Flat Rare Earth Element Patterns Research Articles

Mineral Geochemistry of Basaltic Rocks from IODP Expeditions 334 and 344: Implications for Magmatic Processes of Cocos Ridge Segment Being Subducted Beneath the Middle America Trench

The Cocos Ridge, which is subducted beneath the Central American Volcanic Arc, has a complex tectonic evolution history due to plume-ridge interaction between the Galápagos plume and the Cocos—Nazca spreading center. This study presents major and trace element analyses of plagioclase and clinopyroxenes hosted by Cocos Ridge basaltic rocks that were drilled in three holes (U1381A, U1381C and U1414A) of Sites U1381 and U1414 on the Cocos Ridge close to the Middle America Trench during the Integrated Ocean Drilling Program (IODP) Expeditions 334 and 344. The results show that (1) plagioclases are mainly bytownite and labradorite with subordinate andesine, which are enriched in light rare earth elements (LREE) and some large-ion lithophile elements (LILE) and exhibit marked positive Eu anomalies; and (2) that clinopyroxenes are augites, which are depleted in highly incompatible elements such as LREE and LILE, have nearly flat heavy rare earth elements patterns (HREE) and lack Eu anomalies in chondrite-normalized rare earth element (REE) diagrams. During the ascent to the surface, the primary magmas experienced fractional crystallization of plagioclase, clinopyroxene, Ti-Fe oxides and possibly olivine (complete replacement of olivine by secondary minerals). The crystallization temperatures of plagioclase phenocrysts and microlites are 1050 to 1269 °C, and 866 to 1038 °C, respectively, and the pressures of plagioclase phenocrysts are 0.3–0.7 GPa. The crystallization temperatures of clinopyroxene phenocrysts/micro-phenocrysts is 1174–1268 °C, similar to those of plagioclase phenocrysts, suggesting some of clinopyroxene and plagioclase phenocrysts cotectic crystallized during early stage of magmatic evolution. In addition, the equilibrium pressures of clinopyroxene phenocrysts/micro phenocrysts are 0.02–0.97 GPa, implying that the clinopyroxene started to crystallize within the mantle, and magma evolution has undergone an early crystallization stage with clinopyroxene and no plagioclase.

Forced subduction initiation within the Neotethys: An example from the mid-Cretaceous Wuntho-Popa arc in Myanmar

Abstract Despite decades of research, the mechanisms and processes of subduction initiation remain obscure, including the tectonic settings where subduction initiation begins and how magmatism responds. The Cretaceous Mawgyi Volcanics represent the earliest volcanic succession in the Wuntho-Popa arc of western Myanmar. This volcanic unit consists of an exceptionally diverse range of contemporaneously magmatic compositions which are spatially juxtaposed. Our new geochemical data show that the Mawgyi Volcanics comprise massive mid-oceanic ridge basalt (MORB)-like lavas and dikes, and subordinate island arc tholeiite and calc-alkaline lavas. The Mawgyi MORB-like rocks exhibit flat rare earth elements (REEs) patterns and are depleted in REEs, high field strength elements (except for Th) and TiO2 concentrations relative to those of MORBs, resembling the Izu-Bonin-Mariana protoarc basalts. Our geochronological results indicate that the Mawgyi Volcanics formed between 105 and 93 Ma, coincident with formation of many Neotethyan supra-subduction zone ophiolites and intraoceanic arcs along orogenic strike in the eastern Mediterranean, Middle East, Pakistan, and Southeast Asia. Combined with its near-equatorial paleo-latitudes constrained by previous paleomagnetic data, the Wuntho-Popa arc is interpreted as a segment of the north-dipping trans-Neotethyan subduction system during the mid-Cretaceous. Importantly, our restoration with available data provides new evidence supporting the hypothesis of a mid-Cretaceous initiation of this >8000-km-long subduction system formed by inversion of the ∼E-W–trending Neotethyan oceanic spreading ridges, and that this was contemporaneous with the final breakup of Gondwana and an abrupt global plate reorganization.

Origins of the meta‐mafic rocks in the southern Dunhuang Block (NW China): Implication for tectonic framework of the southernmost Central Asian Orogenic Belt

The Central Asian Orogenic Belt (CAOB) is one of the largest accretionary orogenic collages in the world with prominent juvenile crust addition, where the southernmost margin of the CAOB located is one hot topic in the international studies. The Dunhuang Block located to the south of the Beishan Orogen is a key position for outlining the tectonic framework of the south margin of the CAOB. However, at present, the tectonic attribution of the Dunhuang Block is still controversial. In this paper, we focus on the origins and protoliths of the meta‐mafic rocks from the Hongliuxia complex in the southern Dunhuang Block for determining the tectonic attribution of the Dunhuang Block. In the field, the meta‐mafic rocks are mainly exposed as tectonic blocks within the metasedimentary rocks displaying the “block‐in‐matrix” fabrics or as tectonic slices juxtaposed by faults. Geochemically, the meta‐mafic rocks could be divided into three groups based on the rare earth elements (REE) and trace elements: the group 1 samples are depleted in the LREE relative to HREE and show flat HREE patterns, similar to the mid‐oceanic ridge basalt; the group 2 samples show flat REE patterns without obvious differentiation between the LREE and HREE, like the oceanic plateau basalt; the group 3 samples are enriched in LREE relative to LREE, and have negative Nb, Ta, and Ti anomalies, similar to the island arc basalt. Conclusively, the protoliths of the meta‐mafic rocks dominantly belong to the oceanic plate components. They were metamorphosed during Early Silurian to Middle Devonian in different depths of the subduction zone documented in previous studies. So, we suggest the Hongliuxia complex is an exhumed Palaeozoic subduction–accretion complex (SAC) formed during the oceanic plate subduction. This result confirms the Palaeozoic subduction event occurred in the Dunhuang region and indicates that the Dunhuang Block is a Palaeozoic Orogen rather than a part of Precambrian continent block. Considering the regional geology context, we speculate the Dunhuang Orogen belongs to the southernmost margin of the CAOB.

