; The TG result indicates that MA and St mainly form an alternating copolymer below 90°C. The SEM and DMA result indicates that SMAO improves the morphology and structure which shows plastic deformation of UPR, and there is a certain interface effect between SMAO and UPR. Compared with the traditional method of large molecular weight SMA modified UPR, this method of reinforcing UPR is better for mechanical property, easy to operate, inexpensive, and highly applicable in industrial production.

Enhancing enset fiber‐reinforced polylactic acid composites through different surface treatments for emerging applications

AbstractEnvironmental concerns and the over‐exploitation of natural resources have driven the search for eco‐friendly materials. Agro/industrial waste, often discarded, can be repurposed as fillers in biocomposites. However, bio‐fibers present challenges such as poor compatibility, high moisture absorption, and variable mechanical properties. This study examines various fiber surface modification techniques, including NaOH, silane, alkali‐silane, and pectinase enzyme treatments on enset fiber (EF) to produce sustainable reinforced poly(lactic acid) (PLA) composites. Untreated EF/PLA composites were fabricated for comparison. Results showed that the applied EF surface treatments, especially using pectinase enzyme, significantly enhanced mechanical, thermal, and thermomechanical properties. Pectinase‐treated EF/PLA composites displayed increased tensile strength by 55.99%, elongation at the break by 39.49%, tensile modulus by 32.59%, impact strength by 51.50%, flexural strength by 51.85%, flexural modulus by 60.90%, and improved thermal stability as compared to untreated composite. Scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR) analyses verified better fiber‐matrix interaction with clarity due to reduced non‐cellulosic components. Pectinase enzyme treatment emerged as the most effective, eco‐friendly method, enhancing the enset fiber's potential in polymer biocomposites, suitable for automotive interiors and packaging industries, reducing synthetic plastic pollution, and utilizing agricultural waste.Highlights Enset fibers were modified by NaOH, silane, NaOH/silane, and pectinase enzyme The modified enset/PLA composites were prepared by compression molding Surface treatments enhanced the enset‐PLA matrix interaction Pectinase‐modified enset/PLA composite showed superior properties Improved properties of enset composites make it ideal for various applications

Estimation of Tensile and Flexure Strength of Hybrid Composites along with Epoxy as Matrix and Jute & E-Glass as Reinforcements

The natural fibers have the good properties such as mechanical and physical than artificial fibers in a many cases during the fabrication of composite materials that are used in many engineering applications. Also hybridization of fibers leads to impotent of mechanical properties these composites used in interior of aerospace vehicles, automobiles bumpers, decorative items, window panels, interior paneling, etc. where application pf load is very less. This research work is concentrated on the evolution of hybrid composite of Jute/E-glass reinforced with matrix epoxy using Hand layup method. Laminated composites specimens are prepared by calculating the required number of fiber layers and quantity of matrix based on the different volume fraction. The testing specimens are prepared for Tensile and Bending test as per standard of ASTM. The Universal Testing Machine is used to conducted Tensile and Bending test and results are plotted the graphs.

PHYSICAL-MECHANICAL PROPERTIES OF DYNAMICALLY VULCANIZED BASALT CONTAINING PLASTICS BASED ON COMPATIBILIZED POLYPROPYLENE

The influence of the content of basalt and Exxelor PО1020 compatibilizer on the main physical-mechanical and thermophysical characteristics of composites based on polypropylene is considered. It has been established that the use of a compatibilizer in an amount of 1.0–3.0 wt. % can significantly improve such properties of basalt plastics as tensile strength, yield strength, elongation at break, flexural strength, Vicat softening temperature, and melt flow rate. The possibility of cross-linking basalt plastics with sulfur and dicumyl peroxide is considered, and their role in changing their basic physical-mechanical parameters is determined. A theoretical analysis is given of the formation of an interfacial region with the participation of a compatibilizer and basalt. A micrograph showing the redistribution of basalt in the composition of compatibilized polypropylene is given by electron microscopy. The optimal concentrations of vulcanizing agents are determined, at which the highest strength properties are achieved, provided that elongation at break and the melt flow rate are maintained at a satisfactory level. It has been established that the optimal content of dicumyl peroxide is 0.25–0.5% wt

Ex Vivo Biomechanical Comparison of Four Techniques to Tibiotarsus Osteosynthesis in Adult Laying Hens (Gallus gallus domesticus).

