Fine Grain Research Articles

Influence of sub-zero coolant circulation and additive nanoparticles on performance characteristics of FSPed Al6061 alloy

ABSTRACT Al6061 alloy has become prevalent in the industrial sector because of its low density, excellent machinability, and corrosion resistance but it lacks properties like hardness and wear. Therefore, surface modifications by friction stir processing (FSP) are done with additive nanosized particles like multi-walled carbon nanotubes (MWCNT), Titanium oxide (TiO2), and Graphene nanoparticles (GNP) To perform 2-pass FSP, a uniquely engineered fixture with coolant circulated underneath the plate at sub-zero temperatures is used. Grain refinement has been observed in micrographs as a consequence of 2-pass FSP. The coolant circulated beneath carries the heat generated and enhances the heat dispersion rate, culminating in finer grains. The calculated mean grain size of the Al6061 alloy was considerably decreased in all the surface composites. There is a substantial improvement in the microhardness profile, which has increased by nearly 70–90%, as well as a significant enhancement in tensile strength of almost 20–30% in all the composites. The ductile type of failure during tensile load is revealed by SEM fractography. The process of dynamic recrystallisation is responsible for the development of equiaxed grains. The wear resistance of all the composites is also enhanced, and the COF of Al6061/GNP composite is found to be lowest at 0.23.

Achieving excellent bond strength and tensile strength synergy of ultrafine-grained Al/Cu bimetallic sheets developed by an innovative hybrid manufacturing process

In the present work, two new parameters that influence the bond strength and tensile strength of Al/Cu bimetallic sheets are explored using an innovative hybrid manufacturing process. The innovative hybrid manufacturing process includes engineering of four different microstructures, 1. Ultrafine grained (UFG); 2. Bimodal grained (BM); 3. Fine grained (FG) and 4. Coarse grained (CG) in parent Cu and Al via integration of cryogenic based thermo-mechanical treatment followed by an unique tailored criss-cross surface pattern generation and high deformation roll bonding to develop high performance Al/Cu engineered sheets with four microstructural combinations: UFG‐Al + UFG-Cu, UFG‐Al + BM-Cu, UFG‐Al + FG-Cu and CG‐Al + CG-Cu. The criss-cross pattern aids in initiation of crack at the junctions and fissure formations at cross paths during the roll bonding process. This kind of pattern develops mechanical bond in the form of nugget bunches, which result in enhancement of bond strength in all the microstructural combinations of Al/Cu bimetallic sheets. The ascending order of increase in bond strength-tensile strength synergy of all four engineered microstructural combinations is: CG‐Al + CG-Cu, UFG‐Al + FG-Cu, UFG‐Al + BM-Cu and UFG‐Al + UFG-Cu. The UFG‐Al + UFG-Cu combination has achieved an extraordinary bond strength of 18 N/mm, which is almost 1.6 times the bond strength of its conventional coarse grained counterpart CG‐Al + CG-Cu combination (10 N/mm). Similarly, the UFG‐Al + UFG-Cu combination showed excellent tensile strength of 323 MPa which is around 25 % higher than that of CG‐Al + CG-Cu combination (258 MPa). The engineered UFG microstructure in Al and Cu samples promote the dynamic recrystallization and partial diffusion kinetics at the interface region and established the mechanical and metallurgical bonding between Al/Cu bimetallic sheets during roll bonding process. The adopted surface pattern and the engineered microstructure have enhanced the bond strength and tensile strength of Al/Cu bimetallic sheets both at macro and micro levels. The underlying scientific knowhow for obtaining excellent bond strength-mechanical property synergy in the engineered Al/Cu bimetallic sheets are established.

Achieving high strength and ductility in Inconel 718: tailoring grain structure through micron-sized carbide additives in PBF-LB/M additive manufacturing

ABSTRACT Few attempts have been made so far to develop modifiers for in situ use in Inconel 718 PBF-LB/M fabrication. Reports show an increase in tensile strength compared to unmodified counterparts. However, significant ductility reduction is observed, outweighing the mere tensile strength improvements when considering practical applications. In this study, micron-sized powder modifiers (NbC, TiC, and B4C) were added in proportions of 0.6 wt.% (NbC and TiC) and 0.2 wt.% (B4C) to Inconel 718 powder for PBF-LB/M processing. These modifiers allowed for grain structure control during heat treatment, including hot isostatic pressing. The addition of NbC resulted in a finer grain structure, while the addition of TiC preserved the as-built grain structure after heat treatment. Carbide precipitates led to uniform GND distribution and promoted uniform stress distribution. We show that the trade-off between strength and ductility in carbide-modified IN718 can be overcome by careful PBF-LB/M processing and heat treatment.

