For a continuously changing flow field of a binary mixture assumed to be in local chemical equilibrium, the concentration of species is uniquely determined by the law of mass-action as a function of any two independent thermodynamic variables such as temperature and pressure. This implies infinite large reaction rates leading to indefinite production rates of species. The partial continuity equation is superfluous being replaced by the law of mass-action. This partial continuity equation on the other hand can be used in connection with the other flow equations as well as the law of mass-action to determine this production rate in equilibrium state. Further on, it is shown that for a flat plate boundary layer flow under certain assumptions the profile m ∗ Aδ 2/μ is a similar profile which can be put into a nearly closed analytical form. In this expression, m ∗ A is the production rate of species A, δ the boundary layer thickness and μ the viscosity. This equilibrium profile as well as the equilibrium profiles of concentration and temperature are compared with corresponding nonequilibrium profiles. The equilibrium profiles appear to be limiting profiles approached asymptotically at infinite distances.
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