Ferric Minerals Research Articles

A reversed redox gradient in Earth's mantle transition zone

The Earth's mantle hosts a variety of reduced and oxidized phases, including iron-bearing alloys, diamond, and sulfide and carbonate melts. In the upper mantle, increasing pressure favors the stabilization of reduced iron-bearing phases via disproportionation of ferrous iron into ferric and metallic iron. Pressure-driven disproportionation is thought to continue into the transition zone, based on the extrapolation of experiments conducted at lower pressures. To test this hypothesis, we performed high-temperature and high-pressure experiments on basaltic and peridotitic compositions at pressures of 10 to 20 GPa, buffered at different oxygen fugacities. Under these conditions, majoritic garnet is the dominant ferric-iron bearing phase. We analyze our experimental run products for their ferric iron concentrations with EELS and Mössbauer spectroscopy. Contrary to expectations, results show that at iron saturation, ferric iron content of majorite peaks in the upper transition zone and then decreases between 500 and 650 km depth, destabilizing and resorbing reduced phases. This peak can be explained by decreases in the effective volume of ferrous minerals in transition zone assemblages. We also show that natural diamond-hosted majorite inclusions that equilibrated in the sublithospheric mantle grew from variably reduced fluids. These results are consistent with the idea that these diamonds formed during progressive reduction of an originally carbonatitic melt.

Variations in the Near‐Infrared Spectral Properties of Ferrous Mineral Mixtures With Different Relative Abundances

AbstractIn near‐infrared spectral studies, the relationship between the 1‐μm absorption (Band I) center and the band area ratio (BAR, the area ratio of 2–1‐μm absorption features) is useful in compositional and mineralogical analyses of ferrous mineral‐bearing mixtures. Zhang and Cloutis (2020), https://doi.org/10.1029/2020ea001153, investigated various lunar ferrous iron‐bearing rocks and minerals and found that pyroxene‐bearing materials rich in ilmenite (Ilm), plagioclase (Pl), or glass are offset from the lunar olivine‐clinopyroxene‐orthopyroxene (Ol‐Cpx‐Opx) mixing line in the plot of the BAR versus the Band I center. To analyze the variation trends of the spectral properties of these mixtures with different components, this study presents a systematic evaluation of laboratory spectra of terrestrial and synthetic ferrous iron‐bearing mineral mixtures based on published databases. In general, the mixing trends of the Pl‐pyroxene mixtures, the glass‐pyroxene mixtures, and the Ilm‐basalt mixtures are consistent with the findings of Zhang and Cloutis (2020), https://doi.org/10.1029/2020ea001153. Moreover, this study also finds that the BAR of the Pl‐pyroxene mixtures varies nonlinearly with different relative abundances and that the BAR is generally not sensitive to Pl abundances below 60%. For glass‐pyroxene mixtures, the corresponding data points are usually appreciably offset from the Ol‐Cpx‐Opx mixing line at glass abundances above 20%. The BAR of the Ilm‐basalt mixtures increases with increasing Ilm content, mainly due to the weakening of 1‐μm absorption generally being greater than that of 2‐μm absorption.

Mapping hydrocarbon microseepage prospect areas by integrated studies of ASTER processing, geochemistry and geophysical surveys in Assam-Arakan Fold Belt, NE India

Long-term microseepage of hydrocarbons creates a reducing environment in the near-surface soil and sediment cover inducing an array of diagenetic alterations such as bleaching of red beds and increasing abundance of ferrous, clay and carbonate minerals. Spectral enhancements of satellite images have effectively been used in microseepage-induced mineral mapping in arid regions. However, the present study aims to delineate microseepage-induced mineral alteration areas in Assam-Arakan Fold Belt (AAFB) in the north-eastern part of India, dominated by humid climate and heavy precipitation. The study uses an integrated approach consisting of advanced spaceborne thermal emission and reflection radiometer (ASTER) image processing, geochemistry, gravity and magnetic data. ASTER image processing involves specialized band ratios (BRs), false colour composite (FCC) and spectral angle mapping (SAM). Integration of remote sensing, geochemistry, gravity and magnetic anomaly data successfully delineates microseepage prospect areas in the basin. The study would provide important advantages in hydrocarbon exploration strategy in similar basins around the world.

