Field Sensor Research Articles

Phytic acid-based super antifreeze multifunctional conductive hydrogel for human motion monitoring and energy harvesting devices

Conductive hydrogels have broad application prospects in the field of self-powered sensors and energy harvesting devices due to their good electrical conductivity and flexibility. However, at low temperatures, conductive hydrogels are usually frozen, resulting in problems such as poor electrical conductivity and flexibility, which seriously hinder the application of these fields. To address these challenges, phytic acid (PA) was employed as the crosslinker and antifreezing agent in this study. Polyvinyl alcohol (PVA), 2-acrylamido-2-methyl-1-propanesulfonic acid (AMPS), chitosan (CS), and PA were used as raw materials to successfully synthesize PVA/AMPS/CS/PA (PACP) multifunctional conductive hydrogels with outstanding antifreeze and water retention properties (freezing point below −80 °C, 30-day water loss rate of 3.5%). In addition, PACP hydrogels exhibit exceptional electrical conductivity of up to 9.4 S/m, along with antibacterial and biocompatible properties, enabling their utilization as wearable sensors on human skin tissue. Notably, the PACP hydrogel-based triboelectric nanogenerator (PACP-TENG) excels in accurately monitoring human motion and powering small electronic devices, facilitating remote control of small light switches. The resulting open circuit voltage is as high as 314 V at 25 °C and about 110 V at low temperature. Therefore, PACP hydrogels with excellent properties are expected to expand their applications in these fields.

High-sensitive electrochemical sensor based on Ni/NiCx-integrated functional carbon nanotubes for simultaneous determination of acetaminophen and dopamine

In complex environmental substance monitoring, the simultaneous detection of single and multiple substances with high sensitivity has been a research focus in the field of electrochemical sensors. Rational selection of appropriate dopants to optimize the electrode material is crucial in this regard. In this work, we employed a multi-doping strategy to effectively enhance the electrocatalytic performance of multi-walled carbon nanotubes (MWCNTs). By doping Ni/NiCx onto MWCNTs, we successfully constructed a heterojunction material (Ni/NiCx-N-MWCNTs). The successful doping of Ni/NiCx allows for the synergistic effects of multiple elements. Ni/NiCx serves as a conductive bridge, forming a three-dimensional network of nanotubes, which effectively reduces the aggregation of carbon nanotubes, exposes more active sites, and enhances electrocatalytic activity. The electrochemical sensor based on Ni/NiCx-N-MWCNTs demonstrated high sensitivity, selectivity, and simultaneous electrochemical detection for acetaminophen (1–150 μM, limit of detection (LOD)=0.56 μM) and dopamine (1–80.0 μM, LOD=0.19 μM). Its excellent reproducibility (relative standard deviation (RSD)=2.01 %) and interference resistance provide Ni/NiCx-N-MWCNTs with significant advantages over other electrode materials, indicating a promising application potential.

Relative position estimation using modulated magnetic field for close proximity formation flight

This paper presents a method to estimate relative position vectors between spacecraft equipped with magnetic coils and magnetic field sensors for close proximity operation. Filters can segregate a magnetic field with a particular frequency if spacecraft drive their coils with this specific frequency. The proposed method utilizes the amplitude of the magnetic field with a particular frequency to estimate relative position vectors. The method consists of an initial position estimator and a sequential position estimator, which is an unscented Kalman filter. The initial position estimator provides a coarse estimate for the relative position vectors using the segregated magnetic field. Relation between the magnetic field and relative position vector is derived analytically in this article for the initial position estimator. The unscented Kalman filter refines the estimation accuracy by initializing the filter with the estimate by the initial position estimator. It is shown that a spacecraft can conduct relative position vector estimation using the magnetic field of a target spacecraft, provided that a few conditions clarified in the article are satisfied. Finally, the proposed estimators are evaluated numerically via simulations.

