Ply thickness hybridization is a common strategy in the layup structure of composite laminates. The rational allocation of thin-ply and thick-ply to effectively improve the performance of composite materials is a shared goal. Compared to standard laminates, ultra-thin-ply laminates have many advantages, including design flexibility, better damage tolerance, and enhanced in-situ strength. However, the risk of fiber fracture triggered by ultra-thin-ply requires cautious application. Effectively reducing the risk of fiber fracture caused by ultra-thin-ply laminates has become a challenge in the field of composite materials. Therefore, this paper proposes a thick/thin/thick gradient structure to balance delamination and fiber fracture. Short-beam bending test results demonstrate that this novel gradient structure exhibits good bending load-bearing performance and damage resistance, achieving the coexistence of multiple damage couplings and effectively enhancing damage tolerance.