Defects In Materials Research Articles

A Transformer-based neural network for automatic delamination characterization of quartz fiber-reinforced polymer curved structure using improved THz-TDS

Quartz fiber-reinforced polymer (QFRP) is a vital non-polar material used in aviation wave-transparent structural components. Automatic characterization of delamination defects in QFRP is critical to aviation structural component safety. Terahertz time-domain spectroscopy (THz-TDS) is one of the new non-destructive testing (NDT) methods with highly accurate characterization of internal defects in non-polar material. Hence, attempts to extract features of THz time-domain signals for automatic characterization have been made by using deep learning algorithms. In this work, a Transformer-based neural network to classify the THz time-domain signals collected from a QFRP curved structure for automatic characterization of pre-embedded delamination defects has been reported. A THz-TDS system combined with a collaborative robot for collecting the THz signals from QFRP curved structure has been built. An automatic characterization method framework is developed. Results show that the precision rates of Transformer-based neural network for 1st delamination to 5th delamination are 1.0, 1.0, 1.0, 0.985, 1.0, and F1 score of it is 0.982. During the process of testing, delamination defects inside the QFRP curved structure were visualized using pixels with different colors. Results indicate that the Transformer-based neural network can characterize all pre-embedded delamination defects while minimizing false identification of non-defective areas, performing outstanding generalization.

The fusion of lock-in phase images for the damage investigation in composites materials

Lock-in thermography (LIT) is a type of active thermography capable of detecting and evaluating the subsurface defects in composite materials. The phase or amplitude difference between the defect and sound regions can quantitatively determine the size and depth of defects. One limitation of LIT is that the optimal identification of defects located at specific depths is dispersed within phase images acquired at varying excitation frequencies. If the depth of the defects within the specimen is unknown, it is difficult to determine the excitation frequencies to achieve optimal contrast for all defects and display them in a single image. To address this challenge, a multi-frequency fused method based on lock-in thermography is proposed to improve the quality of defect detection. Initially, the optimal thermal wave excitation frequencies and the number of detection times are determined based on the theoretical solution. Subsequently, phase images at various excitation frequencies are extracted and enhanced using a specified scheme. Finally, we develop an unsupervised encoder-decoder network that combines dense connections and residual modules to fuse these phase images into a single image containing defects at various depths. An experiment is conducted to detect carbon fiber reinforced polymer (CFRP) laminate containing defects with different depths and sizes. The results demonstrate that the proposed method can broaden the detection range of defect depths and improve the quality of the inspected images, providing superior performance compared to traditional sequential image processing methods.

Inducing a tunable skyrmion-antiskyrmion system through ion beam modification of FeGe films

Skyrmions and antiskyrmions are nanoscale swirling textures of magnetic moments formed by chiral interactions between atomic spins in magnetic noncentrosymmetric materials and multilayer films with broken inversion symmetry. These quasiparticles are of interest for use as information carriers in next-generation, low-energy spintronic applications. To develop skyrmion-based memory and logic, we must understand skyrmion-defect interactions with two main goals—determining how skyrmions navigate intrinsic material defects and determining how to engineer disorder for optimal device operation. Here, we introduce a tunable means of creating a skyrmion-antiskyrmion system by engineering the disorder landscape in FeGe using ion irradiation. Specifically, we irradiate epitaxial B20-phase FeGe films with 2.8 MeV Au4+ ions at varying fluences, inducing amorphous regions within the crystalline matrix. Using low-temperature electrical transport and magnetization measurements, we observe a strong topological Hall effect with a double-peak feature that serves as a signature of skyrmions and antiskyrmions. These results are a step towards the development of information storage devices that use skyrmions and antiskyrmions as storage bits, and our system may serve as a testbed for theoretically predicted phenomena in skyrmion-antiskyrmion crystals.

Enhanced Ionic Power Generation via Light-Driven Active Ion Transport Across 2D Semiconductor Heterostructures.

