Cellulose Fibers Research Articles

Modification of bemban fiber (donax canniformis) with variations in NaOH concentration and soaking time

Abstract Modification and characterization of the physical, chemical and morphological properties of chemically engineered bemban fibers have been carried out with various NaOH concentrations and soaking times. The aim is to obtain the most optimal bemban fiber modification result so that they can be recommended as functional material reinforcement in composites. Fibers were modified by soaking for 1, 2 and 3 hours in NaOH solutions with concentrations of 2%, 3% and 4%; and also at 5% NaOH for 0.5 hours, 1 hour and 2 hours. The modification has reduced the lignin content and increased the cellulose fiber content. These results were confirmed by the results of the functional group spectrum using FTIR and fiber morphology using SEM. The physical properties of fiber such as water content, fiber diameter and porosity decreased while fiber density increased. The characteristics of the bemban fiber with modification in 5% NaOH solution for 2 hours have optimum values for the modifications carried out.

Self-adhesive ionic cable derived from natural bark as osmotic energy generator

Osmotic energy conversion technology plays an increasingly important role as clean energy alternatives. However, the excessive use of non-renewable materials in osmotic energy harvesting can lead to serious environmental pollution. Herein, we design a low-cost, eco-friendly, and high-ion-conductance ionic cable directly from natural Eucommia ulmoides bark owing to its unique sandwich structure and abundant charged nanochannels within the well-aligned lignocellulose nanofibers. In the cable, the natural biopolymer E. ulmoides gum (EUG) acts as a bio-adhesive tightly holding cellulose fibers together, rendering it with high morphological stability. The as-prepared ionic cable shows excellent ion conductance of 3.36 × 10−3 S cm−1, far surpassing the performance of natural bark (2.58 × 10−4 S cm−1). This work utilizes the natural E. ulmoides bark components and its unique lignocellulose-EUG sandwich structure to construct fully biomass-based cable with high-ion-conductance and water-stable, providing a sustainable strategy to accelerate the implementation of clean osmotic energy harvesting and forest waste utilization.

Evaluation of the use of rice husk cellulose fiber, acetylated rice starch and crude glycerol in foam formulation

Evaluation of the use of rice husk cellulose fiber, acetylated rice starch and crude glycerol in foam formulation

Sorption properties of a new modified flax fibre sorbent

The purpose of this study is to develop a modified sorbent of flax waste and investigate its sorption properties towards Cu (II) ions. The authors conducted the modification in two steps. The first step was oxidation of flax fibre cellulose with sodium metaperiodate to dialdehyde cellulose, the second one was the addition of taurine to increase the sorption characteristics of the modified sorbent. The paper presents the conditions for the periodate oxidation reaction of flax fibre and the treatment of the resulting dialdehyde cellulose with taurine. We determined the sorption characteristics of the modified sorbent in comparison with the original flax fibre. Kinetic studies allowed us to establish the time of reaching sorption equilibrium in the heterophase system ‘aqueous solution of metal salt-sorbent’ and determine the reaction order using pseudo first and pseudo-second order kinetics models. The authors processed the sorption isotherms obtained during the experiments using the Langmuir model. The maximum sorption capacity increased by 3 times compared to the original flax fibre. IR spectroscopy confirmed the improvement of equilibrium and kinetic characteristics of flax fibre occuring as a result of the appearance of new sorption centres in its structure.

Studies on the effect of reactive dye on jute and jute blended fabrics

Jute is generally not dyed with reactive dye though it is a cellulosic fiber. While jute is dyed with basic dye, but cotton, viscose, and other cellulosic fibers are frequently dyed with reactive dye. In this study, a novel method for dying blended jute fabrics with reactive dye after bleaching them is presented. Two different reactive dye colors were used to treat this blended jute fabric. By contrasting samples of non-dyed grey blended jute fabric, the GSM, Water uptake percentage, and FTIR of dyed fabric were examined. It has been observed that the dyed sample's GSM (average 76) is higher than the grey fabrics GSM (average 65) due to the chemical modification of grey blended jute fabric. Blended jute fabric has a lower water absorption percentage while dyed sample has a higher absorption percentage such as 150% in 40 min and 145% in 140 min. Due to chemical modification of the surface of the blended jute fabrics, the FTIR spectrum report reveals that –OH group peak appeared in the wave number of 3291 cm−1 and the dyeability of the fabric is significant based on peak analysis.