Mechanisms for the dissolved biochar promoted iron dissolution and consequential chromium release

Biochar is widely applied in soil for agricultural and environmental purposes. Soluble fraction of biochar may be released from bulk biochar as dissolved biochar (DBC) after irrigation or rainfall. DBC had been reported to possess high chemical activity in aqueous system, while less attention was paid to the impact of DBC on the soil environmental processes. In this work, the impact of DBC on ferric (hydro) oxides was systematically examined. Our study showed that DBC prepared from rice straw could significantly promote the dissolution of ferric oxides with unstable and metastable crystalline structures, e.g., ferrihydrite under relatively acidic condition. Organic ligand-promoted dissolution was the main mechanism for iron release from ferrihydrite, and the low-molecular-weight DBC component (less than 1000 Da) was the major contributor for this process. Furthermore, the organic carbon content normalized ligand-promoted dissolution capacity for DBC was much higher than common dissolved organic matters. More importantly, DBC could promote the release of Cr from dichromate-adsorbed ferric mineral. Our results suggest that in soils with relatively low pH and high contents of ferric hydroxides, e.g., red soil in southern China, DBC derived from applied biochar could enhance the mobility and bioavailability of iron and other heavy metals. The dissolved metals would play active roles in soil redox cycle and biotic processes. Therefore, it's necessary to evaluate the long-term impact of biochar application on acidic field soils with high iron content.

Efficient goal-oriented mesh refinement in 3-D finite-element modelling adapted for controlled source electromagnetic surveys

SUMMARY We developed a 3-D forward modelling code, which simulates controlled source electromagnetic problems in frequency domain using edge-based finite elements and a total electric field approach. To evaluate electromagnetic data acquired across complex subsurface structures, software performing accurate 3-D modelling is required, especially for incorporation in inversion approaches. Our modelling code aims at finding a good compromise between the necessary solution accuracy at the points of interest and the general problem size by using a goal-oriented mesh refinement strategy designed for models of variable electric conductivity and magnetic permeability. To formulate an improved error estimator suitable for controlled source electromagnetic problems, we developed literature approaches of mesh refinement further targeting three aspects. First, to generate a roughly homogeneously fine mesh discretization around all receiver sites, our new error estimator weights the adjoint source term by the approximate decay of the electric field with increasing distance from the primal source using the expression for a homogeneous half-space. This causes almost no additional computational cost. Second, the error estimator employed in the refinement approach can be optimized for models with pronounced conductivity and magnetic permeability contrasts as often encountered in, for example, mineral prospecting scenarios by optionally including terms that measure the continuity of the normal component of current flow and the tangential component of the magnetic field across interfaces of abutting elements. Third, to avoid amplitude-dependent over-refining of the mesh, we formulate our element-wise error estimators relative to the local amplitude of the electromagnetic field. In this work, we evaluate the implemented adaptive mesh refinement approach and its solution accuracy comparing our solutions for simple 1-D models and a model with 3-D anomalies to semi-analytic 1-D solutions and a second-order finite-element code, respectively. Furthermore, a feasibility study for controlled-source electromagnetic measurements across ferrous mineral deposits is conducted. The numerical experiments demonstrate that our new refinement procedure generates problem-specific finite-element meshes and yields accurate solutions for both simple synthetic models and realistic survey scenarios. Especially for the latter, characteristics of our code, such as the possibility of modelling extended sources as well as including arbitrary receiver distributions and detailed subsurface anomalies, are beneficial.