2D semiconductor heterostructures exhibit broad application prospects. However, regular nanochannels of heterostructures rarely caught the researcher's attention. Herein, a metal-organic framework (i.e., Cu3(HHTP)2) and transition metal dichalcogenides (i.e., MoS2)-based multilayer van der Waals heterostructure (i.e., Cu3(HHTP)2/MoS2) realized band alignment-dominated light-driven ion transport and further light-enhanced ionic energy generation. High-density channels of the heterostructure provide high-speed pathways for ion transmembrane transport. Upon light illumination, a net ionic flow occurs at a symmetric concentration, suggesting a directional cationic transport from Cu3(HHTP)2 to MoS2. This is because Cu3(HHTP)2/MoS2 heterostructures containing type-II band alignment can generate photovoltaic motive force through light-induced efficient charge separation to drive ion transport. After introducing into the ionic power generation system, the maximum power density under illumination can achieve notable improvement under different concentration differences. In addition to the photovoltaic motive force, type-II band alignment and material defect capture-induced surface charge increase also raise ion selectivity and flux, greatly facilitating ionic energy generation. This work demonstrates that 2D semiconductor heterostructures with rational band alignment can not only be a potential platform for optimizing light-enhanced ionic energy harvesting but also provide a new thought for biomimetic iontronic devices.

Study on the preparation and properties of hydrogel electrolytes

Abstract Hydrogels are water-rich network polymers. The hydrophilic groups on the polymer molecular chains ensure their swelling property and high water content, and the cross-linked hydrogel network and the intermolecular interactions between the polymer molecular chains generate cohesive forces to prevent further penetration of water molecules. The porous structure of the gel enables water molecules to freely traverse the polymer network and the high-frequency flow of molecules in water offers a viable method for the preparation of hydrogel electrolytes. As a result, hydrogel electrolytes are now an important conductive material to compensate for the defects of conventional electronic materials, such as hardness and roughness, and lack of environmental friendliness. This paper starts with the method of hydrogel electrolyte preparation. Good stretchability, conductivity, biocompatibility, and self-healing properties are demonstrated by introducing different materials such as conductive nanomaterials. The types of synthetic conductive hydrogel matrices are extended according to the type of composite materials, making the hydrogel electrolytes usable in many fields like sensing, electrochemical energy storage, biomedicine, environmental detection, flexible wearable fields, and other applications.

Enhancing defect detection in solid materials using low-duty cycle square wave lock-in thermography: a time-efficient and quantitative approach

Lock-in thermography has been used to detect material defects but has faced challenges in quantitatively identifying defects. Traditional methods with a sine wave or symmetrical square wave heat source require time-consuming frequency adjustments with multiple experiments. This study introduces a novel technique using a heat source of a low-duty cycle square wave in lock-in thermography. This harmonic-rich heat source provides information on the blind frequency and the depth of defects, significantly reducing testing time. This method was validated by finite element simulations, which generated phase maps and phase difference-frequency curves at multiple frequencies that located defects. The study explored the correlation between thermal diffusion length at the blind frequency and defect depth and the impact of transverse thermal diffusion on depth measurement. The findings indicate that phase maps at the optimal frequency are most suitable for measuring defect edges. This approach offers a promising, time-efficient, and quantitative solution for defect detection.

Topological disclination mode in photonic Chern insulators

Topological defects in topological materials offer novel routes for creating topological modes and probing bulk topology. Disclination, a class of topological defects, has been recently shown to host fractional charges in topological crystalline insulators with well-defined Wannier centers. Here, we study the effects of disclinations in gyromagnetic photonic crystals with non-zero Chern numbers that prohibit the Wannier center picture. We find the emergence of topological disclination modes carrying orbital angular momentum from the interplay between the Chern-type topology and the effective flux induced by the disclination. When the Chern number changes its sign, the chirality of the disclination mode also flips, revealing the bulk-disclination correspondence. Furthermore, we perform numerical experiments to probe the disclination mode. Our results expand the study of disclination physics in photonic crystals to time-reversal-broken systems.