COMPUTATIONAL EXPERIMENTS WHEN STUDYING MATERIALS PROPERTIES INFLUENCED BY "MIXTURE" FACTORS

Short information on computational materials science is given, with the methodology of material properties fields, in composition and process coordinates, as the part of it and as the background of the study presented in this paper. One of the main means of the methodology is random scanning the whole and local fields. These tools were developed and used to solve many problems in materials science related to the properties defined by mutually independent factors. The purpose of the study presented in this paper has been to develop the tool for random scanning the fields of properties effected by "mixtures" of q components, linearly related portions of components in rangers from 0 to 1, with their sum equal to 1. In these cases, the factors domain (or subregion of it) presents the simplex. The special designs of experiments to get reduced polynomials describing the fields in simplex coordinates are used. Two procedures for generating any number of uniformly distributed points on the simplex have been developed. These points define the virtual mixtures simulated in computational experiments. The procedures were tested by scanning the fields of two rheological characteristics of lime suspension filled with "short", “medium", and "long" cellulose fibers. Experimental-statistical models in the form of reduced polynomials for effective viscosity at shear rate equal to1 s-1 and for the rate of destruction of liquid structure (parameters of power-law model of flow, K = η1 and m) obtained in previous study are used to determine the levels of these characteristic for each of simulated mixture. Computational experiments were carried out, in which the fields of η1 and m in whole simplex domain and in some of its zones were scanned, allowing the generalizing indices of the fields and different correlations between η1 and m in different zones of mixture triangle to be estimated. The developed tools, the procedures of generating random points, which would define the simulated compositions of the "mixtures", make significant contribution to the progress of the methodology of recipe-technological fields of properties and to computational materials science.

Comparative investigation of fillers loading effect on morphological, micromechanical, and thermal properties of polyvinyl alcohol/cellulosicfillers-based composites

Polyvinyl alcohol (PVA)-based biocomposites were fabricated by the incorporation of chitosan (Ch), cellulose fibers (CS), and their mixture (1:1 ratio). Fillers with various loading (2, 4, 8, and 10 wt.-%) were incorporated into PVA employing the solution casting method. The fillers and biocomposites were characterized by Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM), brightfield microscopy, tensile and microindentation tests, contact angle measurement and thermogravimetric analysis (TGA). FTIR spectra revealed the removal of lignin, and intermolecular H-bonding between PVA and fillers promoting their filler–matrix interfacial interactions. Crystallographic results showed varied crystallite sizes and crystallinity of composites. Microscopic techniques revealed a uniform filler distribution, attributed to their compatibility with PVA. Tensile and microindentation tests demonstrated a decreased tensile strength (3.3–8.2 MPa of the composites compared to 15.7 MPa of the matrix) and Martens hardness (HM) of biocomposites. However, their value was increased with higher filler concentration, signifying the mechanical reinforcement. Contact angle analysis confirms the decreased wettability (hydrophilicity) of biocomposites, attributed to higher compatibility of fillers with PVA and intermolecular H-bonding between them. A slightly decreased thermal stability of biocomposites with filler incorporation is implied by TGA results despite their uniform distribution and strong matrix–filler interfacial interactions.

Enhanced Cellulose Extraction from Banana Pseudostem Waste: A Comparative Analysis Using Chemical Methods Assisted by Conventional and Focused Ultrasound

This study investigates the effectiveness of various chemical methods, both ultrasound-assisted and non-assisted, for extracting cellulose from banana pseudostem (BPS) waste, comparing the results with commercial pine and eucalyptus cellulose fibers. Delignification treatments with NaOH (25% and 30%) and H2O2 (8%) were evaluated, applied with both conventional and focused sonication. Ultrasound-assisted methods, particularly with NaOH, achieved cellulose percentages as high as 99.5%. X-ray diffraction (XRD) analysis revealed that NaOH treatments significantly increased the cellulose crystallinity index, reaching up to 67.9%, surpassing commercial fibers. Scanning electron microscopy (SEM) results showed that NaOH treatments, especially at 30%, improved fiber morphology and exposure. Thermogravimetric analysis (TGA) indicated that methods using NaOH and focused sonication enhanced the thermal stability of the cellulose. Compared to commercial fibers, some samples obtained with the proposed methods demonstrated higher purity, yield, and thermal stability, highlighting the effectiveness of ultrasound-assisted and NaOH methods.