Recent Applications and Future Trends of Nanostructured Thin Films-Based Gas Sensors Produced by Magnetron Sputtering

The field of gas sensors has been developing for the last year due to the necessity of characterizing compounds and, in particular, volatile organic compounds whose detection can be of special interest in a vast range of applications that extend from clinical evaluation to environmental monitoring. Among all the potential techniques to develop sensors, magnetron sputtering has emerged as one of the most suitable methodologies for the production of large-scale uniform coatings, with high packing density and strong adhesion to the substrate at relatively low substrate temperatures. Furthermore, it presents elevated deposition rates, allows the growth of thin films with high purity, permits a precise control of film thickness, enables the simple manufacturing of sensors with low power consumption and, consequently, low costs involved in the production. This work reviewed all the current applications of gas sensors developed through magnetron sputtering in the field of VOCs assessment by gathering the most relevant scientific works published. A total of 10 compounds were considered for this work. Additionally, 13 other compounds were identified as promising targets and classified as future trends in this field. Overall, this work summarizes the state-of-the-art in the field of gas sensors developed by magnetron sputtering technology, allowing the scientific community to take a step forward in this field and explore new research areas.

Laser-induced in-situ electrohydrodynamic jet printing of micro/nanoscale hierarchical structure

With the rapid advancement of micro/nanoscale devices, there is a growing demand for hierarchical micro/nano porous-structure, particularly in fields of high-performance sensors, electrochemical energy storage, and photocatalysis. The fabrication methods for hierarchical micro/nano-porous structures have been limited by complex processes and high costs, making further development and application difficult. In this paper, a novel strategy of laser-induced in-situ electrohydrodynamic jet (E-Jet) printing of hierarchical micro/nano-porous structures was proposed. Based on the mechanism of high-energy laser beam induction on the jet, it successfully fabricated hierarchical porous ZnO structures from nanoscale to dozens of microns. The jet size focusing and solidification behavior were analyzed by combining experimental and simulative exploration. The resultant effects of the thermal field, flow field, and laser field on the spatial temperature distribution and the jetting morphology were examined. Furthermore, the laser-induced influence on the morphology of the printed micro/nano-porous ZnO structures was explored. Meanwhile, the performance of micro/nano-porous ZnO photoelectric sensors printed by E-Jet under different laser powers was investigated. The laser-induced in-situ E-Jet printing method provided an innovative pattern for the high-resolution additive manufacturing of hierarchical porous structures, demonstrating its potential for applications in advanced material and high-performance devices.

A conductive ionogel with Stretchability, low hysteresis and adjustable adhesion for Air/Underwater mechanosensing

Conductive ionogels based on deep eutectic solvents (DESs) have great application potential in the field of flexible sensors. However, the development of conductive ionogels that are stable under various environmental conditions (such as high and low temperatures, air, and water) remains extremely challenging. In this work, the hydrophobic conductive ionogel BxHyIG was prepared via a one-step photoinitiated copolymerization of butyl acrylate and N-hydroxyethylacrylamide in a hydrophobic DES. The good chemical compatibility between the polymer and DES, as well as the dense and reversible ion–dipole interactions, dipole–dipole interactions and hydrogen bond interactions, endow BxHyIG with satisfactory transparency (80 %), adhesion (polystyrene: 74.56 kPa), mechanical properties (elongation at break: 578 %, tensile strength: 171.25 kPa), a low degree of hysteresis (DH=1.9 %) and conductivity (3.95 × 10-3 S m−1). Strain/pressure sensors and bioelectrodes prepared from ionogels have the characteristics of high sensitivity, fast response and excellent stability and can be used for real-time monitoring of human activities and health status in the atmosphere. In addition, the inherent hydrophobicity of BxHyIG (water contact angle > 110°) can effectively prevent BxHyIG from being eroded and swollen by water, thereby achieving reliable underwater sensing. More importantly, by directly exposing BxHyIG to air or storing it in nitrogen, the surface adhesion of conductive ionogels can be effectively regulated to obtain double-sided, single-sided or even nonadhesive ionogels. Therefore, this study provides new ideas for the development of conductive ionogels that can be applied under various environmental conditions.

