Fine Structure Research Articles

A sense of seaweed: Consumer liking of bread and spreads with the addition of four different species of northern European seaweeds. A pilot study among Swedish consumers.

Current food systems pose one of the greatest health and environmental challenges of the 21st century. Expanded utilization of seaweed for food in Western societies seems like one promising measure in the transition toward sustainable food systems. However, introducing and expanding seaweed to new markets brings certain challenges, such as limited food acceptance and availability. In this pilot consumer study, four common northern European seaweed species (Saccharina latissima, Alaria esculenta, Palmaria palmata, and Ulva sp.) were introduced into two complementary plant-based products (bread and spread), which were presented to consumers (n=49 (bread), n=52 (spread)) in a Swedish setting. The consumers’ liking of the products was evaluated based on a 9-point hedonic scale, and the product characteristics were determined by texture, pH, and color analysis. Whereas the different spreads’ pH was similar, the texture and color overall varied more between the different samples. Overall, the consumers slightly liked the two seaweed-containing products, with taste/flavor and texture being main contributing factors to the consumers’ liking. For the bread, S. latissima was liked best as a supplement. S. latissima and A. esculenta were liked best for the spread, whereas P. palmata received the lowest scores. The preference for brown seaweeds may relate to their relatively more neutral taste/flavors and finer structure, whereas the lower scores for P. palmata may be explained by its marine-associate flavors and coarser structure. The studied consumer liking of seaweed-based products can become valuable for developing and improving future seaweed products and increasing their availability in Western food cultures.

A recombinant amylomaltase from Thermus thermophilus STB20 can tailor the macromolecular characteristics of tapioca starch through its transglycosylation activity

Amylomaltase (AM) is a transglucosylase known for producing glucans exclusively with α-1,4 linkages, which is widely used in the industries for modification of starch. In this paper, a study was conducted to investigate both the characteristics of recombinant amylomaltase from Thermus thermophilus STB20 (TtAM) and its impact on the fine structure of tapioca starch. The TtAM showed an excellent thermostability and a high affinity for larger molecular substrates. Changes in the molecular characteristics of tapioca starch were discussed in terms of chain length distribution (CLD) and molecular weight distribution (Mw) under different enzyme dosages and reaction times. The TtAM degraded amylose, which was transferred to short side chains (DP 11-26) of amylopectin, thereby extending short side chains into longer chains (DP >26). The Mw of TtAM-treated starches initially increased and then decreased. With increasing enzyme dosage and reaction time, the TtAM facilitated hydrolysis activities, reducing the proportion of long side chains, which led to increase the dextrose equivalent (DE) value. Cycloamylose (DP 8 - 33) was generated during the modification process, reflecting a diversified range of the enzyme products, and resulting in a polymodal distribution profile in the Mw. These findings potentially broaden the utilization of TtAM in the production of starch conversion products, indicating that novel starch-based derivatives with tailor-made structures can be obtained by controlling the enzyme dosages and reaction times.

Resolution Dependence of Extreme Wind Speed Projections in the Great Lakes Region

Abstract The effect of anthropogenic climate change on extreme near-surface wind speeds is uncertain. Observed trends are weak and difficult to disentangle from internal variability, and model projections disagree on the sign and magnitude of trends. Standard coarse-resolution climate models represent the fine structures of relevant physical phenomena such as extratropical cyclones (ETCs), upper-level jet streaks, surface energy fluxes, and land surface variability less skillfully than their high-resolution counterparts. Here, we use simulations with the NCAR Community Earth System Model with both uniform (110 km) resolution and the variable-resolution configuration (VR-CESM-SONT, from 110 to 7 km) to study the effect of refined spatial resolution on projections of extreme strong and weak wind speeds in the Great Lakes region under end-of-century RCP8.5 forcing. The variable-resolution configuration projects strengthening of strong-wind events in the refined region with the opposite occurring in the uniform-resolution simulation. The two configurations provide consistent changes to synoptic-scale circulations associated with high-wind events. However, only the variable-resolution configuration projects weaker static stability, enhanced turbulent vertical mixing, and consequentially enhanced surface wind speeds because boundary layer dynamics are better captured in the refined region. Both models project increased frequency of extreme weak winds, though only VR-CESM-SONT resolves the cold-season inversions and summertime high temperatures associated with stagnant wind events. The identifiable mechanism of the changes to strong winds in VR-CESM-SONT provides confidence in its projections and demonstrates the value of enhanced spatial resolution for the study of extreme winds under climate change. Significance Statement In this study, we compare climate change projections of high and low extreme wind speeds in the Great Lakes region between a standard coarse-resolution simulation and a high-resolution simulation performed using the same climate model. The fine-resolution simulation projects strengthening high wind speeds, opposite to the coarse-resolution simulation. Both project increasing frequency of extreme weak winds, but the human-health-related impacts of stagnant winds are only captured at fine resolution. The changes in the coarse-resolution simulation are explained by changes to large-scale circulation, while the fine-resolution changes are linked to local processes the coarse model does not resolve. This helps explain the diverging projections of strong winds and gives greater credibility to the fine-resolution simulation.

