Retention Of Fine Particles Research Articles

Soil fluidisation induced by fine particles migration: Insights from the Shenzhen 2015 landfill landslide

Naturally completely decomposed granite (CDG) soil typically exhibits strain-hardening behavior under undrained shear conditions. Nevertheless, flow-type landslides are not uncommon in CDG landfills. This paper endeavors to address the observed contradiction by conducting a case study of the 2015 Shenzhen landslides. Based on field investigations, we propose a hypothesis for the initiation and evolution of flow-type landslides in CDG landfill slopes, termed ‘clay particle argillization, mud-water migration, and static liquefaction’. This hypothesis was verified by element-scale internal erosion tests and triaxial tests, and further elucidated by microscale particle analysis. It was observed that the internal erosion-induced removal of plastic fine particles and retention of low-plasticity fine particles from CDG soil promotes the sliding and reorganization of coarse granules under shear stress, thereby increasing the soil's susceptibility to fluidization under undrained conditions. The proposed hypothesis and experimental findings provide new insights into the instability and subsequent extensive runout of CDG landfills and analogous broadly graded landslides.

Long- and Intermediate-Term Ambient Particulate Pollution Is Associated with Increased Osteoarthritis Risk: A Population-Based Prospective Analysis.

Recent studies found the intrusion and retention of exogenous fine particles into joints, but epidemiological data for long- and intermediate-term exposure associations are scare. Here, all urban working, retired employee, and rural residents (16.78 million) in Beijing from January 1, 2011 to December 31, 2019 were included to investigate the effects of long- and intermediate-term ambient particulate exposure on development of osteoarthritis. We identified 1,742,067 participants as first-visit patients with osteoarthritis. For each interquartile range increase in annual PM2.5 (23.32 μg/m3) and PM10 (23.92 μg/m3) exposure concentration, the pooled hazard ratios were respectively 1.238 (95% CI: 1.228, 1.249) and 1.178 (95% CI: 1.168, 1.189) for first osteoarthritis outpatient visits. Moreover, age at first osteoarthritis outpatient visits significantly decreased by 4.52 (95% CI: 3.45 to 5.40) days per μg/m3 for annual PM2.5 exposure at below 67.85 μg/m3. Finally, among the six constituents analyzed, black carbon appears to be the most important component associated with the association between PM2.5 exposure and the three osteoarthritis-related outcomes.

Effects of carboxymethyl starch as a papermaking additive

Carboxymethyl starch (CMS) is a bio-based, anionic polymer that has potential as part of a dry-strength additive program for papermaking. Due to its negative charge, its effects can be expected to depend on its interactions with various cationic agents. In this work, the effects of CMS were observed following its sequential addition after one of three selected cationic strength agents at different dosage levels. In selected tests, the furnish was pretreated at the 1% level by a dispersant, sodium polyacrylate, which might represent a high level of anionic contaminants in a paper mill system. Laboratory tests were conducted to show the effects on dewatering, fine-particle retention, and flocculation. These tests were supplemented with measurements of charge demand, zeta potential, and handsheet properties. Sequential addition of cationic glyoxylated acrylamide copolymers (gPAM) and CMS were found to strongly promote dewatering. Two gPAM products and a poly(vinylamine) product in sequential addition with CMS were very effective for promoting fine-particle retention. These same sequential treatments of the stock contributed to moderate fiber flocculation, though severe flocculation was caused by further treatment of the furnish with colloidal silica. Handsheet strength results were mixed. In the default recycled copy paper furnish, the average breaking length for the sheets made with cationic additives followed by CMS was not greatly different from the blank condition. Superior strength resulted when the default furnish was treated with a dispersant alone. When the dispersant-contaminated furnish was treated with the same combinations of cationic additives and CMS, the strength returned to the baseline achieved in the absence of the dispersant. The results were discussed in terms of the charged character of the different additives and their interactions not only with the fiber surfaces but also with each other.

