First-generation Biofuels Research Articles

Biofuels in the long-run global energy supply mix for transportation

Various policy instruments along with increasing oil prices have contributed to a sixfold increase in global biofuels production over the last decade (2000-2010). This rapid growth has proved controversial, however, and has raised concerns over potential conflicts with global food security and climate change mitigation. To address these concerns, policy support is now focused on advanced or second-generation biofuels instead of crop-based first-generation biofuels. This policy shift, together with the global financial crisis, has slowed the growth of biofuels production, which has remained stagnant since 2010. Based upon a review of the literature, this paper examines the potential long-run contribution of biofuels to the global energy mix, particularly for transportation. We find that the contribution of biofuels to global transportation fuel demand is likely to be limited to around 5% over the next 10-15 years. However, a number of studies suggest that biofuels could contribute up to a quarter of global transportation fuel demand by 2050, provided technological breakthroughs reduce the costs of sustainably produced advanced biofuels to a level where they can compete with petroleum fuels.

Fuelling expectations: A policy-promise lock-in of UK biofuel policy

Controversy over EU-wide biofuel policy resonated within the UK, fuelling policy disagreements among UK public authorities. They disagreed over how to protect a space for future second-generation biofuels, which were expected to overcome harm from first-generation biofuels. The UK government defended rising targets for available biofuels as a necessary stimulus for industry to help fulfil the UK's EU obligations and eventually develop second-generation biofuels. By contrast, Parliamentary Select Committees opposed biofuel targets on grounds that these would instead lock-in first-generation biofuels, thus delaying or pre-empting second-generation biofuels. Those disagreements can be explained by different institutional responsibilities and reputational stakes towards ‘promise-requirement cycles’, whereby techno-optimistic promises generate future requirements for the actors involved. The UK government's stance illustrates a ‘policy-promise lock-in’, a dilemma whereby promised support is a requirement for credibility towards technology innovators and thus technoscientific development – but may delay the redirection of support from incumbent to preferable emerging technologies. Thus the sociology of expectations – previously applied to technological expectations from technology innovators – can be extended to analyse public authorities.

Biofuels, tax policies and oil prices in France: Insights from a dynamic CGE model

The 2009 Renewable Energies Directive (RED) has set up ambitious targets concerning biofuel consumption in the European Union by 2020. Nevertheless, budgetary constraints and growing concerns about the environmental integrity of first-generation biofuels have imposed a phasing out of the fiscal instruments to promote them. Focusing on France, this paper combines an exogenous increase in oil prices and tax policies on fossil fuels. The objective is to determine the efficiency of an alternative incentive scheme for biodiesel consumption based on a higher price of the fossil fuel substitute. Policy simulations are implemented through a dynamic computable general equilibrium (CGE) model calibrated on 2009 French data. The results show that the 10% biodiesel mandate set by the RED would not be achieved even if the fixed taxes on diesel reach the same level as those on gasoline. Although integrating the rise in oil prices into the fiscal framework improves the biodiesel penetration rate, it remains below the target. Moreover, we find that the effects of biofuel consumption are limited to the biofuel chain sectors. In other agricultural sectors, the substitution effect of biodiesel with diesel is partially offset by the pricing effect induced by higher energy production costs.

Analysis of the Viability of Ethanol Production in Brazil: Economical, Social & Environmental Implications

The global dependency on fossil fuels as energy sources has encouraged many countries to look for different renewable alternatives. Some have come to consider biofuel production as the ‘solution’ to the oil dependency. The leaders of ethanol production in the world are the United States and Brazil. This paper will focus on ethanol production in Brazil, outlining its development through Brazil’s history as well as the advantages and the negative impacts of such a market. The importance of this energy source in Brazil’s economy and the possible future outcomes of Brazil’s biofuel dependency will be discussed. Three different aspects of primary impacts will be highlighted: economic, environmental and social. The effects of the new advancements in emerging biofuels will be discussed as they pertain to the current market for first-generation biofuels. An analysis of the economic impacts of ethanol will concentrate on the influence of the American ethanol market and its policies on Brazil. The environmental impacts of land use change, with a focus on soil, water and biodiversity, will also be reviewed. Likewise, the social impacts associated with food security, sugarcane workers and indigenous peoples’ rights will be discussed. An overall view of the repercussions of biofuel production will be presented and questions regarding the viability of the biofuel market in Brazil will be addressed.

