Filler In Poly Research Articles

Poly(aniline/aminophenol)-wrapped graphene nanoplates loaded with gabapentin inhibitor as a filler in poly(aniline/vinylalcohol/aminophenol)/acrylic coating to endow corrosion/wear durability by triple protection mechanism

A coating with excellent tribological behavior and corrosion durability was synthesized by chemical/electrochemical method from the composition of polyaniline (PANI), polyaminophenol (PAP), polyvinylalcohol (PVA), and reinforced with PANI/PAP/Gabapentin-functionalized Graphene nanoplates. Acrylic (AC) covered the composite coating as a top layer. According to the evaluations, G@PANI/PAP/GP-reinforced coating has 5 times more corrosion resistance than unreinforced one (on the 1st and 30th days). Not only has the corrosion resistance of PANI/PVA/PAP contained G@PANI/PAP/GP not decreased over time, but it has increased by ∼20 %. The defect density of passive film under (PANI/PVA/PAP)/Acrylic coating containing G@PANI/PAP/GP is 10 times less than that of the (PANI/PVA/PAP)/Acrylic coating. G@PANI/PAP/GP decreased the friction coefficient and wear rate of PANI composite coating over time by ∼47 % and 84 %. Furthermore, the simultaneous presence of graphene and gabapentin has increased the lubrication (Rsk = -0.24 µm) and adhesion (13 %) of the coating. It is how a polyaniline-based composite coating with three mechanisms of passivation, corrosion barrier, and inhibition protects the 304 SS over time.

Epoxidized Soybean Oil Toughened Poly(lactic acid)/Lignin-g-Poly(lauryl methacrylate) Bio-Composite Films with Potential Food Packaging Application.

The application of lignin as a filler for poly (lactic acid) (PLA) is limited by their poor interfacial adhesion. To address this challenge, lignin-graft-poly(lauryl methacrylate) (LG-g-PLMA) was first blended with poly (lactic acid), and then epoxidized soybean oil (ESO) was also added to prepare PLA/LG-g-PLMA/ESO composite, which was subsequently hot pressed to prepare the composite films. The effect of ESO as a plasticizer on the thermal, mechanical, and rheological properties, as well as the fracture surface morphology of the PLA/LG-g-PLMA composite films, were investigated. It was found that the compatibility and toughness of the composites were improved by the addition of ESO. The elongation at break of the composites with an ESO content of 5 phr was increased from 5.6% to 104.6%, and the tensile toughness was increased from 4.1 MJ/m3 to 44.7 MJ/m3, as compared with the PLA/LG-g-PLMA composite without ESO addition. The toughening effect of ESO on composites is generally attributed to the plasticization effect of ESO, and the interaction between the epoxy groups of ESO and the terminal carboxyl groups of PLA. Furthermore, PLA/LG-g-PLMA/ESO composite films exhibited excellent UV barrier properties and an overall migration value below the permitted limit (10 mg/dm2), indicating that the thus-prepared biocomposite films might potentially be applied to environmentally friendly food packaging.

Epoxidized Soybean Oleic Acid/Oligomeric Poly(lactic acid)-Grafted Nano-Hydroxyapatite and Its Role as a Filler in Poly(L-lactide) for Potential Bone Fixation Application.

One of the most effective strategies for modifying the surface properties of nano-fillers and enhancing their composite characteristics is through polymer grafting. In this study, a coprecipitation method was employed to modify hydroxyapatite (HAP) with epoxidized soybean oleic acid (ESOA), resulting in ESOA-HAP. Subsequently, oligomeric poly(lactic acid) (OPLA) was grafted onto the surface of ESOA-HAP, yielding OPLA-ESOA-HAP. HAP, ESOA-HAP, and OPLA-ESOA-HAP were comprehensively characterized. The results demonstrate the progressive grafting of ESOA and OPLA onto the surface of HAP, resulting in enhanced hydrophobicity and improved dispersity in organic solvent for OPLA-ESOA-HAP compared to HAP. The vitality and adhesion of Wistar rat mesenchymal stem cells (MSCs) were assessed using HAP and modified HAP materials. Following culture with MSCs for 72 h, the OPLA-ESOA-HAP showed an inhibition rate lower than 23.0% at a relatively high concentration (1.0 mg/mL), which is three times lower compared to HAP under similar condition. The cell number for OPLA-ESOA-HAP was 4.5 times higher compared to HAP, indicating its superior biocompatibility. Furthermore, the mechanical properties of the OPLA-ESOA-HAP/PLLA composite almost remained unaltered ever after undergoing two stages of thermal processing involving melt extrusion and inject molding. The increase in the biocompatibility and relatively high mechanical properties render OPLA-ESOA-HAP/PLLA a potential material for the biodegradable fixation system.

