Thermal Stability Of Films Research Articles

Thermal annealing effects on optical and dielectric properties of TiOPc thin films for optoelectronic and photonic applications

Abstract Titanyl phthalocyanine (TiOPc) is a metal phthalocyanine compound with interesting electronic and catalytic properties, making it useful in various applications. This study investigates the effects of thermal annealing on the optical and dielectric properties of vacuum-evaporated TiOPc films. The optical and structural characteristics were examined before and after annealing. FTIR spectra show a correlation between the peak positions of the films before and after the annealing process. Additionally, the spectra of the annealed sample show a decrease in C=O and the formation of a coordination bond between the Ti dopant and the phthalocyanine molecule. X-ray diffraction shows an amorphous behavior before and after annealing for TiOPc films. The AFM images show the presence of peaks and valleys of varied sizes. This leads to enhanced light trapping and scattering, improving light absorption and optical properties of the film. Thermal annealing at 473 K for 2 h resulted in a significant reduction in the optical energy gap, with E g1 decreasing by approximately 7% (from 1.58 eV to 1.47 eV) and E g2 by about 6% (from 3.0 eV to 2.83 eV), which indicates the thermal stability of these films. Moreover, the real part of dielectric constants reached appreciable improvements of about 30% at low frequencies. These changes are ascribed to the decreased structural defects and enhanced molecular ordering induced by annealing. The thermal stability of TiOPc films and improvement in the performance of optoelectronic devices such as photodetectors and optical switches by applying TiOPc films can be understood from these explorations. Moreover, the simple and cost-effective vacuum evaporation and annealing fabrication enable large-scale industrial production that would be attractive for application engineers to fully utilize these films in practice.

Color, Structure, and Thermal Stability of Alginate Films with Raspberry and/or Black Currant Seed Oils.

In this study, biodegradable and active films based on sodium alginate incorporated with different concentrations of oils (25% and 50%) from fruit seeds were developed for potential applications in food packaging. The ultraviolet and visible (UV-VIS) spectra of raspberry seed oil (RSO) and black currant seed oil (BCSO) indicated differences in bioactive compounds, such as tocopherols, phenolic compounds, carotenoids, chlorophyll, and oxidative status (amounts of dienes, trienes, and tetraenes) of active components added to alginate films. The study encompassed the color, structure, and thermal stability analysis of sodium alginate films incorporated with RSO and BCSO and their mixtures. The color of alginate films before and after the addition of oils from both fruit seeds was evaluated by measuring color coordinates in the CIELab color space: L* (lightness), a* (red-green), and b* (yellow-blue). The lightness values ranged between 94.21 and 95.08, and the redness values varied from -2.20 to -2.65, slightly decreasing for the films enriched with oils. In contrast, yellowness values ranged between 2.93 and 5.80 for the obtained active materials, significantly increasing compared to the control alginate film (L* = 95.48, a* = -1.92, and b* = -0.14). Changes in the structure and morphology of the alginate films after incorporating bioactive-rich oils were observed using scanning electron microscopy (SEM). Films with RSO and oil mixtures had more developed surfaces than films with BCSO. Moreover, the cross-sections of the films with RSO showed holes evenly distributed inside the films, indicating traces of volatile compounds. Thermal decomposition of the alginate films loaded with oils showed five separate stages (to 125 °C, 125-300 °C, 310-410 °C, 410-510 °C, and 750-1000 °C, respectively) related to the oil and surfactant decomposition. The shape of the thermogravimetric curves did not depend on the oil type. The added oils reduced the efficiency of alginate decomposition in the first stage. The obtained results showed that new functional and thermally stable food packaging films based on sodium alginate with a visual appearance acceptable to consumers could be produced by utilizing oils from fruit seed residues.

