Fiber Segments Research Articles

Fatigue-resistant polyurethane elastomer composites

Polyurethane (PU) elastomers are among the most used rubberlike materials due to their combined merits, including high abrasion resistance, excellent mechanical properties, biocompatibility, and good processing performance. A PU elastomer exhibits pronounced hysteresis, leading to a high toughness on the order of 104 J/m2. However, toughness gained from hysteresis is ineffective to resist crack growth under cyclic load, causing a fatigue threshold below 100 J/m2. Here we report a fatigue-resistant PU fiber–matrix composite, using commercially available Spandex as the fibers and PU elastomer as the matrix. The Spandex fibers are stiff, strong, and stretchable. The matrix is soft, tough, and stretchable. We describe a pullout test to measure the adhesion toughness between the fiber and matrix. The test is highly reproducible, showing an adhesion toughness of 3170 J/m2. The composite shows a maximum stretchability of 6.0, a toughness of 16.7 kJ/m2, and a fatigue threshold of 3900 J/m2. When a composite with a precut crack is stretched, the soft matrix causes the crack tip to blunt greatly, which distributes high stress over a long segment of the Spandex fiber ahead the crack tip. This deconcentration of stress makes the composite resist the growth of cracks under monotonic and cyclic loads. The PU elastomer composites open doors for realistic applications of fatigue-resistant elastomers.

A numerical study on elastic properties of low-density two-dimensional networks of crosslinked long fibers

Fiber-based materials are prevalent in nature and in engineering applications. Microscopically, these materials resemble a discrete assembly of crosslinked or entangled fibers. To understand the relationship between the effective mechanical properties and the underlying microstructures, we consider a variety of periodic and random two-dimensional (2D) networks of crosslinked long fibers. The linearly elastic properties of periodic 2D networks (e.g., square, triangular and Kagome) are well understood. However, for low-density networks, cooperative buckling of the fiber segments can take place at small strains, leading to nonlinear, anisotropic elastic behaviors. A transition from stretch to bending and then back to stretch dominated deformation is predicted for the Kagome and triangular networks. For random 2D networks, the elastic behaviors are different. Under uniaxial tension, the stress–strain behavior is statistically isotropic and slightly nonlinear, dominated by stretch of the fibers aligned closely to the loading direction. Meanwhile, stochastic buckling occurs continuously in the random networks, leading to significant lateral contraction. Consequently, while the effective Young’s modulus follows a nearly linear scaling with respect to the relative density, the effective Poisson’s ratio exhibits a transition from stretch to bending dominated mode as the relative density decreases. A statistical analysis is performed to estimate the relative errors of the effective properties that depend on both the computational box size and the number of random realizations. The comparison between the periodic and random 2D networks highlights the profound effects of the network topology on the effective elastic properties.

Trace copper detection using in-line optical fiber Mach-Zehnder interferometer combined with an optoelectronic oscillator.

We experimentally demonstrate a novel optical fiber chemosensor for trace Cu2+ ions detection that is implemented by using an in-line optical fiber Mach-Zehnder interferometer (MZI) in conjunction with an optoelectronic oscillator (OEO). The MZI is fabricated by lateral offset splicing a section of D-shaped fiber between two single-mode fibers. It splices the broadband optical source into a sinusoidal-shaped light, which can form a single passband microwave photonic filter (MPF) by combining the Mach-Zehnder modulator, a segment of fiber and a photodetector. The center frequency of the MPF, determined by the free spectra range of MZI, is affected by the solution concentration. Incorporating the MPF in the OEO sensor, the oscillation frequency is determined by the solution concentration. Therefore, we can estimate the solution concentration by measuring the microwave frequency change. We carry out a proof to concept experiment. High sensitivity Cu2+ ions concentration sensing with sensitivity of 13 Hz/(μM/L) is achieved. The maximum measurement error of concentration obtained is within 1.38 μM/L. The proposed sensor has merits of high interrogation speed, simple operation, high sensitivity and accuracy, offering the potentials in a wide range of biological application scenarios.

Temperature-compensated optical fiber sensor for volatile organic compound gas detection based on cholesteric liquid crystal.