Microwave Properties of Composite Films Based on Polyvinyl Chloride and Brominated Activated Carbon

AbstractBrominated activated carbon (AC/Br2) powder was used as a filler in poly(vinyl chloride) (PVC) to prepare PVC‐based composite films by hot pressing. The AC/Br2 filler was obtained by liquid phase bromination and contained both oxygen and bromine. In comparison with the unmodified AC, the AC/Br2 was subjected to thermogravimetric analysis in air and argon and temperature‐programmed desorption mass spectrometry in vacuum, which identified carbon‐oxygen and bromine groups and showed the comparable thermal stability of AC/Br2 and AC. XPS shows the predominance of phenolic groups among the carbon‐oxygen groups. Scanning electron microscopy and transmission electron microscopy showed preserved morphology and microstructure, while N2 adsorption showed a microporosity decrease after bromination. FTIR analysis suggested non‐chemical interactions between PVC and AC/Br2. As the AC/Br2 content in the PVC‐based composite films increases from 0.2 to 30 wt %, the electromagnetic radiation (EMR) reflection at Ka‐band microwave frequencies increases. To reduce the EMR reflection, the proposed composite films should contain a maximum of 0.2 wt % AC/Br2. The results indicate that the microwave properties of PVC‐based composite films can be tuned by adjusting the AC/Br2 content.

Regulate transportation of ions and polysulfides in all-solid-state Li-S batteries using ordered-MOF composite solid electrolyte.

A dilemma arises when striving to balance the maximum desired ion conductivity and minimize the undesired lithium polysulfide shuttling effect for all-solid-state lithium-sulfur batteries (ASSLSBs). Here, we introduce a strategy of using ordered MIL-125-NH2 as fillers for poly(ethylene oxide)-based electrolytes to simultaneously regulate the transportation of lithium ions and polysulfides. When compared to electrolytes lacking metal-organic frameworks (MOFs) and those containing disordered MOFs, the electrolyte featuring an ordered-MOF structure, denoted as three-dimensional (3D) MPPL composite solid electrolyte (CSE), exhibits the highest ion conductivity of 8.3 × 10-4 siemens per centimeter at 60°C. As a result, pouch-type ASSLSBs with 3D MPPL CSE maintains stable cycling for 400 cycles at 0.5 C at 60°C, showcasing the successful implementation of this strategy in simultaneously regulating ion and polysulfide transport. This approach opens up alternative avenues to achieve high-performance ASSLSBs with exceptional energy density.

Tailoring diamondised nanocarbon-loaded poly(lactic acid) composites for highly electroactive surfaces: extrusion and characterisation of filaments for improved 3D-printed surfaces

A new 3D-printable composite has been developed dedicated to electroanalytical applications. Two types of diamondised nanocarbons - detonation nanodiamonds (DNDs) and boron-doped carbon nanowalls (BCNWs) - were added as fillers in poly(lactic acid) (PLA)-based composites to extrude 3D filaments. Carbon black served as a primary filler to reach high composite conductivity at low diamondised nanocarbon concentrations (0.01 to 0.2 S/cm, depending on the type and amount of filler). The aim was to thoroughly describe and understand the interactions between the composite components and how they affect the rheological, mechanical and thermal properties, and electrochemical characteristics of filaments and material extrusion printouts. The electrocatalytic properties of composite-based electrodes, fabricated with a simple 3D pen, were evaluated using multiple electrochemical techniques (cyclic and differential pulse voltammetry and electrochemical impedance spectroscopy). The results showed that the addition of 5 wt% of any of the diamond-rich nanocarbons fillers significantly enhanced the redox process kinetics, leading to lower redox activation overpotentials compared with carbon black–loaded PLA. The detection of dopamine was successfully achieved through fabricated composite electrodes, exhibiting lower limits of detection (0.12 μM for DND and 0.18 μM for BCNW) compared with the reference CB-PLA electrodes (0.48 μM). The thermogravimetric results demonstrated that both DND and BCNW powders can accelerate thermal degradation. The presence of diamondised nanocarbons, regardless of their type, resulted in a decrease in the decomposition temperature of the composite. The study provides insight into the interactions between composite components and their impact on the electrochemical properties of 3D-printed surfaces, suggesting electroanalytic potential.Graphical abstract