Tuning Electrochemical Properties and Thermal Stability of YSZ Mesoporous Thin Films for SOFC Applications

Tuning Electrochemical Properties and Thermal Stability of YSZ Mesoporous Thin Films for SOFC Applications

The Development of Intelligent Film From Crosslinked–Acylation Cassava Starch and Purple Sweet Potato Anthocyanin for Monitoring Indian Mackerel Fish Freshness

ABSTRACTEdible coatings and films have gained significant interest due to their ability to extend the shelf life of fresh products. This research aimed to develop a novel indicator film using crosslinked–stearic acid acylation‐modified cassava starch and anthocyanin extracts, both of which can be utilized to create solid matrices that are safe for consumption. The physical properties of the films improved with the use of modified starch, exhibiting a stronger tensile strength (from 0.96 to 1.02 MPa). Additionally, flexibility increased from 121% to 129%, and the water vapor transmission rate was significantly reduced from 5.86 to 1.79 g/m2/h. Anthocyanin extracts also contributed to improvements in flexibility and reductions in water vapor transmission rate. Differential scanning calorimetry analysis indicated an increase in the film's thermal stability, with a transition temperature shifting from 276°C to 299°C, attributing to changes in the starch characteristics following modification. Fourier transform infrared spectroscopy revealed alterations in the molecular interactions between the CH and CC groups. The application of these edible films for storing and monitoring Indian mackerel fish meat demonstrated consistent results, particularly in terms of color change due to an increase in pH levels (from 7 to 8.5 over 2 days). Furthermore, TVB‐N levels in fish meat covered with the edible film were successfully reduced from 71 to 46 mg/100 g over the same period. These findings indicate that the films can function as intelligent food packaging, possessing antioxidant properties beneficial for human health while being biodegradable, thus reducing their environmental impact.

Thermal stability of Li films on a polycrystalline W substrate

Thermal stability of Li films on a polycrystalline W substrate

Physical properties and thermal stability of zirconium platinum nitride thin films

Ternary transition metal nitrides (TMNs) promise to significantly expand the material design space by opening new functionality and enhancing existing properties. However, most systems have only been investigated computationally, and limited understanding of their stabilizing mechanisms restricts translation to experimental synthesis. To better elucidate key factors in designing ternary TMNs, we experimentally fabricate and analyze the physical properties of the ternary Zr–Pt–N system. Structural analysis and density functional theory modeling demonstrate that Pt substitutes nitrogen on the nonmetallic sublattice, which destabilizes the rock salt structure and forms a complex cubic phase. We also show insolubility of Pt in the Zr–Pt–N at 45 at. % with the formation of a secondary Pt-rich phase. The measured reduced plasma frequency, decrease in resistivity, and decrease in hardness reflect a dominance of metallic behavior in bonding. Additionally, we observe the exsolution of Pt nano precipitates from the Zr–Pt–N films upon annealing as well as degradation in the nitridic film's thermal stability. Even at low concentrations (1%), Pt facilitates a solid reaction with the Si substrate that is otherwise inaccessible in ZrN films.

Investigation of Wettability, Thermal Stability, and Solar Behavior of Composite Films Based on Thermoplastic Polyurethane and Barium Titanate Nanoparticles.

Herein, composite films were produced by incorporating different amounts (1, 3, 5, and 7%) of barium titanate nanoparticles into the thermoplastic polyurethane matrix using a solution casting method. This study examined the impact of the presence and concentration of a barium titanate additive on morphologic properties, mechanical performance, thermal stability, solar behavior, and wettability of produced film samples. The films were characterized by Fourier transform infrared spectroscopy, differential scanning calorimetry, thermal gravimetric analysis, scanning electron microscope, ultraviolet-visible near-infrared spectrophotometer, water contact angle, and tensile strength measurements. In the present study, the mass loss of samples containing 7% barium titanate was 24% lower than that of the pure polyurethane reference. The increase of barium titanate rate added to polyurethane enhanced the solar reflectance property of the films, including the near-infrared region. As a prominent result, the transmittance value decreased significantly compared to the reference in the ultraviolet region, and it dropped to 3% for the highest additive concentration. The contact angle values of polyurethane films increased by 11-40% depending on the barium titanate addition ratio. The nano additive also positively affected the mechanical performance of the reference polyurethane film by slightly increasing the tensile strength values.