Optimizing microstructure and strength of CMT-wire arc additive manufactured WE43 Mg alloy through a novel active cooling technique

Cold metal transfer (CMT)-Wire arc additive manufacturing (WAAM) has been widely utilized in the production of large Magnesium (Mg) alloy components. However, the thermal cycling and heat input inherent in the CMT-WAAM process can adversely affect the microstructure and properties of Mg-Rare earth (RE) alloys. Currently, there is a lack of effective, low-cost, and easy-to-implement methods to mitigate these issues. In this study, an active cooling technique (ACT) comprising base cooling and bypass cooling was proposed. The ACT facilitates in-situ cooling of CMT-WAAMed WE43 components through uninterrupted water flow in the substrate and bypass plate, offering advantages in cost-effectiveness, safety, and ease of implementation. It was found that the CMT-WAAMed WE43 alloy thin wall component manufactured with the ACT assistance had fewer hard-brittle eutectic phases and finer grains due to the accelerated cooling rate. ACT effectively reduced the heat accumulation and peak temperatures in the component. Furthermore, it inhibited the transformation of the β1 phase to the β phase and suppressed the coarsening of the β1 phase. ACT also improved the ultimate tensile strength (UTS), yield strength (YS), and elongation (EL) of the CMT-WAAMed WE43 component by 11.7 %, 5.8 %, and 72.3 %, respectively. This study provides a novel approach for the microstructure optimization of CMT-WAAMed Mg-RE alloy, which is crucial for the production of high-performance and large-size components in the aerospace industry.

Effect of fast frequency double pulse current on microstructural characteristics and mechanical properties of wire arc additively manufactured Ti-6Al-4V alloy

This study introduces an innovative technique known as fast-frequency double pulse wire arc metal additive manufacturing (FFDP-WAAM). This method employs periodic fluctuations in arc plasma and force to enhance the stirring effect within the molten pool, resulting in the fragmentation of β grains and the formation of finer prior-β grains. The microstructure primarily comprises α', attributed to the high cooling rates and minimal heat accumulation. Compared to the conventional gas tungsten arc welding-based WAAM (CGT-WAAM) process, FFDP-WAAM significantly reduces α-variant selection, thereby achieving a more uniform α phase orientation distribution. Additionally, ultrasonic vibration in the FFDP-WAAM process facilitates recrystallization and mitigates residual strain. The tensile strength and elongation of the FFDP-WAAM specimens reached 939.2 MPa and 9.0 %, respectively, whereas the CGT-WAAM specimens showed a lower tensile strength of 830 MPa and elongation of 9.2 %. The enhanced strength, fatigue life and microhardness of Ti-6Al-4V produced by FFDP-WAAM is ascribed to the refined grain-size distribution. Furthermore, the low Schmid factor (SF) distribution and the stable triangular structure of Category I α-clusters are anticipated to contribute to the increased strength of the FFDP-WAAM-fabricated wall.

Insight into layer formation during friction surfacing: Relationship between deposition behavior and microstructure

Friction surfacing (FS) is a solid state layer deposition technique with a simple setup, presenting advantages compared to fusion-based approaches. Previous investigations showed microstructural gradients along layer width and thickness. The current study provides new insight into the FS layer formation for aluminum and its relation with the microstructure evolution. Special consumable studs containing two different aluminum alloys were used to visualize the different materials in the resulting deposit. The investigation was performed at different process parameters, revealing some fundamental material flow characteristics. The layer center presents inner stud material, where advancing side and top are formed by outer stud material. The bottom and retreating side present a mixture of inner and outer stud material. The part of the layer that is formed by the outer material, presumably undergoes higher strain rates during deposition, presenting finer grains. The top of FS layers shows a pronounced texture, i.e. shear texture components, compared to the other parts with random texture. This phenomenon can be related to the shearing of the stud material between already deposited material below and the stud at its rear edge. Overall, the FS layer formation characteristics revealed in this study are directly related to local microstructural properties.