Bio-Based White Eggshell as a Value-Added Filler in Poly(Lactic Acid) Composites

Based on its positive environmental impact, poly(lactic acid) (PLA) has been a gradual substitute for synthetic plastics used in diverse applications. The use of industrial limestone (ILS) as a filler in polymers can have advantages of changing the properties of pure polymers. Waste eggshells (WE) can be seen as an alternative filler to ILS as they are also a source of calcium carbonate. To assess the feasibility of both filler types and sizes, PLA composites were manufactured by injection molding with filler contents of 5, 10, and 20 wt.%. Tensile, flexural, and impact mechanical properties were evaluated in addition to water absorption. One-way analysis of variance (ANOVA) was performed to determine whether statistically significant differences among the measured mechanical properties existed. Scanning electron microscopy (SEM) was used to view the morphology of the fillers and fractured surfaces. The composite tensile strengths and flexural strengths performed the best when filler loadings were 5 wt.% and 10 wt.%, respectively, for both filler types. The tensile and flexural modulus both increased with filler loadings. The impact strength for the composites was obtained at a threshold level of 5 wt.% filler loadings for both filler types and slightly better for smaller particles sizes. ANOVA identified statistically significant differences for the mean mechanical property values evaluated. SEM showed the fractured surfaces of the PLA composites were different from the pure PLA indicating some transformation occurred to the matrix. The weight gains due to water absorption were observed to increase with increase in content of both filler types while the smaller particles had slightly higher water weight gains. Although the composites containing ILS fillers had somewhat enhanced mechanical properties over the WE-filled composites, the end application will dictate which filler type to use in PLA.

The Development of Environmentally Sustainable Poly(vinyl chloride) Composite from Waste Non-Metallic Printed Circuit Board with Interfacial Agents.

The recycling of non-metallic printed circuit boards (NMPCB) as a filler in poly(vinyl chloride) (PVC) composite would help to encourage the use of waste NMPCB, thus, reducing some environmental concerns with regard to e-waste. The objective of this study was to comprehensively evaluate the effect of different interfacial agents, namely polypropylene grafted maleic anhydride (PP-g-MAH) and ϒ-aminopropyltriethoxy silane (ATPS) on the morphology and properties of PVC/NMPCB composites. A PVC/NMPCB composite was prepared by melt compounding with varying amounts of NMPCB ranging between 10, 20 and 30 wt.%. Fourier transform infrared spectroscopy-attenuated total reflectance (FTIR-ATR) analysis revealed the interactions between PVC and NMPCB when using both PP-g-MAH and ATPS interfacial agent. The properties and morphology of PVC/NMPCB composites were significantly dependent on the interfacial agent treated on the NMPCB surface. The phase morphology and mechanical properties of PVC/NMPCB composites (30 wt.% of NMPCB) were improved and the result also indicated that the higher compatibility of composites with ATPS as an interfacial agent led to our obtaining the maximum Young's modulus of 484 MPa. The dynamic mechanical analysis revealed the interaction at the interface, with the Tg shifting to a lower temperature in the presence of PP-g-MAH and strong interfacial adhesion noted with the improved Tg in the presence of the ATPS interfacial agent. Further evidence of the improved interaction was observed with the increment in density in the presence of ATPS when compared with PP-g-MAH in PVC/NMPCB composite. Hence, of the two interfacial agents, ATPS showed itself to be more effective when employed as an interfacial agent for NMPCB in PVC composite for industry.

Composites Based on Poly(ε-caprolactone) and Graphene Oxide Modified with Oligo/Poly(Glutamic Acid) as Biomaterials with Osteoconductive Properties.

