The flow velocity of gases in gobs directly influences the kinetics and intensity of gaseous components release during heating and cooling of coal. The assessment of fire hazard is performed on the basis of concentrations of particular gases in a mine air. These concentrations differ in coal heating and cooling phase which was proven in the study. This paper presented the results of the experimental study on temperature distribution in a simulated coal bed in heating (50–250 °C) and cooling (250–35 °C) phases as well as its correlation to variations in concentration of gases released in these phases and flow rates of gases flowing through the coal bed. The research was performed on twenty-two samples of bituminous coals acquired from various coal beds of Polish coal mines. Considerable differences were observed between heating and cooling phases in terms of the concentrations of gases taken into account in calculations of self-combustion index. In the heating phase temperature increase resulted in the decrease of concentrations ratios of ethane, ethylene, propane, propylene and acetylene, while in the cooling phase these ratios increased systemically. The effect of air (in heating phase) and nitrogen (in cooling phase) flow rate on the self-ignition index CO/CO2 was also determined.