Investigation of mechanical and wettability properties of commercial pure titanium by surface mechanical attrition treatment

The examination of mechanical and wettability properties of commercial pure titanium (CP-Ti) introduced a novel challenge. The microstructure of samples was analyzed by using OM and SEM micro-images. In this study, the hardness of the surface and cross section of samples was evaluated, and the effect of several surface mechanical attrition treatments (SMATed) on samples was examined. Also, the tensile test was done to compare the effect of SMAT duration on mechanical properties of samples. The contact angle method was then employed to investigate the impact of SAMT duration on the wettability trend. According to results, as the treatment time increases, twins become evident in the deeper layers of the samples. In contrast, the near-surface twins are shorter than those found in the deeper material, signifying the presence of finer grains. Moreover, the elevated hardness in SMATed samples can be attributed to several key factors, including cold work, a rise in defects and twins, and grain refinement. The surface hardness increases across the sample series (up to Ti6) due to the substantial energy input. Nevertheless, it is anticipated that further continuation of the process will result in a constant surface hardness. The increased strength observed in SMATed samples can be attributed to factors such as reduction in grain size and the formation of twins. The wettability results show that the treated surfaces exhibited a significant change in wettability compared to the untreated samples, with a 25% reduction in the contact angle. This is attributed to the surface modifications induced by the treatment process, which introduced more hydrophilic functional groups. The results also show that after 4 h of treatment, the contact angle increases, suggesting that the trend may plateau with additional treatment time.

Influence of Zr addition on the microstructure, mechanical and electrical properties of Mo-Cu alloy

In order to strengthen the overall properties of Mo-Cu alloy, Zr was added to Mo-Cu alloy to enhance the bond strength of Mo/Cu interface and form solid solution strengthening effect. The excellent properties of Mo-Cu-Zr blocks were attained through infiltrating Cu-Zr blocks containing various Zr contents into the Mo skeleton. Compared to the incoherent interface of Mo/Cu in Mo-Cu block, the addition of Zr changed its interface to the coherent interface of Mo-Zr/Cu-Zr. All Mo-Cu-Zr alloy blocks possessed high densification degrees (97.1 %∼98.4 %) to assure the excellent general properties. Besides, the formations of Mo-Zr and Cu-Zr solid solutions assured the block owned excellent mechanical strength. Especially, the addition of Zr purified the grain boundary through absorbing oxygen to produce ZrO2 which prevented the Mo-Zr grain growth. As increasing Zr amount from 0 to 4.73 wt%, the Mo-Zr (or Mo) grain size reduced from 5 to 4.0 μm. Mo-Cu sintered sample containing 2.40 wt% Zr possessed the highest tension strength of 494 MPa. Besides, since the finer grain size of Mo-Zr alloy, this block also owned the highest micro-hardness (250 HV) and bending strength (1626 MPa), respectively. But, the generations of Cu-Zr solid-solution and ZrO2 also damaged the electrical conductivities to a certain extent. Specifically, as the addition amount of zirconium increased from 0 to 2.40 wt%, the conductivity decreased from 42.67 % to 32.15 %IACS.

Remanufacturing of low-carbon steel components using WAAM: microstructural, mechanical, and parametric analysis

This research paper investigates the remanufacturing of low-carbon steel components using wire-arc additive manufacturing (WAAM), aiming to enhance resource efficiency and sustainability in various industries. The study focuses on repairing flat plate test coupons with a pre-fabricated trapezoidal groove using GMAW-WAAM. The microstructural characteristics and mechanical performance of the repaired samples are compared to the base material, and the influence of heat treatment on the repaired parts is also examined. Planned experiments and empirical modeling are performed to analyze the impact of WAAM process parameters on mechanical properties, establishing correlations between parameters and desired performance characteristics. The WAAM-repaired plate demonstrates higher tensile strength and hardness due to strong bonding, and finer grain structure, while annealing reduces tensile strength and hardness. Additionally, the WAAM-repaired annealed plate exhibits improved elongation compared to the WAAM-repaired plate but remains lower than the base plate. Observations revealed that the strength, elongation, and hardness of repaired samples are influenced by WAAM parameters in complex ways, with favorable combinations yielding improved properties.