The development of new biodegradable biomaterials with osteoconductive properties for bone tissue regeneration is one of the urgent tasks of modern medicine. In this study, we proposed the pathway for graphene oxide (GO) modification with oligo/poly(glutamic acid) (oligo/poly(Glu)) possessing osteoconductive properties. The modification was confirmed by a number of methods such as Fourier-transform infrared spectroscopy, quantitative amino acid HPLC analysis, thermogravimetric analysis, scanning electron microscopy, and dynamic and electrophoretic light scattering. Modified GO was used as a filler for poly(ε-caprolactone) (PCL) in the fabrication of composite films. The mechanical properties of the biocomposites were compared with those obtained for the PCL/GO composites. An 18-27% increase in elastic modulus was found for all composites containing modified GO. No significant cytotoxicity of the GO and its derivatives in human osteosarcoma cells (MG-63) was revealed. Moreover, the developed composites stimulated the proliferation of human mesenchymal stem cells (hMSCs) adhered to the surface of the films in comparison with unfilled PCL material. The osteoconductive properties of the PCL-based composites filled with GO modified with oligo/poly(Glu) were confirmed via alkaline phosphatase assay as well as calcein and alizarin red S staining after osteogenic differentiation of hMSC in vitro.

Effects of a high-performance, solution-cast composite electrolyte on the host electrospun polymer membrane for solid-state lithium metal batteries

Dispersed nano-silica fillers in poly (ethylene oxide) were solution cast on a host electrospun polyacrylonitrile membrane. The host electrospun polyacrylonitrile membrane enhanced the overall elasticity and ionic conductivity of the composite polymer electrolyte membrane for solid-state lithium metal batteries. Three different concentrations of silica fillers were added (1%, 3%, and 5%) called CSE 1, CSE 3, and CSE 5. The composite electrolyte membranes were compared with the 0% concentration of silica fillers and named SE. Among them, the CSE 3 membrane outperformed and delivered an ionic conductivity of 7.1 × 10 −4 S cm−1, lithium-ion transference number of 0.62, and the ultimate tensile strength of 27.3 MPa with 110.9% strain, revealing the elasticity of the CSE 3 membrane. The thermal stability of up to 354 °C and the wide range of electrochemical stabilities of up to 5.1 V were achieved. The symmetric cell Li|CSE 3|Li showed satisfactory long operation of lithium plating/stripping for 500 h without a significant voltage drop or short circuit. Furthermore, the electrode surface showed the homogeneous deposition of lithium on the plated electrode and a relatively smooth surface on the stripped electrode. The LCO|CSE 3|Li exhibits better rate capability and excellent cycling performance with 91.1% capacity retention and maintains 131.9 mAh g−1at 0.5C after 200 cycles.

Evidence of silane coupling in torrefied agro‐industrial residue‐filled poly(styrene‐co‐butadiene) rubber compounds

AbstractHeat‐treated rice hull residues were evaluated as fillers in poly(styrene‐co‐butadiene) rubber (SBR) compounds. The currently used precipitated silica filler was replaced with torrefied filler in concentrations varying from 0 to 100 wt%, and the influence of coupler concentration varying from 0% to 3% (7 parts per hundred rubber or phr total) on the filler‐rubber interaction was investigated. The curing process, dynamic properties, and mechanical properties of the SBR compounds were examined for silica‐filled and torrefied rice hull (TRH)‐filled materials with and without the coupling agent. Partial or full replacement of silica with TRH resulted in a systematic decrease in compound viscosity. Longer scorch (ts2) and shorter cure times (t90) were also observed. Incorporation of TRH increased compound modulus (stress at 100% elongation or M100 and Young's modulus) but decreased tensile strength and elongation. The presence of coupler brought about improved dynamic and mechanical properties and 30% lower tan δ at 3 phr level. Results provided the first evidence that, when used as a filler in an SBR compound, torrefied rice hulls can be chemically coupled to the SBR polymer, resulting in increased polymer‐filler interactions analogous to the conventional silica‐coupler‐polymer system.

Wood Residue-Derived Biochar as a Low-Cost, Lubricating Filler in Poly(butylene succinate-co-adipate) Biocomposites.

This study focused on the development of a novel biocomposite material formed by a thermoplastic biodegradable polyester, poly(butylene succinate-co-adipate) (PBSA), and a carbonaceous filler as biochar (BC) derived by the pyrolysis of woody biomass waste. Composites with various BC contents (5, 10, 15, and 20 wt.%) were obtained by melt extrusion and investigated in terms of their processability, thermal, rheological, and mechanical properties. In all the composites, BC lowered melt viscosity, behaving as a lubricant, and enhancing composite extrudability and injection moulding at high temperatures up to 20 wt.% of biochar. While the use of biochar did not significantly change composite thermal stability, it increased its stiffness (Young modulus). Differential scanning calorimeter (DSC) revealed the presence of a second crystal phase induced by the filler addition. Furthermore, results suggest that biochar may form a particle network that hinders polymer chain disentanglement, reducing polymer flexibility. A biochar content of 10 wt.% was selected as the best trade-off concentration to improve the composite processability and cost competitiveness without compromising excessively the tensile properties. The findings support the use of biochar as a sustainable renewable filler and pigment for PBSA. Biochar is a suitable candidate to replace more traditional carbon black pigments for the production of biodegradable and inexpensive innovative PBSA composites with potential fertilizing properties to be used in agricultural applications.

