Filler Material Research Articles

Field study on vegetation eco-protection technology for red sandstone fill slope against water damage

The construction of fill slopes becomes a critical aspect when there is a need to change the terrain or create new terrain. However, due to the poor engineering properties of the fill material, especially when red sandstone with notable disintegration properties is used, the risk of slippage or collapse may occur. This material is prone to erosion and disintegration under the action of natural factors such as heavy rainfall, leading to severe soil erosion and slope instability. In addition, the construction of fill slopes inevitably causes the destruction of native vegetation, exacerbating environmental problems. To address these problems, an novel ecological approach for preventing water damage to red sandstone fill slopes was developed using the vegetation–high-performance turf reinforcement mat –anchor–drainage pipe–synergistic slope protection system. Three test red sandstone slopes with different protection methods (unprotected, three-dimensional (3D) protection mesh, and vegetation ecological protection system slopes) were constructed, and the feasibility and reliability of ecological protection against water damage to red sandstone fill slopes were analysed via the field test method. The results showed that the vegetation ecological protection system can effectively inhibit soil erosion and increase the survival rate of vegetation roots. Moreover, the the high-performance turf reinforcement mat provides a strong protective complex through interactions with vegetation roots, anchors, and drains, which significantly enhances slope stability. Under heavy rainfall conditions, the vegetation ecological protection system can effectively limit slope erosion due to water scour, thus maintaining the structural integrity of the slope.

Synthesis of stable fluorescent ethylene-vinyl acetate copolymers based on in-situ grafted rare-earth organic complexes and antioxidants through transesterification

The synthesis and application of rare earth organic complexes (REOCs) are gaining attention due to their advantages including low excitation thresholds and high luminescence efficiencies. However, their integration as functional fillers in polymer matrices is constrained by challenges related to poor dispersion and limited stability. This study introduces a novel method for synthesizing stable fluorescent polymers by co-grafting europium (Eu) complexes and the antioxidant 3,9-bis-{1,1-dimethyl-2[β-(3-tert-butyl-4-hydroxy-5-methylphenyl-)propionyloxy]ethyl}-2,4,8,10-tetraoxaspiro[5.5]-undecane (AO-80) onto an ethylene-vinyl acetate (EVA) matrix through an in-situ synchronous grafting strategy, aiming to address these dual challenges of poor dispersion and rapid aging. In this study, Eu complexes characterized by low excitation thresholds and high hexahydrate (EuCl3) and selected ligands - 1,10-phenanthroline (Phen), alpha-thienyl trifluoroacetone (HTTA), and 4-acetoxybenzoic acid (4-ABA). Through transesterifications, the Eu complexes were successfully grafted onto the EVA chain, achieving a uniform dispersion within the EVA matrix to form fluorescent polymers. Furthermore, the incorporation of antioxidant AO-80 as a radical scavenger can significantly mitigate fluorescence attenuation. Through detailed exploration of transesterifications under various conditions, optimal grafting rates of 11.34% for EVA with Eu complexes and 22.87% for EVA with AO-80 were achieved. The synthesized fluorescent polymers of EVA synchronously grafted with Eu complexes and AO-80 have been proven to obtain markedly improved fluorescence stability and aging resistance by outdoor aging tests. Our findings not only validate the in-situ reaction grafting method as an efficient strategy for producing polymer composites with excellent fluorescence stability but also pave the way for future research aimed at overcoming the limitations of REOCs in photovoltaic and agricultural applications.

Investigation on microstructural and mechanical integrity of GTAW dissimilar welded joint of IN 718/ASS 304L using Ni-based filler IN 625 using EBSD and DHD techniques

