In this study, firstly, three first-order local closure vertical diffusion schemes used in multiple mesoscale chemical transport models (CTM) were embedded in the CHIMERE CTM model and tested over a one-year simulation covering the whole France. Three model configurations present a fair reproduction of pollutant concentrations both in urban and rural areas, indicating it is an effective way to reproduce the dispersion of pollutants in chemistry transport modeling. However, it cannot be expected to significantly improve the vertical mixing under the first-order closure scheme. Secondly, a 1.5-order turbulence kinetic energy-based eddy diffusivity closure scheme called as the new eddy diffusion (NED) is implemented in CHIMERE to describe more realistic diffusion processes near the surface. A fifteen-day simulation encompassing a winter pollution episode was performed for three major cities with horizontal resolution of 1.67 km and the first layer height at 12 m, respectively. The NED scheme improved NO2 simulations at most urban sites compared to the initial Kz diffusion scheme (IKD). Taking the root mean square error as evaluation criteria, the average improvements are 18.8%, 24.5% and 9.5% for NO2 simualtion in Paris, Lyon and Bordeaux respectively. For the model performance of PM2.5 and PM10 simulations in the urban areas of Paris, the improvements are 13.5% and 19.1%, respectively. Overall, preliminary outcomes of this study are encouraging. The simulation with more sophisticated and realistic eddy viscosities are better than for IKD that is widely used in CTMs, but we need to realize that this is only a fifteen-day simulation for three cities, for further research, longer periods are needed with a greater variety of meteorological situations to prove the universality of the NED scheme.
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