Filtration Of Solution Research Articles

Empirical formulation of broadband complex refractive index spectra of single-chirality carbon nanotube assembly

Abstract Assemblies of single-walled carbon nanotubes with a specific chiral structure are promising future optofunctional materials because of their strong light–matter coupling arising from sharp optical resonances of quasi-one-dimensional excitons. Their strong optical resonances, which lie in the infrared-to-visible wavelength region, can be selected by their chiralities, and this selectivity promises a wide range of applications including photonic and thermo-optic devices. However, the broadband complex optical spectra of single-chirality carbon nanotube assemblies are scarce in the literature, which has prevented researchers and engineers from designing devices using them. Here, we experimentally determine broadband complex refractive index spectra of single-chirality carbon nanotube assemblies. Free-standing carbon nanotube membranes and those placed on sapphire substrates were fabricated via filtration of the nanotube solution prepared by the separation method using gel chromatography. Transmission and reflection spectra were measured in the mid-infrared to visible wavelength region, and the complex refractive indices of nanotube assemblies were determined as a function of photon energy. The real and imaginary parts of the refractive indices of the nanotube membrane with a bulk density of 1 g cm−3 at the first subband exciton resonance were determined to be approximately 2.7–3.6 and 1.3i–2.4i, respectively. We propose an empirical formula that phenomenologically describes the complex refractive index spectra of various single-chirality nanotube membranes, which can facilitate the design of photonic devices using carbon nanotubes as the material.

Positively charged PVC ultrafiltration membrane via micellar enhanced ultrafiltration for removing trace heavy metal cations

One of the major focuses in the field of sewage is the development of low-pressure driven and high-efficiency filtration membrane, particularly for removing extremely low-concentration heavy metals cations. A new type of polyvinyl chloride (PVC) blended ultrafiltration (UF) membrane was fabricated to reject heavy metal cations (e.g., Cd2+, Co2+, Ni2+, Cu2+, and Zn2+) from simulated waters using micellar enhanced ultrafiltration (MEUF) in this research. The positively charged PVC UF membrane was fabricated by blending PVC and amphiphilic poly (methyl methacrylate-co- dimethylaminoethyl methacrylate) (PMD) which was in-situ quaternized by methyl iodide (CH3I), then the PVC/PMD blended membrane was fabricated via nonsolvent induced phase separation (NIPS) process. The membranes' pore morphology, surface chemical compositions, surface charge, water contact angle, mechanical strength and water flux were investigated in detail. The influence of pH, transmembrane pressure, sodium dodecylbenzene sulfonate (SDBS) concentration on the filtration of pure SDBS solution was studied. SDBS was subsequently used as surfactant to remove heavy metal ions by micellar enhanced ultrafiltration (MEUF). For a molar ratio of 40:1 (SDBS: metal cation), the rejection of feed solution containing 10 ppm metal cations (e.g., Cd2+, Co2+, Ni2+, Cu2+, and Zn2+) surpassed 96% with MEUF method. The results showed that the prepared membrane had low-pressure driven and high-efficiency performance, which provided a potential solution for the high-efficiency removal of trace heavy metals cations.

Adductor Canal Block Combined with Interspace between the Popliteal Artery and Capsule of the Knee (iPACK) versus Periarticular Injection for Total Knee Arthroplasty.

The combination of the adductor canal block (ACB) and the infiltration of anesthetic solution into the interspace between the popliteal artery and capsule of the knee (iPACK) has become increasingly used to augment rapid recovery protocols in total knee arthroplasty (TKA). However, its efficacy in comparison with periarticular anesthetic injection (PAI) alone has yet to be evaluated. Hence, we conducted a retrospective study to compare PAI and ACB + iPACK for controlling pain after TKA. Propensity scores, incorporating American Society of Anesthesiologists scores, body mass index, age, and sex, were used to match the ACB + iPACK group with the PAI group. All patients received the identical surgical technique and postoperative care. Outcome measures were visual analog scale (VAS) for pain, morphine consumption, knee flexion angle, straight leg raising (SLR), postoperative nausea vomiting (PONV), and length of stay (LOS) after the surgery. After matching by propensity score, there were 49 patients with comparable demographic data in each group. The VAS and morphine requirements of the PAI and ACB + iPACK groups were not different during the first 48 hours after TKA. At 72 hours postoperatively, the VAS of the ACB + iPACK was 0.97 higher than that of the PAI group (p = 0.020). Knee flexion angle, SLR, PONV, and LOS were not significantly different between groups. No procedure-related complications were identified in either group. The anesthesiologist-administered ACB + iPACK was as effective as surgeon-administered PAI in controlling pain in the first 48 hours after TKA. However, the ACB + iPACK group had higher intensity of pain than did the PAI group at 72 hours after TKA.