The current study investigates the relationship between the microstructural and structural characteristics of dissimilar gas tungsten arc welding (GTAW) between Inconel 718 (IN 718) and austenitic stainless steel 304L (ASS 304L) using Inconel 625 (IN 625) as a filler material. The microstructural characterization of the dissimilar weld includes the application of an optical microscope (OM), field emission scanning electron microscopy (FE-SEM) including energy dispersive spectroscopy (EDS), and electron backscatter diffraction (EBSD). The optical and FESEM analysis of the base metals (BM) indicates the austenitic nature of the IN 718 BM matrix, which incorporates strengthening precipitates γ′ and γ'' distributed throughout the Nickel matrix. In contrast, the ASS 304L BM exhibits an austenitic microstructure along with twins. Moreover, IN 625 weld metal exhibits austenitic microstructure in the form of cellular, columnar, and equiaxed dendrites. Elemental segregation demonstrates the existence of Nb, and Mo-rich carbides, including the laves phases at the interdendritic regions of the IN 625 weld zone and IN 718 Heat-Affected Zone (HAZ). Ferrite stringers were noticed in the HAZ of ASS 304L. EBSD analysis shows the improved texture of the weld zone exhibiting fine equiaxed recrystallized microstructures. EBSD/Kernel average misorientation (KAM) micrographs reveal the existence of high strain at the weld metal grain boundaries. Vickers microhardness assessment of the dissimilar weld demonstrates the high hardness of 257.5 HV for the IN 625 weld zone because of the occurred NbC, laves phases, and Mo-rich carbides. Room temperature tensile characterization shows the failure of tensile specimens from ASS 304L BM reflecting the high strength of the IN 625 weld metal (662 MPa). Tensile tests at high temperatures were performed at 550 °C, 600 °C, and 650 °C. High-temperature tensile result exhibits a higher tensile strength of IN 625 weld zone than the ASS 304L BM, as the tensile specimens fails from 304L BM. The specimen exposed at 550 °C exhibits the highest tensile strength of 388 MPa. The Charpy impact toughness test was conducted, with notches at the HAZ of ASS 304L, HAZ of IN 718, and the weld center being evaluated. The toughness value of the weld metal decreases (99 J) due to occurrence of the secondary precipitates. To analyze residual stress, the deep hole drilling (DHD) technique was used, which revealed that the peak residual stress (230 MPa) is induced at 6 mm from the weld surface and falls into the tensile stress category.

Flexural behavior analysis of double honeycomb steel composite encased concrete beams: An integrated experimental and finite element study

This research addresses a critical issue in composite sections—insufficient concrete flow on both sides of the steel beam web, leading to discontinuity in the filler material. The study focuses on double honeycomb beams in concrete-enclosed steel structures, categorizing them as pure and enclosed steel. A two-phase approach, comprising experimental and numerical analyses, was employed. Fabrication of specimens representing both beam types was followed by bending tests using the STD600 apparatus. The primary specimen showcased the significant advantages of composite beams over conventional steel in bending scenarios. In the experimental phase, two practical solutions were introduced—transforming beam profiles into honeycomb configurations and optimizing spatial constraints around the central linear variable differential transformer (LVDT). Finite element models, validated against test results, demonstrated the practicality and accuracy of Abaqus software. The findings highlight superior flexural behavior in composite beams, presenting promising implications for the construction industry.

Characterisation of a New Generation of AlMgZr and AlMgSc Filler Materials for Welding Metal–Ceramic Composites

When manufacturing the welded joints of components made of metal–ceramic composites of the Al-Si/SiC type, we encounter significant difficulties. This is related to the presence of a ceramic phase in the aluminium alloy matrix. The interaction between the molten metal matrix and the ceramic particles in the weld pool influences a complex of physicochemical phenomena resulting in, among other things, the structure of the welded joint. This is particularly true of the effect of the distribution of ceramic particles and their influence on the crystallisation process in the weld pool. An important issue is the influence of the reinforcing particles on the susceptibility of the aluminium matrix to both hot and cold cracking. The scope of the research included the development of the chemical composition of an additive material for the TIG welding of aluminium–ceramic composites. This material was made in the form of so-called sticks, cast from alloys containing elements such as magnesium, scandium or zirconium in addition to aluminium. The appropriate composition of the mass content of the individual components was intended to change the crystallisation mode of the weld pool and to obtain strengthening precipitates. The most favourable structure was obtained in the case of a modification of the AlMg5 alloy by the addition of scandium. Minor dispersions of Al3Sc became the nucleation pads of fine grains, which improved the mechanical properties of the alloy. Also, in the case of the addition of zirconium, the crystallisation shifted from dendritic to fine-grain growth. In this paper, the basic strength properties of the developed materials were tested and the most favourable chemical compositions of the filling materials were selected.

