Feshbach Molecules Research Articles

Matter-wave interferometers with trapped strongly interacting Feshbach molecules

We implement two types of matter-wave interferometers using trapped Bose-condensed Feshbach molecules, from weak to strong interactions. In each case, we focus on investigating interaction effects and their implications for the performance. In the Ramsey-type interferometer where interference between the two motional quantum states in an optical lattice is observed, interparticle interactions are found to induce energy shifts in the states. Consequently, this results in a reduction of the interferometer frequency and introduces a phase shift during the lattice pulses used for state manipulation. Furthermore, nonuniformity leads to dephasing and collisional effects contribute to the degradation of contrast. In the Michelson-type interferometer, where matter waves are spatially split and recombined in a waveguide, interference is observed in the presence of significant interaction, however coherence degrades with increasing interaction strength. Notably, coherence is also observed in thermal clouds, indicating the white-light nature of the implemented Michelson-type interferometer. Published by the American Physical Society 2024

Single-particle spectroscopies of p-wave and d-wave interacting Bose gases in normal phase

Motivated by experiments with interacting quantum gases across high partial wave resonance, we investigate the thermodynamic properties and single-particle spectra of Bose gases in normal phase for different interaction strengths for both p- and d-wave interactions. The equation of state, contact density, momentum distributions and self-energies of single-particle Green’s functions are obtained in the spirit of ladder diagram approximations. The radio-frequency (RF) spectrum, as an important experimental approach for detecting Feshbach molecules or the interaction effect, is calculated at different temperatures. A reversed temperature dependence on the Bose–Einstein condensation side and Bardeen–Cooper–Schrieffer side is identified for both p- and d-wave interactions. An estimate for the signal of RF spectra under typical experimental conditions is also provided.

Collisional cooling of a Fermi gas with three-body recombination

Evaporative cooling stands as the prevailing method for achieving ultracold temperatures in atomic systems. Current schemes of evaporation selectively remove the hotter atoms near the edge of the trap, as the hotter and colder atoms are distributed in different spatial regions of the trapping potential. However, a long-standing goal is to directly remove the higher momentum atoms, irrespective of their spatial distribution. For this purpose, we demonstrate collisional cooling for a 6Li Fermi gas through inelastic three-body recombination near a narrow Feshbach resonance. Such three-body recombination can induce either heating or cooling effects, and the decay of the quasi-bound Feshbach molecule stirs the hotter atoms away from the trapping potential. When the threshold energy of the Feshbach molecule exceeds the atom’s average kinetic energy of 3/2kBT, the cooling effect becomes more pronounced. Finally, we observe strong temperature dependence in this collisional cooling process, with greater efficiency achieved at lower temperatures.

Long-lived fermionic Feshbach molecules with tunable p -wave interactions

Ultracold fermionic Feshbach molecules are promising candidates for exploring quantum matter with strong $p$-wave interactions, however, their lifetimes were measured to be short. Here, we characterize the $p$-wave collisions of ultracold fermionic $^{23}\mathrm{Na}^{40}\mathrm{K}$ Feshbach molecules for different scattering lengths and temperatures. By increasing the binding energy of the molecules, the two-body loss coefficient reduces by three orders of magnitude leading to a second-long lifetime, 20 times longer than that of ground-state molecules. We exploit the scaling of elastic and inelastic collisions with the scattering length and temperature to identify a regime where the elastic collisions dominate over the inelastic ones allowing the molecular sample to thermalize. Our work provides a benchmark for four-body calculations of molecular collisions and is essential for producing a degenerate Fermi gas of Feshbach molecules.

Ultracold Feshbach molecules in an orbital optical lattice

Quantum gas systems provide a unique experimental platform to study the crossover between Bose–Einstein condensed molecular pairs and Bardeen–Cooper–Schrieffer superfluidity. The few studies in optical lattices have so far focused on the case when only the lowest Bloch band is populated, thus excluding orbital degrees of freedom. Here we demonstrate the preparation of ultracold Feshbach molecules of fermionic atoms in the second Bloch band of an optical square lattice. We cover a wide range of interaction strengths, including the regime of unitarity in the middle of the crossover. Binding energies and band relaxation dynamics are measured by means of a method resembling mass spectrometry. We find that the longest lifetimes arise for strongly interacting Feshbach molecules at the onset of unitarity. In the case of strong confinement in a deep lattice potential, we observe bound dimers also for negative values of the scattering length, extending previous findings for molecules in the lowest band.