From Traditional to Exceptional: Impact of the Use of Dried Chicken Meat Powder on Sensory and Nutritional Quality of Tarhana

Tarhana is a popular Turkish fermented food, made of a mixture of cereal and yoghurt, generally consumed as soup. Both lactic acid bacteria and yeasts are responsible for the fermentation. The selection and proportions of ingredients integrated along with the production process specify the nutritional value and sensory properties of the final product. Therefore, the first objective of the present study was to process a dried “chicken meat powder (CMP)” that could be used in food formulations. The second objective was to determine the impact of CMP addition on the nutritional and sensorial properties of Uşak tarhana recipe with geographical indication. In order to fulfill these challenges dried chicken meat powder (CMP) at levels of 20, 25, 30, and 35% were included in tarhana recipes for the very first time. Within the scope of the study, organoleptic properties of tarhana soups (control and CMP added) were determined, and the formulation with 30% CMP (TCMP30) achieved the highest sensory evaluation scores. This sample was analyzed further, and its physicochemical properties were compared to a control sample strictly following the traditional Uşak tarhana recipe. In the tarhana samples, the moisture, protein, and total fat content increased with higher CMP additions, while the ash, crude cellulose, carbohydrates, energy, salt, and dietary fiber decreased significantly (p < 0.05). The calcium and sodium contents decreased, however, potassium, phosphorus, and zinc contents increased. The fatty acid composition analysis revealed that Uşak tarhana contained more saturated fatty acids than either CMP or TCMP30; adding 30% CMP reduced the total saturated fatty acids while increasing the monounsaturated fatty acids. The main fatty acids in traditional samples were linoleic, palmitic, and oleic acids, comprising 83.82% of the total fat. In TCMP30, the order changed to oleic > linoleic > palmitic with 83.89% of total fat. Over time, the total phenolic content and antioxidant capacity decreased in the control sample but increased in TCMP30. These results suggest that a formulation including 30% CMP effectively enhances the sensory, functional, and nutritional aspects in tarhana.

AN ANALYSIS ON THE USE OF MODIFIED EXPANDED PERLITE AND PUMICE IN INORGANIC BONDED FIBROUS COMPOSITE BOARDS

It is often stated that there is an energy efficiency difference between optimum energy use and actual energy use in the world. In the construction industry, various building materials are produced and used to optimize energy efficiency in buildings. Among these building materials, inorganic bonded fibrous composite boards, whose energy efficiency criteria have begun to be improved, are widely used both in Türkiye and in the world. This article presents an experimental analysis of the utilization of modified expanded perlite and pumice as key constituents in the development of inorganic bonded fibrous composite boards. The study investigates the influence of these modified porous materials on the physical, mechanical, and thermal properties of the composite boards. For this purpose; composite mortars were produced using micronized quartz sand, a hybrid fiber consisting of cellulose and glass fiber, modified expanded perlite (MEP) with stearic acid (1, 2, 3, 4, 5, 6, 7, 8, 9 wt.%) and modified pumice (MPU) with stearic acid (1, 2, 3, 4, 5, 6, 7, 8, 9 wt.%). In order to make a comparison, a control mortar that did not contain modified expanded perlite and modified pumice was produced. Through a series of experiments, it is concluded that the density values of all other mixture designs with MEP and MPU aggregate additives under equivalent conditions are lower than the control sample. The water absorption values of the samples always remained below the control sample, and with the increase in the MPU ratio and decrease in the MEP ratio, the water absorption values of the samples also decreased. The average modulus of rupture (MOR) value of control sample in the analysis made after 14 days of curing under ambient conditions is 3.73 MPa. The highest MOR value of the test samples is 3.51 MPa, which is the mixture using the highest MPU. The thermal conductivity value of the control mixture is 0.352 W/mK. The thermal conductivity value of test mixtures with MEP and MPU aggregates varies between 0.175 W/mK and 0.287 W/mK.