Radiative and mechanical energies in galaxies. I. Contributions of molecular shocks and PDRs in 3C 326 N

Atomic and molecular lines emitted from galaxies are fundamental tracers of the medium responsible for the emission and contain valuable information regarding the energy budget and the strength of the different feedback mechanisms. The goal of this work is to provide a new framework for the interpretation of atomic and molecular lines originating from extragalactic sources and a robust method to deduce the mechanical and radiative energy budget from a set of observations. Atomic and molecular lines detected in a given object are assumed to result from the combination of distributions of shocks and photo-dissociation regions (PDRs) within the observational beam. The emission of individual structures is computed using the Paris-Durham shock code and the Meudon PDR code over a wide range of parameters. The total emission is then calculated assuming probability distribution functions for shocks and PDRs. A distance between the observational dataset and the model is finally defined based on the ratios of the observed to the predicted intensities. As a test case scenario, we consider the radio galaxy 3C 326 N. The dataset is composed of 12 rotational and ro-vibrational lines of and the fine structure lines of C$^+$ and O. Our interpretative framework shows that both shocks and PDRs are required to explain the line fluxes. Surprisingly, viable solutions are obtained at low density only ($ n_H < 100 $), indicating that most of the emission originates from diffuse interstellar matter. The optimal solution, obtained for $ n_H = 10 $, corresponds to a distribution of low-velocity shocks (between $5$ and $20$ km s$^ $) propagating in PDR environments illuminated by a UV radiation field ten times larger than that in the solar neighborhood. This solution implies that at least 4<!PCT!> of the total mass carried by the PDRs is shocked. The 0-0 S(0) $28 CII and OI lines originate from the PDR components, while all the other lines are mostly emitted by shocks. The total solid angles sustained by PDRs and shocks imply that the radiative and mechanical energies reprocessed by these structures are $ L UV L_ odot $ and $ L K L_ odot $, respectively, in remarkable agreement with the values of the IR luminosity deduced from the fit of the spectral energy distribution (SED) of 3C 326 N, and consistent with a small fraction of the active galactic nuclei (AGN) jet kinetic power dissipated in the interstellar medium ($ 1$<!PCT!>). This work shows that the radiative and mechanical energy budget of galaxies can be derived from the sole observations of atomic and molecular lines. It reveals the unexpected importance of the diffuse medium for 3C 326 N, in contrast to previous studies. A last-minute comparison of the model to new JWST data obtained in 3C 326 N shows a striking agreement and demonstrates the ability of the model to make accurate predictions. This framework opens new prospects for the prediction and interpretation of extragalactic observations, in particular in the context of JWST observations.

A novel AlCo1.2Cr0.8FeNi2.1 eutectic high entropy alloy with excellent corrosion resistance

A novel AlCo1.2Cr0.8FeNi2.1 eutectic high entropy alloy (EHEA) was designed and prepared. The microstructure of the as-cast alloy was characterized that a fine lamellar structure composed of FCC (L12) phase and B2 phase. The mechanical of the EHEA was studies by the tensile tests, and the corrosion properties of the EHEA in 3.5 wt% NaCl solution at room temperature was investigated. The results shown that the alloy exhibits synergistic effect of strength- plasticity with a high tensile strength of 1048.42 MPa and an excellent elongation of 18.92%. Potentiodynamic polarization test and electrochemical impedance spectroscopy (EIS) indicated that the EHEA exhibits spontaneous passivation in 3.5 wt% NaCl solution, forming a protective passive film that exhibits p-type and n-type semiconductor properties, with the main components of Al2O3, CoO, Cr2O3, Fe(OH)3, and NiO. Furthermore, the corrosion mechanism of EHEA was discussed.