External temperature variations inevitably affect the accuracy of a liquid crystal sensor. Therefore, we propose a novel temperature-compensated fiber volatile organic compound (VOC, using acetone as a model compound) gas sensor. The proposed sensor consists of a short segment of hollow-core fiber (HCF), which is spliced on a multimode fiber. Cholesteric liquid crystal (CLC) is sealed into HCF to sense the temperature, and another type of CLC is coated on the end face of HCF for VOC gas detection. The VOC gas concentration and ambient temperature can be simultaneously measured by monitoring the wavelength shifts of two Bragg reflection peaks caused by two types of CLCs. The effects of the CLC thickness on the sensitivities of temperature and acetone concentration are investigated, and optimal parameters are chosen. An optimal sensor can reach a temperature sensitivity of 2.53 nm/°C and acetone concentration sensitivity of 48.46 nm·L/mmol at 8-44°C. In addition, temperature compensation capability, repeatability, response time, and stability are also researched. The experimental results prove this sensor has great application potential in high-precision real-time VOC gas monitoring and detection.

A long pulse bidirectional BOTDA technology developed for strain positioning and measurement

In this paper a long pulse bidirectional BOTDA technique was developed for strain positioning and measurement. Endpoints superposition phenomenon in series Brillouin spectra of a strained fiber detected by different long pulses was analyzed by pulse subdivision theory, based on which the bidirectional exploration BOTDA technique was proposed. With this method a 1 m strained fiber segment on a 24,752 m test fiber was positioned by a long pump pulse (pulse width larger than 50 ns). Strain value of 1660 με was measured with an error of 10 με. Restriction on spatial resolution of a conventional long pulse BOTDA system was removed. Signal-to-noise ratio could be significantly improved which is beneficial for long-distance distributed sensing. Influence of pulse width and Brillouin frequency interval between intrinsic/strained fiber on performance of the method was analyzed. With the characteristic of simplicity, high spatial resolution and strong signal-to-noise ratio supported by a long pulse, the proposed method could find extensive application prospects in distribution sensing fields.

Thermosetting supramolecular polymerization of compartmentalized DNA fibers with stereo sequence and length control

Thermosetting supramolecular polymerization of compartmentalized DNA fibers with stereo sequence and length control

Magnetic Alignment of Electrospun Fiber Segments Within a Hydrogel Composite Guides Cell Spreading and Migration Phenotype Switching.

Fibrous extracellular matrix (ECM) proteins provide mechanical structure and adhesive scaffolding to resident cells within stromal tissues. Aligned ECM fibers play an important role in directing morphogenetic processes, supporting mechanical loads, and facilitating cell migration. Various methods have been developed to align matrix fibers in purified biopolymer hydrogels, such as type I collagen, including flow-induced alignment, uniaxial tensile deformation, and magnetic particles. However, purified biopolymers have limited orthogonal tunability of biophysical cues including stiffness, fiber density, and fiber alignment. Here, we generate synthetic, cell-adhesive fiber segments of the same length-scale as stromal fibrous proteins through electrospinning. Superparamagnetic iron oxide nanoparticles (SPIONs) embedded in synthetic fiber segments enable magnetic field induced alignment of fibers within an amorphous bulk hydrogel. We find that SPION density and magnetic field strength jointly influence fiber alignment and identify conditions to control the degree of alignment. Tuning fiber length allowed the alignment of dense fibrous hydrogel composites without fiber entanglement or regional variation in the degree of alignment. Functionalization of fiber segments with cell adhesive peptides induced tendon fibroblasts to adopt a uniaxial morphology akin to within native tendon. Furthermore, we demonstrate the utility of this hydrogel composite to direct multicellular migration from MCF10A spheroids and find that fiber alignment prompts invading multicellular strands to separate into disconnected single cells and multicellular clusters. These magnetic fiber segments can be readily incorporated into other natural and synthetic hydrogels and aligned with inexpensive and easily accessible rare earth magnets, without the need for specialized equipment. 3D hydrogel composites where stiffness/crosslinking, fiber density, and fiber alignment can be orthogonally tuned may provide insights into morphogenetic and pathogenic processes that involve matrix fiber alignment and can enable systematic investigation of the individual contribution of each biophysical cue to cell behavior.