ANALYSIS OF EXPORT FREIGHT TRANSPORTATION OF UKRAINE IN THE RAILWAY AND SEA CONNECTION

The paper analyzes the export transportation of goods by rail and transshipment in seaports of Ukraine using the methods of mathematical statistics. At present, the export of Ukrainian goods to the countries of the world in terms of traffic exceeds imports several times and is the most dynamically developing international trade sector. Despite the unstable political and economic, and since last year also the sanitary-ecological situation in Ukraine and in the world, exports still have a stable positive dynamics among the total volumes of international traffic. The analysis of export cargo with transshipment in seaports showed that for the sixth year in a row grain cargo ranks first among others in terms of exports. On the railway the key type of cargoes in transportations in recent years also became grain which rates of transportation increase annually. The export component of international trade is also based on ferrous metals, ores, oils, chemical and mineral fertilizers, and mechanical engineering products. The total share of the export component for the EU market as Ukraine's main international trading partner increased from 27.3% in 2008 to 37.3% in 2020. Among the problems hindering the further increase in transshipment in seaports is the still underdeveloped infrastructure, despite the available opportunities to increase technical capacity, and as a result - the limited range of cargo and types of vessels for service, and the use of outdated technologies of ship handling and cargo operations in ports. Ukraine's international trade development projects include attracting investors to port infrastructure through concession tenders in seaports, introduction of private locomotive traction on railways, measures to ensure safety of navigation and maintaining the necessary depths in ports, addressing the shortage of rolling stock on railways, infrastructure development port railway stations. The application of the Fourier analysis technique to detect cyclical fluctuations in transport processes made it possible to obtain a forecast function of grain cargo volumes in certain time intervals, which can be used to develop measures to smooth out uneven traffic flows and reduce uncertainties in transport.

Abiotic dechlorination in the presence of ferrous minerals

Laboratory batch experiments were performed to assess the reduction of trichloroethene (TCE) and oxygen via natural ferrous minerals. TCE reduction under anoxic conditions was measured via the generation of reduced gases, while oxygen reduction via the generation of hydroxyl radicals was measured as a surrogate for potential TCE oxidation. Results showed that TCE reduction under anoxic conditions was observed for ankerite, siderite, and illite, but not for biotite; acetylene was the primary identified dechlorination product. With the exception of biotite, first-order dechlorination rate constants increased with increasing ferrous content of the mineral, with rate constants ranging from 3.1 × 10−8 to 4.8 10−7 L g−1 d−1. Measured reduction potentials (mV vs SHE) ranged from −104 for illite to +84 for biotite. When normalizing measured first-order dechlorination rate constants to the estimated ferrous iron mineral specific surface area (where surface area was based on nitrogen adsorption analysis of the minerals), TCE dechlorination rate constants increased with increasing reduction potentials. Under oxic conditions, hydroxyl radicals were generated with each of the four minerals. However, mineral activity showed no readily apparent correlation to ferrous content or mineral surface area. In terms of TCE and oxygen reduced per mole of ferrous iron initially present in each mineral, illite was the most reactive of the four minerals. Together, these results suggest that several ferrous minerals may contribute to abiotic dechlorination in the natural environment, and (at least for TCE reduction under anoxic conditions) measurement of ferrous mineral content and reduction potential may serve as useful tools for estimating TCE first-order abiotic dechlorination rate constants.

Rapid Attainment of Isotopic Equilibrium after Mercury Reduction by Ferrous Iron Minerals and Isotopic Exchange between Hg(II) and Hg(0)

Rapid Attainment of Isotopic Equilibrium after Mercury Reduction by Ferrous Iron Minerals and Isotopic Exchange between Hg(II) and Hg(0)

Recursos minerais do Brasil

Esta revisão objetiva elaborar diretrizes para aumentar a atratividade de investimentos no setor mineral brasileiro. Fundamenta-se em pesquisa bibliográfica e documental, consultas a diversas órgãos de governo e instituições privadas, visando diagnosticar a situação atual, diante das potencialidades e deficiências. Aborda-se o potencial de depósitos minerais econômicos do país em áreas indígenas e faixas de fronteira, plataforma continental e adjacências e Antártica, focalizando os agrominerais, minerais estratégicos, energéticos e aqueles essenciais à saúde, bem como os usados na construção civil e rochas ornamentais. Mapas indicam áreas mais favoráveis à ocorrência de minerais econômicos, mostrando o grande potencial mineral para ferrosos, não ferrosos, metais preciosos, metais-base, estratégicos e outros. Conclui-se ser necessário, visando ao uso e à exploração sustentáveis: (1) desburocratizar os instrumentos jurídicos para outorga de exploração; (2) agregar valor aos bens minerais; (3) combater a invasão garimpeira; (4) investir na segurança de barragens; (5) redefinir as formas de destinação dos rejeitos.