Effects of tissue additives on copy paper forming and properties

Laboratory tests were conducted in an effort to determine the effects on paper machine process attributes and the properties of paper made from recycled copy paper furnish upon the addition of chemical agents that are commonly used in the production of hygiene tissue products. Due to continuing growth in tissue and towel grades of paper, such agents are experiencing greater usage. Charge titration test results revealed that certain dry strength agents associated with tissue manufacturing have the potential to shift the balance of charge in papermaking furnish to less negative or even positive values. Creping adhesive was found to contribute to fine particle retention, especially when present at relatively high levels. Release aid and a polyacrylate dispersant had the opposite effect. Low addition levels of both a creping adhesive and a debonding agent surprisingly increased a wide range of strength attributes of paper handsheets in comparison to sheets prepared from unaltered recycled copy paper furnish. The debonding agent decreased paper strength at higher levels of addition. Such effects appear to depend not only on the expected effects of agents themselves, but also on how they affect the charge balance of the wet-end system.

Experimental Study on the Migration and Clogging of Fine Particles in Coarse-Grained Soil with Seepage

The migration and clogging of fine particles in the pores of coarse-grained soil with seepage is of great significance to reduce the leakage of soil at the dam base and lower the permeability of soil. Therefore, the homemade infiltration test device was used to test the infiltration and clogging of soil samples with different particle size ratios D15/d85 (D15 represents the particle size corresponding to the cumulative percentage content of soil particles smaller than a certain particle size in the coarse particles which is 15%, and d85 represents the particle size corresponding to the cumulative percentage content of soil particles smaller than a certain particle size in the fine particles group which is 85%). The factors affecting the deposition of fine particles in coarse-grained soil and the characteristics of fine particle migration and penetration were analyzed. The clogging of coarse-grained soil, hydraulic gradient and pore changes characteristics before and after clogging were studied. The results show that: 1) The main factor affecting the retention of fine particles in coarse-grained soil is the particle size ratio, and the retention rules conforms to the Peak-Gauss function relationship. The penetration law of fine particles satisfies the Logistic function relationship, which can directly predict the internal clogging of coarse-grained soil. 2) The particle size ratio is the main factor affecting the blockage in each mode, followed by the influence of the water head, When the particle size ratio is less than 13.10, the clogging ratio decreases with the increase of particle size ratio, and the hydraulic gradient increases with the increase of particle size ratio. When is greater than 13.10, the clogging ratio increases with the increase of particle size ratio, and the hydraulic gradient decreases with the increase of particle size ratio. 3) The degree of clogging in coarsegrained soil is closely related to the change in porosityand and can be judged according to the change of porosity in coarse-grained soil. The research results deepen the understanding of fine particle migration on the rules of coarse-grained soil clogging and can provide a theoretical basis for related engineering applications.

Mechanistic aspects of nanocellulose–cationic starch–colloidal silica systems for papermaking

Optimization of a chemical additive program for a paper machine can require attention to both colloidal charges and kinetic effects. This work considered an additive program with two negatively charged substances (nanofibrillated cellulose [NFC] and colloidal silica) and two positively charged items (cationic starch and cationic acrylamide copolymer retention aid). Results were shown to depend on charge interactions; however, that clearly was not the whole story. Some findings related to cationic demand, dewatering, fine-particle retention, and flocculation among fibers were best explained in terms of at least partly irreversible complexation interactions between the charged entities. Adjustments in ratios between oppositely charged additives, their sequences of addition, and effects of hydrodynamic shear levels all affected the results. In general, the most promising results were obtained at a cationic starch level of 0.25% to 0.5% based on sheet solids in systems where the cationic starch was used as a pretreatment for NFC.

Effects of orders of addition in nanocellulose–cationic starch– colloidal silica systems for papermaking

Two orders of addition were compared when preparing paper handsheets from recycled copy paper furnish in combination with nanofibrillated cellulose (NFC), cationic starch, colloidal silica, and cationic retention aid (cPAM; cationic polyacrylamide). Faster dewatering and higher fine-particle retention were obtained at equal optimized dosages of additives when the colloidal silica was added last, after addition of the cPAM. The same order of addition also provided a higher gain in the paper’s tensile strength. However, higher paper stiffness was achieved when the colloidal silica was instead added to the NFC, after its pretreatment with cationic starch. Results were consistent with the principle that papermaking additives added shortly before sheetforming tend to have the largest effects on drainage and retention. The results also demonstrated a sensitivity to the relative dosages of positively and negatively charged additives.