Edifice of metal stannate as nano-catalyst: An ultra-sensitive and highly selective enhanced electrochemical sensing of chloronitrobenzene

Metal stannate is recognized as an effective electrocatalyst in the electrochemical sensor field. In this case, the simple co-precipitation method was used to produce Zn2SnO4. A range of microscopic and spectroscopic techniques were employed to describe the physicochemical properties of synthesized materials. In a modified glassy carbon electrode (GCE), the electrochemical performance of Zn2SnO4 was investigated using cyclic voltammetry (CV) and differential pulse voltammetry (DPV) in a three-electrode setup. When reducing 1-chloro-4-nitrobenzene (CNB), Zn2SnO4/GCE exhibits strong electrochemical activity, showing a lower peak potential and a larger cathodic peak current than when GCE is used alone. With a sensitivity of 7.2 nM at the lower detection limit, the linear range response ranges from 0.04 to 360.21 µM. Furthermore, when tested with aromatic nitro groups, inorganic species, and antibiotic therapies, the modified electrode shows good storage stability, reproducibility, repeatability, and interference study capabilities. Zn2SnO4/GCE also demonstrates better electrochemical sensitivity for the detection of CNB. The synthesized Zn2SnO4/GCE exhibits remarkable practical ability to identify CNB in water samples with sufficient yield. This is the first report we are aware of regarding Zn2SnO4/GCE studies of electrochemical sensing towards CNB.

Light-based 3D printing of stimulus-responsive hydrogels for miniature devices: recent progress and perspective

AbstractMiniature devices comprising stimulus-responsive hydrogels with high environmental adaptability are now considered competitive candidates in the fields of biomedicine, precise sensors, and tunable optics. Reliable and advanced fabrication methods are critical for maximizing the application capabilities of miniature devices. Light-based three-dimensional (3D) printing technology offers the advantages of a wide range of applicable materials, high processing accuracy, and strong 3D fabrication capability, which is suitable for the development of miniature devices with various functions. This paper summarizes and highlights the recent advances in light-based 3D-printed miniaturized devices, with a focus on the latest breakthroughs in light-based fabrication technologies, smart stimulus-responsive hydrogels, and tunable miniature devices for the fields of miniature cargo manipulation, targeted drug and cell delivery, active scaffolds, environmental sensing, and optical imaging. Finally, the challenges in the transition of tunable miniaturized devices from the laboratory to practical engineering applications are presented. Future opportunities that will promote the development of tunable microdevices are elaborated, contributing to their improved understanding of these miniature devices and further realizing their practical applications in various fields. Graphic abstract

PNIPAAm-based temperature responsive ionic conductive hydrogels for flexible strain and temperature sensing

Conductive hydrogels have received much attention in the field of flexible wearable sensors due to their outstanding flexibility, conductivity, sensitivity and excellent compatibility. However, most conductive hydrogels mainly focus on strain sensors to detect human motion and lack other features such as temperature response. Herein, we prepared a strain and temperature dual responsive ionic conductive hydrogel (PPPNV) with an interpenetrating network structure by introducing a covalent crosslinked network of N-isopropylacrylamide (NIPAAm) and 1-vinyl-3-butylimidazolium bromide (VBIMBr) into the skeleton of the hydrogel composed of polyvinylalcohol (PVA) and polyvinylpyrrolidone (PVP). The PPPNV hydrogel exhibited excellent anti-freezing properties (−37.34 °C) and water retention with high stretchability (∼930 %) and excellent adhesion. As a wearable strain sensor, the PPPNV hydrogel has good responsiveness and stability to a wide range of deformations and exhibits high strain sensitivity (GF=2.6) as well as fast response time. It can detect large and subtle body movements with good signal stability. As wearable temperature sensors, PPPNV hydrogels can detect human physiological signals and respond to temperature changes, and the volumetric phase transition temperature (VPTT) can be easily controlled by adjusting the molar ratio of NIPAAm to VBIMBr. In addition, a bilayer temperature-sensitive hydrogel was prepared with the temperature responsive hydrogel by two-step synthesis, which shows great promising applications in temperature actuators.

Active dual quasi-BICs in a dielectric metasurface with VO2 for slow light and optical modulation.

We investigate the temperature tunable dual quasi-bound states in the continuum (qBICs) in a silicon/vanadium dioxide (Si/VO2) hybrid metasurface with Q-factor being as large as 9.3 × 106 and 2.8 × 107 by breaking the in-plane C2 symmetry. The far-field scattering of multipoles and near-field distributions confirm that the toroidal dipole and magnetic quadrupole dominate the dual qBICs resonance. The high performance of slow light with ultralarge group index exceeding 5.6 × 105 and the inverse quadratic law between the group index and asymmetric parameter are achieved. By temperature tuning of the VO2 thin film at the sub-10 K scale, a modulation depth of 90% and the ON/OFF ratio exceeding 12.8 dB are obtained. The proposed temperature tunable dual qBICs have potential applications in the fields of tunable slow light, temperature switches, and sensors.