Establishing a process route for additive manufacturing of NiCu-based Alloy 400: an alignment of gas atomization, laser powder bed fusion, and design of experiments

Alloy 400 is a corrosion-resistant, NiCu-based material which is used in numerous industrial applications, especially in marine environments and the high-temperature chemical industry. As conventional manufacturing limits geometrical complexity, additive manufacturing (AM) of the present alloy system promises great potential. For this purpose, a robust process chain, consisting of powder production via gas atomization and a design of experiment (DoE) approach for laser powder bed fusion (LPBF), was developed. With a narrow particle size distribution, powders were found to be spherical, flowable, consistent in chemical composition, and, hence, generally applicable to the LPBF process. Copper segregations at grain boundaries were clearly detected in powders. For printed parts instead, low-intensity micro-segregations at cell walls were discovered, being correlated with the iterative thermal stress applied to solidified melt-pool-near grains during layer-by-layer manufacturing. For the production of nearly defect-free LPBF structures, DoE suggested a single optimum parameter set instead of a broad energy density range. The latter key figure was found to be misleading in terms of part densities, making it an outdated tool in modern, software-based process parameter optimization. On the microscale, printed parts showed an orientation of melt pools along the build direction with a slight crystallographic [101] texture. Micro-dendritic structures were detected on the nanoscale being intersected by a high number of dislocations. Checked against hot-extruded reference material, the LPBF variant performed better in terms of strength while lacking in ductility, being attributed to a finer grain structure and residual porosity, respectively.

Microstructural and mechanical properties of Al-5356 alloy structures fabricated using direct energy deposition (DED): In-pursuit to optimizing deposition parameters

Many industries including aerospace make extensive use of lightweight materials like aluminium alloys because of their extraordinary properties. Wire Arc Additive Manufacturing-Cold Metal Transfer (WAAM-CMT) as a part of modern direct energy deposition technique can be recommended for developing aerospace components of aluminium alloys. However, it is still necessary to investigate the impact of the combined change of developing parameters on some of the crucial qualities including metallurgical and mechanical properties. Therefore, in this part of research work, practically, various process parameters were tried for development of aluminium (Al-5356) alloy walls. Finaly, a specific set of parameters namely wire feed speed, scanning speed and inter layer temperature parameters with two levels of each were selected and with the assistance of these, four walls have been fabricated. Th preliminary analysis showed that low heat input accompanied by higher scanning speed of 60 cm/min and lower wire feed rate of 6 m/min was found to best suitable set of parameters for developing dimensionally stable Al wall with flaw less microstructure. The said set of parameters also showed higher hardness that also accompanied with finer grains, lower percentage towards high angle grain boundary and lower KAM. Even slight variation in these parameters that deal to high heat input can give rise of porosity and misalignment in the wall. Details of microhardness reported high hardness in the bottom part of the wall. However, in a single bead the hardness is higher in the top region, which may be owing to finer grains in the specified region. The above said set of parameters also able to deliver better tensile strength and toughness for Al-5356 alloy. The developed alloy showed improved strength in longitudinal orientation owing to intra layer failure with ductile mode of fracture in contrast to transverse orientation, where the failure mode was reported to mixed (ductile as well as brittle) owing to inter layer fracture.

Microstructural analysis and defect characterization of additively manufactured AA6061 aluminum alloy via laser powder bed fusion