The enigma of fine mobile structures on the aortic surface in a patient undergoing transcatheter aortic valve replacement - A case report

Abstract Background The surface of the aorta generally does not show motion unless mobile atheroma, thrombi, vegetations or intimal flaps are present. We previously described unusual mobile filamentous structures in the carotid artery. Here, we describe similar findings in the aorta and their possible cause. Case Summary An 88-year-old female with progressive exertional dyspnea and severe aortic stenosis (AS) had a successful trans-catheter aortic valve replacement (TAVR). A filamentous structure was noted on the focused pre-operative 2D TEE in the proximal descending aorta and post-TAVR as long strand-like structures attached to the thickened intimal wall with a planar component on 3D imaging. These findings were not associated with symptoms or clinical sequelae on short and long-term follow-up. Discussion The mobile structures that we describe are atypical for atheroma, thrombi, vegetations, and dissections in terms of their form and clinical presentation. 2D imaging showed that the filaments had focal thickening and emerged from the aortic surface. These findings suggest a relationship with the intima, perhaps from atherogenesis or injury with disruption or lifting of the intimal surface. No clinical sequelae were detected which may also relate to their position in the descending aorta and not the arch.

An Analysis of a Coarse-Group Subgroup Method Based on the Physical Probability Tables in APOLLO3®

The legacy subgroup method of the APOLLO3® code, denoted the SG-GR-383g method in this paper, relies on the fine structure equation solved by the means of the General Resonance model and of the mathematical probability tables (MPTs) that are computed on the fly for the resonant mixture. Because of the use of these MPTs, a fine energy structure of 383 groups has to be employed. In our recent work, with the intention of decreasing computational time, a subgroup method adapted to coarse-group calculations has been implemented in APOLLO3. It is based on the use of physical probability tables (PPTs), taking into account the mixture treatment, and on the Intermediate Resonance model to derive the subgroup equations, as well as the application of the Superhomogenization correction to ensure the preservation of the reaction rates in a multigroup calculation. This method, denoted SG-IR-69g in this paper, uses a 69-coarse-group energy mesh. This paper presents a comparison of the SG-IR-69g method with the legacy SG-GR-383g method, taking as reference the continuous-energy Monte Carlo TRIPOLI-4® calculations on test cases of 3 × 3 pin cells, with a central cell being either a water hole or a Gd-UO2 pin cell surrounded by UO2 pin cells. Similar accuracy on the multiplication factor was obtained for both the SG-GR-383g and SG-IR-69g methods, although more error compensations were found in the multigroup reaction rates of the latter. Even though the calculation of PPTs is more expensive than that of the mathematical ones, overall the SG-IR-69g method is more time efficient thanks to the decrease in the number of energy groups.

Photon-counting detector CT - first experiences in the field of musculoskeletal radiology.

The introduction of photon-counting detector CT (PCD-CT) marks a remarkable leap in innovation in CT imaging. The new detector technology allows X-rays to be converted directly into an electrical signal without an intermediate step via a scintillation layer and allows the energy of individual photons to be measured. Initial data show high spatial resolution, complete elimination of electronic noise, and steady availability of spectral image data sets. In particular, the new technology shows promise with respect to the imaging of osseous structures. Recently, PCD-CT was implemented in the clinical routine. The aim of this review was to summarize recent studies and to show our first experiences with photon-counting detector technology in the field of musculoskeletal radiology.We performed a literature search using Medline and included a total of 90 articles and reviews that covered recent experimental and clinical experiences with the new technology.In this review, we focus on (1) spatial resolution and delineation of fine anatomic structures, (2) reduction of radiation dose, (3) electronic noise, (4) techniques for metal artifact reduction, and (5) possibilities of spectral imaging. This article provides insight into our first experiences with photon-counting detector technology and shows results and images from experimental and clinical studies. · This review summarizes recent experimental and clinical studies in the field of photon-counting detector CT and musculoskeletal radiology.. · The potential of photon-counting detector technology in the field of musculoskeletal radiology includes improved spatial resolution, reduction in radiation dose, metal artifact reduction, and spectral imaging.. · PCD-CT enables imaging at lower radiation doses while maintaining or even enhancing spatial resolution, crucial for reducing patient exposure, especially in repeated or prolonged imaging scenarios.. · It offers promising results in reducing metal artifacts commonly encountered in orthopedic or dental implants, enhancing the interpretability of adjacent structures in postoperative and follow-up imaging.. · With its ability to routinely acquire spectral data, PCD-CT scans allow for material classification, such as detecting urate crystals in suspected gout or visualizing bone marrow edema, potentially reducing reliance on MRI in certain cases.. Bette S, Risch F, Becker J et al. Photon-counting detector CT - first experiences in the field of musculoskeletal radiology. Fortschr Röntgenstr 2024; DOI 10.1055/a-2312-6914.