High sensitivity potentiometric hydrogen sensor based on ZnFe2O4 electrode

Hydrogen is currently considered to be the best clean energy to replace fossil fuels, so hydrogen leak detection is crucial. The current research field of hydrogen sensors focuses on the discovery and optimization of sensitive materials. ZnFe2O4 powder is prepared by the sol-gel method and sintered at different temperatures. The effects of sintering temperature on electrode morphology and hydrogen sensing performance are investigated. The sensitivity reaches a maximum value of −101.32 mV/decade at the sintering temperature of 1100 °C. The sensor has different sensing performance at different operating temperatures. It has the best response value and sensitivity at 450 °C, and the best response/recovery rate and response curve stability at 550 °C. The sensor responds and recovers in seconds. The material has good H2 selectivity and is suitable for potentiometric hydrogen sensors. CO, NH3, and CH4 have less effect on the response signal and exhibit good long-term stability.

Reducing equivalent magnetic noise by electrode design and magnetic annealing in Quartz/Metglas magnetoelectric sensors

Magnetoelectric (ME) composites are promising for the development of high-performance magnetometers due to their high sensitivity, low cost, low power consumption, and small size. Enhancing the ME coefficient while reducing the background noise is an effective method to improve the performance of ME sensors, which remains challenging. In this work, we propose a method to reduce the equivalent magnetic noise by optimizing the electrode design and the magnetic annealing process in magnetoelectric quartz/Metglas composites. Compared with the non-optimized ME composites, the ME coefficient increases by 1.38 times while the background noise decreases by about 0.78 times, resulting in a LoD of 10 fT at resonance. Due to the high ME coefficient and low background noise, the equivalent magnetic noise from 20 kHz to 50 kHz was less than 6.10 pT/Hz1/2. The results show that proper annealing treatment of Metglas is beneficial for improving the soft magnetic properties. Meanwhile, the hollow electrode of quartz can reduce the equivalent capacitance and enhance the quality factor of the piezoelectric layer. This work demonstrates a feasible way to enhance the performance of ME magnetic field sensors.

Unusual inverse spin Hall effect in Pt/Co/Pt multilayers on single-crystalline YIG

The inverse spin Hall effect (ISHE) is a significant phenomenon that enables the conversion of spin current into charge current, offering promising applications in novel spintronic devices. In conventional ISHE measurements, it is widely recognized that the spin polarization, spin current, and generated charge current are mutually perpendicular. This study systematically investigates the ISHE in Pt/Co/Pt multilayers grown on a single-crystalline yttrium iron garnet (YIG) layer. A non-zero ISHE voltage was obtained along the direction parallel to the external magnetic field within the YIG coercive field range, deviating from the classical ISHE behavior. Our investigation revealed that the in-plane magnetic anisotropy of single-crystalline YIG plays a crucial role, as the easy axis of YIG and the external magnetic field collaboratively determine the polarization direction of the spin current, especially when the external magnetic field is smaller than the YIG coercive force. Furthermore, by tuning the small in-plane magnetization component of the Pt/Co/Pt multilayers, which couples with the YIG magnetization, we were able to control the shape and reversal path of the ISHE voltage loop. These findings deepen our understanding of how magnetic order affects charge current flow in ISHE measurements. The variety of ISHE voltage loop shapes and reversal paths observed suggest potential applications for this device as a magnetic field sensor.