Influence of substrate polarity on thermal stability, grain growth and atomic interface structure of Au thin films on ZnO surfaces

The influence of the polarity of ceramic substrates on the structural evolution of thin metal films during annealing at elevated temperatures is investigated, including the competing processes of solid state dewetting (SSD) and grain growth, as well as the atomic structure of the epitaxial interface. For this purpose, Au thin films on polar O-ZnO(0001‾) and Zn-ZnO(0001) surfaces are annealed at elevated temperatures and times. Whereas SSD dominates on the O-terminated surface, pronounced grain growth is observed on the Zn-terminated surface. The texture analysis revealed that up to 600 °C, both samples exhibit a fiber texture with slightly dominating Au(111)[110] || ZnO(0001)[112¯0] orientation relation (OR 2). At 800 °C, Au on Zn-ZnO exhibits a transformation to a mazed bicrystal structure with Au(111)[110] || ZnO(0001)[101¯0] orientation relation (OR 1). Comparison of various interface structures in density-functional theory (DFT) indicates that atomically sharp interfaces between the Au(111) films and the ideal bulk-truncated polar ZnO surfaces are energetically favored for both substrate polarities in excellent agreement with atomically resolved electron microscopy. Due to the larger period of the coincidence site lattice in OR 2, the corresponding interface can be described as semi-coherent with clearly separated misfit dislocations. In contrast, the much smaller period of the (approximate) coincidence site lattice in OR 1 leads to a largely incoherent interface with local reconstructions. However, in the experimental situation, even a small rotational deviation from the perfect OR 1 can introduce an interfacial screw dislocation network superimposed on the incoherent interface structure, effectively making the interface semi-coherent.

PH-responsive color indicator film based on gelatin/chitosan cross-linking with anthocyanin-Fe2+ chelate for pork freshness monitoring

In this study, the film matrix was formed through polycondensation reactions between citric acid (CA) as a cross-linking agent and bovine bone gelatin (BG) and chitosan (CS). Using blueberry anthocyanin-iron ion chelate (BA-Fe2+) as a pH-sensitive indicator, we aimed to develop a highly sensitive indicator film to monitor the freshness of pork effectively. The study found that adding 50% CS and 7.5% CA maximizes BG's mechanical strength and transmittance. In contrast, chelation with 4 mg/mL blueberry anthocyanin (BA) and 0.05 mg/mL FeSO4·7H2O significantly increases the film's sensitivity to ammonia vapor from 47.23% to 64.49%, without compromising its film-forming ability. Fourier Transform Infrared Spectroscopy and X-ray Diffraction analyses confirmed that the BA-Fe2+ chelate was successfully incorporated into the crosslinked matrix without disrupting its inherent structure. This integration was achieved through hydrogen bonding between the hydroxyl groups of the chelate and the hydroxyl, amino, and ester bonds of the crosslinked matrix. Using scanning electron microscopy and atomic force microscopy, the analysis revealed that the surface of the crosslinked matrix exhibits the advantages of being both dense and highly porous. The colorimetric parameters of the film in different pH buffer solutions indicate that the BA-Fe2+ films generally exhibit greater color differences, making them more easily discernible by the naked eye compared to the films with BA alone. Additionally, the film's thermal stability, barrier properties, antioxidant and antimicrobial activities, and the controlled release capability of BA, have all been significantly enhanced (p < 0.05). Finally, fresh pork packaging experiments validated its efficiency in monitoring meat spoilage. This comprehensive assessment confirms the suitability of our developed film for meat packaging applications, offering a novel solution for meat freshness monitoring.

Effect of Morphology and Concentration of CeO2 Nanoceria on the Thermal Stability of Polyvinyl Alcohol Films

Objective: To determine the thermal stability of polyvinyl alcohol films under different concentrations of CeO2 nanoceria. Method: Cerium Oxide doped polyvinyl alcohol (PVA) nano-composites were synthesized by the traditional solution casting method for various concentrations of nano CeO2 by solution combustion method. The thermal properties of prepared PVA-2.5 wt% CeO2, PVA-7.5 wt% CeO2 , PVA-12.5 wt% CeO2, and PVA-25 wt% CeO2 composite films were elucidated by using techniques such as Differential Scanning Calorimetry, Thermogravimetry analysis and Differential Thermal analysis. Findings: The glass transition temperature of the pure PVA is found to be 114°C, whereas it varies between 110°C-120°C for composite films. The melting temperature of the composite films is the same as that of pure PVA except in the case of 7.5wt% CeO2 and 25wt% CeO2 composites. The reduced melting point of these composites elicits a decrease in crystallinity. A 12.5 wt % and 25 wt% CeO2-PVA nano-composite films exhibit an increase in the final degradation temperature, a high specific heat capacity, low mass loss, and a larger residual weight, indicating their potential applicability in thermal coating and thermal sensing applications. Polyvinyl alcohol (PVA) films are being used routinely as a dielectric layer for electrical applications due to the good physiochemical and dialectic properties of the material. An incorporation of CeO2 nanoceria improves not only the thermal but also the mechanical properties of PVA and extends its application for electrical and optical operation. Here in the present study, different concentrations of CeO2 were incorporated with the PVA and analysed for the thermal properties. The study showed that 12.5 wt % and 25 wt% CeO2-PVA nano-composite enhanced PVA film thermal stability. Keywords: PVA-CeO2 Nanocomposites; Differential Scanning Calorimetry; Thermogravimetry Analysis and Differential Thermal Analysis; Physical properties and thermal properties