Improved extraction of acid-insoluble monosulfide minerals by stannous chloride reduction and its application to the separation of mono- and disulfide minerals in the presence of ferric iron

Metal sulfides, which are important indicators of sulfur cycling, are usually divided into two categories according to sulfur chemical valence: (1) monosulfides (S2−) and (2) disulfides (S22−). The two sulfur species are separated and quantified by a sequential-extraction method. Specifically, monosulfides are extracted as acid-volatile sulfide (AVS) using 6 M HCl prior to the extraction of disulfides using acidic CrCl2, which is defined as chromium-reducible sulfur (CRS). However, the conventional AVS procedure does not result in the quantitative extraction of S2− from the acid-insoluble metal monosulfide, copper sulfide (CuS). Consequently, residual sulfur in CuS (CuS-S) may be extracted as CRS resulting in the inaccurate separation of these two sulfur species. In this study, we used stannous chloride (SnCl2) to improve CuS-S recovery in the AVS procedure and permit the separate extraction of sulfur from CuS and pyrite (FeS2), the most abundant disulfide in nature. Our results show that the addition of SnCl2 increased the recovery of CuS-S as AVS from less than 36% to as high as 92% in the absence of pyrite and Fe3+ and 89% in the presence of pyrite and Fe3+. In addition, based on the observed correlation between the concentration of SnCl2 and the dissolution of FeS2, we identified the appropriate concentration of SnCl2 needed to avoid the dissolution of FeS2 in the AVS procedure. SnCl2 also minimized the oxidation of CuS-S by Fe3+ released from ferric minerals during the extraction of AVS. Based on the results of a series of sequential-extraction experiments, we show that an amendment of SnCl2 in the AVS procedure followed by CRS permits the quantitative separation of CuS-S and FeS2-S while also preventing interference by Fe3+. Our method will find application in research concerned with the fate of metals and the biogeochemistry of sulfur in the environment.

Dps-DNA interaction in Marinobacter hydrocarbonoclasticus protein: effect of a single-charge alteration.

DNA-binding proteins from starved cells (Dps) are members of the ferritin family of proteins found in prokaryotes, with hollow rounded cube-like structures, composed of 12 equal subunits. These protein nanocages are bifunctional enzymes that protect the cell from the harmful reaction of iron and peroxide (Fenton reaction), thus preventing DNA damage by oxidative stress. Ferrous ions are oxidized at specific iron-binding sites in the presence of the oxidant and stored in its cavity that can accommodate up to ca. 500 iron atoms. DNA-binding properties of Dps are associated with the N-terminal, positive charge rich, extensions that can promote DNA binding and condensation, apparently by a cooperative binding mechanism. Here, we describe the binding and protection activities of Marinobacter hydrocarbonoclasticus Dps using Electrophoretic Mobility Shift Essays (EMSA), and synchrotron radiation circular dichroism (SRCD) spectroscopy. While no DNA condensation was observed in the tested conditions, it was possible to determine a Dps-DNA complex formation with an apparent dissociation constant of 6.0± 1.0µM and a Hill coefficient of 1.2 ± 0.1. This interaction is suppressed by the inclusion of a single negative charge in the N-terminal region by point mutation. In Dps proteins containing a ferric mineral core (above 96 Fe/protein), DNA binding was impaired. SRCD data clearly showed that no significant modification existed either in secondary structure or protein stability of WT, Q14E variant and core containing proteins. It was, however, interesting to note that, in our experimental conditions, thermal denaturation induced protein aggregation that caused artifacts in thermal denaturation curves, which were dependent on radiation flux and vertical arrangement of the CD cell.

Catalytic activity comparison of natural ferrous minerals in photo-Fenton oxidation for tertiary treatment of dyeing wastewater.