The influence of doping with different surface modified SiO2 nanoparticles on the dielectric properties of natural ester insulating oil

Nanoparticles are presently considered to be high-potential filler materials in insulation medium. Surface-modified nanoparticles can not only improve the compatibility between nanoparticles and insulation liquid but also enhance the dielectric properties. Herein, models of soybean oil-based natural ester insulation oil doped with two silane coupling agents (A151, KH550) modified SiO2 were established, respectively. Molecular dynamics and DFT first principles were applied to explore the effect of two nanoparticles on the dielectric properties of liquid-insulation medium. The results showed that two types of nanoparticles can restrict the diffusion of water molecules by forming hydrogen bonds, while the number of hydrogen bonds in KH550–SiO2 is one-third more than that in A151-SiO2, and the interaction energy is lower, demonstrating a stronger adsorption effect on water molecules. Moreover, surface electrostatic potential and frontier molecular orbitals showed that KH550–SiO2 have a higher adsorption on charged particles in natural ester insulation oil, which can further inhibit the development of streamer discharge in the liquid insulation medium, improve its dielectric property and delay the aging and deterioration of natural ester insulation oil. This study extends our knowledge into the influence of silane coupling agents modified SiO2 nanoparticles on the dielectric performance of liquid insulation materials from a microscopic perspective.

Modified Release 3D-Printed Capsules Containing a Ketoprofen Self-Nanoemulsifying System for Personalized Medical Application.

This study explores the realm of personalized medicine by investigating the utilization of 3D-printed dosage forms, specifically focusing on patient-specific enteric capsules designed for the modified release of ketoprofen, serving as a model drug. The research investigates two distinct scenarios: the modification of drug release from 3D-printed capsules crafted from hydroxypropyl methylcellulose phthalate:polyethylene glycol (HPMCP:PEG) and poly(vinyl alcohol) (PVA), tailored for pH sensitivity and delayed release modes, respectively. Additionally, a novel ketoprofen-loaded self-nanoemulsifying drug delivery system (SNEDDS) based on pomegranate seed oil (PSO) was developed, characterized, and employed as a fill material for the capsules. Through the preparation and characterization of the HPMCP:PEG based filament via the hot-melt extrusion method, the study thoroughly investigated its thermal and mechanical properties. Notably, the in vitro drug release analysis unveiled the intricate interplay between ketoprofen release, polymer type, and capsule thickness. Furthermore, the incorporation of ketoprofen into the SNEDDS exhibited an enhancement in its in vitro cylooxygenase-2 (COX-2) inhibitory activity. These findings collectively underscore the potential of 3D printing in shaping tailored drug delivery systems, thereby contributing significantly to the advancement of personalized medicine.

Machine learning-based study on the mechanical properties and embankment settlement prediction model of nickel–iron slag modified soil

Nickel–iron slag, a byproduct of industrial processes in China with an annual production exceeding 400,000 tons, is considered an industrial waste material. This study focuses on the rational utilization of nickel–iron slag by investigating its mechanical properties and road performance as a roadbed fill material. Initially, a detailed analysis of the grading curve of pure nickel–iron slag was conducted, leading to the proposal of various modification schemes for nickel–iron slag. Subsequently, static triaxial tests were performed on nickel–iron slag-clay mixtures to explore the impact of different factors on the stress–strain curve of nickel–iron slag-modified soil. Utilizing these discoveries, a formula for the molar Coulomb shear strength of nickel–iron slag-modified soil was derived. In addition, a numerical simulation study of a nickel–iron slag-reinforced embankment was conducted, integrating field tests. This aimed to investigate the variations in the compression layer sedimentation-thickness ratio and settlement factor of nickel–iron slag-modified soil reinforced embankment under different filling heights and slope rates. The results informed the development of a prediction model for the settlement ratio of nickel–iron slag-modified soil-reinforced embankment. Key findings indicate that pure nickel–iron slag exhibits poorly graded gravel sand characteristics, and optimal gradation is achieved when clay doping ranges from 30% to 40%. As the clay content increases, the stress–strain curve of nickel–iron slag-clay transitions from strain-hardening to strain-softening. Furthermore, the stress–strain curve of nickel–iron slag-cement-clay exhibits strain-softening, and the shear strength fitting formula demonstrates high computational accuracy with a small error range. Numerical simulations reveal that the sink-thickness ratio and settlement factor are minimally affected by the slope rate. The sink-thickness ratio increases with the elevation of filling height, while the settlement factor fluctuates within a small range. The proposed sink-thickness ratio prediction model exhibits high accuracy and strong generalization capabilities. This comprehensive study provides valuable insights into the efficient utilization of nickel–iron slag in construction and road engineering.