To assess the biomechanical parameters of intact tibiotarsi (INT) and tibiotarsi with a 5-mm segmental diaphyseal defect repaired using four osteosynthesis techniques: a locking plate (LP), a plate-rod combination, an external skeletal fixator (one end-threaded positive-profile pin per fragment) with an intramedullary pin tie-in (TIF 1), and an external skeletal fixator (two end-threaded positive-profile pins per fragment) with an intramedullary pin tie-in (TIF 2). Sixty tibiotarsi from 30 adult laying hens were allocated into five groups for nondestructive dynamic torsion and four-point bending tests, followed by failure tests. Nondestructive dynamic tests evaluated stiffness over time in torsion and bending. Torsion destructive tests provided maximum torque and rotation values, whereas the four-point bending tests provided the yield load, maximum bending load, and maximum displacement. The INT group showed higher torsional stiffness and maximum torque but similar bending stiffness, torsional strength, and bending strength in one or more groups. LP and TIF 2 exhibited the highest similarity frequencies among the treatment groups, whereas the TIF 1 group displayed lower stiffness and strength for most of the evaluated parameters. Similar results for LP and TIF-2 groups suggest the biomechanical equivalence of these methods for tibiotarsal osteosynthesis in adult hens.

Upscaling of Copper Slag-Based Geopolymer to 3D Printing Technology

Additive manufacturing using cement has evolved rapidly in recent decades, revolutionizing the construction industry. This technology automates building structures through computer-aided design, offering benefits such as reduced material waste, optimized material distribution, and the ability to use composite materials. This paper aims to examine the potential of using copper-slag-based geopolymers in 3D printing. Geopolymers have gained popularity as an alternative and more energy-efficient material to traditional building materials, while copper slag allows for reducing and managing mining industry waste. Moreover, samples formed in molds based on the same material were produced to evaluate the method of manufacturing on the mechanical properties of geopolymers. This paper presents an evaluation of the mechanical properties including the compressive, flexural, and shear strength of the layered material. It reveals promising results, with strength development mainly observed within the first 14 days. The results show that the compressive strength after 28 days of curing is 46.4 MP and 42.1 MPa for formed and printed samples, respectively. Furthermore, the average bending strength value ranges between 7.4 MPa and 7.8 MPa, regardless of the bending direction and forming method. The obtained results show that printed geopolymers demonstrate adequate layer bonding, confirming the profitability of the 3D printing technology. This research confirms that 3D printing technology enables the use of geopolymer binder materials based on copper slag, which opens the door to sustainable alternatives in construction practices.

Incorporating Limestone Powder and Ground Granulated Blast Furnace Slag in Ultra-high Performance Concrete to Enhance Sustainability

Abstract While ultra-high performance concrete (UHPC) offers numerous advantages, it also presents specific challenges, primarily due to its high cost and excessive cement content, which can pose sustainability concerns. To address this challenge, this study aims to develop cost-effective and sustainable UHPC mixtures by incorporating ground granulated blast furnace slag (GGBFS) and limestone powder (LP) as partial replacements for portland cement. Eight fiber-reinforced UHPC mixtures were investigated, with a water-to-cementitious materials (w/cm) ratio of 0.15. In four of the UHPC mixtures, 25% of the cement was replaced with GGBFS, and further, LP was added as a mineral filler, partially substituting up to 20% of the cement. In the remaining four mixtures, cement was replaced with only LP up to 20% (without GGBFS). The 28-day compressive strength of the UHPC mixture with 25% GGBFS and 20% LP was 149 MPa, 3.50% lower than the mixture without GGBFS. Its 28-day flexural strength decreased by 30%. Increasing LP replacement reduced drying and autogenous shrinkage, with a 29% shrinkage reduction at 20% LP replacement. Moreover, UHPC mixtures with GGBFS exhibited lower shrinkage compared to those without GGBFS for all LP replacements up to 20%. For evaluating the sustainability of UHPC mixtures, the cement composition index (CCI) and clinker to cement ratio (CCR) were determined. For 20% LP replacement with 25% GGBFS, CCI was 3.6 and the CCR was 0.5, 38% decrease from the global clinker to cement ratio. Overall, 20% LP replacement UHPC mixtures with and without GGBFS can produce UHPC class performance and reduce the environmental impact.