Natural ferrous minerals are readily available and recyclable catalysts in photo-Fenton-like oxidation for wastewater treatment. In this work, typical ferrous oxide and sulfide minerals including magnetite, chalcopyrite, and pyrrhotite were exploited as catalysts in heterogeneous photo-Fenton oxidation for purification of biological effluent of dyeing wastewater. In a wide initial pH range (3.0~7.5), ferrous mineral-based heterogeneous photo-Fenton-like reactions were proven to be effective on the oxidation of recalcitrant pollutants. COD removals achieved 60.57%, 58.83%, and 57.41% using pyrrhotite, chalcopyrite, and magnetite, respectively, as catalyst under ultraviolet irradiation of 220~275 nm at H2O2 concentration of 9.8 mM. The corresponding COD removals were 51.75% and 34.09% with or without ferrous sulfate additions in UV/H2O2 systems. Minerals exhibited excellent stability and reusability with photo-catalytic activity reduction of less than 10% in the reuse of 5 cycles. Dissolved iron concentrations were determined to be 1.86 mg L-1, 4.62 mg L-1, and 7.53 mg L-1 for magnetite, chalcopyrite, and pyrrhotite, respectively, at pH 3 and decreased to zero in neutral pH environment, which were much lower than those required for homogenous Fenton reaction. It was deduced that oxidation of recalcitrant pollutants was mainly catalyzed by Fe(II) on the mineral surface. The more reactive oxygen species such as hydroxyl radicals were resulted from the reaction of surface Fe (II) with H2O2, H2O2 photolysis, and charge separation of minerals under UV irradiation.

Near‐infrared Spectra of Lunar Ferrous Mineral Mixtures

AbstractIron‐bearing minerals are a major component of materials on the lunar surface, and many of them can be distinguished based on the diagnostic absorption features in visible and near‐infrared reflectance spectra. The relationship between the 1 µm absorption (Band I) center and the band area ratio (BAR), defined as the ratio of 2–1 µm absorption areas, provides a sensitive way to estimate the relative abundance of olivine (Ol) and pyroxene. In the plot of the BAR value versus the Band I center, the Ol‐orthopyroxene (Opx) mixing line (derived from terrestrial materials) is strictly applicable only to Ol‐Opx mixtures. Based on published database of laboratory spectra and compositional data for lunar rocks and mineral separates, this study investigated the spectral characteristics of a variety of common Fe2+‐bearing lunar minerals and rocks, such as clinopyroxene (Cpx), ilmenite‐rich basalt, pyroxene‐bearing anorthosite, and glass‐rich impact melt. The lunar Ol‐Cpx‐Opx mixing line for rocks and minerals is determined, which contains less curvature than the Ol‐Opx mixing line, consistent with both the higher Fe2+ content of lunar mafic silicates and the presence of appreciable Cpx. This study suggests that some of the pyroxene‐bearing lunar materials that are rich in ilmenite, glass, or plagioclase can also be distinguished by this method. These results indicate that the plot of the BAR value versus the Band I center is a useful tool for spectral analysis of lunar composition and mineralogy, especially for those having pyroxene‐dominated spectra.

Investigating the souring mechanism in two giant carbonate oil reservoirs, southwestern Iran

In general, a hydrocarbon reservoir with a produced gas stream having more than three parts per million by volume (ppmv) of hydrogen sulfide is considered a sour reservoir. This study aims to present novel ideas on the main souring mechanisms in Bangestan Group, a well-known Mid-Cretaceous hydrocarbon hosting carbonate in Iran, including Ilam, Sarvak, and Kazhdumi formations. Especially, several scenarios are discussed on potential source of H2S in Sarvak Formation and controversial sweetness of the Upper Ilam Reservoir. At first, both of the bacterial or microbial sulfate Reduction (BSR or MSR) and thermochemical sulfate reduction (TSR) mechanisms were rejected based on the reported bottom-hole temperature and lack of anhydrite in rock matrix, respectively. Moreover, the possibility of souring due to migration was disregarded mainly due to the reported constant concentration of H2S over time and among the target oilfield. At the end, thermal decomposition of organic sulfur compounds within the kerogen or crude oil was introduced as the only potential souring mechanism that was further proven through sulfur isotopic analysis. Furthermore, the possibility of H2S absorption in lower horizons of Ilam Formation, and so sweetness of this formation, due to the presence of ferrous minerals was evidenced through detailed petrographic analysis.