Recording of ultra-low frequency electromagnetic emission during loading of a rock sample

The review of publications devoted to the study and features of the registration of electromagnetic emission observed during the loading of samples of rocks, metals, composite materials in laboratory conditions, as well as in areas of disintegration of rock massifs at mining sites is given. Electromagnetic emission observed during the destruction of rock samples in laboratory experiments and field conditions can appear itself not only in the high and low frequency ranges (1000–3·106 Hz and 500–1000 Hz, respectively), but also in the very low and ultra-low frequency (200–500 Hz and 0.01–200.00 Hz, respectively) ranges. However, the overwhelming majority of experimental studies of rock samples under the influence of a destructive load in laboratory conditions are aimed at measuring electromagnetic emission of the high frequency range. An instrumentation and measurement complex is described that allows recording electromagnetic emission in the ultra-low frequency range. The composition of the instrumentation and measurement complex includes magnetic modulation transducers of magnetic induction as magnetic field sensors. The methodology of laboratory experiments on recording electromagnetic signals arising from the influence of an external load on rock samples using an instrumentation and measuring complex is presented. An example of uniaxial loading of a basalt sample is given. When loading the sample under consideration, the amplitude of the electromagnetic emission pulses exceeds the background values of technogenic magnetic noise by two orders of magnitude. The high sensitivity of the magnetic modulation transducer of magnetic induction allows it to be used to register the components of magnetic induction in the process of destruction of rock samples in conditions of interference from technogenic magnetic noise. The results obtained are important for monitoring and forecasting the process of cracking before mining impacts, as well as for studying the geological environment and processes that generate low-frequency electromagnetic emission in the mining areas.

An unprecedented sensitive material for detecting trimethylamine derived from polyoxometalates @ bimetallic metal organic frameworks

Polyoxometalates (POMs) and metal organic frameworks (MOFs) have attracted increasing attention in the gas sensor field for the detection of volatile organic compounds. Herein, we present novel sensitive materials (PW12-NiO-ZnO hollow polyhedron) derived from POMs@bimetallic MOFs by using a one-step solvothermal approach. The micro-nano structure, compositions, and other chemical and physical properties of the samples were clarified through characterization such as XRD, SEM, TEM and XPS. Significantly, sensor based on PW12-NiO-ZnO hollow polyhedron presents a notable response value as high as 62.6 toward 100 ppm trimethylamine at 350℃, which is nearly 4.3 times that of pure ZnO. Moreover, we conducted other performance tests on the sensor to verify the high selectivity, good response/recovery properties and perfect long-term stability toward trimethylamine. Importantly, possible products on the surface of sensitive materials were analyzed by in situ diffuse reflectance infrared Fourier transform spectra (DRIFTS). In addition, these improved sensing performances is most benefiting from the incorporation of polyoxometalates and the p-n heterojunction between NiO and ZnO. As a pioneering study, this work provides an effective approach for designing diverse sensitive materials in the sensor applications.

Vector magnetic field measurement based on fiber ring microwave photonic filter with the Vernier effect

A vector magnetic field sensor based on enhanced Vernier effect is experimentally demonstrated. The Vernier effect is generated from two microwave photonic filters (MPFs) with close free spectral range (FSR), which is constructed by the fiber ring (FR) and the optical carrier microwave interferometry (OCMI). Linear chirped fiber Bragg grating (LCFBG) is inserted in the FR to act as the dispersion element to provide time delay. By attaching the fiber Bragg grating (FBG) on the magnetostrictive material (MA), the magnetic field can be transferred into the wavelength shift, as well as the time delay of the FR and the frequency response of the FR-MPF. By choosing opposite dispersion of LCFBGs and closer FSRs, cascaded FR-MPFs based sensor can greatly improve the sensitivity. The sensitivities for the magnetic field intensity and direction are 127.71 kHz/Oe, the magnification factor of which is 432, and 418.16 kHz/deg. The proposed scheme has merits of high sensitivity and interference immunity, which is suitable for high precision measurement.

Micro magnetic field sensor based on bifunctional diodes

Multiple-quantum well (MQW) diodes can be used as bifunctional diodes due to the emission-detection spectral overlap. When integrated with magnetic fluids (MFs) that have tunable refractive index, they can be designed as micro magnetic field sensors. The sapphire substrate of the MQW diode chip that consists of an MQW transmitter and receiver that is directly exposed to the MF, and the external magnetic field strength is used to change the refractive index at the boundary between the sapphire and the MF, thus modulating the reflected light and realizing external magnetic field sensing. Verified by experimental measurements, the micromagnetic field sensor has a detection range of 0.001-0.05 T, a sensitivity of 127.3 µA/T, and a resolution of 4.5×10−5 T, with excellent stability and repeatability. Additionally, the sensor demonstrates good velocity resolution under dynamic magnetic fields and can detect the direction of magnetic field motion, providing significant application value.