Evolution of a Neoproterozoic island arc in the northern Arabian-Nubian Shield: Volcanic rocks and their plutonic equivalents in the Hamash area, south Eastern Desert, Egypt

A suite of Neoproterozoic island arc volcanic and plutonic rocks are exposed in the Hamash area of the south Eastern Desert of Egypt. The volcanic assemblage includes metabasalt, a group of andesites with subordinate basalts (the Hamash Volcanics), and felsic volcanic porphyry. The plutonic rocks include a diorite-tonalite series, fine-grained granite, and granite porphyry. The volcanic rocks are generally sub-alkaline and feature a strong depletion in Nb and Ta. The metabasalt belongs to the low-K tholeiitic series and has nearly flat rare-earth element patterns. Its compositional characteristics indicate generation by partial melting of a depleted mantle source in an immature oceanic island arc setting. On the other hand, the basalt, andesite and felsic volcanic porphyry have low- to medium-K calc-alkaline affinity and are enriched in light rare-earth elements and large ion lithophile elements. Their parental magmas likely formed by fluid-assisted partial melting of a less depleted mantle source with major subduction input, in a mature island arc setting. The andesite cannot be derived from the basalt by fractional crystallization; their parental magmas likely represent different degrees of melting underneath crust of different thickness. Estimation of the arc crustal thickness during formation of these rocks yields ~ 5 km for the metabasalt, ~20 km for the Hamash basalt, and ~ 30 km for the Hamash andesite, consistent with a progression in maturity of the arc over time. The geochemical characteristics of the diorite-tonalite series suggest that it represents an intrusive equivalent of the medium-K calc-alkaline Hamash andesite, and the fine-grained granite represents residual liquid after continued fractionation of the parental magma of the andesite and diorite-tonalite. We present thermodynamic fractionation models that constrain the conditions of fractionation for the andesite, diorite-tonalite, and fine-grained granite suite. The compositional similarity of the granite and rhyolite porphyries, especially their SiO2 and Al2O3 contents and Y/Nb ratios, indicate generation by partial melting of similar crustal sources, although greater assimilation of upper crust is evident in elevated Rb/Sr ratios and K2O and light rare-earth element concentrations in the granite porphyry. We conclude that the magmatic rocks of the Hamash area represent an arc crustal section that records the evolution of a Neoproterozoic oceanic island arc. The arc was later caught up in the assembly of the northern Arabian-Nubian Shield.

Rare Earth Element Distributions in Continental Shelf Sediment, Northern South China Sea

A total of 388 surface sediment samples taken from the northern South China Sea (SCS) continental shelf were analyzed to characterize the signature of their rare earth elements (REEs). The average REEs concentration was 192.94 μg/g, with a maximum of 349.07 μg/g, and a minimum of 32.97 μg/g. The chondrite-normalized REEs pattern exhibits a remarkably light REEs accumulation, a relatively flat heavy REEs pattern, and a negative Eu anomaly. We subdivided the study area into three zones using the characteristics of REEs and statistical characteristics. Zone I: continental shelf off western Guangdong Province. Here, the sediment provenance is mainly river-derived from the Pearl River, Taiwanese rivers, and those in the adjacent area. Zone II: Qiongzhou Strait and Leizhou Peninsula. Here, the sediment provenance consists of the Qiongzhou Strait and the Hainan Island. Zone III: Hainan Island and SCS slope sediments are dominated. The REEs compositions are mainly controlled by source rock properties, hydrodynamic conditions, and an intensity of chemical weathering. We reconstructed the sediment dispersal and transport route using the REEs compositions, grain size, and other geochemical characteristics throughout the study area.

Origin and Tectonic Implications of Post-Orogenic Lamprophyres in the Sulu Belt of China

Lamprophyre dykes that crosscut different types of ultrahigh pressure (UHP) metamorphic rocks are widely distributed in the Triassic Sulu UHP orogenic belt. Although abundant studies have been performed on these dykes, their origin and petrogenesis remain topics of controversy. This study presents the results of a detailed field-based study of petrology, whole-rock geochemistry and zircon U-Pb and Lu-Hf isotopes on lamprophyre dykes exposed in the central Sulu UHP zone, aiming at shedding lights on their petrogenesis and providing clues on the geological evolution of eastern continental China during the Cretaceous. The lamprophyres are typically porphyritic, with phenocrysts dominantly composed of amphibole and clinopyroxene set in a lamprophyric matrix. The dykes have moderate SiO2 (47.70 wt.%–60.44 wt.%), variably high MgO (2.58 wt.%–8.28 wt.%) and Fe2O3T (4.88 wt.%–9.26 wt.%) contents with high Mg# of 49–66. Geochemically, they have enriched light rare earth element (REE) and flat heavy REE patterns ((La/Gd)N=5.14–10.56; (Dy/Yb)N=1.43–1.54) with negligible Eu anomalies (Eu/Eu*=0.83–1.10), and they show enrichment in large ion lithophile elements (e.g., Ba and K) but depletion in high-field strength elements (e.g., Nb, Ti and P). In-situ zircon U-Pb geochronology reveals that the lamprophyres have concordant ages of 120–115 Ma, demonstrating that the dykes emplaced in the Early Cretaceous. These zircons have eHf(t) values ranging from −26.0 to −11.0. Inherited zircons that occur in the dykes are dated to be Neoproterozoic, in line with the protolith ages of their host (i.e., the UHP rocks). An integration of these data allows us to propose that the lamprophyres were generated during the Cretaceous, by melting of subcontinental lithospheric mantle-derived metasomatite with enriched chemical compositions underneath the North China Craton. The metasomatite was formed mainly by peridotite-fluid/melt reactions, with the fluids/melts mainly liberated from subducted Yangtze continental crust during the Triassic. Regional extension, lithospheric thinning and mantle upwelling caused by rollback of the subducted paleo-Pacific plate is considered to account for the generation of the lamprophyres as well as the extensive arc-like magmatic rocks in eastern continental China during the Early Cretaceous.

