Finite Energy Density Research Articles

Predicting fatigue life of additively manufactured lattice structures using the image-based Finite Cell Method and average strain energy density

A well-known Achilles' heel of laser powder bed fusion (L-PBF) additive manufactured lattice structures is the difficulty in predicting fatigue properties. The presence of manufacturing-induced defects significantly affects the fatigue resistance of the porous component and must be accurately captured by predictive models. To tackle this challenge, the as-built geometry of the lattice needs to be modeled, which introduces another challenge on the computational front. For the first time, a model based on the computer tomography (μ-CT) reconstruction of the as-built lattice geometry is simulated with the efficient finite cell method and combined with the average strain energy density (ASED) to obtain accurate fatigue predictions. This work presents a workflow for determining the fatigue resistance of lattice metamaterial, followed by a case study for method validation. The validation shows a good agreement between the predicted fatigue life and the experimental results.

All holographic systems have scar states

Scar states are special finite-energy density, but nonthermal states of chaotic Hamiltonians. We argue that all holographic quantum field theories, including N=4 super Yang-Mills, have scar states. Their presence is tied to the existence of nontopological, horizonless soliton solutions in gravity; oscillons and a novel family of excited boson stars. We demonstrate that these solutions have periodic oscillations in the correlation functions and posses low-entanglement entropy as expected for scar states. Also we find that they can be very easily prepared with Euclidean path integral. Published by the American Physical Society 2024

Robust Effective Ground State in a Nonintegrable Floquet Quantum Circuit.

An external periodic (Floquet) drive is believed to bring any initial state to the featureless infinite temperature state in generic nonintegrable isolated quantum many-body systems in the thermodynamic limit, irrespective of the driving frequency Ω. However, numerical or analytical evidence either proving or disproving this hypothesis is very limited and the issue has remained unsettled. Here, we study the initial state dependence of Floquet heating in a nonintegrable kicked Ising chain of length up to L=30 with an efficient quantum circuit simulator, showing a possible counterexample: the ground state of the effective Floquet Hamiltonian is exceptionally robust against heating, and could stay at finite energy density even after infinitely many Floquet cycles, if the driving period is shorter than a threshold value. This sharp energy localization transition or crossover does not happen for generic excited states. The exceptional robustness of the ground state is interpreted by (i)its isolation in the energy spectrum and (ii)the fact that those states with L-independent ℏΩ energy above the ground state energy of any generic local Hamiltonian, like the approximate Floquet Hamiltonian, are atypical and viewed as a collection of noninteracting quasiparticles. Our finding paves the way for engineering Floquet protocols with finite driving periods realizing long-lived, or possibly even perpetual, Floquet phases by initial state design.

Matrix product state approximations to quantum states of low energy variance

We show how to efficiently simulate pure quantum states in one dimensional systems that have both finite energy density and vanishingly small energy fluctuations. We do so by studying the performance of a tensor network algorithm that produces matrix product states whose energy variance decreases as the bond dimension increases. Our results imply that variances as small as ∝1/log⁡N can be achieved with polynomial bond dimension. With this, we prove that there exist states with a very narrow support in the bulk of the spectrum that still have moderate entanglement entropy, in contrast with typical eigenstates that display a volume law. Our main technical tool is the Berry-Esseen theorem for spin systems, a strengthening of the central limit theorem for the energy distribution of product states. We also give a simpler proof of that theorem, together with slight improvements in the error scaling, which should be of independent interest.

Ballistic to diffusive crossover in a weakly interacting Fermi gas

In the absence of disorder and interactions, fermions move coherently and their associated charge and energy exhibit ballistic spreading, even at finite energy density. In the presence of weak interactions and a finite energy density, fermion-fermion scattering leads to a crossover between early-time ballistic and late-time diffusive transport. The relevant crossover timescales and the transport coefficients are both functions of interaction strength, but the question of determining the precise functional dependence is likely impossible to answer exactly. In this work we develop a numerical method (fDAOE) which is powerful enough to provide an approximate answer to this question, and which is consistent with perturbative arguments in the limit of very weak interactions. Our algorithm, which adapts the existing dissipation-assisted operator evolution (DAOE) to fermions, is applicable to systems of interacting fermions at high temperatures. The algorithm approximates the exact dynamics by systematically discarding information from high n-point functions, and is tailored to capture noninteracting dynamics exactly. Applying our method to a microscopic model of interacting fermions, we numerically determine crossover timescales and diffusion constants for a wide range of interaction strengths. In the limit of weak interaction strength (Δ), we demonstrate that the crossover from ballistic to diffusive transport happens at a time tD∼1/Δ2 and that the diffusion constant similarly scales as D∼1/Δ2. We confirm that these scalings are consistent with a perturbative Fermi's golden rule calculation, and we provide a heuristic operator-spreading picture for the crossover between ballistic and diffusive transport. Published by the American Physical Society 2024