AA6061 is a widely used aluminum alloy with significant applications in the aerospace and automotive industries. Despite its popularity, the utilization of additively manufactured AA6061 through the laser powder bed fusion (LPBF) process has been hindered by the pronounced formation of pores and cracks during rapid solidification. This study quantitatively investigated defects, including pores and cracks, and microstructures, including texture, grain size, subgrain structure, and precipitates, of LPBF-manufactured AA6061 across a broad spectrum of laser power and speed combinations. A high relative density of more than 99 % was achieved with a low-power and low-speed condition, specifically 200 W and 100 mm/s, with minimal cracks. Large pores, akin to or exceeding melt pool dimensions, emerged under either low or high energy densities, driven by the lack of fusion and vaporization/denudation mechanisms, respectively. Solidification cracks, confirmed by the fractography, were propagated along grain boundaries and are highly dependent on laser scanning speed. Elevated power and speed exhibited finer grain size with refined subgrain cellular structures and increased precipitates at interdendritic regions. The cooling rate and thermal gradient estimated from thermal analytical solutions explain the microstructures’ characteristics. Nano-sized Si-Fe-Mg enriched precipitates are confirmed in both as-built and heat-treated conditions, whereas T6 heat treatment promotes a uniform distribution with coarsening of those precipitates. The low-power and low-speed conditions demonstrated the highest yield strength, consistent with defect levels. A minimum of 102.3 % increase in yield strength with reduced ductility was observed after heat treatment for all examined conditions. This work sheds light on printing parameters to mitigate the formation of pores and cracks in additively manufactured AA6061, proposing a process window for optimized fabrication and highlighting the potential for enhanced material properties and reduced defects through process control.

Study on asymmetric forming and performance strengthening mechanisms of 6061-T6 aluminum alloy joints fabricated by oscillating laser based on keyhole characteristics and molten pool dynamic behaviors

The study intends to unravel the processes behind the particular forming and performance improvement of 6061-T6 aluminum alloy joints by getting a thorough understanding of keyhole features and dynamical characteristics of molten pools during the laser welding with circular oscillation (C-OLW) process. The C-OLW experiments were carried out considering the pivotal parameters, including oscillation frequency (f) and amplitude (A), and their impacts on joint formation, microstructure, and performance were analyzed. Increasing f from 200 Hz to 300 Hz results in a more homogeneous and centered laser energy distribution, reducing weld breadth and the maximum depth. Raising A from 1.2 mm to 1.5 mm concentrated energy along the workpiece surface, increasing weld breadth but decreasing the maximum weld depth. A three-dimensional transient numerical model was established and verified. The simulation results reveal that increasing f considerably improves keyhole stability by virtue of the beam's mixing effect on energy, resulting in a more evenly distributed temperature within the molten pool. The velocity of the beam's motion intensifies, leading to elevated local temperature and subsequently causing an escalation in splattering. When A grows, keyhole stability reduces, as does the intensity of molten pool flow. The major effect of increased frequency is refining the grain size while increasing amplitude primarily promotes the columnar-to-equiaxed transition (CET) process. The extracted results of temperature distribution illustrate that an increase in f leads to an increase in the solidification rate (R), and temperature gradient values (G) are similar or higher along the same isotherm. Therefore, the G/R ratio rises, promoting the formation of finer microstructures. Although increasing A diminishes G, the reduced overall temperature and molten pool volume contribute to the rise in R. Consequently, the G/R ratio declines, fostering equiaxed grain growth, in line with experimental observations. A higher G value on the left side corresponds to finer grain structures, corroborating experimental findings via Electron Backscatter Diffraction (EBSD). The keyhole stability and microstructure characteristics explain why increasing f or A can enhance joint performance. The research reveals that strategically augmenting both oscillation frequency and amplitude enables the achievement of enhanced performance in 6061-T6 aluminum alloy joints.

Effect of Pouring Temperature Variation on Cooling Rate, Hardness and Microstructure of Al-Zn in Aircraft Structures

Al-Zn alloys are widely utilized in industries such as automotive, aircraft manufacturing, and advanced military equipment due to their exceptional strength-to-weight ratio. Among various fabrication methods, metal casting is a commonly used technique for producing structural components from these alloys. However, a significant challenge with metal casting is the reduction in mechanical properties compared to the base material before melting. This reduction highlights the need for research to identify the optimal casting conditions, particularly the casting temperature, which plays a crucial role in maintaining and potentially enhancing the material's mechanical properties. Aluminum alloy 7075, known for its high strength, was selected for investigation. According to the Al-Zn phase diagram, the melting point of aluminum alloy 7075, based on the weight percentage specified by the Standard Aluminum Association, is approximately 660°C. Experiments were conducted by varying the pouring temperature during casting in 30°C increments above this melting point. Specifically, the alloy was melted and cast at three different temperatures: 690°C, 720°C, and 750°C. The mold temperature was consistently maintained at 220°C to isolate the effects of the pouring temperature. Results indicate that increasing the casting temperature significantly affects the alloy's microstructure and mechanical properties. As the casting temperature increases, the cooling rate decreases, leading to a finer grain structure. This finer grain size directly contributes to an increase in hardness, suggesting that higher casting temperatures can enhance the mechanical properties of Al-Zn alloys. These findings emphasize the importance of precise control over casting temperatures to optimize the performance characteristics of aluminum alloy 7075 in high-strength applications.