Fabrication of mechanical durable novolac matrix composites with recycled and cost-effective candle-soot nano particles

Novolac matrix composites are crucial due to their exceptional resistance to heat, chemicals, and mechanical stress. These advanced materials find applications in aerospace, electronics, and automotive industries, providing high-performance solutions for components requiring superior durability and reliability. In this context, the microstructure, thermal, phase, and mechanical properties of the composites obtained as a result of the recycling-oriented reinforcement of the waste candle-soot (CS) reinforcement at the rate of 1 wt% to the pure novolac (PN) and shaping with the hot press method were examined in detail at first time in the literature. While microstructural properties and fracture mechanisms were investigated by scanning electron microscopy (SEM), thermal properties were investigated by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). The results obtained provided critical findings as the composite hardness, tensile strength, and flexural strength values were 3.28, 2.47, and 3.21 times higher than PN, respectively. CS-reinforced novolac composites made a significant contribution to the literature by introducing a novel and eco-friendly approach to enhance material properties. Their use as a filler material provided insights into sustainable novolac composites, offering potential applications in various industries, such as electronics and aerospace, with improved mechanical and thermal properties.

Pull-out response of a geogrid buried in recycled sands

Recycled construction and demolition waste (RCDW) has demonstrated geotechnical properties that encourage it to be used in reinforced soil structures (RSS) with geosynthetics. However, the interaction between RCDW and reinforcements needs to be better understood, given its importance for design. This paper presents a qualitative study on the interaction between geogrid and recycled sands by means of pull-out tests performed on small equipment. Tests with the same degree of compaction and a geogrid buried in different types of recycled and natural sands (for comparison purposes) were performed. The characterisation of the materials was carried out in the laboratory and the variability of their geotechnical properties was evaluated. In addition, fill material moisture content was investigated as another potential factor influencing soil-geogrid interface shear. The results of the pull-out tests demonstrated the specific influences of the factors investigated. The comparative study showed that recycled sands can be suitable materials to be used as backfill in geosynthetic reinforced soil structures, meeting physical, mechanical and environmental requirements for this kind of work.

Mechanical investigation for enhancing jute fibre vinyl ester composite performance through garnet waste utilization

This study explores the potential utilization of garnet waste, a byproduct of the Abrasive Water Jet Machining process, as a promising filler material in composite manufacturing. The disposal of garnet waste presents significant environmental and economic challenges, underscoring the need for sustainable waste management strategies. To tackle these challenges, this research investigates the incorporation of garnet waste into composites to create value-added materials. Consequently, the study focused on developing garnet-filled jute fibre-reinforced vinyl ester composites using the hand layup method. Various mechanical properties including flexural strength, tensile strength, hardness, and impact strength were assessed. The findings demonstrate that the inclusion of garnet filler enhances the mechanical strength of the composites. Particularly, composites containing 10 wt% garnet exhibit notable improvements in tensile, flexural, impact, and hardness strengths, with increases of 40%, 124%, 26%, and 15%, respectively. This research has the potential to advance the development of advanced materials across diverse industries, marking a significant stride towards sustainable and value-driven composite manufacturing practices.

Multi-objective optimisation of a thermocline thermal energy storage integrated in a concentrated solar power plant

Most of CSP plants built today are all equipped with storage devices. Most are sensitive heat storages, in particular 2-tank systems. The aim of this study is to optimise a thermocline storage, designed for the Andasol CSP plant in Spain, on the basis of exergy, environmental and economic criteria. The optimum tank geometry, particle size and heat transfer fluid/filler material pair must be determined. To achieve this, six different fillers operating with Dowtherm A synthetic oil are being investigated: machined ceramics, ceramics obtained from waste materials and natural rock. The NSGA-II multi-objective genetic algorithm is used to solve the problem. This optimisation selects recycled ceramics as best filler materials. The exergy efficiency is not affected by the filler, with more than 99.8%. The application of TOPSIS method combined with weighting derived from Shannon entropy, selects recycled ceramic obtained from electric furnaces as the best filler. This tank has a tapered shape (diameter of 27.4 m, height of 22.2 m) and a very small particle diameter (6 mm). Compared with an earlier design available in literature, the environmental impact is reduced by 19%. The LCOE reaches 10.8 c€/kWhe, a 48% reduction compared with the selling price of heat in Spain (in 2021).