Quantum state complexity meets many-body scars

Scar eigenstates in a many-body system refers to a small subset of non-thermal finite energy density eigenstates embedded into an otherwise thermal spectrum. This novel non-thermal behaviour has been seen in recent experiments simulating a one-dimensional PXP model with a kinetically-constrained local Hilbert space realised by a chain of Rydberg atoms. We probe these small sets of special eigenstates starting from particular initial states by computing the spread complexity associated to time evolution of the PXP hamiltonian. Since the scar subspace in this model is embedded only loosely, the scar states form a weakly broken representation of the Lie algebra. We demonstrate why a careful usage of the forward scattering approximation (FSA), instead of any other method, is required to extract the most appropriate set of Lanczos coefficients in this case as the consequence of this approximate symmetry. Only such a method leads to a well defined notion of a closed Krylov subspace and consequently, that of spread complexity. We show this using three separate initial states, namely |Z2⟩,|Z3⟩ and the vacuum state, due to the disparate classes of scar states hosted by these sectors. We also discuss systematic methods of remedying the imperfections in the FSA setup stemming from these approximate symmetries.

Extending the thermodynamic form factor bootstrap program: multiple particle-hole excitations, crossing symmetry, and reparameterization invariance

In this study, we further the thermodynamic bootstrap program which involves a set of recently developed ideas used to determine thermodynamic form factors of local operators in integrable quantum field theories. These form factors are essential building blocks for dynamic correlation functions at finite temperatures or non-equilibrium stationary states. In this work we extend this program in three ways. Firstly, we demonstrate that the conjectured annihilation pole axiom is valid in the low energy particle-hole excitations. Secondly, we introduce a crossing relation, which establishes a connection between form factors with different excitation content. Typically, the crossing relation is a consequence of Lorentz invariance, but due to the finite energy density of the considered states, Lorentz invariance is broken. Nonetheless a crossing relation involving excitations with both particles and holes can established using the finite volume representation of the thermodynamic form factors. Finally, we demonstrate that the thermodynamic form factors satisfy a reparameterization invariance, an invariance which encompasses crossing. Reparameterization invariance exploits the fact that the details of the representation of the thermodynamic state are unimportant. In the course of developing these results, we demonstrate the internal consistency of the thermodynamic form factor bootstrap program in a number of ways. Finally, we provide explicit computations of form factors of conserved charges and densities with crossed excitations and show our results can be used to infer information about thermodynamic form factors in the Lieb-Liniger model.

Signatures of interacting Floquet phases in shallow quantum circuits

Many-body phenomena far from equilibrium present challenges beyond reach by classical computational resources. Digital quantum computers provide a possible way forward but noise limits their use in the near term. We propose a scheme to simulate and characterize many-body Floquet systems hosting a rich variety of phases that operates with a shallow circuit, defined as a quantum circuit that does not scale with system sizes. Starting from a periodic circuit that simulates the dynamical evolution of a Floquet system, we introduce quasiperiodicity to the circuit parameters to prevent thermalization by introducing many-body localization. By inspecting the time-averaged properties of the many-body integrals of motion, the phase structure can then be probed using random measurements. This approach avoids the need to compute the ground state and operates at finite energy density. We numerically demonstrate this scheme with a simulation of the Floquet Ising model of time crystals and present results clearly distinguishing different Floquet phases that are protected by many-body localization. Our results pave the way for mapping out phase diagrams of exotic systems on near-term quantum devices.

Quantum many-body scars of spinless fermions with density-assisted hopping in higher dimensions

We introduce a class of spinless fermion models that exhibit quantum many-body scars (QMBS) originating from kinetic constraints in the form of density-assisted hopping. The models can be defined on any lattice in any dimension and allow for spatially varying interactions. We construct a tower of exact eigenstates with finite energy density, and we demonstrate that these QMBS are responsible for the nonthermal nature of the system by studying the entanglement entropy and correlation functions. The quench dynamics from certain initial states is also investigated, and it is confirmed that the QMBS induce nonthermalizing dynamics. As another characterization of the QMBS, we give a parent Hamiltonian for which the QMBS are unique ground states. We also prove the uniqueness rigorously.