Environmental assessment of biofuel pathways in Ile de France based on ecosystem modeling

The objective of the work reported here was to reduce the uncertainty on the greenhouse gas balances of biofuels using agro-ecosystem modeling at a high resolution over the Ile-de-France region in Northern France. The emissions simulated during the feedstock production stage were input to a life-cycle assessment of candidate biofuel pathways: bioethanol from wheat, sugar-beet and miscanthus, and biodiesel from oilseed rape. Compared to the widely-used methodology based on fixed emission factors, ecosystem modeling lead to 55-70% lower estimates for N2O emissions, emphasizing the importance of regional factors. The life-cycle GHG emissions of first-generation biofuels were 50-70% lower than fossil-based equivalents, and 85% lower for cellulosic ethanol. When including indirect land-use change effects, GHG savings became marginal for biodiesel and wheat ethanol, but were positive due to direct effects for cellulosic ethanol.

Technological variation and the US renewable fuel standard

The US Renewable Fuel Standard contains a policy bias that undermines the three-broad policy goals of rural development, energy security, and greenhouse gas reductions. This policy bias, wherein a narrow range of options is expected to address broad societal objectives, contributes to a persistence of first-generation biofuels and limits technical variation. Renewable fuel content requirements have helped to expand the use of ethanol and biodiesel in the short term. However, long-term changes will require greater technological variation to stimulate innovation for the development of sustainable renewable fuel pathways.

Sugarcane ethanol production in Malawi: Measures to optimize the carbon footprint and to avoid indirect emissions

Sugarcane ethanol is considered to be one of the most efficient first-generation biofuels in terms of greenhouse gas (GHG) emissions. The carbon footprint (CF), however, increases significantly when taking into account emissions induced by indirect land-use changes (ILUC). This case study investigates sugarcane ethanol production in the Republic of Malawi, in Sub-Sahara Africa (SSA); the research objectives were to identify and quantify direct and indirect emissions and to identify measures to optimize the CF. The CF has been calculated with a life cycle approach and with data obtained from the involved companies; our estimations with regard to ILUC take into account further expansion plans for sugarcane crop production. Under existing production conditions ethanol produced in Malawi leads to GHG emissions expressed as CO2eq of 116 g MJ−1 of ethanol. However, high optimization potentials exist when the vinasse is used as an input for biogas production and the harvesting switches from pre-harvest burning to green harvesting. ILUC induced by prospective sugarcane expansions in the Southern Region will, according to current planning, probably not occur since these expansions are linked to the implementation of a large-scale irrigation project. However if ILUC takes place, high levels of additional CO2 emissions of about 77 g MJ−1 of ethanol are to be expected. Although the case study results are only valid for a specific region, some of the findings, such as the high compensation potential regarding ILUC through investments in irrigation systems, may be transferable to other regions in SSA.

Characterization of Bio-oils from Different Pyrolysis Process Steps and Biomass Using High-Resolution Mass Spectrometry

Next-generation biofuels have been widely investigated because they have particular advantages compared to first-generation biofuels. Pyrolysis is an example of a thermochemical route extensively used in oil and coal industries worldwide to produce these biofuels. Strategies for low-cost upgrading are among the biggest challenges facing the adoption of bio-oils in the development of commercial biofuels. Specific biomass sources could be the best option for generating bio-oil with the required properties. For this, it is necessary to understand the composition of these biomasses and their bio-oils. Here, we analyzed bio-oil samples from the fast pyrolysis of different biomasses collected during two different steps of the process by direct-infusion high-resolution mass spectrometry. First, a comparative study of two common high-resolution mass spectrometers, quadrupole time-of-flight mass spectrometry (Q-TOF MS) and Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS), was performed to va...