Source of dolomitizing fluids and dolomitization model of the upper Permian Changxing and Lower Triassic Feixianguan formations, NE Sichuan Basin, China

Dolostone reservoirs have been found in the Changxing (P2c) and Feixianguan (T1f) formations in both the east and west platform edges of the Kaijiang-Liangping trough; they are the main natural gas exploration targets in the NE Sichuan Basin. In this study, the sources of the dolomitizing fluids were determined, and a dolomitization model was established based on petrography, rare earth elements (REEs), major and trace element data, and 87Sr/86Sr ratios. The dolostone and limestone samples with ΣREE values of >5 ppm exhibit relatively flat PAAS-normalized REE patterns; their Zr, Sc, and Th concentrations increase with increasing ΣREE; and their Rb/Sr ratios are generally greater than 0.01, suggesting that these samples were likely contaminated by terrigenous components. Therefore, only the REEs and 87Sr/86Sr ratios of samples with ΣREE values of <5 ppm were selected to constrain the dolomitizing fluids. The PAAS-normalized REE patterns of the P2c–T1f dolostones, which are characterized by LREE depletion, negative Ce anomalies (Ce/Ce* of 0.70–0.85), and relatively high Y/Ho ratios (49.0–152.4), are similar to those of the unaltered coeval limestones, suggesting that the dolomitizing fluid was sourced from fluids similar to coeval seawater. The Ce/Ce* values of the dolostones are lower than those of the unaltered limestone, suggesting that the source of the dolomitizing fluids had more oxidizing conditions and most probably contained evaporated seawater from an evaporite platform. The Eu/Eu* values of the P2c dolostone in the west platform (means of 4.95 and 2.76 for the YB and XLC gas fields, respectively) are notably higher than the Eu/Eu* values of the P2c and T1f dolostones in the east platform (mean 1.29 and 1.39 in the PG gas field, respectively), suggesting that the P2c dolostone in the west platform was formed under more reducing conditions and at a deeper burial depth. The 87Sr/86Sr ratios of the T1f and P2c dolostones in the east platform (such as in the Puguang gas field) are similar to those of the co-existing early T1f limestone, while the 87Sr/86Sr ratios of the P2c dolostone in the west platform (such as in the Yuanba gas field) are higher than those of the coexisting P2c limestone but are close to those of the late T1f dolostone in the east platform. This indicates that the dolomitizing fluids were mainly from the early T1f and late T1f evaporated seawater on the east and west platforms, respectively. Driven by the density difference between the evaporated seawater and normal seawater, the evaporated seawater flowed downward and laterally into the limestone in the high-energy reefs and shoals through the original pores and the early selective dissolution pore system and/or through synsedimentary fractures. The continual seepage of evaporated seawater and the relatively high temperatures (50–60 °C) resulted in the large-scale shallow burial dolomitization in the NE Sichuan Basin.

Evidence of melt– and fluid–rock interactions in the refractory forearc peridotites and associated mafic intrusives from the Tuting–Tidding ophiolites, eastern Himalaya, India: Petrogenetic and tectonic implications

We present a comprehensive geochemical data set of whole‐rock geochemistry and mineral phases from the mantle peridotites and mafic intrusives of the Tuting–Tidding Suture Zone (TTSZ) ophiolites, eastern Himalaya, north‐east India. Modal mineralogy, low Al2O3 and CaO, high Cr# of Cr‐spinels, and forsterite number (Fo90–92) in primary olivine indicate the highly refractory nature of the TTSZ peridotites. LREE‐enriched patterns, cumulative olivines in dunites, and Cr‐spinel and olivine compositions further suggest that the peridotites were subjected to high‐temperature melt–rock interaction from a percolating boninitic melt in the nascent forearc of an intra‐oceanic subduction zone. The associated mafic intrusives are tholeiitic in nature and their geochemical characteristics [∑REE = 23.34–59.12; nearly flat rare earth elements (REE) pattern (LaN/YbN = 1.49–2.58); negative anomalies of Nb and Ti] show mid‐oceanic ridge basalt affinity. Trace elemental modelling of the mafic intrusives along with their mineralogy and geochemistry suggests that they formed due to different degrees of partial melting with the involvement of a subduction component in the spreading regime of the forearc region. Based on the presence of hydrous minerals like Cr‐chlorite and tremolite in the peridotites and P–T modelling (525–575°C, 1.05–1.09 GPa) of the mafic intrusives, it is considered that TTSZ ophiolites underwent low‐temperature metamorphism by fluid–rock interaction either during the later phase of subduction (in a cool mature subduction zone) or during Himalayan Orogeny. We also infer that the TTSZ ophiolites resemble other Neo‐Tethyan ophiolites of the Indus‐Tsangpo Suture Zone in terms of their geochemical and petrogenetic aspects.