Influencing factors of neonatal peripherally inserted central venous catheter (PICC)-related phlebitis: a systematic review, meta-analysis and network meta-analysis

A peripherally inserted central venous catheter (PICC) plays an important role in the security of newborns, especially very low birth weight infants and extremely very low birth weight infants. However, PICC-related phlebitis can seriously affect the normal use of catheters and even cause unplanned removals of catheters. In this review, we systematically reviewed and explored the influencing factors of neonatal PICC-related phlebitis. The PubMed, Embase, CENTRAL, CINAHL, CBM, Wanfang and CNKI databases were searched to collect relevant studies on influencing factors of neonatal PICC-related phlebitis. Review Manager software version 5.3 (RevMan; the Cochrane Collaboration 2012, The Nordic Cochrane Center, Copenhagen, Denmark) and GeMTC software version 0.14.3 (Gert van Valkenhoef, Groningen, The Netherlands ) were used for the meta-analysis and network meta-analysis. A total of 32 studies were included, including 14 randomized controlled trials (RCTs), 2 case-control studies, and 16 cohort studies, involving a total of 8278 neonates. The meta-analysis results showed that the influencing factors of neonatal PICC-related phlebitis were catheter malposition (OR (Odds Ratio) = 5.53, 95% CI (Confidence Interval) (1.22, 25.15)), catheter occlusion (OR = 7.18, 95% CI (3.54, 14.56)), gestational age (OR = 2.51, 95% CI (1.35, 4.66)), using a dexamethasone solution to infiltrate the catheter (OR = 0.26, 95% CI (0.17, 0.41)), and innovative nursing interventions (OR = 0.17, 95% CI (0.07, 0.42)). The network meta-analysis results showed that, compared with lower limb veins, the use of scalp veins (OR = 3.57, 95% CI (1.39, 10.18)) and upper limb veins (OR = 1.89, 95% CI (1.08, 3.37)) had a statistically significant difference in the incidence of phlebitis, while there was no statistically significant difference in the incidence of phlebitis between scalp veins and upper limb veins (OR = 0.53, 95% CI (0.20, 1.26)). PICC puncture of the lower limb veins was most likely to lead to phlebitis, followed by upper limb vein puncture, followed by scalp vein puncture. Catheter malposition, catheter occlusion and being small for gestational age were risk factors for PICC-related phlebitis, while dexamethasone solution infiltration of catheters and innovative nursing interventions were protective factors. Venipuncture of the lower limbs is the most likely location to cause PICC-related phlebitis.

Three novel Co(II)-MOFs with a conjugated tetrabenzoic acid supported noble metal nanoparticles for efficient catalytic reduction of 4-nitrophenol

The utilization of porous metal-organic frameworks (MOFs) as catalyst support has attracted intensive attentions in heterogeneous catalysis. However, the study of structure-activity relationship in this confined catalysis system is still scarce. Herein, three isostructural Co(II)-MOFs {Co2L(bpy)}n (CTGU-11), {Co2L(bpe)}n (CTGU-12) and {Co2L(bib)}n (CTGU-13) were synthesized by using 4,4′,4″,4‴-(1,3,6,8-Pyrenetetrayl)tetrabenzoic acid (H4L) as an organic ligand, and introducing three N-donor ligands (bpy ​= ​4,4′-dipyridyl, bpe ​= ​1,2-di(4-pyridyl)ethylene, bib ​= ​1,4-bis(1-imidazoly)benzene) with different length. Among these Co(II)-MOFs, each L4− anion bridges four typical paddle wheel secondary building units (SBUs) to form a two dimensional (2D) sheet, which further expanded to the three-fold interpenetrated structure with the aid of different pillared ligands. Inspired by the eligible structure/surface feature of these frameworks, a series of Co-MOF-supported heterogeneous catalysts (NM@Co-MOFs, NM = Ag, Ru, Pd and Au) have been fabricated successfully via solution infiltration, for the reduction of 4-nitrophenol (4NP). Impressively, 2-Ru@Co-MOFs exhibit remarkable activity in comparison to other NM@Co-MOFs composites with the apparent rate constant reach 50.72 ​s-1 ​g-1, 26.14 ​s-1 ​g-1, and 22.79 ​s-1 ​g-1, respectively. Furthermore, the possible catalytic mechanism of 2-Ru@Co-MOFs has also been discussed based on the analysis of reaction kinetics.