Regulation of oxygen defects in AlGaN-based epilayers grown on high temperature annealed AlN template

The regulation of oxygen (O) point defects in AlGaN-based epilayers grown on high-temperature annealed AlN (HTA-AlN) template by metal–organic chemical vapor deposition (MOCVD) is systematically investigated in this work. The concentration of O impurity in AlN epilayers is restricted to 1 × 1017 cm−3, but decreases by 59 % and 27 % when the AlN layer is replaced by the Al0.5Ga0.5N interlayer (IL) and AlN/Al0.5Ga0.5N superlattice (SL), respectively. By analyzing the growth conditions, the O impurity can be inhibited by raising V/III ratio or decreasing Al component, which increases the formation energy of O point defects according to first-principles calculation. This work provides accurate guidance for regulating O point defects in AlGaN-based materials.

Slow-Release Effect Assisted Crystallization for Sequential Deposition Realizes Efficient Inverted Perovskite Solar Cells.

The two-step sequential deposition strategy has been widely recognized in promoting the research and application of perovskite solar cells, but the rapid reaction of organic salts with lead iodide inevitably affects the growth of perovskite crystals, accompanied by the generation of more defects. In this study, the regulation of crystal growth was achieved in a two-step deposition method by mixing 1-naphthylmethylammonium bromide (NMABr) with organic salts. The results show that the addition of NMABr effectively delays the aggregation and crystallization behavior of organic salts; thereby, the growth of the optimal crystal (001) orientation of perovskite is promoted. Based on this phenomenon of delaying the crystallization process of perovskite, the "slow-release effect assisted crystallization" is defined. Moreover, the incorporation of the Br element expands the band gap of perovskite and mitigates material defects as nonradiative recombination centers. Consequently, the power conversion efficiency (PCE) of the enhanced perovskite solar cells (PSCs) reaches 20.20%. It is noteworthy that the hydrophobic nature of the naphthalene moiety in NMABr can enhance the humidity resistance of PSCs, and the perovskite phase does not decompose for more than 3000 h (30-40% RH), enabling it to retain 90% of its initial efficiency even after exposure to a nitrogen environment for 1200 h.

Defect Engineering in Transition Metal Dichalcogenide-Based Gas Sensors

Since the discovery of innovative two-dimensional (2D) materials, significant efforts have been dedicated to exploring their intriguing properties and emerging applications. Among all candidates, transition metal dichalcogenides (TMDs) have proven to be exceptional for gas sensing, while defects engineering has been introduced to modify the pristine TMDs for better gas sensing performances. In this review, we systematically summarize types of defects, advanced characterization techniques, and state-of-the-art controllable synthetic methods. Various types of defects in TMDs can induce diverse changes in chemical and electron structures, which are closely correlated with gas sensing ability. Therefore, connections between defects and gas sensing mechanisms and performances have been addressed based on both defect categories and electron affinity of gases. This review will be a guide for researchers in defective materials and open up the field of precisely synthesis chemistry and deepen the understanding of the underlying effects of defects in other 2D materials.

Mg-Defect Compensation to Realize High Performance at Room Temperature in Mg3Bi2-Based Thermoelectric Single Crystals.

Mg3Bi2-based materials are a very promising substitute for current commercial Bi2Te3 thermoelectric alloys. The successful growth of Mg3Bi2-based single crystals with high room-temperature performance is especially significant for practical applications. Previous studies indicated that the effective suppression of Mg defects in Mg3Bi2-based materials was crucial for high performance, which was usually realized by applying excessive Mg during syntheses. However, utilization of excessive Mg generates Mg-rich phases between the crystalline boundaries and is unfavorable for the long-term stability of the materials. Here, bulk single crystals with a low-content Mg component such as Mg3.1Bi1.49Sb0.5Te0.01 were successfully grown. For compensating Mg defects, Li was chosen as the additional electron dopant. The results indicate that Li is a very effective electron compensator when low-concentration doping is applied. For high-concentration doping, Mg atoms in the lattice are substituted by Li, leading to decreased electron concentration again. This strategy is very significant for improving the room-temperature performance of Mg3Bi2-based materials. As a result, a record-high figure of merit of 1.05 at 300 K is achieved for Mg3+xLi0.003Bi1.49Sb0.5Te0.01 single crystals.