On the dolomite reservoirs formed by dissolution: Differential eogenetic versus hydrothermal in the lower Permian Sichuan Basin, southwestern China

Dolomite reservoirs formed by dissolution are significant for hydrocarbon exploration, but their origins are poorly understood because of their complexity. This study investigated the lower Permian Qixia Formation of the Sichuan Basin (northern Longmenshan Mountains), southwestern China, which has recently been the location of giant natural gas discoveries. Petrological and geochemical analyses were undertaken, including trace elements and C, O, and Sr isotopes. The results indicate that the reservoirs were formed by differential eogenetic karstification and hydrothermal dissolution of grain dolomites. Core and thin-section observations identified three types of dolomite based on grain size: fine- to medium-crystalline dolomite (Dol-1), medium- to coarse-crystalline dolomite (Dol-2), and coarse- to megacrystalline saddle dolomite (Dol-3). The Dol-2 types can be further divided into three subtypes according to the grain structure and degree of pore development: euhedral medium- to coarse-crystalline dolomite with pores (Dol-2a), porous subhedral–anhedral medium- to coarse-crystalline dolomite (Dol-2b), and tight subhedral–anhedral medium- to coarse-crystalline dolomite (Dol-2c). The Dol-1 types appear to have formed because of the release of and subsequent metasomatism by Mg2+ in trapped seawater along stylolites at shallow burial conditions (500–1000 m). The Dol-2a types resulted mainly from eogenetic karstification of original limestone and subsequent dolomitization by marine-related fluids. These dolomites are geochemically characterized by relatively flat rare-earth element patterns and relatively low Y/Ho values (mean e 37.1). The Dol-2b and Dol-3 types were formed mainly by hydrothermal fluids and have similar rare-earth element patterns with large positive Eu anomalies (mean e 5.7). The Dol-2c types experienced metasomatism by marine-related fluids mixed with minor hydrothermal fluids. All these formation mechanisms reflect the influence of multistage diagenetic and hydrothermal fluids. The Dol-2a types form the most favorable reservoirs in the study area, followed by the Dol-2b types. The distribution of the Dol-2a types was controlled by eogenetic karstification of grain shoals, whereas that of the Dol-2b types reflects the influence of tectonically derived hydrothermal fluid dissolution of grain shoals. As such, both primary sedimentary features and later differential dissolution (eogenetic and hydrothermal) contributed to reservoir development, which involved factors such as the sedimentary facies (grain shoal), sea-level fluctuations (eogenetic karst development), and faulting (hydrothermal dissolution). Therefore, the formation of dolomite and associated reservoirs is complex. The results of this study provide an improved understanding of the origins and complexity of dolomite reservoirs formed by dissolution, which is relevant to exploration for such reservoirs.

Geochemical, Sr–Nd–Pb and zircon U–Pb–Hf isotopic constraints on the Late Carboniferous back-arc basin basalts from the Chengjisihanshan Formation in West Junggar, NW China

AbstractWest Junggar in the southwestern Central Asian Orogenic Belt is a critical area for the study of the Junggar oceanic basin and may also reveal tectonic evolutionary events before the final closure of the Palaeo-Asian Ocean. The sedimentary formations and paragenetic associations of the Upper Carboniferous Chengjisihanshan Formation in southern West Junggar jointly reveal a back-arc basin setting with zircon U–Pb ages of 313–310 Ma for the basaltic rocks. Geochemically, the basaltic rocks are tholeiitic with low SiO2 (47.76–52.06 wt %) and K2O (0.05–0.74 wt %) but high MgO (6.55–7.68 wt %) contents and Mg no. (52.9–58.9) values. They display slightly flat rare earth element patterns with weak positive Eu anomalies, and show enrichments in large ion lithophile elements relative to high field strength elements with negative Nb and Ta anomalies, exhibiting both N-MORB-like and arc-like signatures, similar to the back-arc basin basalt from the Mariana Trough. The high positive zircon εHf(t) and bulk εNd(t) values as well as high initial Pb isotopes, together with relatively high Sm/Yb and slightly low Th/Ta ratios imply a depleted spinel lherzolitic mantle source metasomatized by slab-derived fluids. The field and geochemical data jointly suggest that the volcanic rocks within the Chengjisihanshan Formation were formed in an intra-oceanic back-arc basin above the northwestward subduction of the Junggar oceanic lithosphere in southern West Junggar. The confirmation of the Late Carboniferous back-arc basin basalts, together with other geological observations, indicate that an arc-basin evolutionary system still existed in southern West Junggar at c. 310 Ma, and the Junggar Ocean closed after Late Carboniferous time.