Bidirectional Light-Driven Ion Transport through Porphyrin Metal–Organic Framework-Based van der Waals Heterostructures via pH-Induced Band Alignment Inversion

Bidirectional Light-Driven Ion Transport through Porphyrin Metal–Organic Framework-Based van der Waals Heterostructures via pH-Induced Band Alignment Inversion

Freestanding Ti3C2Tx MXene/Prussian Blue Analogues Films with Superior Ion Uptake for Efficient Capacitive Deionization by a Dual Pseudocapacitance Effect.

Exploring and designing high-performance Faradaic electrode materials is of great significance to enhance the desalination performance of hybrid capacitive deionization (HCDI). Herein, open and freestanding films (MXene/Prussian blue analogues (PBAs), specifically, MXene/NiHCF and MXene/CuHCF) were prepared by vacuum filtration of a mixed solution of PBAs nanoparticles and a Ti3C2Tx MXene dispersion and directly used as HCDI electrodes. The conductive MXene nanosheets bridge the PBAs nanoparticles to form a three-dimensional (3D) conductive network structure, which can accelerate the salt ion and electron diffusion/transport kinetics for HCDI. Additionally, the PBAs nanoparticles can prevent the restacking of MXene nanosheets, expand their interlayer spacing, and facilitate the rapid diffusion and storage of ions. Benefiting from the dual pseudocapacitance and synergistic effect of PBAs and MXene, the obtained MXene/PBAs films show superior properties, with a high desalination capacity (85.1 mg g-1 for the MXene/NiHCF film and 80.4 mg g-1 for the MXene/CuHCF film) and an ultrafast salt-removal rate, much higher than those of other Faradaic electrodes. The synergistic effect, the adsorption of Na+ ions, and the enhanced conductivity of MXene/PBAs films were demonstrated through first-principles calculations. This paper offers a simple and convenient method for the design of freestanding HCDI electrodes and promotes the rapid development of HCDI technology.

Ceramic-supported graphene oxide membrane bioreactor for the anaerobic decolorization of azo dyes

A continuous compact membrane bioreactor consisted of ceramic-supported graphene oxide membrane (CSGoM) was implemented for the first time for anaerobic biodecolorization of monoazo Acid Orange 7 (AO7), diazo Reactive Black 5 (RB5), and triazo Direct Blue 71 (DB71) solutions, showing excellent decolorization potential. The membrane was prepared by vacuum filtration of various graphene oxide solutions using a UF ceramic flat element. The decolorization efficiency of the CSGoM bioreactor, made from 1 mg·mL−1 of GO solution (B-CSGoM-1), was investigated for several structurally distinct azo dyes, initial feed concentrations, and permeate fluxes. Maximum color removal was achieved under low feed concentration (50 mg·L−1) and permeate flux (0.05 L·m−2·h−1), reaching 99% for AO7, 96% RB5, and 92% for DB71. At this low permeate flux, the biodecolorization was stable for all azo dye solutions irrespective of the feed concentration. In a subsequent experiment under higher feed concentration and permeate flux (100 mg·L−1 and 0.10 L·m−2·h−1), the decolorization slightly fell to 93%, 85%, and 81% for monoazo, diazo, and triazo solutions, respectively. The existence of anaerobic bacteria (Geobacter and Pseudomonas guangdongensis) in the B-CSGoM-1 biofilm confirms that they could perform efficient biodegradation of azo dye molecules in association with the graphene oxide membrane.

Improvement of Properties and Performances of Polyethersulfone Ultrafiltration Membrane by Blending with Bio-Based Dragonbloodin Resin.