Multimagnon quantum many-body scars from tensor operators

We construct a family of three-body spin-1/2 Hamiltonians with a super-extensive set of infinitely long-lived multi-magnon states. A magnon in each such state carries either quasi-momentum zero or fixed $p_0\neq$ 0, and energy $\Omega$ . These multi-magnon states provide an archetypal example of quantum many-body scars: they are eigenstates at finite energy density that violate the eigenstate thermalization hypothesis, and lead to persistent oscillations in local observables in certain quench experiments. On the technical side, we demonstrate the systematic derivation of scarred Hamiltonians that satisfy a restricted spectrum generating algebra using an operator basis built out of irreducible tensor operators. This operator basis can be constructed for any spin, spatial dimension or continuous non-Abelian symmetry that generates the scarred subspace.

Engineered networking in a family of solvent-free single-ion conducting borate network polymer electrolytes for Li-metal battery applications

As the state-of-the-art energy storage technology, lithium-ion batteries have been attracting lots of attention, but their finite energy densities cannot satisfy the overwhelming demand for large energy storage and commercial flammable liquid electrolytes are also plagued by safety concerns. Solvent-free single-ion polymer electrolytes with excellent electrochemical properties are expected to solve these issues and enhance the energy density of the next-generation batteries technology. Here, we engineered the networking of a series of solvent-free anionic network polymer electrolytes to improve ionic transport for Li-metal battery applications. The anionic network polymers formed as a diamondoid structure consisting of borate anions bridged by branched ethylene glycol linkers of differing stoichiometric ratios, enabling the controlled segmental mobility of network polymers. The increasing segmental mobility offered an elevated ionic conductivity, revealing ionic transport was mostly controlled by engineering the segmental mobilities of polymers, especially at the given interanionic distance. However, there was a restricted ionic transport in fast segmental dynamics of the network polymers featuring free branches, implying that the branching would less contribute to ionic transport compared to the interanionic distance likely due to the frustration in changing the coordination site. Standout network polymer exhibited notable ion selectivity in Li+ cation transport and high oxidative stability. Galvanostatic cycling reveals outstanding resistance to dendrite growth, suggesting that the solvent-free network polymer can serve as a powerful electrolyte for Li-metal batteries.

Classical algorithms for many-body quantum systems at finite energies

Properties of quantum many-body systems at finite energy densities, such as microcanonical averages, are in general difficult to compute with classical algorithms. Quantum algorithms that combine quantum dynamics with filtering and sampling techniques can however access some of these quantities. Here, the authors show that simulating the time evolution part with tensor networks provides quantum-inspired classical algorithms that reach much larger systems than other numerical methods.

Extensive Multipartite Entanglement from su(2) Quantum Many-Body Scars.

Recent experimental observation of weak ergodicity breaking in Rydberg atom quantum simulators has sparked interest in quantum many-body scars-eigenstates which evade thermalization at finite energy densities due to novel mechanisms that do not rely on integrability or protection by a global symmetry. A salient feature of some quantum many-body scars is their subvolume bipartite entanglement entropy. In this Letter, we demonstrate that such exact many-body scars also possess extensive multipartite entanglement structure if they stem from an su(2) spectrum generating algebra. We show this analytically, through scaling of the quantum Fisher information, which is found to be superextensive for exact scarred eigenstates in contrast to generic thermal states. Furthermore, we numerically study signatures of multipartite entanglement in the PXP model of Rydberg atoms, showing that extensive quantum Fisher information density can be generated dynamically by performing a global quench experiment. Our results identify a rich multipartite correlation structure of scarred states with significant potential as a resource in quantum enhanced metrology.