Defect Engineering and Emission Tuning of Wide-Bandgap MAPbCl3 Perovskite.

Lead-chloride perovskites are promising candidates for optoelectronic applications, such as visible-blind UV photodetection. It remains unclear how the deep defects in this wide-bandgap material impact the carrier recombination dynamics. In this work, we study the defect properties of MAPbCl3 (MA = CH3NH3) based on photoluminescence (PL) measurements. Our investigations show that apart from the intrinsic emission, four sub-bandgap emissions emerge, which are very likely to originate from the radiative recombination of excitons bound to several intrinsic vacancy and interstitial defects. The intensity of various emission features can be tuned by adjusting the type and ratio of precursors used during synthesis. Our study not only provides important insights into the defect property and carrier recombination mechanism in this class of material but also demonstrates efficient strategies for defect passivation and engineering, paving the way for further development of lead-chloride perovskite-based optoelectronic devices.

Detection method for structural defects of U-shaped hanging ring for power fittings based on magnetic leakage principle

The U-shaped hanging ring of electric power fittings is usually installed outdoors and operates in harsh environments. Under the combined effect of the weight of the conductor and wind load, the bending part at the bottom of the U-shaped hanging ring often experiences wear and cracks due to friction contact, which can easily lead to accidents such as the detachment of transmission lines. Traditional methods for detecting structural defects in ferromagnetic materials, such as ultrasonic testing, eddy current testing, and manual testing, are affected by environmental factors, have a shallow measurement depth, and are difficult to quantify. In order to solve the above problems, this paper proposes a measurement method for detecting structural defects in the U-shaped hanging ring of electric power fittings based on the principle of magnetic leakage. The magnetic leakage signal characteristics of U-shaped hanging ring defects under different excitation structural parameters and different defect types are analyzed. The method of arranging magnetic leakage signal measurement points is studied. The detection of defect parameters is achieved based on the characteristic quantity of the magnetic leakage signal under different defect conditions. Finally, the method is analyzed and verified through examples. The results show that this method can achieve quantitative detection of defect parameters in the U-shaped hanging ring under uniform structural defect and crack structural defect, and has the advantages of high measurement accuracy and small error. The research results of this paper can provide a scientific theoretical basis for the inspection and replacement of transmission line fittings in engineering, which is of great engineering significance for ensuring the safe and stable operation of the power grid.

Perspective on electrically active defects in β-Ga2O3 from deep-level transient spectroscopy and first-principles calculations

The ultra-wide bandgap of gallium oxide provides a rich plethora of electrically active defects. Understanding and controlling such defects is of crucial importance in mature device processing. Deep-level transient spectroscopy is one of the most sensitive techniques for measuring electrically active defects in semiconductors and, hence, a key technique for progress toward gallium oxide-based components, including Schottky barrier diodes and field-effect transistors. However, deep-level transient spectroscopy does not provide chemical or configurational information about the defect signature and must, therefore, be combined with other experimental techniques or theoretical modeling to gain a deeper understanding of the defect physics. Here, we discuss the current status regarding the identification of electrically active defects in beta-phase gallium oxide, as observed by deep-level transient spectroscopy and supported by first-principles defect calculations based on the density functional theory. We also discuss the coordinated use of the experiment and theory as a powerful approach for studying electrically active defects and highlight some of the interesting but challenging issues related to the characterization and control of defects in this fascinating material.

ZIF-8 Vibrational Spectra: Peak Assignments and Defect Signals.