Magnetic field sensor based on one-dimensional binary photonic crystal

The work describes the study of a 1D photonic crystal to detect the magnetic fluid as a function of temperature and magnetic field. The structural dimensions are designed by incorporating alternating layers in a periodic way. Each layer is formed as a pair, in which a combination of two materials, PbS and air, is made with a thickness of 91 nm and 387 nm. Along with the structure, there is another mode called the defect mode, with a thickness of 277.5 nm, where the detecting magnetic fluid is injected. The overall PC structure is characterized by the transfer matrix method (TMM), whose results in the transmission spectrum as a function of wavelength are analyzed theoretically. In response to the magnetic fluid, the defect mode is generated and meets resonance at a particular wavelength. The change in shift for magnetic fluid gives the results for sensor performances. In particular, the proposed sensor is optimized by its structural perceptions, and its sensitivity is identified for both magnetic field and temperature through the absorption of magnetic fluid. The study of the temperature dependence of magnetic fluid is carried out at high temperatures up to 500 K. The sensitivity is calculated by noting the shift in defect mode for various incident angles, thicknesses, and temperatures. An increase in the angle of incidence improves both the sensitivity and FOM. The maximum sensitivity achieved, which depends on magnetic field and temperature, is 31.2 pm Oe−1 and 6.46 pm K−1, respectively, for a thickness of 305.25 nm at an angle of incidence of 50°. A maximum FOM of 57.884 Oe−1 is also achieved at an incident angle of 50° and a temperature 300 K. The work’s findings suggest developing prospective photonic devices, and the proposed PC has dual sensor characteristics that may be tuned.

Bimetallic ions modified 2‐methylimidazolium functionalized polypyrrole/graphene oxide for the improved supercapacitor

AbstractThin films with two‐dimensional (2D) nanostructures possess good environmental stability, thinner thickness and large surface area, which are widely used as a promising modified electrode material in the field of energy storage, supercapacitors, electrochemical sensors and biosensors. Herein, unique bimetallic ions modified polypyrrole/graphene oxide (PPy/GO) nanosheets, including Co2+‐Zr4+/(2‐MeIm)x@PPy/GO and Co2+‐Run+/(2‐MeIm)x@PPy/GO (n = 0, 4), are prepared by using 2‐methylimidazolium (2‐MeIm) as the linkers between PPy/GO and metal ions. The obtained electrodes constructed by Co2+‐Run+/(2‐MeIm)x@PPy/GO (n = 0, 4) and Co2+‐Zr4+/(2‐MeIm)x@PPy/GO exhibit improved capacitor electrochemical properties due to the reversible redox reaction, the large specific surface area and the high theoretical specific capacitance value of the metal ions compared to the unmodified PPy/GO. Especially, the specific capacitance value of Co2+‐Run+/(2‐MeIm)x@PPy/GO (n = 0, 4) electrode reaches 321.78 F g−1 at a current density of 1 A g−1 and the capacitance retention rate is achieved to 100% in the long cycle charge/discharge test after 10 000 cycles (10 A g−1). It will provide a practical experience for the design and preparation of supercapacitors based on bimetallic ions modified PPy/GO.

High-resolution temperature, salinity and depth data from southeastern Australian estuaries, 2018–2021

Estuaries are the important interface between the land and sea, providing significant environmental, economic, cultural and social values. However, they face unprecedented pressures including eutrophication, harmful algal blooms, habitat loss, and extreme weather due to climate change. Here we present an open access, quality-controlled water quality dataset collected from twelve diverse estuaries spanning 1000 km along the southeastern Australian coastline. Water depth, temperature and salinity data were collected across two years (2018–2021) capturing drought, wildfire and flood periods, using high accuracy Seabird MicroCAT field sensors located within oyster leases. These fully autonomous instruments collected and transmitted data every 10 minutes before downstream quality checking and uploading onto a public website. Simultaneous, high-resolution, longitudinal environmental data collected across multiple estuaries throughout a range of extreme weather events are exceptionally rare in the Southern Hemisphere, yet provide an invaluable resource for the aquaculture industry, researchers and environmental regulators alike.