Polyethersulfone (PES) is the most commonly used polymer for membrane ultrafiltration because of its superior properties. However, it is hydrophobic, as such susceptible to fouling and low permeation rate. This study proposes a novel bio-based additive of dragonbloodin resin (DBR) for improving the properties and performance of PES-based membranes. Four flat sheet membranes were prepared by varying the concentration of DBR (0–3%) in the dope solutions using the phase inversion method. After fabrication, the membranes were thoroughly characterized and were tested for filtration of humic acid solution to investigate the effect of DBR loading. Results showed that the hydrophilicity, porosity, and water uptake increased along with the DBR loadings. The presence of DBR in the dope solution fastened the phase inversion, leading to a more porous microstructure, resulted in membranes with higher number and larger pore sizes. Those properties led to more superior hydraulic performances. The PES membranes loaded with DBR reached a clean water flux of 246.79 L/(m2·h), 25-folds higher than the pristine PES membrane at a loading of 3%. The flux of humic acid solution reached 154.5 ± 6.6 L/(m2·h), 30-folds higher than the pristine PES membrane with a slight decrease in rejection (71% vs. 60%). Moreover, DBR loaded membranes (2% and 3%) showed an almost complete flux recovery ratio over five cleaning cycles, demonstrating their excellent antifouling property. The hydraulic performance could possibly be enhanced by leaching the entrapped DBR to create more voids and pores for water permeation.

Boosting performance of the solid oxide fuel cell by facile nano-tailoring of La0.6Sr0.4CoO3-δ cathode

Sluggish kinetics for oxygen reduction reaction (ORR) is one of the greatest challenges limiting the electrochemical performance of solid oxide fuel cells (SOFCs). Surface modification through solution infiltration is recognized as a promising approach to boost the performance of the SOFCs. The conventional infiltration of electrocatalyst in porous scaffold results in discrete particles of active catalyst. However, in this study, we report a novel technique to produce the nano-tailored film of Sm0.5Sr0.5CO3-δ (SSC) active catalyst on to La0.6Sr0.4CoO3-δ (LSC) cathode of SOFC through controlling the drying rate during the infiltration process which resulted in a continous film like coating of SSC. The SOFC with LSC cathode containing SSC film-like nanostructure showed a two-fold performance increment and an excellent durability compared to the LSC cathode prepared through conventional methods. The higher performance of the film-like nanostructured LSC-SSC cathode is attributed to the remarkable reduction in the area-specific ohmic and polarization resistance due to the extension of cathode reaction sites and shorter diffusion lengths, thus, facilitating the ORR.

Deep groundwater physicochemical components affecting actinide migration

To better understand the migration behavior of actinides in deep groundwater (GW), the interactions between doped tracers and deep GW components were investigated. La, Sm, Ho, and U tracers (10 or 100 ppb) were doped into sedimentary rock GW samples collected from 250 to 350 m deep boreholes in the experimental gallery of the Horonobe Underground Research Laboratory (URL), Hokkaido, Japan. To evaluate the effect of GW composition on the chemical speciation of actinides, the same tracers were doped into crystalline rock GW samples collected from 300 to 500 m deep boreholes in the experimental gallery at the Mizunami URL, Gifu Prefecture, Japan. Each GW sample was sequentially filtered through a micro-pore filter (0.2 μm) and ultrafilters with a 10 kDa nominal molecular weight limit. Next, the filtrate solutions were analyzed using inductively coupled plasma–mass spectrometry to determine the concentration of tracers retained in solution during each filtration step, and the used filters were analyzed using time-of-flight secondary ion mass spectrometry element mapping and X-ray absorption fine structure spectroscopy to determine the chemical species of the tracers trapped on each filter. It was determined that lanthanide migration was controlled by the amount of phosphates in the Horonobe GW. Therefore, it was expected that the solubility of minor actinides (MAs), which exhibit a similar chemical behavior to that of lanthanides, would be controlled by the formation of phosphates in sedimentary rock GW. Moreover, the data on the Mizunami GW indicated that a fraction of lanthanides and MAs formed hydroxides and/or hydroxocarbonates.

The Effect of Disinfectants Absorption and Medical Decontamination on the Mechanical Performance of 3D-Printed ABS Parts.