СОРБЕНТ-ОРИЕНТИРОВАННЫЙ МЕТОД ДЕТОКСИКАЦИИ ПОЧВ ОТ ТЯЖЕЛЫХ МЕТАЛЛОВ

Abstract. The sorbent-based method is one of the key methods for solving the problem of limiting the mobility of pollutants and the effective implementation of reclamation works. Despite the level of knowledge of the problem, the use of the sorbent-based method is of a fragmented experimental nature. Objective: to study the experience of implementing the sorbent-based method for the adsorption of heavy metals in order to determine the most promising compositions of sorbents for further research work on their improvement. Methods: General scientific methods were used, such as dialectical, historical, analysis, synthesis, comparison, grouping, as well as systematic and empirical approaches. Results: The presence of pluralism of definitions in relation to the term “heavy metals”was revealed. The main criterion for attribution is the relative atomic mass of more than 50 g/mol. An additional criterion is the density, which is approximately equal to or greater than the density of iron (rounded 8 g / cm3). There are other classifications that rely on threshold density or atomic mass values. It is proved that the main role of the immobilization of heavy metals is their transfer to new, more geochemical stable phases by sorption, precipitation, and complex formation processes. The widespread use of the sorbent-based method, which solves the problem of converting heavy metals into a sedentary form and difficult-to-dissolve compounds, has been identified. It is revealed that an important process affecting the mobility of heavy metals in the soil is their fixation with humus. It is established that rocks and minerals have pronounced sorption properties. The most common rocks are clays. They are characterized by a significant sorption capacity and a high specific surface area. In order to increase the sorption properties, the materials can be subjected to various modifications. Peat occupies a special place among effective natural sorbents. The development of technologies for the creation and use of new sorbents made from industrial waste is a promising direction. A method of remediation based on the use of ameliorants–stabilizers of heavy metals has been developed: among the mineral elements of the solid phase, fine clay and ferrous minerals are isolated; compost and manure are often used as organic stabilizers. The possibility of rerational use of industrial waste components as meliorants-stabilizers of heavy metals is investigated, and the sediments of water treatment at filtration stations are of interest in this regard. The remediation potential of water treatment sediments can be enhanced by joint application with natural or modified peat.

Fermentation, methanotrophy and methanogenesis influence sedimentary Fe and As dynamics in As-affected aquifers in Vietnam.

High arsenic (As) concentrations in groundwater are a worldwide problem threatening the health of millions of people. Microbial processes are central in the (trans)formation of the As-bearing ferric and ferrous minerals, and thus regulate dissolved As levels in many aquifers. Mineralogy, microbiology and dissolved As levels can vary sharply within aquifers, making high-resolution measurements particularly valuable in understanding the linkages between them. We conducted a high spatial resolution geomicrobiological study in combination with analysis of sediment chemistry and mineralogy in an alluvial aquifer system affected by geogenic As in the Red River delta in Vietnam. Microbial community analysis revealed a dominance of fermenters, methanogens and methanotrophs whereas sediment mineralogy along a 46m deep core showed a diversity of Fe minerals including poorly crystalline Fe (II/III) and Fe(III) (oxyhydr)oxides such as goethite, hematite, and magnetite, but also the presence of Fe(II)-bearing carbonates and sulfides which likely formed as a result of microbially driven organic carbon (OC) degradation. A potential important role of methane (CH4) as electron donor for reductive Fe mineral (trans)formation was supported by the high abundance of Candidatus Methanoperedens, a known Fe(III)-reducing methanotroph. Overall, these results imply that OC turnover including fermentation, methanogenesis and CH4 oxidation are important mechanisms leading to Fe mineral (trans)formation, dissolution and precipitation, and thus indirectly affecting As mobility by changing the Fe-mineral inventory.