Mechanical behaviour of pineapple leaf fibers reinforced Lapox L-12 epoxy composites

To meet the increasing need for composites in sectors such as medical, transportation, safety, and athletics, researchers continuously develop novel composites. This study investigated the effects of boron carbide filler particles in epoxy by fabricating composites from Lapox L-12 epoxy with 20 and 30 wt. % of pineapple leaf fibres (PALF) utilising the hand layup method. The mechanical parameters of the synthesised composites were evaluated according to ASTM standards, encompassing hardness, ultimate tensile strength, yield strength, elongation, and flexural strength. The addition of pineapple leaf fibres to epoxy Lapox L-12 resulted in enhanced hardness, tensile strength, and flexural strength, accompanied by a minor reduction in percentage elongation. Lapox L-12 composites supplemented with 30 wt.% of PALF exhibited enhancements of 60.8% in hardness, 66.2% in ultimate strength, and 101% in flexural strength.

Effects of Er:YAG laser debonding on changes in the properties of dental zirconia.

To investigate changes in the optical and mechanical properties of novel zirconia ceramics applied in dentistry after Er:YAG laser debonding and to evaluate the feasibility and value of reusing zirconia restorations debonded by an Er:YAG laser. Four types of zirconia ceramics were investigated: self-glazed zirconia (SGZ), 3Y-TZP, 4Y-PSZ and 5Y-PSZ. Forty rectangular (25 mm*8 mm*1.5 mm) specimens were fabricated for each zirconia type, and a total of 160 specimens were manufactured. The zirconia specimens were divided into four subgroups according to the applied Er:YAG laser debonding process: the control group, 4 W laser group, 5 W laser group, and 6 W laser group. For each subgroup, 10 specimens were subjected to color tests (color difference (△E) and transparency parameter (TP) tests) and subsequent mechanical tests (flexural strength (FS), elastic modulus (EM), Vickers hardness (VH) and surface roughness (Ra) tests). The △E, TP, FS, EM, VH and Ra values were measured and calculated. One random sample from each subgroup was observed by SEM. Statistical analyses were performed by one-way ANOVA followed by post hoc comparisons (α = 0.05). The △E and TP values after Er:YAG laser debonding were not significantly different among the subgroups (P > 0.05). However, the 6 W laser group had the highest △E and lowest TP. The ranges of changes in △E and TP were below the clinically detectable threshold (△E = 1.2, △TP = 1.33). In terms of the mechanical properties, there were no significant differences in the FS, EM, VH or Ra among the subgroups. No obvious microcracks were detected on the surfaces of the zirconia specimens during SEM. Er:YAG laser debonding does not obviously affect the optical or mechanical properties of novel zirconia ceramics in dentistry. Moreover, it is potentially feasible and valuable to reuse zirconia restorations after Er:YAG laser debonding.

Mechanical properties and crack deflection mechanisms in 3D-Printed porous geopolymers with cellular structures

ABSTRACT This study focuses on using helical design patterns via 3D printing to create geopolymer with a highly porous structure in order to enhance their strength-density relationship and fracture properties. In this regard, to create porous structure, different pitch angles and infill densities were chosen, and mechanical and fracture properties were examined. The results of mechanical strength tests revealed that while the pitch angle does not significantly affect compressive strength, flexural strength is improved by implementing a low pitch angle helical structure, which leads to the strength-density relationship improvement. Additionally, the work of fracture results demonstrated an enhancement for samples with low pitch angles, such as α15° and α30°, compared to cast and non-directional printed samples. The digital image correlation and fracture surface analysis showed several fracture mechanisms, predominantly crack deflection and twisting, in samples with low pitch angles, which contributes to the observed improvements in the work of fracture.