Nanocellulose–cationic starch– colloidal silica systems for papermaking: Effects on process and paper properties

Laboratory tests were conducted to better understand effects on the papermaking process and handsheets when recycled copy paper furnish was treated with combinations of nanofibrillated cellulose (NFC), cat-ionic starch, colloidal silica, and cationic retention aid (cPAM; cationic polyacrylamide). Dosage-response experiments helped to define conditions leading to favorable processing outcomes, including dewatering rates and the efficiency of fine-particle retention during papermaking. Effects were found to depend on the addition amounts of cationic starch and colloidal silica added to the system. It was shown that the presence of a polymer additive such as cationic starch was essential in order to achieve large strength gains with simultaneous usage of NFC.

Role of suspended particulate material on growth and metal bioaccumulation in oysters (Crassostrea gigas) from a French coastal semi-enclosed production area, Arcachon Bay

Arcachon Bay is a prominent oyster production area on the coast of Western Europe, and is subject to chemical contamination including by trace metals. Recently, the national “mussel-watch” monitoring network – using local bivalves as semi-quantitative bioindicators of coastal chemical contamination – highlighted a significant increase in copper (Cu) concentrations in oysters from this bay. Here, we conducted a one-year multi-compartment and multi-parameter field study to investigate some aspects of the surrounding environment of oysters that could explain their metal bioaccumulation. Sediment, seawater (through punctual and passive sampling), particles (suspended particulate material of selected sizes, including trophic resources for oysters) and transplanted oysters were regularly collected at two contrasted sites of the bay (i.e. under continental versus more oceanic influence). These matrices were characterised for their total Cu, zinc (Zn), nickel (Ni), cadmium (Cd) and lead (Pb) concentrations. Several physico-chemical and biological parameters (e.g. salinity, particle loads, oyster growth rate and condition indices, carbon and nitrogen stable isotope compositions, etc.) were also analysed. Overall, sediment, particles and oysters from the outermost site had slightly lower δ 13 C values, confirming the more oceanic influence in this part of the bay. Among organic particles, although dinoflagellates tended to be more abundant at the outermost site while ciliates were more abundant at the innermost site of the bay, the two sites did not differ in mean total microphytoplankton and diatom densities. However, the variations observed for most of the other parameters studied show that oysters located near the continental shore are exposed to higher loads of particles in general, and to higher metal contents in the dissolved phase and “bulk” seawater (dissolved plus particulate phases) during the year. While fluvial inputs and continental/urban run-offs are suspected sources of anthropogenic metal inputs into the bay, (fine) sediment particle resuspension appears to be a likely major contributor to metal release and hence to the contamination of the bay including oysters. The decline of seagrass beds in the last two decades in the bay could also have decreased the potential of fine particle retention in the sedimentary stratum. Concomitantly, oysters presenting the highest metal concentrations were those with the lower growth rates and condition indices, which may be induced by physical constraints, high amounts of pseudo-faeces produced and/or reduced food and energy acquisition by oysters due to high particle loads in the water column. The findings of this study imply that using raw metal concentrations in bivalves to monitor marine coastal contamination can lead to misleading interpretations if potentially great spatial variations in bivalve growth rates or condition indices are not considered. Finally, peculiar trends were observed for Cu compared to other metals, highlighting the need of further studies to fully address the Cu contamination in this marine system (e.g. specific sources of contamination for this metal in the bay). This study more broadly raises the issue of potentially man-induced ecological changes (e.g. modification of natural habitats) and their consequences on metal transfer and physiological performance of marine biota. • A multi-compartment and multi-parameter study to unravel oyster metal contamination. • Higher contamination found in dissolved and particulate seawater phases inside the bay. • Contamination likely explained by river flows and tidal resuspension of sediments. • Higher particle loads observed with higher oyster metal concentrations and lower growth. • Differences in oyster bioaccumulation patterns for copper compared to other metals.

