The decline in photovoltaic cell efficiency due to temperature elevation, coupled with solar energy's inherent intermittency, presents challenges for solar systems, including photovoltaic panels and solar thermal (ST) collectors. The integration of phase change materials (PCMs) emerges as a promising solution to enhance thermal energy storage and regulation, thereby improving system performance and sustainability. This study investigates the performance of series-connected photovoltaic thermal (PVT) and ST systems with integrated PCMs from energy and exergy viewpoints, utilizing a 3D transient numerical simulation. The proposed system's performance is compared with that lacking a PCM across various heat transfer fluid mass flow rates. Suitable PCM selection based on melting temperature is explored, along with PCM layer thickness and nanoparticle augmentation. The research highlights that PCM integration effectively regulates PV cell temperature, enhancing electrical power and exergy rate. While increasing the mass flow rate improves thermal and electrical power, it reduces the thermal exergy rate. Comparing different PCMs (RT28 HC, RT35 HC, and RT44 HC), the RT28 HC PCM provides the lowest temperature of PV cells and the best electrical performance during the day. Moreover, increasing PCM layer thickness results in lowering PV cell and outlet temperatures and storing more heat. Nanoparticles added to PCMs lead to a marginal improvement in energy and exergy, especially for the system with RT28 HC. This analysis emphasizes PCM integration's role in enhancing solar thermal system performance, highlighting the importance of considering the PCM's melting temperature for effective thermal energy management.
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