Secular structure of 1:2 and 1:3 mean motion resonances with Neptune

The 1:N mean motion resonances (MMRs) with Neptune are of particular interest in astrophysical research because they have two asymmetric resonance islands, where the distribution of trapped objects may bear important clues to resolving the history of the Solar System. To explore the dynamics of these resonances and to investigate whether the imprints left by the early stage evolution can be preserved in the resonances, we conducted a comprehensive analysis of the 1:2 and 1:3 resonances. By mainly adopting the frequency analysis method, we calculated the proper frequencies of the motion of objects in the resonances and determined the secular mechanisms that influence the dynamics. Using the spectral number (SN) as an indicator of orbital regularity, we constructed dynamical maps on representative planes. After comparing the structures in the maps with the locations of the secular mechanisms, we find that the von-Zeipel-Lidov-Kozai mechanism and the $g=2s$ mechanism destabilize the influenced orbits and thus sculpt the overall structure of the 1:2 and 1:3 resonances. The secular resonance of $2g-s=s_8$ opens a channel for objects to switch between the leading and trailing resonance islands, which can alter the population ratio between these two islands. The secondary resonances associated with the quasi 2:1 resonance between Uranus and Neptune were also detected, likely introducing more chaos to the motion. The fine dynamical structures of the 1:2 and 1:3 resonances revealed in this paper, combined with knowledge of resonant capture, provide a compelling explanation for the eccentricity distribution of observed Twotinos. Furthermore, we anticipate a more complete understanding of the history of planetary migration in the Solar System can be achieved by comparing the results in this paper with the populations in the 1:N resonances, with forthcoming observations offering more objects for study in the future.

Internal magnetic field structures observed by PSP/WISPR in a filament-related coronal mass ejection

We investigated the coronal mass ejection (CME) related to an eruptive filament over the southwestern solar limb on December 8, 2022, at around 8 UT. We tracked localized density enhancements reflecting the magnetic structures using white-light data taken with the Wide-field Instrument for Solar PRobe (WISPR) aboard the Parker Solar Probe (PSP). We aim to investigate the 3D location, morphology and evolution of the internal magnetic fine structures of CMEs. Specifically, we focused on the physical origin of the features in the WISPR images, how the white-light structures evolve over time, and their relationship with the source region, filament, and the flux rope. The fast tangential motion of the PSP spacecraft during its perihelion permits a single event to be viewed from multiple angles in short times relative to the event's evolution. Hence, three-dimensional information of selected CME features can be derived from this single spacecraft using triangulation techniques. We grouped small-scale structures with roughly similar speeds, longitude, and latitude into three distinct morphological groups. We found twisted magnetic field patterns close to the eastern leg of the CME that may be related to "horns" outlining the edges of the flux-rope cavity. We identified aligned thread-like bundles close to the western leg, and they may be related to confined density enhancements evolving during the filament eruption. High density blob-like features (magnetic islands) are widely spread in longitude (sim 40°) close to the flanks and the rear part of the CME. We also note that the large-scale outer envelope of the CME, seen clearly from 1 AU, was not well observed by PSP. We demonstrate that CME flux ropes, apart from the blobs, may comprise different morphological groups with a cluster behavior; the blobs instead span a wide range of longitudes. This finding may hint at either the three-dimensionality of the post-CME current sheet (CS) or the influence of the ambient corona in the evolutionary behavior of the CS. Importantly, we show that the global appearance of the CME can be very different in WISPR (0.11--0.16 AU) and the instruments near 1 AU because of the shorter line-of-sight integration of WISPR.