Zeolitic imidazolate framework (ZIF-8) is a promising material for gas separation applications. It also serves as a prototype for numerous ZIFs, including amorphous ones, with a broader range of possible applications, including sensors, catalysis, and lithography. It consists of zinc coordinated with 2-methylimidazolate (2mIm) and has been synthesized with methods ranging from liquid-phase to solvent-free synthesis, which aim to control its crystal size and shape, film thickness and microstructure, and incorporation into nanocomposites. Depending on the synthesis method and postsynthesis treatments, ZIF-8 materials may deviate from the nominal defect-free ZIF-8 crystal structure due to defects like missing 2mIm, missing zinc, and physically adsorbed 2mIm trapped in the ZIF-8 pores, which may alter its performance and stability. Infrared (IR) spectroscopy has been used to assess the presence of defects in ZIF-8 and related materials. However, conflicting interpretations by various authors persist in the literature. Here, we systematically investigate ZIF-8 vibrational spectra by combining experimental IR spectroscopy and first-principles molecular dynamics simulations, focusing on assigning peaks and elucidating the spectroscopic signals of putative defects present in the ZIF-8 material. We attempt to resolve conflicting assignments from the literature and to provide a comprehensive understanding of the vibrational spectra of ZIF-8 and its defect-induced variations, aiming toward more precise quality control and design of ZIF-8-based materials for emerging applications.

Electronic Properties of W’ Twin Walls in Ferroelastic BiVO4

AbstractTopological defects in ferroic materials can exhibit intrinsic properties that differ from the bulk. Here， structural and electronic variations of non‐prominent (W’) ferroelastic twin domain walls are investigated in BiVO4, a widely investigated photocatalytic material. Using aberration‐corrected scanning transmission electron microscopy (STEM), a kink configuration of the sharp ferroelastic twin wall with an altered electronic structure is revealed. Nanoscale conductivity measurements by conductive atomic force microscopy (c‐AFM) show higher conductivity at twin walls compared to non‐conductive bulk domains. Electronic structure investigation by electron energy loss spectroscopy (EELS) shows a higher density of oxygen vacancies and possible polaron accumulation at the wall. These findings reveal the electronic properties of BiVO4 domain walls, which are interesting for nanoscale‐engineered catalytic concepts of BiVO4 and materials design for photochemistry‐relevant applications.

Influence of Nb substrate morphology and atomic structure on Sn nucleation and early Nb3Sn growth

The enhanced accelerating performance of Nb3Sn-coated Nb superconducting radio frequency (SRF) cavities is severely limited by quenching sites at material defects formed during the Nb3Sn film growth procedure. In this work, we aimed to understand the complex surface-mediated interactions that drive initial Nb3Sn formation during the Sn vapor deposition procedure used to fabricate Nb3Sn coated SRF cavities. Nb substrates were modified, coated with Sn, and then characterized using an ultra-high vacuum (UHV) chamber equipped with metal deposition and in situ surface analysis capabilities. The atomic structure of the Nb oxide surface was modified to assess how the Nb surface defect density and crystallographic orientation impact the size of nucleated Sn islands and relative Nb3Sn growth rates. Formed Nb3Sn/Nb surfaces were visualized using ex situ scanning electron microscopy (SEM) and post-deposition annealing revealed Sn desorption and Nb3Sn degradation pathways. Finally, we showed that the Sn deposition conditions can be modified to overcome the growth barriers that are imposed by the Nb morphology. This study provides a unique bridge between fundamental growth studies in pristine conditions with observed phenomena of Nb3Sn grown on realistic cavity surfaces.

Life on the line - Incidence and management of central venous catheter complications in intestinal failure

