As the main energy consumption of aviation and aerospace, the study of combustion characteristics of aviation kerosene is of great significance. In this paper, through the self-built experimental system, the combustion flame characteristics of pure aviation kerosene, aviation kerosene mixed with n-amyl alcohol, aviation kerosene mixed with dimethylfuran were studied under different working conditions, and the physicochemical properties of soot particles generated in the flame, and the effects of mixing n-amyl alcohol and dimethylfuran on the formation of soot particles were analyzed from the microscopic perspective. The results show that: 1. The soot particles in the combustion of aviation kerosene mixed with n-amyl alcohol and dimethylfuran show some characteristics of amorphous structure, unclear outline and incomplete curing; 2. Under K-D20 condition, nitrates are included in particulate matter generated by soot; 3. After mixing n-amyl alcohol and dimethylfuran, the degree of graphitization continues to decrease.