Lignification in Sugarcane: Biochemical Characterization, Gene Discovery, and Expression Analysis in Two Genotypes Contrasting for Lignin Content

Sugarcane (Saccharum spp.) is currently one of the most efficient crops in the production of first-generation biofuels. However, the bagasse represents an additional abundant lignocellulosic resource that has the potential to increase the ethanol production per plant. To achieve a more efficient conversion of bagasse into ethanol, a better understanding of the main factors affecting biomass recalcitrance is needed. Because several studies have shown a negative effect of lignin on saccharification yield, the characterization of lignin biosynthesis, structure, and deposition in sugarcane is an important goal. Here, we present, to our knowledge, the first systematic study of lignin deposition during sugarcane stem development, using histological, biochemical, and transcriptional data derived from two sugarcane genotypes with contrasting lignin contents. Lignin amount and composition were determined in rind (outer) and pith (inner) tissues throughout stem development. In addition, the phenolic metabolome was analyzed by ultra-high-performance liquid chromatography-mass spectrometry, which allowed the identification of 35 compounds related to the phenylpropanoid pathway and monolignol biosynthesis. Furthermore, the Sugarcane EST Database was extensively surveyed to identify lignin biosynthetic gene homologs, and the expression of all identified genes during stem development was determined by quantitative reverse transcription-polymerase chain reaction. Our data provide, to our knowledge, the first in-depth characterization of lignin biosynthesis in sugarcane and form the baseline for the rational metabolic engineering of sugarcane feedstock for bioenergy purposes.

The Utilization of Rapeseed for Biofuels Production in the EU

Abstract Biofuels production has risen rapidly in the past decade. Growing tendency can be expected in the future if national governments will continue in achievement of higher share of ‘green energy’. Diversification and self-sufficiency in energy and environmental aspects should underpin national and international policy. Consumption of biofuels in the transport sector has been significantly increasing since 2000. Biofuels produced in the EU are mostly first-generation biofuels, mainly produced from agricultural raw materials. The aim of the article is utilization assessment of the main agriculture crop used in biofuels production in the EU, which is rapeseed. For achievement of the research objective have been used analysis methods, basic statistical indices, the share of rapeseed production used in industrial purposes estimation and self - sufficiency index. The results of the research confirm authors’ expectations concerning shifting of agricultural production primarily intended for food and feed production to industrial purposes due to continually growing demand for biofuels.

Integrating place-specific livelihood and equity outcomes into global assessments of bioenergy deployment

Integrated assessment models suggest that the large-scale deployment of bioenergy could contribute to ambitious climate change mitigation efforts. However, such a shift would intensify the global competition for land, with possible consequences for 1.5 billion smallholder livelihoods that these models do not consider. Maintaining and enhancing robust livelihoods upon bioenergy deployment is an equally important sustainability goal that warrants greater attention. The social implications of biofuel production are complex, varied and place-specific, difficult to model, operationalize and quantify. However, a rapidly developing body of social science literature is advancing the understanding of these interactions. In this letter we link human geography research on the interaction between biofuel crops and livelihoods in developing countries to integrated assessments on biofuels. We review case-study research focused on first-generation biofuel crops to demonstrate that food, income, land and other assets such as health are key livelihood dimensions that can be impacted by such crops and we highlight how place-specific and global dynamics influence both aggregate and distributional outcomes across these livelihood dimensions. We argue that place-specific production models and land tenure regimes mediate livelihood outcomes, which are also in turn affected by global and regional markets and their resulting equilibrium dynamics. The place-specific perspective suggests that distributional consequences are a crucial complement to aggregate outcomes; this has not been given enough weight in comprehensive assessments to date. By narrowing the gap between place-specific case studies and global models, our discussion offers a route towards integrating livelihood and equity considerations into scenarios of future bioenergy deployment, thus contributing to a key challenge in sustainability sciences.

Asia and European transport biofuels stalled at the same place?