Evaluation of Flexural Strength and Vickers Micro Hardness of Three Different Denture Base Resin Materials

ABSTRACT Objectives: To evaluate the Vickers hardness and flexural strength of computer-aided design/computer-aided manufacture (CAD/CAM) milled, 3D-printed, and traditional heat-polymerized denture base resins used in computer-aided design and manufacture. Materials and Methods: A total of 60 samples were fabricated from CAD/CAM milled resin (PMMA dental material-Ruthinium disc, Badia Polesine (Rovigo) Italy), CAD/CAM 3D-printed resin (NextDent Denture 3D+, Soesterberg, The Netherlands) and conventional heat-polymerized (HP) denture base resin (DBR) (Triplex hot Ivoclar-Vivadent, Liechtenstein). Based on the three different denture base resin materials (n = 10/material) (30/flexural strength and 30/microhardness), the samples were split into six groups. The 3-point bending test was used to assess flexural strength, while Vickers microhardness test was used to assess surface hardness. The acquired data was statistically assessed. Results: CAD/CAM milled resins showed appreciably greater values for both the flexural strength and surface hardness, followed by conventional HP denture base resin and CAD/CAM 3D-printed resin. Pairwise comparison for Flexural Strength and Vickers microhardness revealed significant differences between groups. Conclusion: CAD/CAM milled resins had the highest surface hardness and flexural strength compared to Conventional HP denture base resin and CAD/CAM 3D-printed resin.

The Flexural Strength and the Effect of the Autoclave Sterilization of Polypropylene/Natural Rubber Blended Materials

Background: Rubber dam clamps are used extensively in dentistry, especially during root canal treatment. However, existing rubber dam clamps have several drawbacks, including discomfort and potential damage to vital tissue in the oral cavity. To address these existing issues, a new rubber dam clamp should be developed. The aim of this study was to identify the optimum ratios of polypropylene and natural rubber (PP/NR) for a customized rubber dam clamp in dentistry. This study was focused on the flexural strength of PP/NR in various ratios. Moreover, the impact of autoclave sterilization was also considered. Methods: Six proportions of PP/NR blends (100/0, 90/10, 80/20, 70/30, 60/40 and 50/50) were prepared and assessed for flexural strength using a three-point bending test. After this test, the PP/NR blends with 100/0, 90/10 and 80/20 ratios were selected and underwent autoclave sterilization for 1, 5 and 10 cycles. Eventually, the flexural strength testing was repeated and investigated. An analysis of variance and Tukey’s test were used to evaluate the flexural strength of various PP/NR blends before autoclave sterilization at p < 0.05. An analysis of variance and Dunnett’s T3 test were used to evaluate the flexural strength of selected PP/NR blends before and after autoclave sterilization at p < 0.05. Results: The results revealed that the flexural strength of PP/NR blended materials showed a statistically significant difference in every group of this study. The autoclave sterilization test revealed that the flexural strength of the PP/NR 90/10 and 80/20 ratios was significantly increased after sterilization for 1, 5 and 10 cycles. In addition, the PP/NR 90/10 ratio was also comparable to the 100/0 ratio. The lower NR content in PP/NR blends resulted in significantly higher flexural strength, and autoclave sterilization had an effect on this property. Conclusions: This study suggested that the PP/NR blend with a 90/10 ratio might be considered as an alternative material for developing rubber dam clamps.

Performance Research and Engineering Application of Fiber-Reinforced Lightweight Aggregate Concrete