Primary Sludge from Paper Processing as Filler in Poly(lactic acid) Composite: Physical, Thermal and Mechanical Properties

Primary Sludge from Paper Processing as Filler in Poly(lactic acid) Composite: Physical, Thermal and Mechanical Properties

Barium titanate based paraelectric material incorporated Poly(vinylidene fluoride) for biomechanical energy harvesting and self-powered mechanosensing

Being a superior dielectric material exhibiting low loss, x = 0.4 composition of Ba1-xSrxTiO3 nanoparticles have been widely used as fillers in poly(vinylidene fluoride) (PVDF) for efficient flexible dielectric and electrical energy storage application. The mentioned composition of the material is also very attractive choice of interest to the researchers due to its ability of ferroelectric to paraelectric phase transition. Due to its paraelectric nature, Ba0.6Sr0.4TiO3 has not been used for mechanical energy harvesting application till date. Here we have used Ba0.6Sr0.4TiO3 particles as fillers in PVDF matrix for efficient mechanical energy harvesting purpose. In the present work, along with the flexible dielectric, ferroelectric and energy storage applications, the developed composite films have been explicitly used for efficient biomechanical energy harvesting, powering small electronic devices and pressure sensing. The fabricated nanogenerator successfully generated a maximum output voltage and output power density of 15 V and 6.75 μW/cm2 respectively on repeated human finger tapping. The obtained output power has been clearly explained on the basis of polar phase formation and consideration of stress concentration effect.

Electrically Conductive Biocomposites Based on Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) and Wood-Derived Carbon Fillers

In this paper, biobased carbons were used as fillers in poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV). The mechanical and electrical properties of these 100% biocomposites were analyzed. First, biocarbons were prepared from wood dust and cellulose fibers using carbonization temperatures ranging 900–2300 °C. XRD revealed significant improvements of the graphitic structure with increasing temperatures for both precursors, with slightly higher ordering in wood-dust-based carbons. An increase of the carbon content with continuous removal of other elements was observed with increasing temperature. The carbonized cellulose fiber showed an accumulation of Na and O on the fiber surface at a carbonization temperature of 1500 °C. Significant degradation of PHBV was observed when mixed with this specific filler, which can, most probably, be attributed to this exceptional surface chemistry. With any other fillers, the preparation of injection-molded PHBV composites was possible without any difficulties. Small improvements in the mechanical performance were observed, with carbonized fibers being slightly superior to the wood dust analogues. Improvements at higher filler content were observed. These effects were even more pronounced in the electrical conductivity. In the range of 15–20 vol.% carbonized fibers, the percolation threshold could be reached, resulting in an electrical conductivity of 0.7 S/cm. For comparison, polypropylene composites were prepared using cellulose fibers carbonized at 2000 °C. Due to longer fibers retained in the composites, percolation could be reached in the range of 5–10 vol.%. The electrical conductivity was even higher compared to that of composites using commercial carbon fibers, showing a great potential for carbonized cellulose fibers in electrical applications.

Polymeric Nanofibers of Various Degrees of Cross‐Linking as Fillers in Poly(styrene‐stat‐n‐butyl acrylate) Nanocomposites: Overcoming the Trade‐Off between Tensile Strength and Stretchability

Synthesis of light polymer nanocomposites with high strength and toughness has been a significant interest for its potential applications in industry. Herein, the authors have synthesized polymerization-induced self-assembly (PISA) derived nanodimensional polymeric worm (fiber) reinforced polymer nanocomposites by a simple and environmentally friendly synthesis process without the addition of volatile organic compounds. PISA-derived worms with a core-forming block of low glass transition temperature (Tg ≈27.1°C) comprising poly(styrene-stat-n-butyl acrylate) have been employed as reinforcing filler. The influence of core-segment cross-linking on reinforcement efficiency has been explored by comparing noncross-linked worms, and worms cross-linked with a small amount of ethylene glycol diacrylate introduced at t=0h or t=2h of polymerization. Upon addition of 1wt% of noncross-linked, t=0h cross-linked, and t=2h cross-linked worms, toughness of polymer nanocomposites can be enhanced by 62%, 114%, and 120%, respectively. The results suggest that the reinforcement efficiency of worms is significantly influenced by the cross-linking of core-segments regardless of cross-linking methods. This work broadens the understanding in application of PISA-derived worms as reinforcing filler by demonstrating the efficient reinforcement with low Tg worms.