A study integrating in-process thermal signatures, microstructure, and corrosion behaviour of AISI 316L coatings on low carbon steel substrate deposited by laser-directed energy deposition (L-DED)

Surface coating through Laser Directed Energy Deposition (L-DED) of AISI 316L on low-carbon steel was carried out by varying laser fluence. The resulting melt pool characteristics, obtained through IR pyrometer, played a significant role in evolution of the microstructure. A higher heat input resulted in an equiaxed grain structure with finer grain sizes and improved deposition quality. The quantitative phase analysis revealed the presence of a dominant austenite phase and a secondary ferrite phase, along with traces of molybdenum carbide. Corrosion analysis reveals improved resistance at a higher laser fluence, attributed to increased content of corrosion-resistant alloying elements (Mo, Cr) and predominance of the austenite phase. Electrochemical Impedance Spectroscopy (EIS) confirms a higher corrosion resistance at a higher laser fluence, supported by a significantly higher polarization resistance and presence of a duplex-structured passive film. Results indicate that moderate laser fluence levels, ranging from 5 to 7.5 kJ/cm2, accompanied by medium to high thermal signatures and moderate cooling rates, yield coatings with refined microstructures, enhanced mechanical strength, and corrosion resistance. For superior corrosion resistance, a laser fluence of 10 kJ/cm2 is recommended, although careful consideration of its potential impact on mechanical properties is advised.

Microstructural and Magnetic Characteristics of Nanocrystalline Sm4ZrFe33 Alloys

This work focuses on the study of the microstructure and magnetic properties of nanocrystalline powders of Sm4ZrFe33, prepared by high‐energy ball milling. The Sm4ZrFe33 compound adopts a monoclinic structure (space group Cm). Upon annealing, these Sm4ZrFe33 samples exhibit notable variations in their extrinsic magnetic properties, closely linked to temperature fluctuations. The investigation delves into the correlation between morphology, grain size and magnetic characteristics. A significant enhancement in coercivity (Hc), remanent magnetization (Mr), and maximum energy product ((BH)max) is observed, primarily attributed to the finer grain structure present in the samples. Particularly noteworthy, among all annealed specimens, the nanocrystalline Sm4ZrFe33 compound annealed at a temperature of Ta = 973 K demonstrates the most promising magnetic properties. This specimen exhibits a coercivity Hc of 18 500 Oe, remanent magnetization (Mr) of 58 emu g−1, maximum energy product ((BH)max) of 5.18 MGOe, Curie temperature (TC) of ≈804 K, and magnetic anisotropy field (Ha) of 115 980 Oe. These research findings pave the way for future investigations and applications in the realm of permanent magnets, spintronic devices, and magnetic recording, utilizing nanocrystalline alloys based on the Sm4ZrFe33 compound.

Melt Pool Flow Dynamics of Copper Imbued Surface Alloyed 304 Stainless Steel: Role of Laser Power and Scanning Speed Tuning

This study emphasizes the crucial role of Marangoni convection in the laser surface-alloying of 304 stainless steel (304 SS) with copper (Cu). By studying the microscopic behavior of the melt pool during CO2 laser alloying, the study reveals the association between Marangoni convection and the resulting microstructure. The findings demonstrate that the most optimum deposited track can be observed at power 80 W with a scanning speed of 0.4950 mm/s while the highest scanning speed of 0.6329 mm/s produced the finest grains. From the microhardness analysis, sample with the scanning speed of 0.6329 mm/s yielded the best microhardness due to fast cooling and solidification, highlighting the importance of controlling the process parameters to achieve the desired outcome. This data provides valuable insights into the laser-matter interaction and underscores the need to understand underlying melt pool flow dynamics mechanisms such as Marangoni convection to optimize the process for high-quality results.