Producing parts by 3D printing based on the material extrusion process determines the formation of air gaps within layers even at full infill density, while external pores can appear between adjacent layers making prints permeable. For the 3D-printed medical devices, this open porosity leads to the infiltration of disinfectant solutions and body fluids, which might pose safety issues. In this context, this research purpose is threefold. It investigates which 3D printing parameter settings are able to block or reduce permeation, and it experimentally analyzes if the disinfectants and the medical decontamination procedure degrade the mechanical properties of 3D-printed parts. Then, it studies acetone surface treatment as a solution to avoid disinfectants infiltration. The absorption tests results indicate the necessity of applying post-processing operations for the reusable 3D-printed medical devices as no manufacturing settings can ensure enough protection against fluid intake. However, some parameter settings were proven to enhance the sealing, in this sense the layer thickness being the most important factor. The experimental outcomes also show a decrease in the mechanical performance of 3D-printed ABS (acrylonitrile butadiene styrene) instruments treated by acetone cold vapors and then medical decontaminated (disinfected, cleaned, and sterilized by hydrogen peroxide gas plasma sterilization) in comparison to the control prints. These results should be acknowledged when designing and 3D printing medical instruments.

Treating Full Depth Cartilage Defects with Intraosseous Infiltration of Plasma Rich in Growth Factors: An Experimental Study in Rabbits.

Intraarticular (IA) administration of platelet-rich plasma (PRP) has been proposed as a new strategy to halt osteoarthritis (OA) progression. In patients with severe OA, its potential is limited because it is unable to reach the subchondral bone, so a new strategy is needed, and intraosseous (IO) infiltration has been suggested. The purpose is to assess the impact of IA together with IO infiltration of plasma rich in growth factors (PRGF) in serum hyaluronic acid (HA) and type II collagen cleavage neoepitope (C2C) levels. A total of 32 rabbits were included in the study and randomly divided into 2 groups: control and treatment. A 4-mm chondral defect was created in the medial femoral condyle and IA followed by IO infiltration were performed. Serum C2C and HA levels were measured using enzyme-linked immunosorbent assay (ELISA) tests before infiltration and 28, 56, and 84 days post-infiltration. Significant lower C2C serum levels were obtained in treatment group (IA + IO infiltration of PRGF) at 84 days post-infiltration than in control group (IA infiltration of PRGF + IO infiltration of saline solution), while no significant differences between groups were reported at any other study times. Regarding HA, at 56 days post-infiltration, greater significant levels were seen in the treatment group. However, at 84 days post-infiltration, no significant differences were obtained, although lower levels were reported in the treatment group. Despite inconclusive, the results suggest that the combination of IA and IO infiltration with PRGF may enhance cartilage and subchondral bone regeneration, but further studies are needed.

The effect of high-molecular compounds nature on the electroflotation removal of the metal compounds from electrolyte solutions

• Removal of heavy metal ions (Fe (III), Ni (II), Cu (II), Pb (II) and Zn (II)) as part of the multi-component system from electrolyte solutions by means of electroflotation and filtration with presence of the high-molecular compounds (HMC) of different nature. • Effect of solution pH, metal and electrolyte concentration on the dispersed properties and electrokinetic potential of the dispersed low-soluble metal compounds and efficiency of their electroflotation removal. • Effect of HMC (flocculants and surfactants) with the anionic, cationic, non-ionic and amphoteric nature upon the dispersed properties, electrokinetic potential and efficiency of electroflotation and electroflotation with subsequent filtration removal of the low-soluble metal compounds particles in electrolyte solutions. • The efficiency of electroflotation removal of heavy metals from concentrated electrolyte solutions with the anionic HMS runs to 98–99% for all components. The process of removal of heavy metal ions as part of the multi-component system from electrolyte solutions by means of electroflotation and filtration with presence of the high-molecular compounds (HMC) of different nature has been studied. Studies were performed in solutions with ions of iron (III), nickel (II), copper (II), lead (II) and zinc(II), as well as NaCl and Na 2 SO 4 (pH 9.5–10.5). It has been shown that addition of the sulphate and sodium chloride mixture in 50 g/L concentration to solutions containing metal ions with total 0.1 g/L concentration reduced the absolute value of dispersed phase ζ-potential from −2.5 mV to −6 mV. The dispersed phase size is getting smaller, two particle types appear in the solution − 54 µm (72% of the total particle quantity) and 5.0 µm (28%). Rise of the total metal ion concentration up to 0.2 g/L results in reduction of the dispersed phase size: 1.5 µm (63%) and 46 µm (37%) particles prevail, the ζ-potential is reduced slightly (-7.1 mV). In this case, the rate of removal of the studied metals by mean of electroflotation is not more than 32–46%. Addition of the anionic HMS (flocculants and surfactants) to the solutions with the total concentration of metal ions of 0.2 g/L and salts of 50 g/L results in rise of dispersed phase ζ-potential and tends its value to the isoelectric point (±0 mV). When the cationic surfactants are added, the particle surface is recharged, the ζ-potential acquires the + values (5.3–7.8 mV). It has been concluded, that the rate of electroflotation removal of heavy metals from concentrated electrolyte solutions with the anionic HMS runs to 98–99% for all components. Subsequent solution filtration with the anionic flocculant allows for reduction of the residual concentration to the following values: 0.5∙10 -4 g/L for Fe (III), Cu (II) and Pb (II) ions and. 0.1∙10 -4 g/L for for Ni (II), 0.14∙10 -3 g/L for Zn (II). Addition of the cationic, non-ionic and amphoteric surfactants does not result in increase of electroflotation process efficiency.