On Emergent Particles and Stable Neutral Plasma Balls in SU(2) Yang-Mills Thermodynamics

For a pure SU(2) Yang–Mills theory in 4D, we revisit the spatial (3D), ball-like region of radius r0 in its bulk subject to the pressureless, deconfining phase at T0=1.32Tc, where Tc denotes the critical temperature for the onset of the deconfining–preconfining phase transition. Such a region possesses finite energy density and represents the self-intersection of a figure-eight shaped center-vortex loop if a BPS monopole of core radius ∼r052.4, isolated from its antimonopole by repulsion externally invoked through a transient shift of (anti)caloron holonomy (pair creation), is trapped therein. The entire soliton (vortex line plus region of self-intersection of mass m0 containing the monopole) can be considered an excitation of the pressureless and energyless ground state of the confining phase. Correcting an earlier estimate of r0, we show that the vortex-loop self-intersection region associates to the central part of a(n) (anti)caloron and that this region carries one unit of electric U(1) charge via the (electric-magnetic dually interpreted) charge of the monopole. The monopole core quantum vibrates at a thermodynamically determined frequency ω0 and is unresolved. For a deconfining-phase plasma oscillation about the zero-pressure background at T=T0, we compute the lowest frequency Ω0 within a neutral and homogeneous spatial ball (no trapped monopole) in dependence of its radius R0. For R0=r0 a comparison of Ω0 with ω0 reveals that the neutral plasma oscillates much slower than the same plasma driven by the oscillation of a monopole core.

Subdiffusive dynamics and critical quantum correlations in a disorder-free localized Kitaev honeycomb model out of equilibrium

Disorder-free localization has recently emerged as a mechanism for ergodicity breaking in homogeneous lattice gauge theories. In this work we show that this mechanism can lead to unconventional states of quantum matter as the absence of thermalization lifts constraints imposed by equilibrium statistical physics. We study a Kitaev honeycomb model in a skew magnetic field subject to a quantum quench from a fully polarized initial product state and observe nonergodic dynamics as a consequence of disorder-free localization. We find that the system exhibits a subballistic power-law entanglement growth and quantum correlation spreading, which is otherwise typically associated with thermalizing systems. In the asymptotic steady state the Kitaev model develops volume-law entanglement and power-law decaying dimer quantum correlations even at a finite energy density. Our work sheds light onto the potential for disorder-free localized lattice gauge theories to realize quantum states in two dimensions with properties beyond what is possible in an equilibrium context.

Motif magnetism and quantum many-body scars

We generally expect quantum systems to thermalize and satisfy the eigenstate thermalization hypothesis (ETH), which states that finite energy density eigenstates are thermal. However, some systems, such as many-body localized systems and systems with quantum many-body scars, violate ETH and have high-energy athermal eigenstates. In systems with scars, most eigenstates thermalize, but a few atypical scar states do not. Scar states can give rise to a periodic revival when time-evolving particular initial product states, which can be detected experimentally. Recently, a family of spin Hamiltonians was found with magnetically ordered 3-colored eigenstates that are quantum many-body scars [Lee et al. Phys. Rev. B 101, 241111(2020)]. These models can be realized in any lattice that can be tiled by triangles, such as the triangular or kagome lattices, and have been shown to have close connections to the physics of quantum spin liquids in the Heisenberg kagome antiferromagnet. In this work, we introduce a generalized family of $n$-colored Hamiltonians with "spiral colored" eigenstates made from $n$-spin motifs such as polygons or polyhedra. We show how these models can be realized in many different lattice geometries and provide numerical evidence that they can exhibit quantum many-body scars with periodic revivals that can be observed by time-evolving simple product states. The simple structure of these Hamiltonians makes them promising candidates for future experimental studies of quantum many-body scars.

Quantum scars and bulk coherence in a symmetry-protected topological phase

Formation of quantum scars in many-body systems provides a novel mechanism for enhancing coherence of weakly entangled states. At the same time, coherence of edge modes in certain symmetry protected topological (SPT) phases can persist away from the ground state. In this work we show the existence of many-body scars and their implications on bulk coherence in such an SPT phase. To this end, we study the eigenstate properties and the dynamics of an interacting spin-$1/2$ chain with three-site "cluster" terms hosting a $\mathbb{Z}_2 \times \mathbb{Z}_2$ SPT phase. Focusing on the weakly interacting regime, we find that eigenstates with volume-law entanglement coexist with area-law entangled eigenstates throughout the spectrum. We show that a subset of the latter can be constructed by virtue of repeated cluster excitations on the even or odd sublattice of the chain, resulting in an equidistant "tower" of states, analogous to the phenomenology of quantum many-body scars. We further demonstrate that these scarred eigenstates support nonthermal expectation values of local cluster operators in the bulk and exhibit signatures of topological order even at finite energy densities. Studying the dynamics for out-of-equilibrium states drawn from the noninteracting "cluster basis", we unveil that nonthermalizing bulk dynamics can be observed on long time scales if clusters on odd and even sites are energetically detuned. In this case, cluster excitations remain essentially confined to one of the two sublattices such that inhomogeneous cluster configurations cannot equilibrate and thermalization of the full system is impeded. Our work sheds light on the role of quantum many-body scars in preserving SPT order at finite temperature and the possibility of coherent bulk dynamics in models with SPT order beyond the existence of long-lived edge modes.

