Ferroan Calcite Research Articles

Carbonate cementation patterns, potential mass transfer, and implications for reservoir heterogeneity in Eocene tight-oil sandstones, Dongying depression, Bohai Bay Basin, China: Evidence from petrology, geochemistry, and numerical modeling

This paper investigates transport mechanisms involving carbonate cementation in Eocene, tight-oil sandstones in Bohai Bay Basin, China, to determine potential mass transfer between adjacent mudstones and sandstones. Evidence from petrology, geochemistry, and numerical modeling suggests two generations of carbonate cementation: (1) early nonferroan calcite (formed at 28°C–41°C) and dolomite (formed at 45°C–63°C); and (2) later ferroan calcite (formed at 105°C–124°C) and ankerite (formed at 101°C–137°C). Based on a one-dimensional model for a coupled sandstone–mudstone system under low and high temperatures, different distribution patterns of carbonate cements reflect episodic concentration gradients that led to diffusive transport of bicarbonate species during progressive burial. Firstly, extensive precipitation of early nonferroan calcite followed by dolomite at or near mudstone–sandstone contacts resulted from initial concentration gradients related to different compositions in primary mineral assemblages. Secondly, introduction of aqueous CO2 from adjacent mudstones into sandstones resulted in dissolution of early nonferroan carbonates and led to diffusive transport of bicarbonate species. These bicarbonate species were incorporated with Fe2+ and subsequently reprecipitated as ferroan carbonate minerals at distances greater than 2 m (>6.6 ft) from sandstone–mudstone contacts. Therefore, short-distance diffusive transport is inferred to have been the predominant transport mechanism associated with carbonate cementation. Large-scale mass transfer between sandstones and adjacent mudstones occurred in a relatively open geochemical system on a very local scale. Numerical model results show that low porosity zones (2.6%–5.1%) exhibit coherence with high abundances of carbonate cements (13.9%–21.2%). Tightly cemented intervals were created by different generations of carbonate cementation and resulted in destruction of sandstone reservoir porosity.

Formation of zoned ankerite in gravity-flow sandstones in the Linnan Sag, Bohai Bay Basin, eastern China: Evidence of episodic fluid flow revealed from in-situ trace elemental analysis

It has been shown that ankerite in clastic reservoirs can preserve an extended record of diagenesis and thus the fluid flow history in sedimentary basins. Ankerite cements with distinct zoning textures are well developed in gravity-flow sandstones associated with magmatic intrusions in the Linnan Sag, Eastern China. This example offering a rare opportunity to investigate the history of complex diagenetic fluid flow events in a lacustrine rift basin. An integrated study including thin section petrography, fluid inclusion micro-thermometry, carbon and oxygen isotope, SEM-EDS, XRD, CL, BSE-EPMA, LA-ICP-MS analyses was undertaken. The aim is to resolve the mineralogical, geochemical and isotopic composition of the sandstone and constitutional minerals. The sandstones are mainly of lithic arkoses (Q43F34L23), with an average carbonate cements of approximately 8.2 wt %. The carbonate cements are dominated by zoned ankerite appearing as rhombohedral and poikilotopic blocky crystals. Calcite, ferroan calcite, dolomite and siderite cements are also present. Non-carbonate cements including barite, authigenic clay minerals, and quartz overgrowth are common in the sandstone. The δ13 C values of ferroan calcite range from −4.2‰ to +1.2‰ PDB. Ferroan calcite was re-precipitated at a temperature of 93.1 °C at the expense of the dissolution of eodiagenesis carbonate cement in the sandstone. Ankerite was precipitated at temperature ranges from 107.8 to 140.9 °C, accompanied with the formation of pore-filling barite. The δ13C values of ankerite range from −1.8‰ to +1.1‰, and δ18O values range from −14.8‰ to −10.5‰, indicating an involvement of hydrothermal fluids in the formation of the zoned ankerite. The hydrothermal fluids were probably related to the mafic magmatic activities and migrated into the sandstones along faults. These fluids are rich in iron and magnesium, and also contains abundant inorganic carbon dioxide and sulphate, episodic charging into the reservoir. The abundances of most of the elements, including magnesium, iron, REEs and trace elements in the zoned ankerite consistently decrease away from the magma intrusion centres. We therefore conclude that multiple magmatic activities were primarily responsible for the zoned ankerite precipitation in the research area. The intimate relationship between magmatic activity and carbonate cementation in sandstone reservoirs documented in this paper may have significant implications for studying fluid flow in lacustrine rift basins.