Physical, mechanical and thermal properties of novel bamboo/kenaf fiber-reinforced polylactic acid (PLA) hybrid composites

This study investigates the physical, mechanical, and thermal properties of bamboo (BF) and kenaf (KF) fiber-reinforced polylactic acid (PLA) hybrid composites. Three hybrid (30BF-70KF, 50BF-50KF, and 70BF-30KF) and two non-hybrid (BF-PLA and KF-PLA) composites were developed through twin screw extrusion and compression molding techniques. The physical properties (density, void content, crystallinity via XRD, and chemical interactions via FTIR), mechanical properties (tensile, flexural, compressive, impact, and hardness), and thermal properties (Thermogravimetric analysis-TGA and Differential scanning calorimetry-DSC) were thoroughly analyzed. BF reinforcement reduced the composites’ density to 1.1826 g/cm³, while the inclusion of KF increased it to 1.2479 g/cm³. 50:50 blend of bamboo-kenaf reinforcement achieved the lowest void content of 0.27 %. The XRD patterns revealed heightened crystallinity in the BF-PLA composite. FTIR analysis showed stable functional groups, with O–H absorption bands indicative of cellulosic fibers. The BF-PLA non-hybrid composite exhibited the highest tensile strength at 25.95 MPa and compressive strength at 173.15 MPa, with the 30BF-70KF hybrid composite showing notable impact strength. Fractured morphology by FESEM revealed superior fiber-matrix adhesion for BF-PLA composite. TGA demonstrated a variation in thermal degradation temperatures, with the BF30-KF70 composite showing the highest onset of degradation at 484 °C. DSC analysis indicated a reduction in the glass transition temperature (Tg) across all fiber-reinforced samples and revealed significant adjustments in melting and crystallization temperatures. This research highlights the potential of BF-KF/PLA hybrid composites in the development of eco-friendly plastic furniture and consumer products.

Behavior of Cellulosic Fiber Board Wood-Frame Shear Walls with and without Openings under Cyclical Loading

Behavior of Cellulosic Fiber Board Wood-Frame Shear Walls with and without Openings under Cyclical Loading

Extrusion pre-treatment of cowpea (Vigna unguiculata (L.) Walp.) lignocellulosic sidestream to produce cellulose fibres.

Various agricultural sidestreams have been demonstrated as feedstock to produce cellulose. To the best of our knowledge, there is no research work on the potential of agricultural sidestream from cowpea (Vigna unguiculata (L.) Walp.), a neglected and underutilised crop to produce cellulose fibres. Conventional methods to produce cellulose consume large amounts of chemicals (NaOH) and produce a high amount of effluent waste. Herein, we investigated extrusion pre-treatment without and with an alkali followed by bleaching as an alternative method to conventional alkaline pre-treatment followed by bleaching to produce cellulose fibres from cowpea sidestream. Cellulose extracted by extrusion without and with mild alkali followed by bleaching consumed about 20 times less NaOH compared to the conventional method and produced less effluent waste. Extrusion with mild alkali followed by bleaching resulted in higher cellulose yield, purity, and crystallinity compared to extrusion without an alkali followed by bleaching. However, the conventional method resulted in higher cellulose yield, purity and crystallinity compared to extrusion pre-treatment followed by bleaching. Scanning electron microscopy revealed that micro-sized cellulose fibres with an average diameter of 10-15 μm were extracted using both methods. Notably, cellulose fibres extracted using extrusion pre-treatment were shorter than those extracted using the conventional method. Extrusion pre-treatment is a promising continuous alternative to alkaline pre-treatment to produce micro-sized cellulose fibres from low-value, underutilised cowpea lignocellulosic sidestream, for potential use as a filler in composite plastics. © 2024 The Author(s). Journal of the Science of Food and Agriculture published by John Wiley & Sons Ltd on behalf of Society of Chemical Industry.