Over the past decade, both Asia and Europe have devoted considerable effort to expanding the production of first-generation biofuels to fuel cars, taxis, buses, trucks, motorcycles, etc. On the one hand, with “peak oil” potentially looming in the future, and on the other, with an insatiable need for petroleum and diesel, the prospect of large-scale use of biofuels enjoyed tremendous public appeal as they seemed to provide a long-term alternative and clean fuel source in Asia and Europe. However, globally today, biofuels constitute only 3 % of the total transport fuel mix. Production is still steadily increasing in some countries, but their economic competitiveness and environmental sustainability have come into question in others with the result that production has slowed down considerably or even halted. The outlook for second- and third-generation biofuels is promising. However, they also cannot yet supplement, far less substitute, for petroleum and diesel in a commercially viable way.

Prospects for Biofuels: A Review

Biofuels have the potential to be sustainable, secure, low carbon footprint transportation fuels. Primarily due to government mandates, biofuels have become increasingly adopted as transportation fuels over the last decade and are projected to steadily increase in production. Here the prospects of biofuels are summarized in terms of several important performance measures, including: lifecycle greenhouse gas (GHG) emissions, energy return on investment (EROI), land and water requirements, and tailpipe emissions. A review of the literature leads to the conclusion that most first-generation biofuels, including corn ethanol and soybean biodiesel produced in the United States, reduce tailpipe pollutant emissions and GHG emissions—provided their feedstocks do not replace large quantities of fixed carbon. However, their production is perhaps unsustainable due to low EROI and significant land-use and water requirements. Second-generation biofuels; for example ethanol produced from lignocellulosic biomass, have the potential for larger reductions in GHG emissions and can provide sustainable EROI with reasonable land area usage; however, they require water inputs several orders-of-magnitude greater than required by petroleum fuels. Advanced biofuels from algal oils and synthetic biological processes are further from commercial reality and require more assessment but potentially offer better performance due to their orders-of-magnitude greater yields per land area and lower water requirements; at present, the energy costs of such biofuels are uncertain.

Growing a sustainable biofuels industry: economics, environmental considerations, and the role of the Conservation Reserve Program

Biofuels are expected to be a major contributor to renewable energy in the coming decades under the Renewable Fuel Standard (RFS). These fuels have many attractive properties including the promotion of energy independence, rural development, and the reduction of national carbon emissions. However, several unresolved environmental and economic concerns remain. Environmentally, much of the biomass is expected to come from agricultural expansion and/or intensification, which may greatly affect the net environmental impact, and economically, the lack of a developed infrastructure and bottlenecks along the supply chain may affect the industry’s economic vitality. The approximately 30 million acres (12 million hectares) under the Conservation Reserve Program (CRP) represent one land base for possible expansion. Here, we examine the potential role of the CRP in biofuels industry development, by (1) assessing the range of environmental effects on six end points of concern, and (2) simulating differences in potential industry growth nationally using a systems dynamics model. The model examines seven land-use scenarios (various percentages of CRP cultivation for biofuel) and five economic scenarios (subsidy schemes) to explore the benefits of using the CRP. The environmental assessment revealed wide variation in potential impacts. Lignocellulosic feedstocks had the greatest potential to improve the environmental condition relative to row crops, but the most plausible impacts were considered to be neutral or slightly negative. Model simulations revealed that industry growth was much more sensitive to economic scenarios than land-use scenarios—similar volumes of biofuels could be produced with no CRP as with 100% utilization. The range of responses to economic policy was substantial, including long-term market stagnation at current levels of first-generation biofuels under minimal policy intervention, or RFS-scale quantities of biofuels if policy or market conditions were more favorable. In total, the combination of the environmental assessment and the supply chain model suggests that large-scale conversion of the CRP to row crops would likely incur a significant environmental cost, without a concomitant benefit in terms of biofuel production.

Food Price Inflation as Redistribution: Towards a New Analysis of Corporate Power in the World Food System

This paper outlines the contours of a new research agenda for the analysis of food price crises. By weaving together a detailed quantitative examination of changes in corporate profit shares with a qualitative appraisal of the restructuring in business control over the organisation of society and nature, the paper points to the rapid ascendance of a new power configuration in the global political economy of food: the Agro-Trader nexus. The agribusiness and grain trader firms that belong to the Agro-Trader nexus have not been mere ‘price takers’, instead they have actively contributed to the inflationary restructuring of the world food system by championing and facilitating the rapid expansion of the first-generation biofuels sector. As a key driver of agricultural commodity price rises, the biofuels boom has raised the Agro-Trader nexus's differential profits and it has at the same time deepened global hunger. These findings suggest that food price inflation is a mechanism of redistribution.