Low strength and low impact toughness are two of the main issues affecting the use of lightweight aggregate concrete in harsh cold environments. In this study, the strength of concrete was improved by adding high-strength fibers to bear tensile stress and organize crack propagation. Four sets of comparative experiments were designed with freeze–thaw cycles of 0, 50, 100, and 150 to study the mechanical properties of fiber-reinforced lightweight aggregate concrete under freeze–thaw conditions. A detailed study was conducted on the effects of freeze–thaw on the compressive strength, flexural strength, impact toughness, and microstructure of concrete with different fiber contents (3, 6, and 9 kg/m3). The results show that for ordinary lightweight aggregate concrete, under the freeze–thaw cycle, the internal pore water of the concrete froze and generated expansion stress, resulting in tensile cracks inside the concrete. The cracks gradually accumulated and expanded, ultimately leading to cracking and damage of concrete structures. After 150 cycles, the strength loss rate exceeded 25%. When adding a reasonable amount of fiber (6 kg/m3), the fiber took on the tensile stress and hindered the development of internal cracks, significantly enhancing the splitting tensile strength, flexural strength, and impact toughness of lightweight aggregate concrete. And the failure pattern of concrete was significantly improved. At the beginning of the freeze–thaw cycle, the internal tensile stress was less than the fiber tensile strength and the fiber–matrix bonding strength, and the strength reduction rate of the concrete was slow. Relying on the friction absorption capacity between the fiber and the matrix, the fiber used its own deformation to resist the tensile stress. In the late stage of the freeze–thaw cycle, due to the destruction of the fiber–matrix transition zone structure, the bond strength decreased, the crack resistance and toughening effect decreased, and the strength of the concrete decreased rapidly. Moreover, the reduction in impact toughness was greater than the compressive strength and flexural strength under static load.

Impact of geopolymer aggregate on the mechanical properties and durability characteristics of concrete

This study examined the use of geopolymer aggregate (GPA), produced from slag and an alkaline solution, as a substitute for coarse aggregate in conventional concrete. The research aimed to evaluate how different proportions of GPA (25%, 50%, 75%, and 100% replacement) affect the durability and mechanical properties of concrete. A series of tests were conducted, including slump, compressive strength, flexural strength, chloride resistance, sulfate resistance, sorptivity, and water absorption. The results demonstrated significant improvements in concrete properties with the inclusion of GPA. The compressive strength of GPA concrete ranged from 31 to 38 MPa, showing a 10%–15% increase over that of standard concrete. Flexural strength improved by 6% at 7 days and 7.5% at 28 days compared to control mixes. Water absorption was reduced by 42.58%, and sorptivity decreased by 47.9% compared to ordinary aggregate concrete. GPA concrete also excelled in acid resistance, with a weight loss of 28.6% and a lower reduction in strength compared to traditional acidic aggregates. In sulfate resistance tests, GPA concrete showed a 31% reduction in both weight and strength loss. These results highlight the advantages of using GPA as an alternative to conventional coarse aggregates. GPA not only enhances the mechanical and durability properties of concrete but also presents a more sustainable option, contributing to reduced environmental impacts associated with traditional aggregate materials.

High‐performance engineered geopolymer composites: A sustainable approach using recycled brick waste

AbstractThis study examines the viability of using construction waste, specifically recycled brick waste powder (RBWP), as an alternative conventional industrial byproduct (fly ash) in the manufacturing of engineered geopolymer composites (EGC). The EGC mixtures are made with 40 μm diameter and 12 mm length polyvinyl alcohol (PVA) fiber. RBWP replaces class‐F fly ash in EGC by 0, 20%, 40%, 60%, 80%, and 100%. This study produces six distinct EGC mixtures in total. The flexural strength, abrasion resistance, sorptivity, and water absorption of the EGC are investigated. Microstructural characterization is carried out using scanning electron microscopy (SEM). Based on the results, when fly ash is replaced by 40% and 100%, respectively, adding RBWP to the EGC mixes significantly improves flexural strength by 39% and midspan deflection by 169%. Nevertheless, abrasion resistance significantly improves when fly ash is completely replaced with RBWP, even though sorptivity and water absorption increase by about 128% and 240%, respectively. The volume change is reduced by 25.4% when RBWP is used. Furthermore, the SEM study shows that the RBWP undergoes active geopolymerization in the EGC mixes.

