The stochiometric PrP is a van Vleck paramagnet with a nonmagnetic Λ 1-singlet crystal field ground state. Compounds with defects in the P-sublattice show a spontaneous ferromagnetic moment and a peak in the initial susceptibility at low temperatures. Nonstrochiometric PrP seems to be an induced van Vleck ferromagnetic spin glass with fluctuating crystal field splittings and exchange interactions.
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