Fast and accurate computation of interactions between linear fiber segments

PurposeFiber networks represent a vast class of materials, which can be modeled by representing its microstructure using one-dimensional fiber embedded in three-dimensional space. Investigating the statics, dynamics and thermodynamics of such structures from computational first principles requires the efficient estimation of cohesive-repulsive energies and forces between interacting fiber segments. This study offers a fast, efficient and effective computational methodology to estimate such interactions which can be coupled with Hamiltonian mechanics to simulate the behavior of fibrous systems.Design/methodology/approachThis method preserves the uniformly continuous distribution of particles on the line segments and utilizes adaptive numerical integration of relevant distance-distribution functions to estimate the effective interaction energy and forces.FindingsThis method is found to be cheaper to compute and more accurate than the corresponding discrete scheme. This scheme is also versatile in the sense that any pair-wise interaction model can be used.Research limitations/implicationsThe scheme depends on the availability of a suitable pair-interaction potential, such as a Lennard-Jones potential or Morse potential. Additionally, it can only be used for systems which are purely fibrous in nature. For example, fiber composites with a non-fibrous matrix are not addressed.Practical implicationsPaper, woven and hair can be represented as purely fibrous at some relevant length scales and are thus excellent candidate systems for this scheme.Originality/valueThis paper presents a novel method which allows rapid and accurate implementation of an otherwise computationally expensive process.

Objective-lens-free confocal endomicroscope using Lissajous scanning lensed-fiber

We report an objective-lens-free endomicroscopic catheter for compact Lissajous scanned confocal endomicroscopic system using a scanning lensed-fiber. The fiber scanner comprises a single-mode fiber (SMF) spliced with a coreless silica fiber segment and quadrupole piezoelectric tube. An objective lens was directly formed at the distal end of an SMF using a fusion splicer. The lensed fiber eliminates the need for conventional beam focusing elements such as a gradient index rod lens and precise optical alignment, allowing low cost and facile fabrication of an exceptionally short endomicroscopic catheter. The endomicroscopic scanner was fully packaged within a stainless tube of 2.6 mm in outer diameter and 20 mm in length, which can be easily inserted through the working channel of conventional laparoscope or colonoscope. The microscopic images of a stained kidney section and ear of a mouse were successfully obtained with the Lissajous scanning confocal endomicroscope. The compact Lissajous scanning lensed fiber can provide a new route for diverse in vivo endomicroscopic applications.

Engineering a Highly Biomimetic Chitosan-Based Cartilage Scaffold by Using Short Fibers and a Cartilage-Decellularized Matrix.

Engineering scaffolds with structurally and biochemically biomimicking cues is essential for the success of tissue-engineered cartilage. Chitosan (CS)-based scaffolds have been widely used for cartilage regeneration due to its chemostructural similarity to the glycosaminoglycans (GAGs) found in the extracellular matrix of cartilage. However, the weak mechanical properties and inadequate chondroinduction capacity of CS give rise to compromised efficacy of cartilage regeneration. In this study, we incorporated short fiber segments, processed from electrospun aligned poly(lactic-co-glycolic acid) (PLGA) fiber arrays, into a citric acid-modified chitosan (CC) hydrogel scaffold for mechanical strengthening and structural biomimicking and meanwhile introduced cartilage-decellularized matrix (CDM) for biochemical signaling to promote the chondroinduction activity. We found that the incorporation of PLGA short fibers and CDM remarkably strengthened the mechanical properties of the CC hydrogel (+349% in compressive strength and +153% in Young's modulus), which also exhibited a large pore size, appropriate porosity, and fast water absorption ability. Biologically, the engineered CDM-Fib/CC scaffold significantly promoted the adhesion and proliferation of chondrocytes and supported the formation of matured cartilage tissue with a cartilagelike structure and deposition of abundant cartilage ECM-specific GAGs and type II collagen (+42% in GAGs content and +295% in type II collagen content). The enhanced mechanical competency and chondroinduction capacity with the engineered CDM-Fib/CC scaffold eventually fulfilled successful in situ osteochondral regeneration in a rabbit model. This study thereby demonstrated a great potential of the engineered highly biomimetic chitosan-based scaffold in cartilage tissue repair and regeneration.