Across‐Arc Diversity in Rhyolites From an Intra‐oceanic Arc: Evidence From IODP Site U1437, Izu‐Bonin Rear Arc, and Surrounding Area

AbstractFelsic magmas from the Izu‐Bonin rear arc have compositions that resemble average continental crust in some respects. In order to understand their origin, we studied 1.1–4.4 Ma tephras in a rear‐arc drill core from International Ocean Discovery Program Expedition 350, Site U1437. They provide a well‐dated record of changing magmatic compositions during the early stages of the most recent episode of Izu‐Bonin arc rifting. Based on our comprehensive recontextualization of published analyses of &lt;7 Ma regional dredged rocks across the arc, basalts to rhyolites are shown to vary in coherent chronological and spatial trends and can be classified into three series: light rare earth element‐depleted volcanic front series; a rift‐related series with nearly flat rare earth element patterns; and light rare earth element‐enriched rear‐arc seamount chain‐type (RASC‐type) series, which are abundant in the studied Site U1437 tephra record. All three series erupted simultaneously between 4.4 and 1.1 Ma, including the RASC‐type rhyolites which erupted until 1.1 Ma in significant quantities. Remarkably, trace element and radiogenic isotope ratios are similar between rhyolites and basalts from the same region. This recontextualization of rhyolite affinity represents a significant departure from existing frameworks. Geochemical modeling shows that fractional crystallization can largely explain &lt;4.4 Ma RASC‐type rhyolites with some additional open system processing evident in rhyolites with &gt;73% SiO2. However, trace element and Hf isotope ratios preclude rear‐arc rhyolite derivation by partial melting of the Oligocene‐Eocene arc basement. Thus, we favor a model where fractional crystallization is more important than crustal melting in producing intra‐oceanic arc rhyolites in this region.

GEOCHEMICAL APPLICATION IN UNRAVELING PALEOWEATHERING, PROVENANCE AND ENVIRONMENTAL SETTING OF THE SHALE FROM CHIA GARA FORMATION, KURDISTAN REGION, IRAQ

The geochemical characteristics of the shale of the Chia Gara Formation (Middle Tithonian-Berriasian) from the Imbricated Zone (Barsarin section) and High Folded Zone (Banik section) Kurdistan Region, Iraq, was carried out to constrain their paleoweathering, provenance, and depositional environment. There are no clear differences in the major and trace elements of the Chia Gara Formation between the two studied sections. The chemical index of alteration (CIA) is significantly higher in the Barsarin than the Banik shales, suggesting more intense weathering of the Barsarin than the Banik shales. The samples of the Banik and some of Barsarin are clustered near the A-K line in A-CN-K plot suggests intense chemical weathering (high CIA) without any clear-cut evidence of K-metasomatism. The other samples of Barsarin have a weathering trend parallel to the A-CN line, indicating relatively steady state weathering conditions. The geochemical parameters of the shale (Al2O3/TiO2, Th/Sc, La/Th, La/Sc, La/Co, Th/Co, Cr/Th, (La/Lu)cn and Eu/Eu*cn), and the diagrams (Th/Sc-Zr/Sc and La/Th-Hf) indicate that they were derived from felsic (from the Rutba Uplift and/or Mosul High) and intermediate (from volcanic material during the spreading of Southern Neo-Tethys Ocean) components. The chondrite-normalized REE patterns are similar to those of Post Archean Australian Shale (PAAS), with the light rare earth element (REE) enrichment, a negative Eu anomaly, and almost flat heavy REE pattern. The geochemical parameters such as authigenic uranium, U/Th, V/Cr, Ni/Co, and V/Sc ratios, and Al2O3-V and Al2O3-P2O5 diagrams indicate that these shales were deposited under deep marine suboxic to anoxic environment and shale of Banik section was deposited slightly under deeper environment than shale of Barsarin section.

Mineralogy and geochemistry of alluvial sediments from the Kadey plain, eastern Cameroon: Implications for provenance, weathering, and tectonic setting

Mineralogical analyses by X-ray diffraction and geochemical analyses by X-ray fluorescence and inductively coupled plasma-mass spectrometry were performed on the Kadey Plain clastic sediments in order to determine their provenance and weathering. The Kadey Plain has four types of clastic sediments, shales, wackes, litharenites, and Fe-sands. The shales and wackes consist of kaolinite, quartz, muscovite, gibbsite, illite, anatase, and goethite. In the litharenites, minerals found are quartz, illite, kaolinite, gibbsite, muscovite, and goethite. Fe-sands consist of quartz, muscovite, and kaolinite, whereas gibbsite, illite, iron oxyhydroxides and anatase occur as traces. The U/Th (0.11–0.37) and V/Cr (0.99–1.73) ratios indicate an oxidising deposition environment. The behavior of trace elements is the same in these sediments, except for U content which is depleted in Fe-sands. Rare earth elements (REE) normalized with chondrite for the studied clastic sediments, demonstrate a slightly light REE enrichment (3.74 < (La/Sm)n < 5.80) and comparatively flat heavy REE patterns (1.12 < (Gd/Yb)n < 1.78) associated to negative Eu anomaly (0.51 < Eu/Eu* < 0.67). These materials disclose less fractionation of REE [7.10 ≤ (La/Yb)n ≤ 18.41]. These ratios are higher than that of Post-Archean Australian Average Shale [(La/Yb)n = 9.15], except for wackes. Al2O3/TiO2 vs. (SiO2)adj diagram, Eu/Eu*, La/Sc, Th/Sc, La/Co, Th/Co, and Th/Cr ratios suggest that the studied clastic sediments were derived from felsic sources. The REE patterns for sediments from the Kadey Plain disclosed closer resemblance to those of granites, quartzites, migmatites, and chlorite schists found relatively near to the study area. The tectonic discrimination diagrams indicate chiefly passive margin setting for these alluvial sediments.