A Feshbach resonance in collisions between triplet ground-state molecules

Collisional resonances are important tools that have been used to modify interactions in ultracold gases, for realizing previously unknown Hamiltonians in quantum simulations1, for creating molecules from atomic gases2 and for controlling chemical reactions. So far, such resonances have been observed for atom-atom collisions, atom-molecule collisions3-7 and collisions between Feshbach molecules, which are very weakly bound8-10. Whether such resonances exist for ultracold ground-state molecules has been debated owing to the possibly high density of states and/or rapid decay of the resonant complex11-15. Here we report a very pronounced and narrow (25 mG) Feshbach resonance in collisions between two triplet ground-state NaLi molecules. This molecular Feshbach resonance has two special characteristics. First, the collisional loss rate is enhanced by more than two orders of magnitude above the background loss rate, which is saturated at the p-wave universal value, owing to strong chemical reactivity. Second, the resonance is located at a magnetic field where two open channels become nearly degenerate. This implies that the intermediate complex predominantly decays to the second open channel. We describe the resonant loss feature using a model with coupled modes that is analogous to a Fabry-Pérot cavity. Our observations provide strong evidence for the existence of long-lived coherent intermediate complexes even in systems without reaction barriers and open up the possibility of coherent control of chemical reactions.

Observation of collectivity enhanced magnetoassociation of 6Li in the quantum degenerate regime

The association process of Feshbach molecules is well described by a Landau–Zener (LZ) transition above the Fermi temperature, such that two-body physics dominates the dynamics. However, using 6Li atoms and the associated Feshbach resonance at B r = 834.1 G, we observe an enhancement of the atom–molecule coupling as the fermionic atoms reach degeneracy, demonstrating the importance of many-body coherence not captured by the conventional LZ model. In the experiment, we apply a linear association ramp ranging from adiabatic to non-equilibrium molecule association for various temperatures. We develop a theoretical model that explains the temperature dependence of the atom–molecule coupling. Furthermore, we characterize this dependence experimentally and extract the atom–molecule coupling coefficient as a function of temperature, finding qualitative agreement between our model and experimental results. In addition, we simulate the dynamics of molecular association during a nonlinear field ramp. We find that, in the non-equilibrium regime, molecular association efficiency can be enhanced by sweeping the magnetic field cubically with time. Accurate measurement of the atom–molecule coupling coefficient is important for both theoretical and experimental studies of molecular association and many-body collective dynamics.

Resonance-to-bound transition of He5 in neutron matter and its analogy with heteronuclear Feshbach molecules

We theoretically investigate the fate of a neutron-alpha $p$-wave resonance in dilute neutron matter, which may be encountered in neutron stars and supernova explosions. While $^5$He is known as a resonant state that decays to a neutron and an alpha particle in vacuum, this unstable state turns into a stable bound state in the neutron Fermi sea because the decay process is forbidden by the Pauli-blocking effect of neutrons. Such a resonance-to-bound transition assisted by the Pauli-blocking effect can be realized in cold atomic experiments for a quantum mixture near the heteronuclear Feshbach resonance.

Observation of low-field Feshbach resonances between Dy161 and K40

We report on the observation of Feshbach resonances at low magnetic field strength (below 10 G) in the Fermi-Fermi mixture of $^{161}$Dy and $^{40}$K. We characterize five resonances by measurements of interspecies thermalization rates and molecular binding energies. As a case of particular interest for applications, we consider a resonance near 7.29 G, which combines accurate magnetic tunability and access to the universal regime of interactions with experimental simplicity. We show that lifetimes of a few 100 ms can be achieved for the optically trapped, resonantly interacting mixture. We also demonstrate the hydrodynamic expansion of the mixture in the strongly interacting regime and the formation of DyK Feshbach molecules. Our work opens up new experimental possibilities in view of mass-imbalanced superfluids and related phenomena.

Full optical preparation of an absolute ground-state ultracold CsYb molecule via laser-assisted self-induced Feshbach resonance

We investigate theoretically the formation of an ultracold CsYb molecule in the absolute ground state by full optical control. The laser-assisted self-induced Feshbach resonance takes place when the trap state in the optical lattice is coupled with a rovibrational state of the ground electronic state. The Feshbach molecule is formed in the resonant rovibrational state via an adiabatic population transfer by ramping the frequency of a chirped pulse. Two schemes are designed to prepare the absolute ground-state molecule starting from the Feshbach molecule: a pump–dump scheme controlled by short pulses and a stimulated-Raman-adiabatic-passage (STIRAP) scheme steered by long pulses. The probabilities of converting the Feshbach molecule to the absolute ground state molecule by using the pump–dump and the STIRAP schemes are 16% and 99%, respectively.