Clogging effect of fines in seepage erosion by using CFD–DEM

The macroscopic phenomena and microscopic origin of penetrative migration and retention of fine particles in porous skeleton under the action of seepage are not yet clear. Migrating fine particles experience physical interactions with impermeable walls, carrier fluids, particle skeleton and other fines. Therefore, the simulations of suffusion based on the coupled computational fluid dynamics–discrete element method (CFD–DEM) are carried out with consideration of different coarse particle size distributions, flow velocities and inflow fines concentrations. Simulations are performed by releasing continuously produced fines into the coarse-grained matrix under hydraulic force. Macroscopic alterations (including the loss rate, concentration ratio, concentration region of cluster, velocity and size distribution of fine particle, pore throat diameter and permeability) and microscopic features (including interparticle force network, the spatial distribution and velocity field of fines) are quantified during suffusion. The results reveal that the pore size of porous media significantly contributes to the degree and position of clogging. Flow velocity affects interception efficiency and distribution of clusters. Additionally, the prominent development of particle clusters in the flow-avoidable areas is aided by the appearance of more inflow fines. With both macroscopic and microscopic responses, this study may increase the knowledge of clogging phenomena during suffusion.

Composition and size of retained aerosol particles on urban plants: Insights into related factors and potential impacts

The role of plants in alleviating aerosol pollution has drawn extensive attention. Most studies focus on compositions of aerosol particles on urban plants, while the leaf traits related to particle retention have not yet been intensively studied. This study selected five typical urban plants (Loropetalum chinense, Rhododendron simsii, Euonymus japonicus, Photinia × fraseri, Osmanthus fragrans), and employed scanning electron microscope (SEM) and ion chromatography, aiming to investigate the accumulation features of aerosol particles and the relationships between leaf traits and particle retention. Results show that aerosol particles were mainly retained on the adaxial leaf surface, the fine particles (Φ ≤ 2.5 μm) were the predominant components (77.8 % by number) on the leaves, and the dominant water-soluble ions of particles were Ca2+, SO42−, and NO3−. By comparison, E. japonicus and P. fraseri were efficient in the retention of fine and coarse particles (2.5 <Φ ≤ 10 μm), but L. chinense was capable to retain more large particles (Φ > 10 μm). The correlation analysis indicates that leaf traits are closely related to the accumulation of aerosol particles. The result shows that plant leaves with larger stomatal area, lower stomatal density, smaller specific leaf area and higher in epicuticular wax content can retain more aerosol particles. This result indicates that the leaves are capable of retaining aerosol particles via the synergy of multiple leaf traits, such as higher wax content and the fewer but larger stomata on their leaf surfaces. This study is helpful to understand the interactions between leaf traits and particle retention, and it further contributes to the selection of potential dust-retaining plants, which is of great significance for the alleviation of urban air pollution.

Novel laboratory methodology for fines migration testing for SAGD wells

The sand retention and the retained permeability or flow performance of sand control screens in unconsolidated formations are usually evaluated through the pre-packed sand retention testing (SRT) procedures. These procedures attempt to address a complex process of fines migration which influences the flow performance of screens in formations with relatively high fines content. Plugging of sand control screens and flow impairment of SAGD wells in unconsolidated Alberta's oil sands is a common problem in which the role of fines migration is prominent. Previous SRT studies for the SAGD wells did not purposefully explore the fines migration process. In this study, a set of pre-packed SRT experiments with comprehensive long-term testing procedures were conducted to simulate the fines migration process and assess the flow performance behavior of a sand screen under SAGD well conditions.The experiment results indicate a non-monotonic behavior of permeability with an initial decrease followed by an increasing trend for the near screen interval of the sand pack. It is observed that the effect of releasing fine particles from or near the pore throats on permeability is dominant compared with the retention of fine particles over the thin pore throats at the first stages of the experiments. Because of testing limitations concerning initial attachment of fine particles at pore surfaces, pore size distribution, and the amount of mobile fine particles as a function of time, most results were inconsistent with decreasing trend behavior of permeability in the field and actual core flooding observations. However, a decreasing behavior was observed by conducting a new test procedure replicating a representative worst-case flow condition in the field. As the main conclusion, the previous SRT test procedures and the design criterion should be revised to enhance the flow performance assessment of sand control screens for formations susceptible to the fines migration process.