Decimeter-scale mapping of carbonate-controlled trace element distribution in Neoarchean cuspate stromatolites

Ancient stromatolites can provide key insights into the early evolution of life on Earth. Neoarchean fenestrate stromatolites from the ∼2520 Ma Upper Nauga Formation (Transvaal Supergroup, South Africa) preserve cuspate morphologies. They possess clearly delineated support and drape structures interpreted as dolomitized microbial mat material. Petrographic observations show that the biogenic structures are composed of planar-s to non-planar ferroan dolomite, encased in ferroan calcite, including herringbone calcite textures. The cuspate stromatolites were analyzed using Synchrotron Rapid Scanning X-Ray Fluorescence (SRS-XRF) and more conventional techniques to determine: (i) whether element distributions could be distinguished in ancient stromatolites at both cm to dm scales, (ii) whether element distributions show variation between biogenic and abiogenic textures, and (iii) the sample’s paragenesis. The distributions of Ca, Fe, Mn, Pb, Cu, As, Br, Al, Si, P, and S directly correspond to dolomitized stromatolitic structures and show trace element distributions are principally controlled by calcite and dolomite occurrence. Dolomite formation was mainly driven by seawater-derived fluids given the high concentrations of Fe and retention of marine shale-normalized rare earth element and yttrium (REY SN ) patterns, however the spatial association of dolomite to stromatolite structures may reflect microbially-influenced mineral nucleation. Given the complexity of this sample’s paragenetic evolution, trace metal distributions cannot be conclusively tied to specific metabolic pathways, bioaccumulation or passive binding, however, the results show SRS-XRF can be used for quantifiable, spatial, in-situ investigation of ancient microbialites.

Origin of spherulitic and cone-in-cone concretions in Cambro-Ordovician black shales, St Lawrence Estuary, Quebec, Canada

AbstractSpherulitic concretions are very rare among carbonate concretions that generally consist of micritic carbonate. The occurrence of spherulitic concretions in Cambro-Ordovician black shales of unknown stratigraphic age on a mid-channel island in the St Lawrence Estuary in Quebec is a new example in addition to only three hitherto reported occurrences of spherulitic carbonate concretions. Their origin is still poorly understood. These concretions occur in close association with, and show various transitions to, cone-in-cone structure. The spherules, measuring 0.5 to 12 mm in diameter, consist of intergrown fine fibres of ferroan calcite and quartzine, pointing to the formation of the concretions below the sulfate-reduction zone. A phenomenological theory of spherulitic crystallization relates the thickness δ of an impurity-rich layer in front of impurity-rejecting growing crystals to the impurity-diffusion coefficient D and the growth velocity G of the crystal by δ = D/G. In spherulite-forming environments, extremely small values of δ (in the order of <10−4 cm) in conjunction with cellulation lead to spherulitic fibre growth. The theory of spherulitic crystallization is here applied to sedimentary deposits for the first time. The intimate association of calcite and quartzine in the concretions requires a chemical change from alkaline to acidic conditions, which occurs below the carbonate-reduction zone owing to the dissolution of sponge spicules or radiolarians. The transition from spherulite to the silica-free cone-in-cone structure occurs when the silica reservoir that acted as an impurity is exhausted in the crystallization process.