Structure and properties of the cellulose fibres spun from imidazolium-based carboxylate functionalized zwitterionic liquid

Dissolution of cellulose without further derivatization has been an active area of research in recent years. There are still challenges in developing a commercially viable solvent system for the dissolution and regeneration of cellulose as films and fibres. We report here a process for making cellulose fibres through the dry-jet wet spinning method by utilizing aqueous zwitterionic liquid (ZIL), viz., (6-(1-(2-methoxyethyl) imidazol-3-io)-hexanoate), in which oxyethylene substituted imidazolium-based cation and a carboxylate anion is covalently tethered. Our results suggest that 11 % ZIL dope could be successfully prepared and spun under industrially viable process conditions. The resultant fibres have properties comparable to that of commercial-grade Lyocell fibres. Particularly, the cellulose fibres spun from a cellulose ZIL solution exhibited a denier of 1.2–1.6, a tenacity of 3.5–4.0 g per denier (gpd), and an elongation at break of 8–10 %, which is comparable to cellulose fibres produced using ionic liquid and N-methyl-morpholine-N-oxide (NMMO) solvent. Cellulose fibres obtained from zwitterionic liquid have a crystallinity of 60 %, which is comparable to Lyocell fibres. To the best of our knowledge, this is the first report to demonstrate the successful spinning of regenerated cellulose fibres using zwitterionic liquids with mechanical properties comparable to commercial Lyocell fibres.

A FACILE METHOD TO PRODUCE HIGH-BULK AND HIGH-STRENGTH ROLLED RECONSTITUTED TOBACCO SHEET WITH REFINED TOBACCO CELLULOSE FIBERS

The rolling method is a pivotal means for reconstituted tobacco sheet (RTS) production due to its cost-effectiveness. However, the traditional rolling method is limited by its raw material grinding processes and yields of rolled RTS (RRTS) with subpar strength and bulk. Therefore, it is a challenge to develop a method to produce high-strength and high-bulk RRTS. Here, by replacing traditional raw materials grinding processes with papermaking refining processes, we present a facile and practical method to produce RRTS with elevated bulk and strength. This method separately refines tobacco leaves and stems into long and coarse leave and stem cellulose fibers. These fibers were subsequently reconstructed into RRTS. The detailed process parameters were optimized. The comparative RRTS with flax fibers instead of stem fibers was investigated. The optimal formula of new RRTS was determined. The updated processes, along with the use of refined cellulose fibers, led the RRTS to a significant improvement in strength and bulk, with a 5.3-fold increase in strength, and a 0.7-fold increase in bulk, while smoking qualities were preserved, which surpassed the smoking experience of RRTS with flax fibers. We anticipate this work will enhance the qualities of RTS and facilitate the transition of traditional tobacco industries toward healthier directions.

Research progress in bacterial cellulose synthase subunit diversity and fiber structure formation

Bacterial cellulose (BC) is the glucose polymer produced by bacterial metabolism. The bacterial cellulose synthase (BCS) is the key enzyme for catalyzing the formation of BC. The cooperation between different submits of BCS is necessary for the intracellular formation and extracellular secretion of BC. This review summarized the BC-producing strains and the differences of BCS among different strains. Furthermore, we detailed the BC synthesis mechanism, the interactions between BCS subunits, and the relationship between the structural characteristics of strains and the formation of highly ordered fiber structures. A comprehensive insight into the mechanism of BC synthesis and secretion will supply more strategies for optimizing the BC synthesis via methods of synthetic biology.

Effect of Silane Grafted Polyethylene terephthalate Foam, Areca Fruit Fibre and Microcrystalline Cellulose Toughened Vinyl Ester Composite on Thermal and Water Accelerated Ageing

Effect of Silane Grafted Polyethylene terephthalate Foam, Areca Fruit Fibre and Microcrystalline Cellulose Toughened Vinyl Ester Composite on Thermal and Water Accelerated Ageing

Brewer's Spent Grain-Cellulose-Coated Copper Electrode-Based Extended Gate Field-Effect Transistor for Nonenzymatic Glucose Detection toward Diagnosis of Diabetes Mellitus.