Peptides-modified cellulose microspheres for adsorption of ochratoxin A: Performance and mechanism

In this study, peptides with ochratoxin A (OTA) recognition and adsorption capability were designed, among which lysine, histidine, arginine and tyrosine were crucial. Peptide CYFRFYSNLHPK showed the strongest affinity for OTA (Ka = 1.74 × 105 M−1). Theoretical calculations revealed that the differences in the affinity of peptides for OTA were attributed to differences in the type, number and position of amino acids residues. Peptides were conjugated with porous cellulose microspheres to form peptide-modified pretreatment materials (Pep-MPA-RCMs) for adsorption of OTA. The morphology and composition of the prepared Pep-MPA-RCMs were characterized by scanning electron microscopy, X-ray photoelectron spectroscopy, fourier transform infrared spectroscopy, thermogravimetric analysis and X-ray diffraction. The effects of pH, adsorption time, initial concentration and temperature on the adsorption process were investigated. The adsorption performance was correlated with the pseudo-second order kinetic and Sips adsorption isotherm model. Thermodynamic studies further proved that the adsorption was exothermic and the prepared Pep-MPA-RCMs showed the maximum adsorption capacity of 9.87 mg/g for OTA at 25℃. A simple adsorption column for OTA was prepared by using Pep-MPA-RCMs as filler material, which still maintained more than 80 % of the removal rate after five consecutive adsorption-elution cycles. The prepared pretreatment material was successfully applied to remove OTA in real samples and was a promising adsorbent for practical applications.

Syntheses of diphenolic resin based anti-corrosion coating material and reinforce its performance through MWCNT-Ag and MWCNT-Ag/PANI nanofillers

In the present work, a novel anti-corrosion coating material was developed using diphenolic resin and multiwalled carbon nanotube (MWCNT) based nanofillers. In this concern, phenylmethylene diphenolic resin (PMD) and its 2-(4-methylbenzyl) oxirane derivative (PMDD) were synthesized using phenol and benzaldehyde. Silver-decorated MWCNT (MWCNT-Ag) and polyaniline (PANI) synthesized on MWCNT-Ag (MWCNT-Ag/PANI) were also fabricated and employed as filler materials to enhance the anti-corrosion performance of PMDD. The resins were analyzed by LC-MS and FT-IR, and the nanofillers were characterized using XRD, SAED, EDX, TEM, and XPS techniques. The synthesized PMD and PMDD and different weight percentages of fillers blended PMDD were coated on the mild steel (MS) sample using doctor blade method. The surface morphology and roughness of the coatings were examined by SEM and AFM analyses. The anti-corrosion ability of the coated samples was assessed by electrochemical impedance spectroscopy (EIS) and salt spray testing (SST). All the results showed an excellent anti-corrosion performance of PMDD by the incorporation of 0.2 wt% of MWCNT-Ag/PANI. Withstanding the 5 wt% NaCl salt spray atmosphere for about 144 h and >460 days in 3.5 wt% NaCl solution reflects its strong barrier property and long-term durability. The cross-linking of resins, blockade of defects by nanofiller and an additional protective layer developed by conductive PANI make the coating material efficient and durable in highly corrosion environments.

Influence of arch action on load-carrying capacity of double-sized industrial precast slabs: A combined numerical and experimental study