Effects of alternating injection-interruption periods on the fine particle transport and retention in granular media

This study investigates the impact of interruption of injections on the transfer and retention of suspended particles (SP) in granular media. Columns packed with sand were operated in the laboratory, and a series of experiments of SP injections were conducted: the first by injecting SP without interrupting injection, the second and third experiments with 3 pauses of injection of 24 h and 48 h, respectively. Results showed that interrupted injections induced a significant release of particles showing peaks of concentration in the effluent immediately after the pause periods. These peaks increase with pause durations. Interruption of injections allowed the transport of coarser particles deeper into the columns. For all experiments carried out, the hydraulic conductivity, measured during injection, decreased with the number of pore volumes injected. This decrease is almost linear for continuous injection experiments. Whereas, the hydraulic conductivity decreased brutally when reinjecting SP, after pauses, highlighting the desaturation of the porous medium during pause periods. The results obtained show that all the phenomena (hydraulic conductivity drop, SP transport, and deeper transfer of coarser particles) occurred during the dynamic phase of the experiments for the first 75% of pore volumes injected. Beyond that, the porous medium is completely clogged.

Carbon and Nitrogen Contents Driven by Organic Matter Source within Pichavaram Wetland Sediments

Differences in grain size, total organic carbon (OC), total nitrogen (TN), OC/TN ratios, and stable isotope (δ13C and δ15N) were assessed in sediments from areas covered by mangrove and saltmarsh vegetation within Pichavaram estuary (Southeast India). The mean percentage contents of silt and clays (70 vs. 19%), OC (5.7 vs. 2.0%), and TN (0.39 vs. 0.14%) were consistently higher in the mangrove as compared to those observed in the saltmarsh tidal zone. These differences may obey the higher deposition and retention of fine particles in the presence of a mangrove root system that may facilitate the accumulation and preservation of organic matter within these sedimentary systems. Further, higher OC and TN contents were associated to higher terrestrial or mangrove-derived organic matter contribution with lighter δ13C signatures (−26.0‰) in both sedimentary tidal zones, whereas lower OC and TN contents were associated to heavier δ13C signatures. This study is in agreement with previous studies which indicate that the presence of wetland vegetation may increase the carbon and nutrient storage capacity within estuarine ecosystems, highly relevant information for the establishment of further conservation strategies for blue carbon ecosystems at global scales.

Tyre and road wear particles - A calculation of generation, transport and release to water and soil with special regard to German roads

Tyre and road wear is one of the main emission sources of particulate plastics (microplastics). In this study, the emissions of tyre wear particles (TWP) which are annually generated on the German road network were calculated. Emissions are calculated by applying two different data sets of emission factors and the annual mileage for distinct vehicles and road types (urban roads, rural roads, highways). Environmental entry paths of tyre and road wear particles (TRWP) were considered including releases to ambient air, soils and surface waters. Road runoff treatment was taken into account differentiated into sewage systems in urban areas and at non-urban roads. This study identifies the soundest data available concerning emission factors, data on traffic and road systems as well as comprehensive information on road runoff treatment in Germany. Applying this data and assuming that 5% of the total emissions are ‘fine’ air-borne particles, the emissions of coarse ‘non-airborne’ particles are 75,200–98,400 t/a; . the transport to road banks and soils near roads is 57,300–65,400 t/a (66–76%) including runoff and drift; 8700–19,800 t/a (12–20%) are released to surface waters. Due to lack of data, degradation in soils and surface waters was not considered. Besides soils, urban wastewater treatment plants are expected to be an important sink of TRWP assuming that most of the particles are incorporated in the sewage sludge. Due to the application of sewage sludge as a fertilizer, 1400–2800 t/a TWP are currently deposited on agricultural areas. No reliable data was available to estimate the masses of TWP which are transported from freshwaters into the marine environment. Existing mitigation measures should be improved according to the principle of precaution by installation of road runoff treatment systems and retrofitting of existing plants regarding optimum fine particle retention.