The Effects of Phosphate Gangue on the Leaching of Uranium from Brannerite

Brannerite, UTi2O6, is the most common of the refractory uranium minerals and requires leaching under intense conditions to effectively extract the uranium contained within. Brannerite is often found together with apatite in metasomatic uranium deposits. Apatite and other phosphate gangue minerals can inhibit uranium leaching by generating phosphate ions which interfere with the reactions between acidic ferric sulphate and uranium minerals. As part of a detailed fundamental study on the leaching reaction mechanisms for brannerite, tests under a range of selected leach conditions were carried out with the addition of 10 g/L fluorapatite with the goal of identifying conditions where the negative effects of phosphate are reduced. Leaching was carried out for 5 hours with 0.05 mol/L Fe3+ as Fe2(SO4)3 with 0.25–1.00 mol/L H2SO4 and at temperatures between 25 and 96 °C. A single test was performed with 0.05 mol/L Fe3+ as FeCl3 and 1.00 mol/L HCl. In the sulphate system, the effect of phosphate was weakest at the highest acid concentration (1.00 mol/L H2SO4). In the chloride system, phosphate did not suppress uranium extraction, suggesting that HCl leaching could be a viable alternative for the leaching of high-phosphate refractory uranium ores.

Application of Enhanced Gravity Separators for Fine Particle Processing: An Overview

Beneficiation of low-grade ore is of critical importance in order to meet the growing demand for coal and mineral industries. But, low-grade ores require fine grinding to obtain the desired liberation of valuable minerals. As a result, production of fine particles makes the beneficiation process difficult through conventional gravity separators. Hence, alternative beneficiation techniques are being investigated for upgradation of metal values from low-grade ores. The gravitational force effecting the separation is replaced by the centrifugal force to usher in enhanced gravity separators. The objective of the present paper is to summarize the applicability aspect of enhanced gravity separators for different mineral systems including non-ferrous, precious, ferrous, and industrial minerals. These mineral systems include run off mine ore, secondary products like tailings and plant slags, etc. For this purpose, the design, operational features, types, and separation mechanism of enhanced gravity separators, such as Falcon concentrator, Knelson concentrator, multi-gravity separator (MGS), and Kelsey Jig, are discussed. Based on our review, research scope and future possibilities of enhanced gravity separators are also proposed.

Recycled calcium carbonate is an efficient oxidation agent under deep upper mantle conditions

Observations of high ferric iron content in diamond garnet inclusions and mantle plume melts suggest a highly heterogeneous distribution of ferric iron in the mantle. Recycling of oxidized materials such as carbonates from Earth’s surface by subduction could explain the observed variations. Here we present high-pressure high-temperature multi-anvil experiments to determine the redox reactions between calcium-, magnesium-, or iron-carbonate and ferrous iron-bearing silicate mineral (garnet or fayalite) at conditions representative of subduction zones with intermediate thermal structures. We show that both garnet and fayalite can be oxidized to ferric iron-rich garnets accompanied by reduction of calcium carbonate to form graphite. The ferric iron content in the synthetic garnets increases with increasing pressure, and is correlated with the Ca content in the garnets. We suggest that recycled sedimentary calcium carbonate could influence the evolution of the mantle oxidation state by efficiently increasing the ferric iron content in the deep upper mantle.

Mercury Reduction by Nanoparticulate Vivianite.

Mercury (Hg) is a toxic trace element of global environmental concern which has been increasingly dispersed into the environment since the industrial revolution. In aquatic and terrestrial systems, Hg can be reduced to elemental Hg (Hg0) and escape to the atmosphere or converted to methylmercury (MeHg), a potent neurotoxin that accumulates in food webs. FeII-bearing minerals such as magnetite, green rusts, siderite, and mackinawite are recognized HgII reducers. Another potentially Hg-reducing mineral, which commonly occurs in Fe- and organic/P-rich sediments and soils, is the ferrous iron phosphate mineral vivianite (FeII3(PO4)2·8H2O), but its reaction with HgII has not been studied to date. Here, nanoparticulate vivianite (particle size ∼ 50 nm; FeII content > 98%) was chemically synthesized and characterized by a combination of chemical, spectroscopic, and microscopic analyses. Its ability to reduce HgII was investigated at circumneutral pH under anoxic conditions over a range of FeII/HgII ratios (0.1–1000). For FeII/HgII ratios ≥1, which are representative of natural environments, HgII was very quickly and efficiently reduced to Hg0. The ability of vivianite to reduce HgII was found to be similar to those of carbonate green rust and siderite, two of the most effective Hg-reducing minerals. Our results suggest that vivianite may be involved in abiotic HgII reduction in Fe and organic/P-rich soils and sediments, potentially contributing to Hg evasion while also limiting MeHg formation in these ecosystems.