The precast industry offers slab panels of different geometries according to the field conditions. These slab panels are popular in temporary constructions and beneficial in sustainability but have some financial limitations and local constraints. For a long time, the construction industry has used the arch action method, which restricts the stresses to the compression zone in concrete members and develops the required load-carrying capacity. For the same motives, industrial buildings have preferred semi-circular precast roofs, but the morphology was not suitable. For the proposed slab in this research, firstly, the typical industrial precast slab panel was doubled in width to minimize the time and efforts required for its casting, curing, and placement. Secondly, that doubled-in-width slab was provided with the arch action to confine the stresses to compression and benefit from the section entirely. Lastly, the top of the slab was kept flat to take advantage of the roof space. All these changes aimed for structural stability, reduced material's weight, improved load-carrying capacity, appropriate mobilization, and financial viability. A numerical approach and practical testing were adopted using the finite element modeling software, ABAQUS, to analyze load–deflection responses of both slabs through the concrete damage plasticity model. The proposed slab exhibited better performance as its capacity enhanced by about 1.5 times that of a typical slab. Although the volume of the material in the proposed slab increased slightly from 0.040 m3 to 0.045 m3, the reductions in joint filler materials, reinforcements, and efforts required for mixing and lifting machinery compensated for this increase significantly. Hence, the slab can be recommended for the industry to save the costs while taking heavier loads efficiently.

Synergistic effects of Monel 400 filler wire in gas metal arc welding of CoCrFeMnNi high entropy alloy

Weldability plays a crucial role in the journey of high entropy alloys towards their engineering applications. In this study, gas metal arc welding was performed to join an as-rolled CoCrFeMnNi high entropy alloy using Monel 400 as the filler wire. The present research findings demonstrate a favorable metallurgical chemical reaction between the Monel 400 filler and the CoCrFeMnNi high entropy alloy, resulting in compositional mixing within the fusion zone that promotes a solid-solution strengthening effect, counteracting the typical low hardness associated to the fusion zone of these alloys. The weld thermal cycle induced multiple microstructure changes across the joint, including variations in the grain size, existing phases and local texture. The grain size was seen to increase from the base material toward the fusion zone. An FCC matrix and finely sparse Cr-Mn-based oxides existed in both base material and heat affected zone, while in the fusion zone new FCC phases and carbides were formed upon the mixing of the Monel 400 filler. The role of the filler material on the fusion zone microstructure evolution was rationalized using thermodynamic calculations. Texture shifted from a γ-fiber (in the base material) to a strong cubic texture in the fusion zone. Digital image correlation during tensile testing to fracture coupled with microhardness mapping revealed that, stemming from the process-induced microstructure changes, the micro and macromechanical response differed significantly from the original base material. This study successfully established a correlation between the impact of the process on the developed microstructural features and the resultant mechanical behavior, effectively assessing the processing-microstructure-properties relationships towards an improved understanding of the physical metallurgy associated to these advanced engineering alloys. In conclusion, this work provides an important theoretical framework and practical guidance for optimizing the engineering applications of high entropy alloys.

Matrix‐phase material selection for shape memory polymer composites: A comparative analysis of multi‐criteria decision‐making

AbstractIn the present study, the selection of suitable shape memory polymers (SMPs) to be used as the matrix‐phase material with various (In)organic filler materials to achieve the required optimum multi‐stimuli response in shape memory polymer composites (SMPC) systems is analyzed. The selection of these materials is based on their mechanical and physical properties as well as other underlying factors such as cost, availability, shape recovery rate, and aesthetic characteristics. In this study, the entropy method was applied to estimate the weightages of the various criteria while the gray relation analysis (GRA) and the technique for order preference by similarity to ideal solution (TOPSIS). Multi‐criteria decision‐making (MCDM) approaches have been used to rank the suitable matrix‐phase polymer materials for manufacturing shape memory polymer composites (SMPC) system. A total of eight alternative SMP matrix‐phase materials based on a set of nine criteria were analyzed and ranked. The proposed methodology and the result obtained thereof have been illustrated in detail. The results obtained from TOPSIS and GRA methods have been compared to conclude the effects of the material properties on the ranking and the selection of the SMP materials. Among all the eight alternatives considered, thermoplastic polyurethane (TPU) was found to be the best material in both the MCDM methods. The material cost, resistivity, % elongation, and hydrophobicity present the most influencing properties on the SMP material selection, whereas density presents no effect on the SMP matrix material selection. The robustness of the results for the comparative analysis was verified using TOPSIS methodology to validate its reliability. It was revealed that the TPU, polycarbonate, polypropylene, and epoxy‐resin/poly(lactic acid) are the most dominant matrix‐phase SMP material alternatives when a deviation in the entropy weights of the primary evaluation criteria is applied. The novelty of this study is the exploration and application of statistical MCDM methods of engineering material selection problems based on a set of decision criteria, which can be time‐consuming and costly while using experimental analysis methods.Highlights SMPCs are applicable engineering materials thus making their research viable. SMPC systems can undergo various shape changes under external stimuli. Selection of matrix‐phase polymer is critical in achieving desired objectives. GRA and TOPSIS MCDM approaches have been applied in the selection process. TPU was found as the best material in both methods.