All-fiber figure-eight wavelength-tunable noise-like pulse lasers

All-fiber wavelength-tunable fiber laser is a desirable light source architecture in many fields owing to their low cost, compactness and easy integration. However, most of them have independent filter elements and saturated absorption elements, which will undoubtedly increase the redundancy of laser. In this paper, we realize an all-fiber wavelength-tunable noise-like pulse (NLP) laser with the tunable central wavelength from 1547 nm to 1600 nm based on fiber loop mirror (FLM). The fiber loop (FLM) fused with two segments of polarization-maintaining fibers (PMF) acts as both a comb filter and a saturable absorber (SA). Such an all-fiber tunable NLP mode-locked laser wavelength at C-band (1530–1565 nm) and L-band (1565–1625 nm) is a potential choice for many practical applications.

Highly sensitive fiber-optic temperature sensor based on tapered no-core fiber for biomedical and biomechanical applications

A low-cost, easy to fabricate real-time temperature sensation device built on an In-Line Mach–Zehnder interferometer basis was manufactured by fusing a segment of no-core fiber amongst two fibers of single-mode. Two different structures, tapered no-core fiber, and untapered no-core fiber both retaining acrylate polymer coating were investigated. The 3 cm length tapered no-core fiber sensor showed the highest sensitivities of ∼ −1.943 nm ◦C−1 and ∼ −1.954 nm ◦C−1 for two different dips respectively. The sensor exhibited high linearity with a very good resolution of 0.0102 ◦C. making the most of the high coefficient of thermal expansion, thermo-optic properties of the acrylate polymer, and the tapering effect, the sensor could be utilized in many temperatures observing applications like biochemical labs, biomechanical studies, and bio-sensing analyses.

Fabrication of Lensed Optical Fibers for Biosensing Probes Using CO2 and Femtosecond Lasers

We propose a new method for precisely fabricating a lensed fiber with a desired focal length by first cleaving a coreless silica fiber using an ultrafast femtosecond laser without thermal effects and subsequently shaping the radius of curvature at the optical-fiber end using a CO2 laser. The precisely cleaved segment of the coreless silica fiber obtained with the femtosecond laser is attached to a long single-mode fiber. The beam-exposure time and laser power of the CO2 laser are adjusted to melt the coreless-fiber end to yield a uniform, consistent, and precise radius of curvature, thereby realizing a lensed optical fiber. The precision of the radius of curvature in this case is greater than those obtained with the conventional arc discharge method with thermal treatment requiring fairly complex processes and yielding relatively low fabrication accuracy. In our study, we observe a difference between the measured and calculated focal lengths of the fabricated lens, possibly because the exact value of the mode field diameter is uncertain. On the other hand, the beam size measured using the knife-edge method matches closely with the theoretical size. Our findings confirm the feasibility of fabricating lensed optical fibers for fiber-based biosensing using CO2 and femtosecond lasers.

A semi-analytic method for FM-EDFA intensity model

Based on the intensity model of few-mode erbium-doped fiber amplifiers (FM-EDFAs), we put forward a semi-analytic method for efficiently calculating the signal mode gains by solving the analytical expression for the average population inversion over each fiber segment. Our studies show that, the semi-analytic method can offer a desirable calculation accuracy, very close to that of the full approach method. According to the length dependency of the overlap integral between the normalized transverse distribution of population inversion and the signal modal field, a large iterative step size is verified to be feasible for the semi-analytic method, which is helpful for greatly reducing the iterative times. We also take the example of designing FM-EDFA’s overall gain using the semi-analytic method. The semi-analytic method is not only suitable for the FM-EDFAs with complex erbium-ion doping profile, the cladding pumping scheme and the cascaded FM-EDFAs, but also helpful for greatly improving the optimization efficiency of FM-EDFAs in combination with relevant optimization algorithms.

Controlled Transportation of Light by Light at the Microscale.

We show how light can be controllably transported by light at microscale dimensions. We design a miniature device that consists of a short segment of an optical fiber coupled to transversally oriented input-output microfibers. A whispering gallery soliton is launched from the first microfiber into the fiber segment and slowly propagates along its mm-scale length. The soliton loads and unloads optical pulses at designated input-output microfibers. The speed of the soliton and its propagation direction is controlled by the dramatically small, yet feasible to introduce, permanently or all-optically, nanoscale variations of the effective fiber radius.

Stable evanescent wave mode-locked laser based on a photonic-crystal-fiber-induced Mach-Zehnder filter as a gain-tilt equalizer.