Preparation of pectin/carboxymethyl cellulose composite films via high-pressure processing and enhancement of antimicrobial packaging

This study investigated the impact of high-pressure processing (HPP) treatment on the structure and physicochemical properties of pectin (PEC)/carboxymethyl cellulose (CMC) composite films, along with the development of new active films incorporating emodin as an antibacterial agent. The results showed that 500 MPa/20 min HPP treatment significantly improved the tensile strength (from 45.91 ± 4.63 MPa to 52.24 ± 4.87 MPa) and elongation at the break (from 5.00 ± 1.44 % to 11.72 ± 2.97 %) of the films. It also improved the film's thermal stability and had no significant effect on its thermal degradability. Moreover, emodin was incorporated into the PEC/CMC film-forming solution and subjected to 500 MPa/20 min HPP treatment to investigate the structure, functional properties, optical properties, and antibacterial activity of the film. The emodin caused the film structural alteration, but significantly improved the water vapor barrier properties. It also reduced the film brightness and light transmission. The antibacterial assessment demonstrated that the film's antibacterial activity was correlated positively with increasing emodin content, and the number of viable cells of Staphylococcus aureus decreased by 1.29 log10 CFU/mL, 1.70 log10 CFU/mL, and 1.80 log10 CFU/mL with different levels of EM antimicrobial films after 12 h.

Green synthesized CeO2 nanoparticles-based chitosan/PVA composite films: Enhanced antimicrobial activities and mechanical properties for edible berry tomato preservation.

The current study is intended to enhance unique bioactive and eco-friendly composite films following a simple solvent-casting approach by incorporating cerium oxide nanoparticles (CeO2 NPs) with a chitosan (CS)/polyvinyl alcohol (PVA) matrix. Antimicrobial activity, preservation impact, mechanisms for the edible berry tomatoes and physicochemical properties of the produced films were tested. FTIR, SEM-EDX, XRD, UV–vis spectroscopy and contact angle were used to characterize the films. Incorporated (3.0 wt%) CeO2 NPs practically developed composite film's thermal stability, structural, mechanical, bioactive, antioxidant, barrier and wettability properties. The tomatoes' look, weight loss and stiffness were better preserved after 25 days of storage at room temperature (25 ± 5 °C) when 3.0 wt% CeO2 NPs films were used instead of the original CS/PVA film. CS and CeO2 NPs have unique physiochemical and antibacterial properties. Food packaging extensively investigates the modified films as antimicrobials and preservatives to increase the shelf life of packaged foods, owing to their ability to inhibit gram-positive bacteria (Bacillus cereus and Staphylococcus aureus), gram-negative bacteria (Klebsiella pneumoniae and Pseudomonas aeruginosa), and filamentous fungi (Bipolaris sorokiniana, Fusarium op., and Alternaria sp.). Our findings indicated that the CeO2/CS/PVA composite films could be used as effective wrapping materials for food preservation.

Impact of agar–glycerol ratios on the physicochemical properties of biodegradable seaweed films: A compositional study

To develop technology more applicable to industrial settings, this study aimed to produce agar-based bioplastic films using extrusion followed by hot compression. The research examined various amounts of glycerol incorporation as the plasticizer, which also facilitated the flowability of the extrusion process. These variations included agar–glycerol ratios of 75:25, 70:30, 65:35, 60:40, and 55:45 (% w/w). Moreover, the films underwent thorough testing to assess their physical, mechanical, chemical, water sensitivity, surface imaging, and biodegradability properties. The results showed that increasing the amount of glycerol in the agar film matrix generally made the films more sensitive to water, resulting in greater hydrophilicity. This change was primarily owing to the increased presence of hydroxyl groups. It also affected other characteristics, such as enhancing the film's stretchability and thermal stability. Furthermore, a decrease in film density was observed, leading to reduced tensile strength and barrier properties. Moreover, the higher glycerol content improved its surface wettability and the higher agar content accelerated the film's biodegradability rate. Microstructural examination using scanning electron microscopy and chemical analysis (FTIR) revealed a homogeneous mixture of agar and glycerol produced through the extrusion process. These findings demonstrate the potential of extrusion techniques for the large-scale production of agar-based bioplastics.