Influence of grain size and grain edge phase on the flexural strength of aluminum nitride ceramics with Y2O3 sintering additive

The necessity for efficient heat dissipation compels AlN packaging materials towards a thinner profile. In response to the ensuing concerns regarding the reliability of strength, the effects of the grain edge phases and grain size on flexural strength are investigated in this study. Different preparation processes, including (hot-pressed sintering, pressureless sintering, and annealing) are employed to prepare AlN ceramics with different grain edge phases and grain sizes. After classifying the morphology of the grain edge phases and fitting the Hall-Petch relationship, it is found that the grain edge phases had a more significant influence on the flexural strength. Depending on the morphology, the negative effects can be divided into three degrees. While the finer grain size proves advantageous for the flexural strength. Consequently, in the non-additive system, the flexural strength of AlN ceramic is 422 MPa, with an average grain size of 8.47 μm. For the additive-doped system, the maximum flexural strength can reach 532 MPa, which can be attributed to the limited average grain size resulting from the hot-pressed sintering process, approximately 1.32 μm. These results could potentially be employed in the microstructural design of high-strength AlN ceramics.

Forming mechanism of a novel shape-surface integrated incremental sheet forming process for fabricating parts with enhanced surface functionality

Metallic components with surface microfeatures are increasingly used in aerospace, automotive and other applications due to their drag-reducing properties. In this situation, we proposed a novel shape-surface integrated incremental sheet forming (S2-ISF) process to achieve the simultaneous fabrication of both surface microfeatures and desired geometric shape. It was found that an increase in the forming angle was most effective in improving the formation of microgroove array, followed by the step size, the spindle speed and the feed rate. Moreover, when the forming angle is constant, the step size and microgroove pitch increase linearly. Compared to the as-received sheet, the yield strength is increased by more than 20% after the S2-ISF process. Moreover, we observed that the increase of forming angle in the S2-ISF process has promoted grain deformation and grain fragmentation, which is favorable for the formed part to obtain more uniform and finer grains. The grain size distribution along the thickness direction shows the characteristics of ‘coarse in the middle and fine at both ends’. Finally, we found that the formed parts with different microgroove pitch from the S2-ISF process have the significant enhancement on the hydrophobicity and anti-friction property. When microgroove pitch is 155.5 μm, the surface contact angle of formed part improved from 70.65° to 101.39°, and the wear volume of formed part decreases from 4.89 × 10−3 mm3 to 3.65 × 10−3 mm3. This work provides a solution for the efficient and economical fabrication of three-dimensional thin-walled parts with microgroove array to enhance surface functionality.

Ultra-high hard and fracture-resistant multi-phase nanocrystalline AlCrFeMoNbNi multi-principal element alloy

Multi-phase nanocrystalline AlCrFeMoNbNi multi-principal element alloy was developed using mechanical alloying followed by spark plasma sintering. Mechanical alloying resulted in a two-phase microstructure (BCC and FCC), whereas subsequent sintering resulted in a multi-phase microstructure consisting of FCC, Rhombohedral and B2 phases. Extremely high hardness values in the range of 35.79–16.05 GPa were measured as a function of indentation load between 25 and 5000 g. A highly pronounced indentation size effect was observed. From classic Nix-Gao analysis, a load independent hardness of 13.82 GPa was estimated. The high hardness arises from a combination of finer grain size and solid solution strengthening (FCC phase) and multi-phase structure consisting of B2 and Rhombohedral phases. The major phase being FCC (83%) offers nearly 85% of the total flow stress realized for this MPEA and the remaining 15% of the flow stress must be arising from both the B2 and Rhombohedral phases. It is to be noted that the phase fractions of B2 and Rhombohedral phases are 10% and 7% respectively. Indentation fracture toughness, evaluated using the cracks developed during Vickers indentation, yielded encouraging numbers in the range 12.28–13.85 MPam. The excellent combination of ultra-high hardness and indentation fracture toughness of this AlCrFeMoNbNi MPEA surpasses the reported data on several related harder materials, including silicides, nitrides, carbides, etc.