Observation of the Hanbury Brown–Twiss effect with ultracold molecules

Measuring the statistical correlations of individual quantum objects provides an excellent way to study complex quantum systems. Ultracold molecules represent a powerful platform for quantum simulation1 and quantum computation2 due to their rich and controllable internal degrees of freedom. However, the detection of correlations between single molecules in an ultracold gas has yet to be demonstrated. Here we observe the Hanbury Brown–Twiss effect—the emergence of bunching correlations of indistinguishable particles collected by separate detectors—in a gas of bosonic 23Na87Rb Feshbach molecules, enabled by the realization of a molecular quantum gas microscope. We detect the characteristic bunching correlations in the density fluctuations of a two-dimensional molecular gas released from and subsequently recaptured in an optical lattice. The quantum gas microscope allows us to extract the positions of individual molecules with single-site resolution. As a result, we obtain a two-molecule interference pattern with high visibility. Although these measured correlations purely arise from the quantum statistics of the molecules, the demonstrated imaging capabilities open the way for site-resolved studies of interacting molecular gases in optical lattices.

Tunable Feshbach Resonances and Their Spectral Signatures in Bilayer Semiconductors.

Feshbach resonances provide an invaluable tool in atomic physics, enabling precise control of interactions and the preparation of complex quantum phases of matter. Here, we theoretically analyze a solid-state analog of a Feshbach resonance in two dimensional semiconductor heterostructures. In the presence of interlayer electron tunneling, the scattering of excitons and electrons occupying different layers can be resonantly enhanced by tuning an applied electric field. The emergence of an interlayer Feshbach molecule modifies the optical excitation spectrum, and can be understood in terms of Fermi polaron formation. We discuss potential implications for the realization of correlated Bose-Fermi mixtures in bilayer semiconductors.

High phase-space density gas of NaCs Feshbach molecules

We report on the creation of ultracold gases of bosonic Feshbach molecules of NaCs. The molecules are associated from overlapping gases of Na and Cs using a Feshbach resonance at 864.12(5) G. We characterize the Feshbach resonance using bound state spectroscopy, in conjunction with a coupled-channel calculation. By varying the temperature and atom numbers of the initial atomic mixtures, we demonstrate the association of NaCs gases over a wide dynamic range of molecule numbers and temperatures, reaching 70 nK for our coldest systems and a phase-space density near 0.1. This is an important stepping-stone for the creation of degenerate gases of strongly dipolar NaCs molecules in their absolute ground state.

Improved characterization of Feshbach resonances and interaction potentials between Na23 and Rb87 atoms

The ultracold mixture of \Na and \Rb atoms has become an important system for investigating physics in Bose-Bose atomic mixtures and for forming ultracold ground-state polar molecules. In this work, we provide an improved characterization of the most commonly used Feshbach resonance near 347.64 G between \Na and \Rb in their absolute ground states. We form Feshbach molecules using this resonance and measure their binding energies by dissociating them via magnetic field modulation. We use the binding energies to refine the singlet and triplet potential energy curves, using coupled-channel bound-state calculations. We then use coupled-channel scattering calculations on the resulting potentials to produce a high-precision mapping between magnetic field and scattering length. We also observe 10 additional $s$-wave Feshbach resonances for \Na and \Rb in different combinations of Zeeman sublevels of the $F = 1$ hyperfine states. Some of the resonances show 2-body inelastic decay due to spin exchange. We compare the resonance properties with coupled-channel scattering calculations that full take account of inelastic properties.

Empirical LiK excited state potentials: connecting short range and near dissociation expansions.

We report on a high-resolution spectroscopic survey of 6Li40K molecules near the 2S + 4P dissociation threshold and produce a fully empirical representation for the B1Π potential by connecting available short- and long-range data. The purpose is to identify a suitable intermediate state for a coherent Raman transfer to the absolute ground state, and the creation of a molecular gas with dipolar interactions. Starting from weakly bound ultracold Feshbach molecules, the transition frequencies to twenty-six vibrational states are determined. Our data are combined with long-range measurements [Ridinger et al., EPL, 2011, 96, 33001], and near-dissociation expansions for the spin-orbit coupled potentials are fitted to extract the van der Waals C6 dispersion coefficients. A suitable vibrational level is identified by resolving its Zeeman structure and by comparing the experimentally attained g-factor to our theoretical prediction. Using mass-scaling of the short-range data for the B1Π [Pashov et al., Chem. Phys. Lett., 1998, 292, 615620] and an updated value for its depth, we model the short- and the long-range data simultaneously and produce a Rydberg-Klein-Rees curve covering the entire range.