Multistage W-mineralization and magmatic-hydrothermal fluid evolution: Microtextural and geochemical footprints in scheelite from the Weondong W-skarn deposit, South Korea

Weondong deposit is one of the W-skarn deposits in South Korea, and main ore mineral is scheelite (CaWO4). Scheelite occurs in both a massive skarn zone (MSZ; Type I) and a quartz porphyry fracture zone (QPFZ; Type II), forming solid solution with powellite (CaMoO4). We examined the relationship between the evolution of ore-forming fluids and formation of multistage scheelites based on microtextural and geochemical features. Type I scheelites can be divided into Type Ia and Type Ib. Type Ia scheelites are characterized by complex internal textures with oscillatory zoning. The texturally associated clinopyroxene (diopside), garnet (andradite), and magnetite strongly suggest an oxidized prograde skarn origin. They are also characterized by enriched light rare earth elements (LREEs) and a negative Eu anomaly. Type Ib scheelites are W-enriched (74–81 wt% of WO3) with no internal zoning. Relict grossular garnet, calcite, pyrrhotite, serpentine, and vesuvianite indicate its relatively reduced retrograde skarn origin. Their rare earth element (REE) pattern is flat with a negative Eu anomaly. Type II scheelites can further be divided into Types IIa and IIb based on textural and geochemical differences. The former largely exhibit patchy zoning with minor oscillatory zoning that normally occurs along microfractures in association with fluorite. Type IIa scheelites show REE fractionation between W- and Mo-enriched zones (i.e., those containing 60–71 wt% of WO3 and 15–25 wt% of MoO3, respectively). Tungsten enriched scheelites show middle rare earth element (MREE)-enriched patterns with a strong negative Eu anomaly; Mo-rich zones are MREE-depleted and show a weak negative Eu anomaly. Type IIb scheelites are W-rich and rarely have zoned texture, similar to Type Ib scheelites. Type IIb scheelites generally coexists with sulfide minerals, indicating a relatively high sulfur fugacity (fS2) retrograde conditions. The REE pattern is flat with a negative Eu anomaly. These results indicate that Type Ia and Type IIa scheelites were formed during prograde conditions at each stage, followed by Type Ib and Type IIb in retrograde conditions. Type Ia scheelites have LREE-enriched patterns, which mimic the REE profile of juvenile magmatic fluids under open systems. Type IIa scheelites have MREE-enriched fractionation patterns that likely reflect a highly evolved magmatic fluid origin in a closed system. The flat REE pattern in Type Ib and IIb scheelites is due to meteoric water in retrograde conditions. This causes changes in the trace element composition of scheelites that reflect differences in the fluid origin and stages of evolution. The geochemical characteristics of both scheelite types match well with their microtextural features and provide crucial evidence for understanding the multistage formation of the Weondong W-skarn.

Geochemistry of volcanic rocks from Oldoinyo Lengai, Tanzania: Implications for mantle source lithology

Oldoinyo Lengai is the only active carbonatite volcano within the East African Rift Valley in northern Tanzania. The volcano is dominated by peralkaline silicate rocks with natrocarbonatites. This study presents new mineralogical and geochemical data, including Sr–Nd–Pb–Hf–Mg isotopic compositions, for volcanic rocks at Oldoinyo Lengai and lavas from the nearby Gregory Rift Valley. The samples analyzed in this study include olivine melilitite, melanephelinite, wollastonite nephelinite, and phonolite. The olivine melilitites and melanephelinites have highly fractionated rare-earth-element (REE) patterns with (La/Yb)N values of 26.4–64.9, suggesting that they formed from magmas generated by low-degree (up to ∼7%) of partial melting within the garnet stability field. The wollastonite nephelinites have much higher (La/Sm)N values but lower (Sm/Yb)N values relative to typical oceanic island basalts (OIB), with flat heavy REE patterns [(La/Yb)N = ∼22]. The phonolites have elevated REE abundances but with patterns intermediate between the other two sample groups [(La/Yb)N = ∼41]. All samples have primitive-mantle-normalized incompatible element patterns that are characterized by negative K and Rb anomalies but no significant Eu anomalies. They also have elevated Yb contents relative to the compositions of modeled garnet peridotite-derived melts, suggesting that they were derived from a sublithospheric source containing enriched HIMU-like recycled oceanic crustal material. However, the wollastonite nephelinites have significantly positive Ba, U, Sr, and Pb anomalies similar to those found within the Oldoinyo Lengai natrocarbonatites. The wollastonite nephelinites might have been sourced from a region of sub-continental lithospheric mantle (SCLM) that was previously metasomatized by interaction with carbonatite melts. The phonolites in the study area have also weakly positive Pb and Sr anomalies indicative of some interaction with the SCLM. All samples have δ26Mg values (−0.39‰ ± 0.07‰) lighter than the composition of normal mantle material (−0.25‰ ± 0.04‰). In addition, a negative correlation between δ26Mg values and MgO concentrations suggests derivation from a source region containing recycled carbonate. The samples from the study area define a mixing array between HIMU- and EM1-type OIB in Sr–Nd and Pb–Pb isotopic correlation diagrams, and have pronounced Nd–Hf isotopic decoupling, plotting below the mantle regression line in Nd–Hf isotopic space. The negative deviation from the Nd–Hf isotopic mantle array and the presence of an EM1-type mantle component in the Sr–Nd isotopic compositions of the Oldoinyo Lengai volcanic rocks can be generated by recycling of E-MORB-type oceanic crustal material with an age of 1.5–1.0 Ga.

