Radar word extraction is the analysis foundation for multi-function radars (MFRs) in electronic intelligence (ELINT). Although neural networks enhance performance in radar word extraction, current research still faces challenges from complex electromagnetic environments and unknown radar words. Therefore, in this paper, we propose a promising two-stage radar word extraction framework, consisting of segmentation and recognition. To fill the vacancy of radar word segmentation, we establish the mathematical model from the time series analysis viewpoint and design a novel segmentation neural network based on Bi-direction Long Short-Term Memory with a filter module (BiLSTM-Filt). Specific radar word structure characteristics are extracted by training the network and applied for detecting radar words in the pulse train. To further improve segmentation performance, a bounding box regression method is designed to merge information from sub-region structures. Simulation experiments on a typical MFR, Mercury, reveal that the proposed method can outperform the baseline methods within complex electromagnetic environments, containing corrupted environments, various pulse backgrounds, and variable pulse train lengths. Due to the artificial design structure, the proposed method can also make a trial on unknown radar word segmentation.