Polynomial-time algorithm for studying physical observables in chaotic eigenstates

We introduce an algorithm, the orthogonal operator polynomial expansion (OOPEX), to approximately compute expectation values in energy eigenstates at finite energy density of nonintegrable quantum many-body systems with polynomial effort, whereas exact diagonalization (ED) of the Hamiltonian $H$ is exponentially hard. The OOPEX relies on the eigenstate thermalization hypothesis, which conjectures that eigenstate expectation values of physical observables in such systems vary smoothly with the eigenstate energy (and other macroscopic conserved quantities, if any), and it computes them through a series generated by repeated multiplications, rather than diagonalization, of $H$ and whose successive terms oscillate faster with the energy. The hypothesis guarantees that only the first few terms of this series contribute appreciably. We further show that the OOPEX, in a sense, is the most optimum algorithm based on series expansions of $H$ as it avoids computing the many-body density of states, which plagues other similar algorithms. Then, we argue nonrigorously that working in the Fock space of operators, rather than that of states as is usually done, yields convergent results with computational resources that scale polynomially with $N$. We demonstrate the polynomial scaling by applying the OOPEX to the nonintegrable Ising chain and comparing with ED and high-temperature expansion (HTX) results. The OOPEX provides access to much larger $N$ than ED and HTX do, which facilitates overcoming finite-size effects that plague the other methods to extract correlation lengths in chaotic eigenstates. In addition, access to large systems allows us to test a recent conjecture that the Renyi entropy of chaotic eigenstates has positive curvature if the Renyi index is greater than 1, and we find encouraging supporting evidence.

Topological or rotational non-Abelian gauge fields from Einstein-Skyrme holography

We report analytically known states at non-zero temperature which may serve as a powerful tool to reveal common topological and thermodynamic properties of systems ranging from the QCD phase diagram to topological phase transitions in condensed matter materials. In the holographically dual gravity theory, these are analytic solutions to a five-dimensional non-linear-sigma (Skyrme) model dynamically coupled to Einstein gravity. This theory is shown to be holographically dual to mathcal{N} = 4 Super-Yang-Mills theory coupled to an SU(2)-current. All solutions are fully backreacted asymptotically Anti-de Sitter (AdS) black branes or holes. One family of global AdS black hole solutions contains non-Abelian gauge field configurations with positive integer Chern numbers and finite energy density. Larger Chern numbers increase the Hawking-Page transition temperature. In the holographically dual field theory this indicates a significant effect on the deconfinement phase transition. Black holes with one Hawking temperature can have distinct Chern numbers, potentially enabling topological transitions. A second family of analytic solutions, rotating black branes, is also provided. These rotating solutions induce states with propagating charge density waves in the dual field theory. We compute the Hawking temperature, entropy density, angular velocity and free energy for these black holes/branes. These correspond to thermodynamic data in the dual field theory. For these states the energy-momentum tensor, (non-)conserved current, and topological charge are interpreted.

Development of Metal and Metal-Based Composites Anode Materials for Potassium-Ion Batteries

Potassium-ion batteries (KIBs) are considered the next powerful potential generation energy storage system because of substantial potassium resource availability and similar characteristics with lithium. Unfortunately, the actual application of KIBs is inferior to that of lithium-ion batteries (LIBs), in which the finite energy density, ordinary circular life, and underdeveloped fabrication technique dominate the key constraints. Various works have recently been directed to growing novel anode electrodes with superior electrochemical capability. Noticeably, metals/metal oxides materials (e.g., Sb, Sn, Zn, SnO2, and MoO2) have been widely investigated as KIBs anodes because of high theoretical capacity, suggesting outstanding promise for high-energy KIBs. In this review, the latest research of metals/metal oxides electrodes for potassium storage is summarized. The major strategies to control the electrochemical property of metals/metal oxides electrodes are discussed. Finally, the future investigation foreground for these anode electrodes has been proposed.