Thermal stability of gold films on titanium-adhered silicon substrate

In this study, thermally induced changes in the surface of a thin gold film deposited on Si(100) with a 5 nm thick titanium adhesion layer were investigated. The analysis involved X-ray photoelectron spectroscopy, low-energy electron diffraction, and scanning tunnelling microscopy. The sample was subjected to stepwise annealing under ultra-high vacuum conditions at temperatures ranging from 430 to 1330 K. Low-temperature annealing up to 450 K did not alter the morphology but improved the cleanliness of the gold film surface. Annealing between 530 and 930 K resulted in the disintegration of the gold film, along with mixing and interaction between the sample components. Annealing the sample at 980 K led to the emergence of a gold silicide surface on Si(100) exhibiting the (5 × 3.2)R5.7° reconstruction.

Biodegradable active composite film based on pea protein isolate, sage seed gum, and cumin essential oil: Fabrication and characterization

The present study perused the physicochemical, mechanical, thermal, barrier, and optical properties of pea protein isolate (PPI)-Sage seed gum (SG) (3:1, 1:1, and 1:3) composite films incorporated with cuminum essential oil (CEO, 0, 1, and 2 %). Results indicated that the thickness, contact angle (CA), yellowness index (a*), total color differences (∆E), and opacity (OP) significantly enhanced with increasing PPI portion and CEO concentration (p < 0.05), as well as heterogeneous and inconsistent structure were increased in film surface due to protein agglomeration and oil droplets. However, the moisture content (MC), water solubility (WS), and swelling ratio (SR) decreased. Results also indicated that the antioxidant property significantly increased (P < 0.05) following the increase in CEO concentration. The highest tensile strength (TS) and elastic modulus (EM) and the least elongation at break (EAB) in PPI 3-SG 1–0 % were estimated. The potential antimicrobial property of CEO containing film was confirmed, and the maximum inhibition zone for E.coli, S.aureus, C.albicans, and A.niger were measured in film containing 2 % CEO. The barrier properties of the film against water and oxygen (WVP, OXP) diminished with increases the SG ratios, due to the hydrophilic nature of SG. The FTIR analysis identified the functional groups in film components and the interaction between film components. The DSC thermogram indicated the thermal stability of films and the highest decomposition temperature in PPI 3-SG 1–2 % film. XRD revealed a semi-crystalline structure of biopolymer active films. With the increase of SG portion and CEO concentration, the crystallinity of the films was enhanced. Results also indicated that prepared films were more than 90 % biodegradable.

Exploring the Feasibility of Polysaccharide-Based Mulch Films with Controlled Ammonium and Phosphate Ions Release for Sustainable Agriculture.

Bio-based polymers are a promising material with which to tackle the use of disposable and non-degradable plastics in agriculture, such as mulching films. However, their poor mechanical properties and the high cost of biomaterials have hindered their widespread application. Hence, in this study, we improved polysaccharide-based films and enriched them with plant nutrients to make them suitable for mulching and fertilizing. Films were produced combining sodium carboxymethyl cellulose (CMC), chitosan (CS), and sodium alginate (SA) at different weight ratios with glycerol and CaCl2 as a plasticizer and crosslinker, respectively, and enriched with ammonium phosphate monobasic (NH4H2PO4). A polysaccharide weight ratio of 1:1 generated a film with a more crosslinked structure and a lower expanded network than that featuring the 17:3 ratio, whereas CaCl2 increased the films' water resistance, thermal stability, and strength characteristics, slowing the release rates of NH4+ and PO43-. Thus, composition and crosslinking proved crucial to obtaining promising films for soil mulching.

Development of Polymeric Films Based on Sunflower Seed Proteins and Locust Bean Gum.

