A class of non-Gaussian entangled states is introduced by applying the nonlocal single-photon addition to two-mode squeezed vacuum state and the properties of entanglement are numerically investigated according to linear entropy and Einstein–Podolsky–Rosen (EPR) steering. After the nonlocal single-photon addition operation, Wigner function of the generated state appears some negative region and loses its Gaussian property in phase space. In essence, non-Gaussian entangled states are generated after applying nonlocal single-photon addition. Additionally, by studying the linear entropy and EPR steering, we find that single-photon addition can enhance their entanglement degree and non-Gaussian steering can be witnessed in a large range of squeezing parameter for the second-order quadratures, which may provide a well application in the fields of quantum information processing.