Effect of recycled molybdenum tailings on mechanical properties of ultra-high-performance concrete

This paper presents experimental studies on mechanical properties and micro-structures of ultra-high performance concrete (UHPC) made of recycled molybdenum tailings. The particle size distribution and chemical compositions of recycled molybdenum tailings were analysed at first. Then, compressive and flexural tests were conducted on UHPC in which different volume fractions of recycled molybdenum tailings were used to replace silica sand. The effects of recycled molybdenum tailings replacement ratio on the compressive and flexural strengths were determined through comparisons. Besides, X-ray diffraction tests and backscattered electron tests were carried out to analyse the effect of molybdenum tailings on the micro-structure of UHPC. Based on test data, an optimal replacement ratio of molybdenum tailings was determined which could significantly reduce the cost of UHPC but maintain the mechanical properties in compression. A molybdenum tailings replacement ratio of 30% was recommended to maximise the economic effect and to reduce the carbon emission.

Study on the mechanical properties of layered gradient structure PBT-based flame retardant composite materials

Abstract To enhance the flame retardancy of Polybutylene Terephthalate (PBT) based composite materials and overcome the decrease in mechanical properties due to the high content of nano-antimony trioxide (nano-Sb2O3), this study initially applies a composite modification method to treat the surface of nano-Sb2O3. Subsequently, composite materials with a gradient distribution of nano-Sb2O3 are prepared through lamination hot-pressing technology, and their mechanical and flame retardant properties are investigated. The results show that the modifiers CTAB and KH560 are successfully grafted onto the surface of nano-Sb2O3, altering its surface properties. Through lamination hot-pressing technology, a gradient distribution from the surface to the core is achieved. Compared to the homogeneous distribution P666, G828 exhibits a 6% increase in Limiting Oxygen Index (LOI), improving the flame retardancy of the composite material. As nano-Sb2O3 enriches on the composite material's surface, the amount of char residue increases. The tensile strength, bending strength, and impact strength of G828 composite material increase by 19.7%, 37.1%, and 103%, respectively, compared to the homogeneous composite material P666, proving the significant effect of G828's gradient distribution in enhancing the mechanical properties of the composite material.

Investigation of the effect of urease bioadditives on porosity and water absorption of cement composites

The results of the application of the biomineralization process in concrete to improve concrete properties such as porosity and water absorption are presented. As a result of the research, an assessment of the activity of various bioadditives based on the Bacillus subtilis strain and isolates isolated from samples of chernozem soil of the Yelets district of the Lipetsk region was given.It was found that the immobilized bacteria slightly differ from the native form in terms of urease activity, however, when stored for more than 50 days. they maintain their activity at a high level, and native microorganisms lose their ability to function, reducing urease activity by 10 times practically to minimum values. It was also revealed that when using Portland cement of various types, there is a decrease in water absorption up to 30%, and porosity decreases up to 40%.The use of different types of fine aggregate also affects porosity, so when using the same parts of sand P1 and P2, porosity is lower than with a homogeneous fine aggregate.It was also noted that all samples had increased strength characteristics – compressive strength and bending strength by 15–25%, respectively. Thus, the use of bioadditives is optimal to achieve improved concrete characteristics.

Redispersible Acrylic Ester Polymers: Effect of Polymer Property Changes Due to Polymerization Method Modification and Functional Additives on the Performance of Polymer Cement Mortar

This paper presents an experimental study aimed at improving the performance of polymer cement mortar by evaluating the properties of acrylic ester redispersible polymers, synthesized using a change in polymerization method from emulsion monomer to monomer dropwise addition methods, along with the use of a functional additive in the form of a foaming agent. To achieve the research objectives, a polymer with a glass transition temperature of −11 °C was synthesized by fixing the monomer ratio, particle-size distribution, and glass transition temperature, and the physical properties of the polymer cement mortar were assessed. The results showed that polymers synthesized using the modified polymerization method increased elongation at break and possessed a 35% smaller average particle size. The use of the foaming agent also resulted in enhanced tensile strength. The polymer cement mortars made with these respective polymers demonstrated improvements in compressive strength 11~25%, flexural strength 53~77%, bond strength 78~113%, volumetric changes 65~88%, and water absorption 30~70%. These findings suggest that changes in the polymerization method and the incorporation of functional additives influence the average particle size and air entrainment control properties of the polymers, thereby positively impacting the performance of the cement hydrates.