Efficient conversion of closed-channel-dominated Feshbach molecules of Na23K40 to their absolute ground state

We demonstrate the transfer of $^{23}\mathrm{Na}^{40}\mathrm{K}$ molecules from a closed-channel-dominated Feshbach-molecule state to the absolute ground state. The Feshbach molecules are initially created from a gas of sodium and potassium atoms via adiabatic ramping over a Feshbach resonance at 78.3 G. The molecules are then transferred to the absolute ground state using stimulated Raman adiabatic passage with an intermediate state in the spin-orbit-coupled complex $|{c}^{3}{\mathrm{\ensuremath{\Sigma}}}^{+},\phantom{\rule{0.16em}{0ex}}v=35,\phantom{\rule{0.16em}{0ex}}J=1\ensuremath{\rangle}\ensuremath{\sim}|{B}^{1}\mathrm{\ensuremath{\Pi}},\phantom{\rule{0.16em}{0ex}}v=12,\phantom{\rule{0.16em}{0ex}}J=1\ensuremath{\rangle}$. Our measurements show that the pump transition dipole moment linearly increases with the closed-channel fraction. Thus, the pump-beam intensity can be two orders of magnitude lower than is necessary with open-channel-dominated Feshbach molecules. We also demonstrate that the phase noise of the Raman lasers can be reduced by filter cavities, significantly improving the transfer efficiency.

Quenched magneto-association of ultracold Feshbach molecules

We study enhanced magneto-association of atoms into weakly-bound molecules near a Feshbach resonance using a quench preparatory stage. In anticipation of experiments with NASA's Cold Atom Laboratory aboard the International Space Station, we assume as a baseline a dual-species ($^{87}$Rb and $^{41}$K) gas in a parameter regime enabled by a microgravity environment. This includes subnanokelvin temperatures and dual-species gases at densities as low as 10$^8$/cm$^3$. Our studies indicate that, in such a regime, traditional magneto-association schemes are inefficient due to the weak coupling between atomic and molecular states at low-densities, thus requiring extremely long magnetic field sweeps. To address this issue we propose a modified scheme where atoms are quenched to unitarity before proceeding with magneto-association. This substantially improves molecular formation, allowing for up to $80\%$ efficiency, and within time-scales much shorter than those associated to atomic and molecular losses. We show that this scheme also applies at higher densities, therefore proving to be of interest to ground-based experiments as well.

High-fidelity formation of deeply bound ultracold molecules via non-Hermitian shortcut to adiabaticity

Stimulated Raman adiabatic passage allows robust transfer between two ends of a three-state quantum system and has been employed to transfer weakly bound Feshbach molecules into their deeply bound rovibrational ground state. However, the efficient transfer remains to be explored. Here we propose a possible alternative route, based on a recently developed non-Hermitian shortcut to adiabaticity method. It is able to realize single-step transfer efficiencies up to 100% even in the presence of a decaying excited level, surpassing all the previous methods. We also prove that our scheme is robust against the external field parameter fluctuations and is expected to be applicable for abundant molecular species.

Random Matrix Theory Analysis of a Temperature-Related Transformation in Statistics of Fano-Feshbach Resonances in Thulium Atoms.

Recently, the transformation from random to chaotic behavior in the statistics of Fano–Feshbach resonances was observed in thulium atoms with rising ensemble temperature. We performed random matrix theory simulations of such spectra and analyzed the resulting statistics in an attempt to understand the mechanism of the transformation. Our simulations show that, when evaluated in terms of the Brody parameter, resonance statistics do not change or change insignificantly when higher temperature resonances are appended to the statistics. In the experiments evaluated, temperature was changed simultaneously with optical dipole trap depth. Thus, simulations included the Stark shift based on the known polarizability of the free atoms and assuming their polarizability remains the same in the bound state. Somewhat surprisingly, we found that, while including the Stark shift does lead to minor statistical changes, it does not change the resonance statistics and, therefore, is not responsible for the experimentally observed statistic transformation. This observation suggests that either our assumption regarding the polarizability of Feshbach molecules is poor or that an additional mechanism changes the statistics and leads to more chaotic statistical behavior.

Detection of NaRb Feshbach molecules by photodissociation

We demonstrate detection of NaRb Feshbach molecules at high magnetic field by combining molecular photodissociation and absorption imaging of the photofragments. The photodissociation process is carried out via a spectroscopically selected hyperfine Zeeman level correlated with the Na ($3P_{3/2}$) + Rb ($5S_{1/2}$) asymptote which, following spontaneous emission and optical pumping, leads to ground-state atoms in a single level with near unity probability. Subsequent to the dissociation, the number of molecules is obtained by detecting the resultant $^{23}$Na and $^{87}$Rb atoms. We have also studied the heating effect caused by the photodissociation process and optimized the detection protocol for extracting the temperature of the molecular cloud. This method enables the $in~situ$ detection of fast time scale collision dynamics between NaRb Feshbach molecules and will be a valuable capability in studying few-body physics involving molecules.