Infant intra-oceanic arc magmatism due to initial subduction induced by oceanic plateau accretion: A case study of the Bangong Meso-Tethys, central Tibet, western China

The Meso-Tethyan oceanic plateaus are becoming conspicuous as giant units on the oceanic floor and have played important roles in both continental marginal orogenesis and Tethys oceanic evolution. In this study, we present mineralogical, geochronological, geochemical and Sm–Nd isotopic data for basaltic lavas from the Namco ophiolite and a high-Mg pillow lava–dyke–gabbro association from the Pengco ophiolite in central Tibet. Zircon U–Pb and Ar–Ar dating reveals that the Namco lavas erupted at ∼181 Ma while the Pengco boninitic association formed at ∼164 Ma. The Namco lavas display nearly flat rare-earth element (REE) patterns with no Nb–Ta depletions as well as high εNd values, characteristic of oceanic plateau lava. In contrast, the Pengco high-Mg rocks exhibit low REE concentrations below the normal mid-ocean ridge basalt (N-MORB), ubiquitous Nb–Ta depletions and low εNd values, and the dykes and gabbros are characterized by U-shape REE patterns, indicating that they could have derived from a depleted mantle source that was contaminated by sedimentary flux and marking a mid-Jurassic initial intra-oceanic arc magmatism erupted on the Early Jurassic Meso-Tethyan oceanic plateau represented by the Namco ophiolite. Our Pengco boninitic rocks, along with the literature data, indicate a 167–160 Ma boninitic-like initial intra-oceanic arc within the Bangong Meso-Tethys, running from the Shiquanhe area to the Naqu area with a length of ∼1000 km, which was uniformly built on the Early Jurassic Meso-Tethyan oceanic plateau. Our literature investigation also indicates a ∼175 Ma accretionary orogeny with distinct signature of the oceanic plateau involvements along the southern Qiangtang continental margin, which is manifested by regional metamorphic, magmatic and depositional records. We thus suggest that the accretion of the Early Jurassic Meso-Tethyan oceanic plateau onto the southern Qiangtang continental margin resulted in the extensive orogeny along the continental margin, jammed the subduction zone at ∼175 Ma and induced intra-oceanic subduction initiation as well as the intra-oceanic infant arc magmatism in the Meso-Tethys at ∼164 Ma.

Factors controlling the crystal morphology and chemistry of garnet in skarn deposits: A case study from the Cuihongshan polymetallic deposit, Lesser Xing'an Range, NE China

Abstract The grossular-andradite solid solutions in garnet from skarn deposits in relation to hydrothermal processes and physicochemical conditions of ore formation remain controversial. Here we investigate garnet occurring in association with calcic and magnesian skarn rocks in the Cuihongshan polymetallic skarn deposit of NE China. The calcic skarn rocks contain three types of garnets. (1) Prograde type I Al-rich anisotropic garnets display polysynthetic twinning and a compositional range of Grs18–80Adr10–75. This type of garnet shows markedly low rare earth element (REE) contents (3.27–78.26 ppm) and is strongly depleted in light rare earth elements (LREE, 0.57–44.65 ppm) relative to heavy rare earth elements (HREE, 2.31–59.19 ppm). They also display a significantly negative Eu anomaly (Eu/Eu* of 0.03–0.90). (2) Fe-rich retrograde type II garnets are anisotropic with oscillatory zoning and own wide compositional variations (Grs1–47Adr30–95) with flat REE (13.73–377.08 ppm) patterns. (3) Fe-rich retrograde type III isotropic garnets display oscillatory zoning and morphological transition from planar dodecahedral {110} crystal faces to {211} crystal faces in the margin. Types III garnets exhibit relatively narrow compositional variations of Grs0.1–12Adr85–97 with LREE-enrichment (0.80–51.87 ppm), flat HREE patterns (0.15–2.46 ppm) and strong positive Eu anomalies (Eu/Eu* of 0.93–27.07 with almost all &gt;1). The magnesian skarn rocks contain euhedral isotropic type IV Mn-rich garnet veins with a composition of Grs10–23Sps48–62Alm14–29. All calcic garnets contain considerable Sn and W contents. Type II garnet containing intermediate compositions of andradite and grossular shows the highest Sn contents (64.36–2778.92 ppm), albeit the lowest W range (1.11–468.44 ppm). Birefringence of garnet is probably caused by strain from lattice mismatch at a twinning boundary or ion substitution near intermediate compositions of grossular-andradite. The fine-scale, sharp, and straight garnet zones are probably caused by self-organization, but the compositional variations of zones from core to rim are probably caused by external factors. The zoning is likely driven by external factors such as composition of the hydrothermal fluid. REE concentrations are probably influenced by the relative proportion and temperature of the system. Moreover, the LREE-HREE fractionation of garnet can be attributed to relative compositions of grossular-andradite system. The W and Sn concentrations in garnet can be used as indicators for the exploration of W-Sn skarn deposits.