Feasibility of Using Recycled Materials in Construction Materials

The increasing amount of solid waste has become a significant environmental issue that has garnered significant attention and concern. In an effort to mitigate the adverse effects commonly associated with prominent sectors and simultaneously promote credibility in the energy- and resource-intensive realms of development and construction, significant endeavors have been directed towards competitive areas of strength for the purpose of recycling, with the ultimate goal of utilizing such materials in sustainable development products. The present study provides an overview of the ongoing evaluations pertaining to the utilization of conventional and enhanced solid waste for the production of geo-polymer composites. Great attention is devoted to the implementation of these geo-polymer composites. The primary findings of this study revealed that both ordinary and sophisticated solid waste have the potential to be integrated into geo-polymer composites in various forms, such as precursor, complete, additive, reinforcement fiber, or filler material. The findings indicate that the utilization of such waste may have a negative impact on certain properties of geo-polymer composites. However, this issue can be mitigated through the implementation of an open degree plan and appropriate treatment techniques, which can facilitate the recycling process. In conclusion, a concise discourse is presented to acknowledge the significant need for future research and enhancement in advancing the utilization of solid waste materials in the emerging sustainable geo-polymer industry. This study proposes an improved ecological solution for managing municipal and industrial solid waste by transforming waste materials into environmentally friendly construction materials with consistent properties. Special attention is given to the overall performance of geo-polymer composite products. The primary findings of this study reveal that urban and industrial solid waste can be efficiently incorporated into geo-polymer composites through the use of precursors, aggregates, additives, reinforcing fibers, or filler materials. The results indicate that while the inclusion of waste materials may negatively impact certain properties of geo-polymer composites, a well-designed protocol and effective treatment approach can mitigate these adverse effects and facilitate the recycling process. Finally, a brief dialogue is presented to differentiate the key needs in forthcoming research and development aimed at enhancing the utilization of solid waste materials in the upcoming sustainable geopolymer sector. This study provides guidance for the sustainable management of urban waste by transforming waste materials into environmentally friendly construction materials.

Influence of Ultrasonication Treatment on Mechanical, Optical, and Physiochemical Properties of Polyvinyl-alcohol/cornstarch Biocomposite Thin Films

Over the past few decades, Polyvinyl-alcohol (PVOH)/cornstarch (CS)-based composite thin films have garnered significant interest due to their enhanced properties. Synthesis of such films relies heavily on depolymerization reactions within the solution of the PVOH/CS blends. Understanding how depolymerization affects the crystal structure and properties of these films is crucial for further improvement. This study aims to evaluate the depolymerization effects of crosslinked PVOH incorporated with CS as filler materials (with an 80:20 mass ratio) using ultrasonication at various time intervals while maintaining a constant frequency of 25 KHz. The prepared solution is then cast into thin films using blade coating. Comparative analyses were then conducted between samples subjected to ultrasonication (treated) and without ultrasonication (untreated) to assess their properties based on structural physical, mechanical, optical, and aspects of biodegradability . The investigation revealed significant changes in crystal structure and lattice strains following ultrasonication of the PVOH/CS solution when compared to untreated PVOH/CS samples. Importantly, longer ultrasonication times correlated with increased tensile strength. Additionally, the treated samples led to improvements in thin film transparency and a notable decrease in absorbance. These changes were attributed to the mechanical depolymerization induced by ultrasonication, aligning the thin films with the necessary properties for food packaging applications.

Numerical investigation of phase change material integration in structured thermocline systems for concentrated solar power

The integration of encapsulated PCM in a structured thermal energy storage system is studied. The fluid and filler material are discretized using a one-dimensional approach, while the PCM is discretized two-dimensionally. The accumulated energy for the height percentage of PCM and cutoff temperature differences are obtained for three PCMs, NaNO3, KOH and H380, to obtain the best options to enhance the accumulated energy using encapsulated PCM.