Sustainability impacts of first-generation biofuels

Sustainability impacts of first-generation biofuels

Overexpression of plastidial thioredoxin f leads to enhanced starch accumulation in tobacco leaves

Starch, the most abundant storage carbohydrate in plants, has been a major feedstock for first-generation biofuels. Growing fuel demands require, however, that the starch yields of energy crops be improved. Leaf starch is synthesised during the day and degraded at night to power nonphotosynthetic metabolism. Redox regulation has been associated with the coordination of the enzymes involved in starch metabolism, but neither the signals nor mechanisms that regulate this metabolism are entirely clear. In this work, the thioredoxin (Trx) f and m genes, which code for key enzymes in plastid redox regulation, were overexpressed from the plastid genome. Tobacco plants overexpressing Trx f, but not Trx m, showed an increase of up to 700% in leaf starch accumulation, accompanied by an increase in leaf sugars, specific leaf weight (SLW), and leaf biomass yield. To test the potential of these plants as a nonfood energy crop, tobacco leaves overexpressing Trx f were subjected to enzymatic hydrolysis, and around a 500% increase in the release of fermentable sugars was recorded. The results show that Trx f is a more effective regulator of photosynthetic carbon metabolism in planta than Trx m. The overexpression of Trx f might therefore provide a means of increasing the carbohydrate content of plants destined for use in biofuel production. It might also provide a means of improving the nutritional properties of staple food crops.

Influence of biofuel crops on mosquito production and oviposition site selection

The proposed expansion of biofuels production may cause unintended land-use changes and potentially alter ecosystem services. This study evaluated the impact of first-generation (corn) and second-generation (switchgrass and Miscanthus) biofuel crops on production and oviposition site selection by two vector mosquitoes, the yellow fever mosquito Aedes aegypti and the Asian tiger mosquito Aedes albopictus. Larvae of the two species were reared at varying conspecific and heterospecific densities in senescent leaf infusions prepared from one of the three biofuel crops and their survival and development time to adulthood determined. The effects of the three leaf infusions on water chemistry and oviposition site selection by the two mosquito species were also determined. Ae. albopictus females deposited significantly fewer eggs in Miscanthus than in corn infusion while Ae. aegypti females deposited significantly fewer eggs in Miscanthus than in both corn and switchgrass infusion. Survival to adulthood for both mosquito species was significantly lower in corn than in switchgrass and Miscanthus infusions; was consistently lower at high- (0:40 and 20:20) than at low density treatments in both switchgrass and Miscanthus infusions; and significantly lower at high intraspecific density (40:0 and 0: 40) than at high interspecific density (20:20) in Miscanthus infusion. Development time to adulthood was positively related to larval density, but was not influenced by biofuel leaf treatment. Corn infusion had lower pH values and higher salinity, conductivity, total dissolved solids (TDS), and temperature values than switchgrass and Miscanthus infusions. These findings demonstrate the potential for biofuel crops to modify the chemistry of aquatic habitats in ways that may influence mosquito production and thereby the risk of exposure to mosquito-borne diseases.

Motivations, Incentives and Risks of Investment in Biofuels

Different factors such as rising oil prices, climate change and energy security have generated much interest in renewable energy sources such as biofuels. Investment in this new industry involves certain motivations, incentives and risks. While there is now some experience in working with the first generation of biofuels, the second and third (which seem to have greater potential) are still in their infancy, yet are viewed as important investment opportunities by companies such as BP or ExxonMobil. This essay provides an overview of the motivations, incentives, and risks involved in investment in each generation of biofuels. Furthermore, it provides some examples of investments by the ‘Big Players’: BP, ExxonMobil, and D1 Oils.

Websites of note

Websites of note