Geochemical characterisation of the Neoarchaean newer dolerite dykes of the Bahalda region, Singhbhum craton, Odisha, India: Implication for petrogenesis

The mafic dyke swarm, newer dolerite dykes (NDDs) intrudes the Archaean Singbhum granite of the Singhbhum craton, eastern India. The present investigation focuses on the petrography and geochemistry of 19 NNE–SSW to NE–SW trending NDDs in two sectors in the northern and south-western part of Bahalda town, Odisha, Singhbhum. Chondrite normalised rare earth element (REE) patterns show light REE (LREE) enrichment among majority of the 13 dykes while the remaining six dykes show a flat REE pattern. Critical analyses of some important trace element ratios like Ba/La, La/Sm, Nb/Y, Ba/Y, Sm/La, Th/La, La/Sm, Nb/Zr, Th/Zr, Hf/Sm, Ta/La and Gd/Yb indicate that the dolerite dykes originated from a heterogeneous spinel peridotite mantle source which was modified by fluids and melts in an arc/back arc setting. REE modelling of these dolerite dykes were attempted on LREE-enriched representative of NDD which shows that these dykes might have been generated by 5–25% partial melting of a modified spinel peridotite source which subsequently suffered around 30% fractional crystallisation of olivine, orthopyroxene and clinopyroxene. The reported age of ~2.75–2.8 Ma seems to be applicable for these dykes and this magmatism appears to be contemporaneous with major scale anorogenic granitic activity in the Singhbhum craton marking a major event of magmatic activity in eastern India.

Migmatites record multiple episodes of crustal anatexis and geochemical differentiation in the Sulu ultrahigh‐pressure metamorphic zone, eastern China

AbstractPartial melting of ultrahigh‐pressure (UHP) metamorphic rocks is common during collisional orogenesis and post‐collisional reworking, indicating that determining the timing and processes involved in this partial melting can provide insights into the tectonic evolution of collisional orogens. This study presents the results of a combined whole‐rock geochemical and zirconological study of migmatites from the Sulu orogen in eastern China. These data provide evidence of multiple episodes of crustal anatexis and geochemical differentiation within the UHP metamorphic rocks. The leucosomes contain higher concentrations of Ba and K and lower concentrations of the rare earth elements (REE), Th and Y, than associated melanosomes and granitic gneisses. The leucosomes also have homogenous Sr–Nd–O isotopic compositions that are similar to proximal (i.e. within the same outcrop) melanosomes, suggesting that the anatectic melts were generated by the partial melting of source rocks that are located within individual outcrops. The migmatites contain zircons with six different types of domains that can be categorized using differences in structures, trace element compositions, and U–Pb ages. Group I domains are relict magmatic zircons that yield middle Neoproterozoic U–Pb ages and contain high REE concentrations. Group II domains represent newly grown metamorphic zircons that formed at 230 ± 1 Ma during the collisional orogenesis. Groups III, IV, V, and VI zircons are newly grown anatectic zircons that formed at 222 ± 2 Ma, 215 ± 1 Ma, 177 ± 2 Ma, and 152 ± 2 Ma, respectively. The metamorphic zircons have higher Th/U and lower (Yb/Gd)N values, flat heavy REE (HREE) patterns with no significantly negative Eu anomalies relative to the anatectic zircons, which are characterized by low Th/U ratios, steep HREE patterns, and negative Eu anomalies. The first two episodes of crustal anatexis occurred during the Late Triassic at c. 222 Ma and c. 215 Ma as a result of phengite breakdown. The other two episodes of anatexis occurred during the Jurassic period at c. 177 Ma and c. 152 Ma and were associated with extensional collapse of the collision‐thickened orogen. The majority of Triassic anatectic zircons and all of the Jurassic zircons are located within the leucosomes, whereas the melanosomes are dominated by Triassic metamorphic zircons, suggesting that the leucosomes within the migmatites record more episodes of crustal anatexis. Both metamorphic and anatectic zircons have elevated εHf(t) values compared with relict magmatic zircon cores, suggesting that these zircons contain non‐zircon Hf derived from material with more radiogenic Hf isotope compositions. Therefore, the Sulu and Dabie orogens experienced different episodes of reworking during the exhumation and post‐collisional stages.

The Zealandia Volcanic Complex: Further evidence of a lower crustal “hot zone” beneath the Mariana Intra‐oceanic Arc, Western Pacific

AbstractThis paper addresses formation of felsic magmas in an intra‐oceanic magmatic arc. New bathymetric, petrologic, geochemical, and isotopic data for Zealandia Bank and two related volcanoes in the south‐central Mariana arc is presented and interpreted. These three volcanoes are remnants of an older andesitic volcano that evolved for some time and became dormant long enough for a carbonate platform to grow on its summit before reawakening as a rhyodacitic volcano. Zealandia lavas are transitional between low‐ and medium‐K and tholeiitic and calc‐alkaline suites. They define a bimodal suite with a gap of 56–58 wt% SiO2; this suggests that mafic and felsic magmas have different origins. The magmatic system is powered by mantle‐derived basalts having low Zr/Y and flat rare earth element patterns. Two‐pyroxene thermometry yields equilibration temperatures of 1000–1100 °C for andesites and 900–1000 °C for dacites. Porphyritic basalts and andesites show textures expected for fractionating magmas but mostly fine‐grained felsic lavas do not. All lavas show trace element signatures expected for mantle and crustal sources that were strongly melt‐depleted and enriched by subduction‐related fluids and sediment melts. Sr and Nd isotopic compositions fall in the normal range of Mariana arc lavas. Felsic lavas show petrographic evidence of mixing with mafic magma. Zealandia Bank felsic magmatism supports the idea that a large mid‐ to lower‐crustal felsic magma body exists beneath the south‐central Mariana arc, indicating that MASH (mixing, assimilation, storage, and homogenization) zones can form beneath intra‐oceanic as well as continental arcs.