Cements, Waters, and Scales: An Integrated Study of the Szeged Geothermal Systems (SE Hungary) to Characterize Natural Environmental Conditions of the Thermal Aquifer

The study area, Pannonian Basin (Central Europe), is characterized by high heat flow and presence of low-enthalpy geothermal waters. In the Szeged Geothermal Systems (Hungary), having Miocene to Pliocene sandstone aquifers with dominantly Na–HCO3-type thermal water, unwanted carbonate scaling was observed. An integrated approach consisting of host rock and scale mineralogical and petrographic analyses as well as water chemistry led to a better understanding of the characteristic natural (geogenic) environmental conditions of the geothermal aquifers and to highlight their technical importance. Analyses of the reservoir sandstones showed that they are mineralogically immature mixed carbonate-siliciclastic rocks with significant macroporosity. Detrital carbonate grains such as dolomite and limestone fragments appear as important framework components (up to ~20–25%). During water–rock interactions, they could serve as a potential source of the calcium and bicarbonate ions, contributing to the elevated scaling potential. Therefore, this sandstone aquifer cannot be considered as a conventional siliciclastic reservoir. In mudrocks, a significant amount of organic matter also occurs, triggering CO2producing reactions. Correspondingly, framboidal pyrite and ferroan calcite are the main cement minerals in all of the studied sandstone samples which can suggest that calcite saturation state of the thermal fluid is close to equilibrium in oxygen-depleted pore water. Analysis of the dominant carbonate crystals in the scale can suggest that growth of the feather dendrites of low-Mg calcite was probably driven by rapid CO2degassing of CO2-rich thermal water under far-from-equilibrium conditions. Based on hydrogeochemical data and related indices for scaling and corrosion ability, the produced bicarbonate-rich (up to 3180 mg/l) thermal water has a significant potential for carbonate scaling which supports the aforementioned statement. Taking into consideration our present knowledge of geological setting of the studied geothermal systems, temporal changes in chemical composition and temperature of the thermal water during the heating period can indicate upwelling fluids from a deep aquifer. Regarding the pre-Neogene basement, hydrologic contact with a Triassic carbonate aquifer might be reflected in the observed chemical features such as decreased total dissolved solids and increased bicarbonate content with high scale-forming ability. The proposed upflow of basin-derived water could be channeled by Neogene to Quaternary fault zones, including compaction effects creating fault systems above the elevated basement high. The results may help to understand the cause of the high carbonate scale precipitation rates in geothermal systems tapping sandstone aquifers.

Characteristics and origin of the major authigenic minerals and their impacts on reservoir quality in the Permian Wutonggou Formation of Fukang Sag, Junggar Basin, western China

Abstract This research is focused on the characteristics and origin of major authigenic minerals and the influences on the reservoir quality of the Permian Wutonggou Formation sandstones in the eastern slope of Fukang Sag, Junggar Basin, Western China. Authigenic cements were observed and described from thin sections, scanning electron microscopy, fluorescence, and cathodoluminescence. The elemental concentrations of the authigenic minerals were measured by electron probe microanalysis. Additional characterizations were obtained from O and C stable isotope ratios and from the homogenization temperature of aqueous fluid inclusions. The results show that the sandstones in the Wutonggou Formation are dominated by volcanic lithic fragments. Carbonates and laumontites are the major authigenic minerals in the study area. Authigenic quartz and kaolinite can also be observed. Two types of carbonate cements are identified. The first type is calcite with yellow fluorescent hydrocarbon inclusions. The carbon and oxygen isotopes in the calcites are highly C-depleted and O-depleted. The homogenization temperatures of the aqueous fluid inclusions in the calcite cements are higher than the highest paleogeotemperatures during the burial history. Combined with the presence of authigenic fibrous illites and the illitization of kaolinites, it is determined that the precipitation of the calcites is related to the upwelling of deep fluids and was impacted by the CO 2 from the thermal decarboxylation of organic matters during the middle-late Jurassic. The second type is ferroan calcite with blue fluorescent hydrocarbon inclusions and higher contents of Fe, Mn, Cr, and Mg than in the calcites. The ferroan calcites in the Beisantai uplift are rich in 13 C (δ 13 C (V-PDB) values are +22.10‰ and +22.16‰). The precipitation of these ferroan calcites was impacted by the CO 2 from crude oil biodegradation after the late Jurassic. Two types of laumontites are identified. The first type is partially dissolved and is characterized by a high Ca/Na ratio and low Fe contents. The second type is hardly dissolved, has hydrocarbon inclusions with yellow and blue fluorescence, and is characterized by a low Ca/Na ratio and high Fe contents. The first type of laumontite was precipitated prior to hydrocarbon charging and the second type was formed after hydrocarbon charging and meteoric water leaching. The hydration of the volcanic debris provided the source materials for both types of laumontite. The authigenic quartz and kaolinite were formed by the alteration of feldspars, laumontites, and volcanic materials. The evolution of the reservoir properties was impacted by various degrees of cementation and dissolution; as a result, the reservoir quality in the Beisantai uplift was better than in the Shaqiu area.

