Sediment runoff from dense highland field areas greatly affects the quality of downstream lakes and drinking water sources. In this study, multiple linear regression (MLR) models were built to predict diffuse pollutant discharge using the environmental parameters of a basin. Explanatory variables that influence the sediment and pollutant discharge can be identified with the model, and such research could play an important role in limiting sediment erosion in the dense highland field area. Pollutant load per event, event mean concentration (EMC), and pollutant load per area were estimated from stormwater survey data from the Lake Soyang basin. During the wet season, heavy rains cause large amounts of suspended sediment and the occurrence of such rains is increasing due to climate change. The explanatory variables used in the MLR models are the percentage of fields, subbasin area, and mean slope of subbasin as topographic parameters, and the number of preceding dry days, rainfall intensity, rainfall depth, and rainfall duration as rainfall parameters. In the MLR modeling process, four types of regression equations with and without log transformation of the explanatory and response variables were examined to identify the best performing regression model. The performance of the MLR models was evaluated using the coefficient of determination (R2), root mean square error (RMSE), coefficient of variation of the root mean square error (CV(RMSE)), the ratio of the RMSE to the standard deviation of the observed data (RSR) and the Nash–Sutcliffe model efficiency (NSE). The performance of the MLR models of pollutant load except total nitrogen (TN) was good under the condition of RSR, and satisfactory for the NSE and R2. In the EMC and load/area models, the performance for suspended solids (SS) and total phosphorus (TP) was good for the RSR, and satisfactory for the NSE and R2. The standardized coefficients for the models were analyzed to identify the influential explanatory variables in the models. In the final performance evaluation, the results of jackknife validation indicate that the MLR models are robust.