Highly Effective Anti-Organic Fouling Performance of a Modified PVDF Membrane Using a Triple-Component Copolymer of P(Stx-co-MAAy)-g-fPEGz as the Additive

In this study, a triple-component copolymer of P(Stx-co-MAAy)-g-fPEGz containing hydrophobic (styrene, St), hydrophilic (methacrylic acid, MAA), and oleophobic (perfluoroalkyl polyethylene glycol, fPEG) segments was synthesized and used as an additive polymer to prepare modified PVDF membrane for enhanced anti-fouling performance. Two compositions of St:MAA at 4:1 and 1:1 for the additive and two blending ratios of the additive:PVDF at 1:9 and 3:7 for the modified membranes were specifically examined. The results showed that the presence of the copolymer additive greatly affected the morphology and performance of the modified PVDF membranes. Especially, in a lower ratio of St to MAA (e.g., St:MAA at 1:1 versus 4:1), the additive polymer and therefore the modified PVDF membrane exhibited both better hydrophilic as well as oleophobic surface property. The prepared membrane can achieve a water contact angle at as low as 48.80° and display an underwater oil contact angle at as high as 160°. Adsorption experiments showed that BSA adsorption (in the concentration range of 0.8 to 2 g/L) on the modified PVDF membrane can be reduced by as much as 93%. From the filtration of BSA solution, HA solution, and oil/water emulsion, it was confirmed that the obtained membrane showed excellent resistance to these organic foulants that are often considered challenging in membrane water treatment. The performance displayed slow flux decay during filtration and high flux recovery after simple water cleaning. The developed membrane can therefore have a good potential to be used in such applications as water and wastewater treatment where protein and other organic pollutants (including oils) may cause severe fouling problems to conventional polymeric membranes.

Polyvinyl alcohol‐based membranes for filtration of aqueous solutions: A comprehensive review

AbstractThis review provides a comprehensive overview on applications, preparation methods, and most notably the performance efficiency of polyvinyl alcohol (PVA)‐based membranes for filtration of aqueous environments. Incorporation of PVA into the membrane matrix significantly enhances such characteristics as antifouling and antibacterial properties as well as hydrophilicity and permeability in the water and wastewater filtrations. Contribution of different PVA‐based modular membranes for water purification targets via a comparative review on previous researches is the main theme in this work. Alongside with the focused topic, some basic theories and principals of blend and composite polymer films as well as polymer fibers are debated before the main discussions. This review will ultimately facilitate further development of PVA membranes for the future investigations.

Evaluation of the Effectiveness of a Soil Treatment Using Calcium Carbonate Precipitation from Cultivated and Lyophilized Bacteria in Soil’s Compaction Water

Microbial-induced carbonate precipitation (MICP) is a bio-inspired solution where bacteria metabolize urea to precipitate. This carbonate acts as a bio-cement that bonds soil particles. The existing framework has focused mainly on applying MICP through infiltration of liquid bacterial solutions in existing soil deposits. However, this technique is inefficient in soils with high fines content and low hydraulic conductivity, and thus few studies have focused on the use of MICP in fine soils. The main objective of this study was to evaluate the effect of MICP applied to compaction water in soils containing expansive clays and sandy silts. This approach searches for a better distribution of bacteria, nutrients, and calcium sources and is easy to apply if associated with a compaction process. In soils with expansive minerals, the effect of MICP in swelling potential was explored at laboratory and field scales. In sandy silts, the evolution of the stiffness and strength were studied at the laboratory scale. The treatment at the laboratory scale reduced the swelling potential; nevertheless, no significant effect of MICP was found in the field test. In sandy silts, the strength and stiffness increased under unsaturated conditions; however, subsequent saturation dissolved the cementation and the improvement vanished.