Fine particle transport dynamics in response to wood additions in a small agricultural stream

AbstractWood additions to streams can slow water velocities and provide depositional areas for bacteria and fine particles (e.g., particulate organic carbon and nutrients sorbed to fine sediment), therefore increasing solute and particle residence times. Thus, wood additions are thought to create biogeochemical hotspots in streams. Added wood is expected to enhance in‐stream heterogeneity, result in more complex flow paths, increase natural retention of fine particles and alter the geomorphic characteristics of the stream reach. Our aim was to directly measure the impact of wood additions on fine particle transport and retention processes. We conducted conservative solute and fluorescent fine particle tracer injection studies in a small agricultural stream in the Whatawhata catchment, North Island of New Zealand in two reaches—a control reach and a reach restored 1‐year earlier by means of wood additions. Fine particles were quantified in surface water to assess reach‐scale (channel thalweg) and habitat‐scale (near wood) transport and retention. Following the injection, habitat‐scale measurements were taken in biofilms on cobbles and by stirring streambed sediment to measure fine particles available for resuspension. Tracer injection results showed that fine particle retention was greater in the restored compared to the control reach, with increased habitat‐scale particle counts and reach‐scale particle retention. Particle deposition was positively correlated with cobble biofilm biomass. We also found that the addition of wood enhanced hydraulic complexity and increased the retention of solute and fine particles near the wood, especially near a channel spanning log. Furthermore, particles were more easily remobilized from the control reach. The mean particle size remobilized after stirring the sediments was ~5 μm, a similar size to both fine particulate organic matter and many microorganisms. These results demonstrate that particles in this size range are dynamic and more likely to remobilize and transport further downstream during bed mobilization events.

Design Factors in Fountain Confined Conical Spouted Beds

The design factors of fountain confined conical spouted beds have been assessed in order to determine their best combination for scaling up and enhancing fine particle retention. The results evidence that the length of the confiner and the height of the draft tube entrainment zone are the key design factors, causing the highest entrainment reduction. Thus, the optimum confiner length is within the range of 2-3 times the bed surface diameter and the desirable height of the entrainment zone is approximately 1-2 times the tube diameter. This study also concludes that the best system for attaining high stability with minimum elutriation is the one equipped with an open-sided draft tube with an aperture ratio of around 20%.

Fine sediment particle microscopic characteristics, bioavailable phosphorus and environmental effects in the world largest reservoir

The transport and retention of sediments in fine grain sizes plays an important role in the cycles of phosphorus (P), and is closely related to the extent and potential for eutrophication in water reservoirs. In order to highlight the environmental indications for the transport of fine sediment particles and the associated bioavailable phosphorus (Bio-P) in the world largest reservoir, the Three Gorges Reservoir (TGR), the suspended and bed sediments were collected at 13 sections in 2016. The sediment physicochemical properties, micromorphology of sediment particles, distribution of elements on particle surface, P adsorption parameters, and P fractions in different grain sized sediments were analyzed. The results showed that the fine sediment particles had a strong P adsorption ability due to their micromorphology, mineral compositions, and the high contents of Fe/Al/Mn (hydr)oxides, which contributed a higher concentration of Bio-P in <16 μm sediment particles. The adsorption of P on the sediment particles occurred longitudinally along the TGR, and the fine sediment particles (<16 μm) dominated the transport and distribution of Bio-P in the TGR sediments. The reduced inflow and retention of fine sediment particles, caused by the construction of cascade reservoirs along the Jinsha River (upper reach of the Yangtze River), has resulted in the decrease in the retention of Bio-P in the TGR. Therefore, we conclude that the continuously decrease of inflow and retention of the fine sediment particles in the TGR, and with it a reduced sediment P buffer capacity, may enhance algal blooms occurrence also in view of the increased P discharge from the overall TGR catchment. The study results can contribute to improved management guidance on fine sediment particles and associated phosphorus for the operation and environmental protection of other large reservoirs in the world.