Diagenesis and reservoir quality of the Upper Triassic Chang 6 member in Jingan Oilfield, Ordos Basin, China

Abstract The Chang 6 reservoir of Yanchang formation in Jingan oilfield has relatively poor quality: the porosity ranges mainly from 8 to 14%, and permeability ranges from 0.018 to 10.48 md, with a mean of 1.10 md, categorized as low porosity and low permeability reservoir type with strong heterogeneity. Petrographic and geochemical analyses of various components in these sandstones have provided clues of diagenesis. The sandstones at the early stage of diagenesis are characterized by non-ferroan calcite cementation, grain-coating, pore-lining clay minerals, and initial dissolution of detrital grains. Authigenic quartz, pore-filling and grain-replacive laumontites, albitized detrital plagioclase, authigenic K-feldspar, illite and late ferroan calcite cement dominate the late diagenesis. Reservoir quality is influenced by products of late diagenesis stage, the cement (calcite, albite, quartz, illite, and laumontite) occluded primary and secondary porosity. The organic acidic fluid derived from organic matter in the source rocks during the late diagenesis, which results in the dissolution of detrital plagioclase and laumontite cement and was the main reason for the enhancement of reservoir-quality. As a result of that, the residual primary pore and dissolution pore comprised the main accumulation space for oil and gas, and thus become important targets for hydrocarbon exploration.

Diagenetic evolution and chemical changes of deep-water mudstones of Shahejie Formation in the Dongying Sag, Jiyang Depression, Eastern China

Abstract The diagenetic evolution and chemical changes of mudstones have a significant influence on the reservoir quality of the mudstones and their interbedded sandstones. To investigate, a variety of methods were applied to the mudstones in the middle of the third member of the Shahejie Formation (Es3z), which were formed in a lacustrine basin during 43.7–38.2 Ma. Optical microscopy and XRD analysis show that the mudstones are dominated by clay minerals (56.8%) followed by carbonate (18.2%), quartz (14.9%), feldspar (8.4%), pyrite (0.9%), anhydrite (0.8%), and total organic carbon (TOC: 2.4%). Cementation and replacement are the main diagenetic events in the mudstone of Es3z. Carbonates and clay minerals are the most common cements, but occasionally authigenic pyrite, albite, and quartz are also present. At the eogenetic stage, the diagenetic events comprised precipitation of pyrite, siderite, dolomite, and calcite besides transformation of K-feldspar into kaolinite. During the mesogenetic stage, the main diagenetic events included precipitation of fracture-filling calcite, ferroan calcite, ankerite, microcrystalline quartz, quartz overgrowth, and transformation of K-feldspar into illite and albite. The limited variation of the Nb/Ta and Zr/Hf ratios and the almost identical distribution pattern of the REE and trace elements indicate that the detrital material in the mudstones was sourced by a common provenance of felsic igneous rocks. The CIA values of Es3z mudstones vary from 50.59 to 65.05 and the PIA values vary from 50.86 to 75.58, which confirm a low-intensity weathering of the source area. Thus, the variation in the bulk-rock geochemical composition of the mudstones may not be primary, but instead a result of mass transfer with the interbedded sandstones during diagenesis. Changes ratios between aim elements (Al, Si, Ca and K) and immobile elements with burial depth in combination with mass balance calculation indicate that aluminum and silicon were retained by the precipitation of authigenic minerals in the mudstone. The mudstones have received progressively more potassium with increasing depths, whereas calcium has been expelled. The reservoir quality of the Es3z sandstones has mainly been affected by the diagenetically induced decrease in the carbonate content in the mudstones causing carbonate cementation in the sandstones.