A Review on Nanocomposites with Graphene Based Fillers in Poly(ether ether ketone)

A Review on Nanocomposites with Graphene Based Fillers in Poly(ether ether ketone)

Improved dielectric and energy storage properties of polymer composites with BNNSs/AgNPs hybrid nanofiller

ABSTRACT The development of polymer nanocomposites with superior dielectric performances is critical for flexible capacitive energy storage applications. However, the common approach to fabricate polymer composites with high-dielectric-constant ceramics as fillers always bring about exaggerate dielectric losses, hence low energy density and energy efficiency of polymer composites. In this work, BNNSs/AgNPs nanohybrids, where Ag nanoparticles were deposited on the surface of boron nitride nanosheets (BNNSs), are employed as fillers for poly(vinylidene fluoride-hexafluoropropylene) (PVDF-HFP) based nanocomposites. The contributions by enhanced interface polarisation and the internal barrier layer capacitor (IBLC) effect generated by the uniform distribution of conductive Ag nanoparticles on the insulative BNNSs, result in a large increase in dielectric constant and electric displacement meanwhile simultaneously suppressed dielectric losses. The BNNSs/AgNPs/PVDF-HFP nanocomposites exhibit much higher energy density and energy efficiency than the pristine PVDF-HFP and the BNNSs/PVDF-HFP composites counterparts, being great potential for dielectric energy storage applications.

Poly (Lactic Acid) (PLA)/Recycled Styrene Butadiene Rubber (rSBR) Composites

Recycled styrene butadiene rubber (rSBR) from waste car tires was used as a filler in poly(lactic) acid (PLA) to modify its properties. The compounds were prepared via twin-screw extrusion and molded by injection with different rSBR contents (0 to 25% wt.). Additionally, recycled rubber particle size was controlled between 125 and 1000 μm to determine the effect of this parameter. From the samples produced, a series of morphological, physical and mechanical characterizations were performed. As expected, rSBR addition decreased the PLA stiffness. Up to 5% rSBR, the flexural and elastic moduli were unchanged, but the tensile strength, elongation at break and impact toughness were decreased. The highest tensile strength, elongation at break and impact toughness were achieved for PLA/rSBR blends filled with small rubber particles (125-250 μm). According to the morphological analysis, this behavior was associated to better interfacial interactions between smaller rSBR particles (higher specific surface area) and PLA resulting in a more uniform filler distribution and better stress transfer from PLA to rSBR. Finally, to complete the mechanical properties of the materials, fatigue tests were carried out on different blends and the results were related to instrumented indentation to get some more local information.

Utilization of Kiwi Peel Lignocellulose as Fillers in Poly(Lactic Acid) Films

Lignocellulosic structures extracted from agricultural wastes have great potential in re-designing sustainable packaging materials. In this study, the utilization of kiwifruit peels (KFP) (unt) and lignocellulosic structures extracted from KFP, which were alkali-treated (al), acid-treated (ac), and acetylated (ace), in poly(lactic acid) (PLA) films were investigated. Untreated and treated lignocellulosic structures were added to PLA film-forming solutions at 5% (w/w based on PLA). The film samples were characterized by their mechanical, water vapor permeability (WVP), FTIR, and optical properties. FTIR results presented that the acid treatment and acetylation have changed the chemical structure of KPF, which resulted in changes in intensities and peak shifts between 1400-1900 cm-1. WVP of the films containing KPF-based lignocellulosic structures was lower than control PLA films (p<0.05). The addition of KPF-based lignocellulosic structures increased the tensile strength and elastic modulus (p>0.05) compared to PLA control films. Films including acid-treated lignocellulosic structures had high opacity and relatively low lightness values (p<0.05). These results showed that adding lignocellulosic structures into PLA films is a promising method to improve the film properties.