Hydrogeology Response to the Coordinated Mining of Coal and Uranium: A Transparent Physical Experiment

The migration of fracture and leaching solute caused by mining activity is critical to the hydrogeology. To characterize liquid and solid migration in a mining area of intergrown resources, the coordinated mining of coal and uranium was considered, and a physical experiment based on transparent soil was conducted. A well experimental performance of transparent soil composed of paraffin oil, n-tridecane, and silica gel and the leaching solution comprised of saturated oil red O dye was observed for hydrogeology characterization. An “arch-shaped” fracture zone with a maximum height of 90 m above the mined goaf and a “horizontal-shaped” fracture zone with a fractured depth of 9.97–16.09 m in the uranium-bearing layer were observed. The vertical leachate infiltration of 4.83 m was observed in the scenario of uranium mining prior to coal, which is smaller than those in the scenarios of comining of coal and uranium (10.26 m) and coal mining prior to uranium (16.09 m). A slight strata movement below the uranium was observed, and the leaching solution infiltration in the coal mining area was not observed in a short period in the scenario of uranium mining prior to coal; both of those was presented in the scenarios of comining of coal and uranium and coal mining prior to uranium.

The research of the composition of mineral component of compact bone tissue after flow delipidation using the optic method

The results of the research of bone mineral component (BMC) composition using the Raman spectroscopy method are presented in the work. The subjects of the research were the groups of BMC samples made of compact bone tissue of cows using “Lyoplast”® technology where vacuum delipidation of initial material was replaced by the flow one by washing it out in hydrogen peroxide and ether. The solution filtration after bone tissue demineralization was used as additional treatment. The results of the experiment show that the flow delipidation can be used for preparing this biomaterial (BMC), which is cost-effective compared to standard vacuum cleaning and additional filtration stage can be rejected.

High-performance nanofiltration membranes consisting of the new functionalized mesoporous for enhanced antifouling attributes and simultaneous removal of salts, dyes and heavy metals

For the first time, the tetrathioterephthalate functionalized KIT-6 (T-KIT-6) mesoporous was synthesized and then characterized using FTIR, XRD, zeta potential, and FESEM analysis. The synthesized T-KIT-6 mesoporous was used to prepare a novel nanofiltration (NF) membrane for the removal of dyes, salts, and heavy metal ions from contaminated waters. The effects of T-KIT-6 mesoporous loading on the membrane morphology, properties, and proficiency were studied by FTIR, EDS, TGA, FESEM, AFM, water contact angle and zeta potential measurements, etc. The performance of the prepared membranes was investigated by milk solution filtration experiments. The maximum pure water flux was 45.2 kg/m 2 h for the membrane containing 0.3 wt% T-KIT-6 mesoporous (TKM-0.3), which was much higher than that of the membrane without mesoporous. Moreover, the TKM-0.3 membrane featured effectual antifouling properties with a low irreversible fouling ratio of 4.8% and a high flux recovery ratio of 95.2%, accompanied by long-term stability. All membranes showed the highest rejection for Na 2 SO 4 and the lowest rejection for NaCl, which was in good accordance with the rejection sequence of the negatively charged NF membranes. The TKM-0.3 membrane also showed the highest dye rejections (˃ 98%) and superior removal of heavy metal ions (Mn 2 + = 98 . 21 % , Cu 2 + = 97 . 52 % , Ni 2 + = 95 . 00 % , Pb 2 + = 93 . 43 % ). Regarding the good performance in multipollutant removal and long-term stability for heavy metal removal, this study describes the fabrication of antifouling NF membrane as an economic and efficient technology for wastewater treatment. • A T-KIT-6 mixed matrix membrane was prepared for removal of salts, dyes and metals. • The effect of T-KIT-6 mesoporous enhanced the hydrophilicity and porosity. • The membrane exhibited superior antifouling properties and metal ions rejection.