Spin-orbit torque driven domain wall motion in the absence of Dzyaloshinskii-Moriya interactions

Abstract The fine structure and dynamics of magnetic domain walls in ultrathin films with perpendicular magnetization, in presence of a secondary anisotropy, is analysed owing to micro-magnetics. Two cases are considered, a cubic anisotropy typical for (111) oriented garnet epitaxial films, and an orthorhombic anisotropy as found in e.g. Co/W(110) films. The statics is solved first, showing that, in general, domain walls are not of the pure Bloch type. The dynamics under the spin Hall effect induced by a current flowing in an adjacent layer is then monitored. Finite and non-negligible domain wall velocities are predicted in both cases, in the absence of Dzyaloshinskii-Moriya interactions, with distinct behaviours regarding the current density and its orientation with respect to the secondary anisotropy axes. The relevance of these results to recent reports of current driven domain wall dynamics in insulating ultrathin garnet films, capped with platinum, is discussed.

The Electric Properties of the Magnetopause Boundary Layer

The magnetopause plays a pivotal role in the coupling among solar wind, the magnetosheath, and the magnetosphere. By analyzing magnetopause crossing events using MMS, we reveal a local non-neutrality of electric charges in the magnetopause boundary layer and the associated electric field. There are two types of electric structures. In one group, which typically occurs on the dusk side, the electric field directs towards the Earth. In the other, which generally occurs on the day side, the field directs away from the Earth. The spatial extent of this electric non-neutrality spans approximately 600 km, which is at the scale of ion gyrational motion. These findings provide valuable insights into the fine structures of the magnetopause and the coupling between the magnetosheath and the magnetosphere.

The Rapid Decline in Interaural-Time-Difference Sensitivity for Pure Tones Can Be Explained by Peripheral Filtering.

The interaural time difference (ITD) is a primary horizontal-plane sound localization cue computed in the auditory brainstem. ITDs are accessible in the temporal fine structure of pure tones with a frequency of no higher than about 1400Hz. How listeners' ITD sensitivity transitions from very best sensitivity near 700Hz to impossible to detect within 1 octave currently lacks a fully compelling physiological explanation. Here, it was hypothesized that the rapid decline in ITD sensitivity is dictated not by a central neural limitation but by initial peripheral sound encoding, specifically, the low-frequency (apical) portion of the cochlear excitation pattern produced by a pure tone. ITD sensitivity was measured in 16 normal-hearing listeners as a joint function of frequency (900-1500Hz) and level (10-50dB sensation level). Performance decreased with increasing frequency and decreasing sound level. The slope of performance decline was 90dB/octave, consistent with the low-frequency slope of the cochlear excitation pattern. Fine-structure ITD sensitivity near 1400Hz may be conveyed primarily by "off-frequency" activation of neurons tuned to lower frequencies near 700Hz. Physiologically, this could be realized by having neurons sensitive to fine-structure ITD up to only about 700Hz. A more extreme model would have only a single narrow channel near 700Hz that conveys fine-structure ITDs. Such a model is a major simplification and departure from the classic formulation of the binaural display, which consists of a matrix of neurons tuned to a wide range of relevant frequencies and ITDs.

Photoacoustic/ultrasound dual-modal imaging of human nails: A pilot study

Traditional diagnostic techniques including visual examination, ultrasound (US), and magnetic resonance imaging (MRI) have limitations of in-depth information for the detection of nail disorders, resolution, and practicality. This pilot study, for the first time, evaluates a dual-modality imaging system that combines photoacoustic tomography (PAT) with the US for the multiparametric quantitative assessment of human nail. The study involved a small cohort of five healthy volunteers who underwent PAT/US imaging for acquiring the nail unit data. The PAT/US dual-modality imaging successfully revealed the fine anatomical structures and microvascular distribution within the nail and nail bed. Moreover, this system utilized multispectral PAT to analyze functional tissue parameters, including oxygenated hemoglobin, deoxyhemoglobin, oxygen saturation, and collagen under tourniquet and cold stimulus tests to evaluate changes in the microcirculation of the nail bed. The quantitative analysis of multispectral PAT reconstructed images demonstrated heightened sensitivity in detecting alterations in blood oxygenation levels and collagen content within the nail bed, under simulated different physiological conditions. This pilot study highlights the potential of PAT/US dual-modality imaging as a real-time, noninvasive diagnostic modality for evaluating human nail health and for early detection of nail bed pathologies.

