Geopolymer concrete (GPC) that is prepared from eco-friendly materials exhibits much more excellent resistance on high temperature compared with ordinary Portland cement concrete. In this study, hybrid fibers containing varying proportions of steel fiber (0.5%-2.0%) and polyvinyl alcohol (PVA) fiber (0.2%-0.8%) were incorporated in GPC. The hybrid fiber-reinforced geopolymer concrete (HFRGC) was subjected to temperatures ranging from 200 °C to 800 °C. The physical properties tests, mechanical properties tests, and microstructure tests of HFRGC were carried out at elevated temperatures, while the environmental impact and cost-effectiveness of HFRGC were assessed. The results of physical properties tests showed that the appearance and mass loss of the HFRGC were mainly affected by temperature, while hybrid fibers had a negligible effect on both. The appearance of HFRGC gradually transformed from gray to brick red with increasing temperature, and the mass loss of HFRGC at 800 °C was as high as 9.4%. The mechanical performance test results indicated that the mechanical strength of HFRGC increased at 200 °C and then decreased with elevated temperature. At 200 °C, the compressive strength, splitting tensile strength, and flexural strength of HFRGC containing 1.5% steel fibers and 0.6% PVA fibers were respectively increased by 13.1%, 14.7%, and 4.4% as compared with ambient conditions. The microstructure test results showed that further geopolymerization at 200 °C promoted the densification of the matrix. The matrix was damaged at higher temperatures violently while the porosity of HFRGC was dramatically increased from 13.35% at 25 °C to 27.83% at 800 °C. Based on the thermal behavior, environmental impact, and cost-effectiveness of HFRGC, a reference for future research in the fire prevention of GPC was provided.
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