Genesis and distribution pattern of carbonate cements in lacustrine deep-water gravity-flow sandstone reservoirs in the third member of the Shahejie Formation in the Dongying Sag, Jiyang Depression, Eastern China

Abstract The lacustrine deep-water gravity-flow sandstone reservoirs in the third member of the Shahejie Formation are the main exploration target for hydrocarbons in the Dongying Sag, Eastern China. Carbonate cementation is responsible for much of the porosity and permeability reduction in the lacustrine deep-water gravity-flow sandstone reservoirs. The sandstones are mainly lithic arkose with an average framework composition of Q43F33L24. The carbonate cements are dominated by calcite, ferroan calcite, ankerite and a small amount of dolomite. The calcite and ferroan calcite are mainly poikilotopic blocky crystals, while the dolomite and ankerite are mainly euhedral rhombohedra crystals filling intergranular and intragranular pores. The relatively positive δ13C values (−2‰ to +3.9‰) of the carbonate cements in the sandstone reflect a mainly inorganically sourced carbon. From 32 Ma to 25 Ma, the pore water was rich in bicarbonate and Ca2+ due to carbonate dissolution in mudstone, and which were transported with the pore water from mudstone to sandstone via advection and precipitated calcite cementation in thinly bedded sandstones and some high permeability zones in the middle of medium-to-thick sandstone beds. From 12 Ma to present, abundant Ca2+, Fe3+, Fe2+, Mg2+ and bicarbonate had been transported from mudstone to sandstone via diffusion to form tight ferroan calcite cementation in the upper and lower parts of the medium-to-thick bedded sandstones. Ankerite is mainly distributed in the reservoirs associated with oil migration or charge, because change of Fe3+ to Fe2+ from oil charge may supply sufficient Fe2+ for ankerite precipitation. The center of sandstone beds (>0.6 m) is with potential of high-quality reservoirs in the research area. Carbonate cementation appears to be an important factor that controls the accumulation of oil in deep-water gravity-flow sandstone reservoirs in the study area.

Diagenetic evolution and its implication for reservoir quality: a case study from the Eocene Es4 interval, Dongying Depression, Bohai Bay Basin, China