High-precision spectral inversions: Determining what is important for the accurate definition of incident radiation boundary conditions

Spectral inversions are used to analyse spectroscopic observations with the aim of deriving the physical properties of the observed plasma, such as the kinetic temperature, density, pressure, degree of ionisation, or macroscopic velocities. One of the key factors ensuring the high precision of the derived plasma properties is having accurately defined input parameters of the models on which spectral inversions rely. The illumination, which chromospheric and coronal structures receive from the solar surface (and corona), is one of the most crucial input parameters of these models. We do not perform spectral inversions in this work. Our aim is to study two important factors that contribute to the accurate definition of the incident radiation boundary conditions: the altitude above the solar surface and the dynamics of the illuminated plasma. This investigation takes into account a diverse range of solar structures from the high-rising eruptive prominences to low-lying spicules. To study the influence of the altitude and dynamics of the observed plasma on the incident radiation boundary conditions, we used geometrical principles valid for any spectral line. However, to demonstrate the strong impact of dynamics, we considered the specific case of narrow spectral lines of which are highly sensitive to the presence of velocities. We argue that the altitude of the illuminated plasma strongly influences the way we need to define the incident radiation boundary conditions to achieve the most accurate results. For low-lying structures, generally below 50,000 km, the incident radiation may need to be specified directly from the composition of the portion of the solar disc that illuminates them. For high-altitude structures, generally above 300,000 km, the fraction of the solar disc illuminating the analysed plasma is large enough to be realistically approximated by the composition of the entire disc. We also show that for the narrow spectral lines, such as the lines, the impact of dynamics on the incident radiation intensity and profile shapes starts from radial velocities of 30 km $. Such velocities are even exhibited by the fine structures of quiescent prominences and are easily exceeded in spicules or eruptive prominences. The two aspects of the incident radiation definition studied here are relevant for spectral inversions based on any kind of modelling approach. However, their impact on the precision of the results of spectral inversions is likely less significant than the impact of the choice of the complexity of the model geometry, for example.

Physicochemical Properties and Fine Structure of Starch in Jinong Xiangruan 1 and DGR1 Soft Rice Varieties Cultivated in Different Regions of China

Rice, a staple food for billions around the globe, is cultivated in numerous forms. Among them, soft rice is well known, which is characterized by its tender, creamy consistency and desirable texture. In this study, we examined the physicochemical properties and fine structure of starch from two soft rice varieties, Jinong Xiangruan 1 and DGR1, cultivated in different regions in China (Baodi District, Tianjin City; Liaoning Province; and Fengyang City, Anhui Province). The aim was to understand how amylopectin content (AC) influences rice quality. This research aims to bridge the knowledge gap regarding the role of amylopectin in determining rice’s adhesive consistency and viscosity. Significant regional differences were observed in yield components such as the number of grains per panicle, seed setting rates and 1000-grain weight, with Liaoning generally showing higher performance metrics compared to other regions. Physicochemical analysis highlighted that though glue consistency and taste values showed little regional variation, AC significantly influenced rice hardness and viscosity. Rapid Visco Analyzer (RVA) profile analysis further demonstrated distinct differences in viscosity characteristics, underscoring the regional impacts on starch behavior. Additionally, molecular weight distribution and amylopectin chain length analysis, conducted via SEC-MALLS-RI and ICS ion chromatography, revealed notable differences in starch composition across varieties and locations. The findings suggest that environmental conditions play a crucial role in defining starch characteristics and, consequently, the eating quality of rice. This provides valuable insights for breeding high-quality japonica rice with broad adaptability.

Extraction of Pithecellobium clypearia Benth polysaccharides by dual-frequency ultrasound-assisted extraction: Structural characterization, antioxidant, hypoglycemic and anti-hyperlipidemic activities

In this research, the extraction process of polysaccharides from Pithecellobium clypearia Benth (PCBPs) was optimized using dual-frequency ultrasound-assisted extraction (DUAE). The biological activities of PCBPs were investigated by in vitro antioxidant, hypoglycemic, and anti-hyperlipidemic assay. High-performance anion-exchange chromatography, high-performance gel permeation chromatography, SEM, UV–Vis spectroscopy, and FT-IR spectra were used to analyze the monosaccharide composition, molecular weight, microscopic morphology, and characteristic structure of PCBPs. The results showed that the maximum extraction rate of PCBPs was 9.90 ± 0.16% when the ultrasonic time was 8 min, the liquid-to-material ratio was 32 mL/g, and the ultrasonic power was 510 W. The PCBPs also possessed excellent in vitro antioxidant, hypoglycemic, and anti-hyperlipidemic activities. In addition, the average molecular weight of PCBPs was 15.07 kDa. PCBPs consisted of rhamnose, arabinose, galactose, glucose, xylose, mannose, and glucuronic acid, with the molar ratios of 11.07%, 18.54%, 48.17%, 10.44%, 4.62%, 4.96%, and 2.20%, respectively. Moreover, the results of SEM showed that PCBPs mainly showed a fine spherical mesh structure. The above studies provided a valuable theoretical basis for the subsequent in-depth study of PCBPs.