Most polymeric food packaging materials are non-biodegradable and derived from petroleum, thus recent studies have focused on evaluating alternative biodegradable materials from renewable sources, with polysaccharides and proteins as the main types of employed biopolymers. Therefore, this study aimed to develop biopolymeric films based on sunflower proteins and galactomannans from locust bean gum. The influence of the galactomannan amount (0.10%, 0.30%, 0.50%, and 0.75% w/v) on the physicochemical, thermal, and mechanical properties of cast sunflower protein-based films was studied. Sunflower proteins gave rise to yellowish, shining, and translucid films. With the incorporation of locust bean gum-derived galactomannans, the films became more brown and opaque, although they still maintained some translucency. Galactomannans significantly changed the proteins' secondary structures, giving rise to films with increased tensile resistance and stretchability. Nevertheless, the increase in the galactomannan amount did not have a significant effect on the film's thermal stability. The protein/galactomannan-based films showed values of water vapor and oxygen permeability that were slightly higher than those of the pristine materials. Overall, blending locust bean gum galactomannans with sunflower proteins was revealed to be a promising strategy to develop naturally colored and translucid films with enhanced mechanical resistance while maintaining flexibility, fitting the desired properties for biodegradable food packaging materials.

Thermal stability prediction of copolymerized polyimides via an interpretable transfer learning model

To address the issues with molecular representation of copolymerized polyimides (PIs) and the mini dataset of PI powders. We constructed an interpretable machine learning (ML) model for PI films using the weighted-additive Morgan Fingerprints with Frequency descriptors and developed an interpretable transfer learning model for PI powders. To enhance Thermal Stability (Temperature at 5% weight loss) of PI films and powders, it is recommended to add conjugated functional groups to diamines, control phenyl ring side chains, and reduce pyridine and hydroxyl groups; select copolyimides (co-PIs); ensure that anhydride is directly connected to the benzene ring in dianhydrides, avoiding aliphatic cycles. It is noteworthy that the close alignment between experimental results and model predictions serves to confirm the model is a reliable prediction tool. It is hoped that this polymer informatics approach will provide further implementation for practical applications of other functional materials.

Nelumbo nucifera flower extract incorporated alginate/polyvinyl alcohol films as a sustainable pH indicator for active food packaging applications

In recent years, there has been a growing demand for environmentally friendly smart packaging materials. Therefore, in this study, we developed an eco-friendly pH-sensitive indicator film through the solvent casting process, incorporating alginate, polyvinyl alcohol, garlic, and Nelumbo nucifera flower extract. The effect of extract on the chemical and physical properties of the film were extensively studied using various characterization techniques. XRD and FTIR reveal the strong interaction between the polymers and the extract. The incorporation of the extract influenced various parameters such as swelling behavior, water solubility, and moisture content, while also improving the film's thermal stability, biodegradability, as well as its antioxidant and antimicrobial properties. Interestingly, the film exhibited a color change in response to pH change. During shrimp storage, the film showed a visible transition from purple to green, indicating shrimp spoilage. Additionally, the film's ability to detect freshness was confirmed by measuring total volatile basic nitrogen (TVBN). These findings suggest that the PVA/alginate/garlic/Nelumbo nucifera film shows promise as an intelligent packaging material for real-time food monitoring applications.

Fabricating active Egg Albumin/Sodium Alginate/Sodium Lignosulfonate Nanoparticles film with significantly improved multifunctional characteristics for food packing

In food packaging, sodium lignosulfonate nanoparticles (SLS NPs) showed significant antibacterial properties, antioxidant and UV barrier activities. Herein, the SLS NPs were synthesized via a sustainable green method and were added into egg albumin/sodium alginate mixture (EA/SA) to fabricate a safe, edible EA/SA/SNPs food packaging. A composite film EA/SA/SNP was examined microstructurally and physicochemically. The mechanical characteristics, UV protection, water resistance, and the composite film's thermal stability were all enhanced by the inclusion of SLS NPs, and water vapor permeability reduced by 44 %. This composite film exhibited robust antioxidative properties with DPPH and ABTS free radical scavenging rates reaching 76.84 % and 92.56 %, and effective antimicrobial activity against Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus) with antibacterial rates reaching 98.25 % and 97.13 % for the positively charged nanoparticles interacting with the cell membrane. Freshness tests showed that the EA/SA/SNPs packaging film could delay the quality deterioration of fresh tomatoes. This composite film can slow down spoilage bacteria proliferation and prolongs food's preservation period by eight days at ambient temperature.