In this paper, a switchable multichannel ytterbium-doped fiber laser based on a Mach-Zehnder interferometer (MZI) has been experimentally demonstrated. The MZI is fabricated by splicing a short piece of nonlinear photonic-crystal fiber (NLPCF) between two segments of a single-mode fiber. MZI-based NLPCF gathering with the intracavity birefringence polarization controller offers functions as both the selective comb filter and the mode locker. The laser can emit a single, dual, triple, or quadruple channel that can be varied in the spectral span around1030-1050 nm by only adjusting the pump power or polarization state. A stable evanescent wave, picosecond mode-locking generation with variable repetition rate (24.5 to 18.23 MHz and 34.64 MHz) has been realized via only inserting the polarization controller and adjusting its state inside the cavity. To the best of the authors' knowledge, this the first demonstration of a passive filter based on a NLPCF-MZ interferometer to generate switchable mode-locked pulses delivered from a single laser oscillator.

Distributed strain and temperature sensing over 100 km using tunable-wavelength OTDR based on MEMS filters.

The possibility of distributed wide-range strain and temperature measurements in a 100 km long optical fiber using tunable-wavelength low-coherence optical time-domain reflectometer (OTDR) is demonstrated. The specified distance range is provided by employing two narrowband microelectromechanical system (MEMS) spectral filters tuned synchronously as well as by taking advantage of Raman amplification and amplification by remotely pumped erbium-doped fiber segments built into the fiber under test. With the time of a single measurement of 10 min and the spatial resolution of about 1 m, the measurement range reached 1000 µɛ in strain units, which is equivalent to the temperature range of 110°C.

Microresonator devices lithographically introduced at the optical fiber surface.

We present a simple lithographic method for fabrication of microresonator devices at the optical fiber surface. First, we undress the predetermined surface areas of a fiber segment from the polymer coating with a focused CO2 laser beam. Next, using the remaining coating as a mask, we etch the fiber in a hydrofluoric acid solution. Finally, we completely undress the fiber segment from coating to create a chain of silica bottle microresonators with nanoscale radius variation [surface nanoscale axial photonics (SNAP) microresonators]. We demonstrate the developed method by fabrication of a chain of five 1 mm long and 30 nm high microresonators at the surface of a 125 µm diameter optical fiber and a single 0.5 mm long and 291 nm high microresonator at the surface of a 38 µm diameter fiber. As another application, we fabricate a rectangular 5 mm long SNAP microresonator at the surface of a 38 µm diameter fiber and investigate its performance as a miniature delay line. The propagation of a 100 ps pulse with 1 ns delay, 0.035c velocity, and negligible dispersion is demonstrated. In contrast to previously developed approaches in SNAP technology, the developed method allows the introduction of much larger fiber radius variation ranging from nanoscale to microscale.

Age-Related Differences in White Matter: Understanding Tensor-Based Results Using Fixel-Based Analysis.

Aging is associated with widespread alterations in cerebral white matter (WM). Most prior studies of age differences in WM have used diffusion tensor imaging (DTI), but typical DTI metrics (e.g., fractional anisotropy; FA) can reflect multiple neurobiological features, making interpretation challenging. Here, we used fixel-based analysis (FBA) to investigate age-related WM differences observed using DTI in a sample of 45 older and 25 younger healthy adults. Age-related FA differences were widespread but were strongly associated with differences in multi-fiber complexity (CX), suggesting that they reflected differences in crossing fibers in addition to structural differences in individual fiber segments. FBA also revealed a frontolimbic locus of age-related effects and provided insights into distinct microstructural changes underlying them. Specifically, age differences in fiber density were prominent in fornix, bilateral anterior internal capsule, forceps minor, body of the corpus callosum, and corticospinal tract, while age differences in fiber cross section were largest in cingulum bundle and forceps minor. These results provide novel insights into specific structural differences underlying major WM differences associated with aging.

Fiber laser refractometer operating in the 2 μm spectral region based on the MMI effect

We experimentally demonstrate a fiber laser refractometer based on the use of a multimode interference (MMI) fiber structure. The MMI filter is constructed with an uncladded fiber segment which acts as sensing element to determine the refractive index (RI) of liquid solutions. The laser emission, generated at the 2 μm waveband, is wavelength shifted in linear proportion to the RI of the liquid. The proposed fiber laser refractometer exhibits high sensibility of 937.81 nm/RIU.