The demand for environmentally friendly, reliable, and cost-effective electrodes for glucose sensor technology has become a major research area in the paradigm shift toward green electronics. In this regard, cellulose has emerged as a promising flexible biopolymer solution with unique properties such as biocompatibility, biodegradability, nontoxicity, renewability, and sustainability. Because of their large surface area and porous structure, fibrous cellulose substrates quickly adsorb and disperse analytes at detection sites. This work focuses on utilizing glyoxal-treated cellulose (derived from brewer's spent grain (BSG)) for the fabrication of extended gate field-effect transistor (EGFET)-based glucose sensors. This investigation extends to the utilization of BSG-cellulose for glucose detection in biomimicking electrolytes (phosphate buffer saline) to facilitate glucose detection in human blood samples. The fabricated electrode demonstrates a linear range of glucose detection from 1 to 13.5 mM with a Langmuir adsorption coefficient (K) of 0.102. Also, its selectivity toward glucose over interfering molecules such as sucrose, fructose, ascorbic acid, and uric acid under physiological conditions has been demonstrated. This cellulose-based EGFET electrode exhibits a sensitivity of 6.5 μA mM-1 cm-2 with a limit of detection (LOD) of 0.135 mM. Computational studies by density functional theory calculations confirmed the higher binding affinity of glucose molecules with glyoxal-modified cellulose (-0.95 eV) than with pristine cellulose (-0.46 eV). Here, the novelty lies in the fabrication of electrodes with biodegradable catalysts and their integration into the EGFET configuration.

Impact of deep eutectic solvent pre-treatment on the extraction of cellulose nanofibers

Deep Eutectic Solvents (DESs) have emerged as promising eco-friendly pre-treatment agents for lignocellulosic biomass, offering considerable advantages for the nanofibrillation process. This study investigates the impact of DESs on cellulose fibers morphology, focusing on solubilization phenomena in the amorphous regions that may facilitate cellulose nanofiber production. The pre-treatment process combining a DES (triethylmethylammonium chloride and imidazole, TEMA:IMD) with microwave (MW) energy was optimized to enhance the solubility of cellulosic fibers. A response surface methodology (RSM) was employed to optimize the DES-MW-assisted pre-treatment. Results show that the reaction time and the temperature significantly influence the solubility of cellulosic fibers. The optimized conditions resulted in cellulose fibers with low content of hemicellulose and lignin, high crystallinity index, and improved thermal stability. The effectiveness of DES-MW pre-treatment in producing cellulose nanofibers (CNFs) from native and pre-treated fibers was investigated. Cellulose fibers pre-treated with a DES yielded CNFs with a narrower diameter distribution. Overall, optimized DES-MW pre-treatment offers a promising strategy for the efficient and sustainable extraction of CNFs.

Cellulose Fiber with Enhanced Mechanical Properties: The Role of Co-Solvents in Gel-like NMMO System.

Cellulose has garnered attention in the textile industry, but it exhibits limitations in applications that require high strength and modulus. In this study, regenerated cellulose fiber with enhanced mechanical properties was fabricated from a gel-like N-methylmorpholine N-oxide (NMMO)-cellulose solution by modulating the intermolecular interaction and conformation of the cellulose chains. To control the interaction, two types of co-solvents (dimethyl acetamide (DMAc) and dimethyl formamide (DMF)) were added to the cellulose solutions at varying concentrations (10, 20, and 30 wt%). Rheological analysis showed that the co-solvents reduced the solution viscosity by weakening intermolecular interactions. The calculated distance parameter (Ra) in Hansen space confirmed that the co-solvent disrupted intermolecular hydrogen bonding within cellulose chains. The solutions were spun into fiber via a simple wet spinning process and were characterized by X-ray diffraction (XRD) and universal testing machine (UTM). The addition of co-solvent led to an increased crystallinity index (C.I.) owing to the extended cellulose chains. The modulus of the resulting fiber was increased when the co-solvent concentration was 10 wt%, regardless of the co-solvent type. This study demonstrates the potential for enhancing the mechanical properties of cellulose-based products by modulating the conformation and interaction of cellulose chains through the addition of co-solvent.