Background & AimsLoss of venous access is threatening for patients with intestinal failure (IF) under long-term parenteral nutrition (PN). We aimed to identify the incidence of central venous catheter (CVC) complications, compare different devices, and analyze interventional recanalizing procedures to restore the patency of occluded CVCs. MethodsFor this retrospective cohort study, patient data from a prospective IF database spanning 16 years was analyzed at a tertiary referral center. Catheter dwell times (CDT) were distinguished by Kaplan-Meier survival analysis and subgroup analyses were performed for different CVC types (tunneled/ port catheters). Specific complications (occlusion, catheter-related infection (CRI), displacement, and material defect) were analyzed. Explantation rates and CDT were compared. ResultsOverall, 193 CVCs in 77 patients with IF under PN could be enrolled (62.524 “CVC-days”). Broviac type “B” was found to be significantly superior to type “A” regarding occlusion, CRI, and material defects (log-rank test: p=0.05; p=0.026; p=0.005 respectively). Port catheters were displaying the highest incidence of CRI (2.13 events/1000 catheter days). Interventional catheter recanalization was performed 91 times and significantly increased the CDT from a median of 131 days (IQR: 62; 258) to 388.5 days (IQR: 262; 731) (Mann-Whitney-U-test: p= <0.001) without increasing complications. ConclusionsDifferent complication rates and CDT were seen depending on CVC type. Tunneled catheters were significantly superior concerning CRI. Interventional catheter recanalization is a viable alternative to fibrinolytics to restore CVC patency, but long-term patency data is scarce.

Cyclic R‐Curve Measurements for Structural Metallic Alloys

Fractures nucleated from defects and subjected to cyclic loading can experience propagation for a range of stress intensity factor ΔK well below the so‐called long crack threshold. This phenomenon is attributed to the development of crack closure mechanisms which may differ from those observed in laboratory tests conducted in accordance with current standards. Cracks originating from material defects require a specific degree of extension to develop the plastic wake, thus achieving a stabilized condition called the long crack threshold. However, in certain materials, this stabilization length can extend up to several millimeters, effectively encompassing a significant portion of the component's fatigue life. Therefore, understanding and quantifying the development of ΔKth with crack extension is important for implementing a reliable assessment procedure based on the fracture mechanics theory. Herein, R‐curve measurements are presented for five distinct structural metallic alloys widely used in various industrial applications. Additionally, the impact of load ratio is investigated, providing a comprehensive analysis of fatigue crack resistance in terms of the R‐curve concept. This study underscores the necessity of ruling new experimental techniques to measure and implement the long crack threshold, thereby ensuring the development of a reliable and robust framework for fatigue assessment.

A Novel 3D High Resolution Imaging Method Using Correlative X-Ray and Electron Microscopy to Study Neodymium-Doped Yttrium Aluminum Garnet Laser-Induced Defects in Intraocular Lenses.

Cataract extraction is the most frequently performed ophthalmological procedure worldwide. Posterior capsule opacification remains the most common consequence after cataract surgery and can lead to deterioration of the visual performance with cloudy, blurred vision and halo, glare effects. Neodymium-doped yttrium aluminum garnet (Nd:YAG) laser capsulotomy is the gold standard treatment and a very effective, safe and fast procedure in removing the cloudy posterior capsule. Damaging the intraocular lens (IOL) during the treatment may occur due to wrong focus of the laser beam. These YAG-pits may lead to a permanent impairment of the visual quality. In an experimental study, we intentionally induced YAG pits in hydrophilic and hydrophobic acrylic IOLs using a photodisruption laser with 2.6 mJ. This experimental study established a novel 3D imaging method using correlative X-ray and scanning electron microscopy (SEM) to characterize these damages. By integrating the information obtained from both X-ray microscopy and SEM, a comprehensive picture of the materials structure and performance could be established. It could be revealed that although the exact same energies were used to all samples, the observed defects in the tested lenses showed severe differences in shape and depth. While YAG pits in hydrophilic samples range from 100 to 180 µm depth with a round shape tip, very sharp tipped defects up to 250 µm in depth were found in hydrophobic samples. In all samples, particles/fragments of the IOL material were found on the surface that were blasted out as a result of the laser shelling. Defects in hydrophilic and hydrophobic acrylic materials differ. Material particles can detach from the IOL and were found on the surface of the samples. The results of the laboratory study illustrate the importance of a precise and careful approach to Nd:YAG capsulotomy in order to avoid permanent damage to the IOL. The use of an appropriate contact glass and posterior offset setting to increase safety should be carried out routinely.