Floral morphology and development of Pteridophyllum racemosum Siebold & Zucc. (Papaveraceae)

ABSTRACT Papaveraceae are known for their often showy flowers and diverse morphologies. Pteridophyllum racemosum (Siebold & Zucc.) is the only member in the Pteridophylloideae within the Papaveraceae, and its phylogenetic position has long been controversial, and a comprehensive analysis of its floral morphology was lacking. Our study focuses on the floral morphogenesis of P. racemosum. Histological sections complemented with scanning electron microscopy allowed a detailed characterization of P. racemosum floral development including description of the vegetative morphology, showing (1) the fine structure of the unusual pinnate leaves; (2) the well-defined floral structure and disymmetry; (3) a series of landmarks in floral development stages, with emphasis on the development of the gynoecium. Interestingly, the P. racemosum floral architecture is similar to that of the proposed ancestral Papaveraceae flower supporting the phylogenetic placement of P. racemosum as an early branching lineage within the Papaveraceae. Our comprehensive overview adds to the colorful library of floral diversity in Papaveraceae, providing a solid base for comparative analyses.

Study on the performance of photothermal catalyzed carbon dioxide hydrogenation to CH4 over doped sodium tantalate-based perovskite catalysts

NaTaO3 (ABO3)-based catalysts with B-site substituted metals M= (Co, Ni, Fe, Ga, Ti) for photothermal-catalyzed carbon dioxide reduction hydrogenation to C1 products were prepared via a simple one-step hydrothermal method. The B-site metal doping catalysts exhibited excellent performance for the aimed photothermal catalytic reaction. Among them, the NaTa0.9Co0.1O3 was the most eye-catching catalyst with a stable crystal cell, an excellent heterojunction structure, and a bandgap structure for light absorption, The fine structure properties results in a low electron-hole recombination rate and high photoelectron transfer efficiency under light conditions. The suitable alkaline adsorption sites and thermal reduction properties also be the effective assistance for the catalytic process. The CO yield and CH4 yield of the NaTa0.9Co0.1O3 catalyst were 6.6 times and 120 times higher than those of the pure-phase NaTaO3, respectively, and the CH4 selectivity was up to 98% under the illumination condition of 300 ℃. For the photothermal hydrogenation reaction, thermal catalysis dominates the reaction, and light illumination promotes the generation and transfer of photogenerated electrons and improves the catalyst stability. The above studies show that NaTaO3 based perovskite has a great potential in the field of photothermal catalyzed carbon dioxide reduction.

R-matrix calculations for opacities: I. Methodology and computations

An extended version of the R-matrix methodology is presented for calculation of radiative parameters for improved plasma opacities. Contrast and comparisons with existing methods primarily relying on the distorted wave approximation are discussed to verify accuracy and resolve outstanding issues, particularly with reference to the opacity project (OP). Among the improvements incorporated are: (i) large-scale Breit–Pauli R-matrix calculations for complex atomic systems including fine structure, (ii) convergent close coupling wave function expansions for the (e + ion) system to compute oscillator strengths and photoionization cross sections, (iii) open and closed shell iron ions of interest in astrophysics and experiments, (iv) a treatment for plasma broadening of autoionizing resonances as function of energy-temperature-density dependent cross sections, (v) a ‘top-up’ procedure to compare convergence with R-matrix calculations for highly excited levels, and (vi) spectroscopic identification of resonances and bound (e + ion) levels. The present R-matrix monochromatic opacity spectra are fundamentally different from OP and lead to enhanced Rosseland and Planck mean opacities. An outline of the work reported in other papers in this series and those in progress is presented. Based on the present re-examination of the OP work, opacities of heavy elements might require revisions in high temperature-density plasma sources.