Influence of sand addition in the early stage retention of fine sludge dewatering by geotextile

The need to investigate viable methods to facilitate correct disposal of high-water content waste is immediate in the scenario of water source degradation. In this context, Closed Geotextile Systems (CGS) have shown promise for dewatering a variety of high water-content sediments, aiming to reduce the waste final volume, encapsulating particles, and at the same time allowing fluid drainage. Especially in Water Treatment Plants, the geotextiles generally employed in these systems have good tensile strength and rigidity to support mechanical solicitations and hydraulic properties that warrant good drainage conditions. In these applications, the geotextile element should assure the waste confinement and retention of some particles that will form a filter cake which will control internal flow conditions. The present work investigated how small portions of sand influence fine-particle retention. The sludge used consisted of a mixture of filtered water with two well-defined fractions of ground quartz: FG, a silt and CG, a fine sand. The results show that small amounts of sand are capable of leading to the formation of a pre-filter, even if the maximum diameter of the fine particles is much less than the geotextile filtration opening size. The test results indicate that the retention efficiency gradually increases as CG increases in the solution, up to a fraction of CG close to 14%, which represents only 0.7% of the total solution mass. The increase in particle retention was directly proportional to the increase in the GC fraction until reaching the filtration efficiency of approximately 72% where it stabilizes.

Development of Nanofluids for the Inhibition of Formation Damage Caused by Fines Migration: Effect of the interaction of Quaternary Amine (CTAB) and MgO Nanoparticles.

Fines migration is a common problem in the oil and gas industry that causes a decrease in productivity. In this sense, the main objective of this study is to develop nanocomposites based on the interaction of quaternary amine (hexadecyltrimethylammonium bromide—CTAB) and MgO to enhance the capacity of retention of fine particles in the porous medium. MgO nanoparticles were synthesized by the sol–gel method using Mg(NO3)2·6H2O as a precursor. Nanoparticles were characterized by dynamic light scattering (DLS), the point of zero charge (pHpzc), thermogravimetric analysis, and Fourier transform infrared spectroscopy (FT-IR). Different nanoparticle sizes of 11.4, 42.8, and 86.2 nm were obtained, which were used for preparing two system nanofluids. These systems were evaluated in the inhibition of fines migration: in the system I MgO nanoparticles were dispersed in a CTAB-containing aqueous solution, and system II consists of a nanocomposite of CTAB adsorbed onto MgO nanoparticles. The fines retention tests were performed using Ottawa sand 20/40 packed beds and fine particles suspensions at concentrations of 0.2% in a mass fraction in deionized water. Individual and combined effects of nanoparticles and CTAB were evaluated in different treatment dosages. The analysis of the interactions between the CTAB and the MgO nanoparticles was carried out through batch-mode adsorption and desorption tests. The best treatment in the system I was selected according to the fines retention capacity and optimized through a simplex-centroid mixture design for mass fractions from 0.0% to 2.0% of both CTAB and MgO nanoparticles. This statistical analysis shows that the optimal concentration of these components is reached for a mass fraction of 0.73% of MgO nanoparticles and 0.74% in mass fraction of CTAB, where the retention capacity of the porous medium increases from 0.02 to 0.39 mg·L−1. Based on the experimental results, the nanofluids combining both components showed higher retention of fines than the systems treated only with CTAB or with MgO nanoparticles, with efficiencies up to 400% higher in the system I and higher up to 600% in the system II. To evaluate the best performance treatment under reservoir conditions, there were developed core flooding tests at fixed overburden pressure of 34.5 MPa, pore pressure at 6.9 MPa and system temperature at 93 °C. Obtaining critical rate increases in 142.8%, and 144.4% for water and oil flow in the presence of the nanofluid. In this sense, this work offers a new alternative for the injection of nanocomposites as a treatment for the problem of fines migration to optimize the productivity of oil and gas wells.