Petrographic analysis combined with thin section observation, fluid inclusions, burial history analysis, and core porosity and permeability, were used to determine diagenetic evolution and its effect on reservoir-quality of beach-bar sandstone reservoirs of Eocene Es4s interval in the Boxing sag, Bohai Bay Basin. Diagenesis is mainly characterized by strong compaction, undercompaction, cementation of carbonate, quartz, pyrite and clay minerals, dissolution of detrital grains and carbonate cements, lime-mud matrix recrystallization and hydrocarbon filling. Paragenetic sequence is determined as “early compaction / precipitation of calcite, dolomite and framboidal pyrite → dissolution of feldspar grains and early-formed carbonate cements/precipitation of quartz → hydrocarbon filling → precipitation of ferroan calcite and ankerite/lime-mud matrix recrystallization → dissolution of ferroan carbonate cements”. In the same diagenetic environment, diagenetic processes for different lithofacies significantly varied and subsequently resulted in great heterogeneity for reservoir quality during progressive burial. Lithofacies for both bar body and beach edge subfacies which are far from sandstone-mudstone contacts, are well sorted and have a strong ability to resist compaction. Abundant primary and secondary porosities are well developed because of modifications by acidic dissolution and hydrocarbon filling. The present physical properties are relatively well and numerous oil beds are developed through shallow to deep burial depth. Lithofacies for both bar body and beach edge subfacies which are adjacent to sandstone-mudstone contacts, are typically characterized by extensive cementation of calcite and dolomite. The present physical properties are bad and dry beds are extensively developed for sandstone reservoirs in both bar body and beach edge subfacies which are adjacent to sandstone-mudstone contacts. Lithofacies for both bar edge and beach mat subfacies were deposited in weak hydrodynamic conditions with high contents of limemud matrix. The reservoir porosity decreases continually due to strong compaction and weak dissolution. The present physical properties are extremely poor and dry beds are commonly developed through shallow to deep burial except for minor oil beds developed in the shallow burial.

Diagenetic F-rich ferroan calcite and zircon in the offshore Scotian Basin, eastern Canada: Significance for understanding thermal evolution of the basin

In the Scotian Basin, offshore eastern Canada, an unusual combination of high heat flow in the Cretaceous and the abundance of halite has resulted in unusual diagenetic minerals such as sphalerite. The Newburn H-23 well is the most distal well in the basin with good core samples and has two previously unknown diagenetic mineral occurrences: fluorine-rich ferroan calcite and diagenetic zircon. This study uses SEM backscattered electron images and EDS analyses, EMP WDS mineral analyses and Raman spectroscopy to determine mineral chemistry and textures to investigate the diagenetic and thermal significance of these minerals. Late diagenetic Fe-calcite contains 1–2.5 wt% fluorine, mostly from adsorption, but rarely as small fluorite crystals. Fluoride is also adsorbed on the surfaces of some framework minerals and chlorite. Fluoride was transported in highly saline formation brines derived from the Argo salt Formation. Zircon grains, 20–40 μm in size, have crystal outlines that are straight adjacent to pores, partially lobate filling porosity, and cross cutting other grains: these may be diagenetic. Some zoned detrital zircon grains show 1–3 μm wide diagenetic outgrowths. Neoformation of diagenetic zircon requires temperatures of >250 °C. Transport of zirconium is favored by ligands in low-pH solution, principally fluoride and phosphate anions, with zirconium mobilized during the alteration of metamict detrital zircon under low-grade metamorphic conditions. The presence of diagenetic sphalerite and the documented mid-Cretaceous thermal event in the Scotian Basin indicate conditions that could have been suitable for the formation of diagenetic zircon in this well. Suitable geological conditions for such diagenetic formation of zircon will be found in a subsiding rift basin with early evaporites that are affected by a subsequent phase of volcanism due to new rifting or subduction.

Geology, geochemistry and geochronology of the Songwe Hill carbonatite, Malawi

Songwe Hill, Malawi, is one of the least studied carbonatites but has now become particularly important as it hosts a relatively large rare earth deposit. The results of new mapping, petrography, geochemistry and geochronology indicate that the 0.8 km diameter Songwe Hill is distinct from the other Chilwa Alkaline Province carbonatites in that it intruded the side of the much larger (4 × 6 km) and slightly older (134.6 ± 4.4 Ma) Mauze nepheline syenite and then evolved through three different carbonatite compositions (C1–C3). Early C1 carbonatite is scarce and is composed of medium–coarse-grained calcite carbonatite containing zircons with a U–Pb age of 132.9 ± 6.7 Ma. It is similar to magmatic carbonatite in other carbonatite complexes at Chilwa Island and Tundulu in the Chilwa Alkaline Province and others worldwide. The fine-grained calcite carbonatite (C2) is the most abundant stage at Songwe Hill, followed by a more REE- and Sr-rich ferroan calcite carbonatite (C3). Both stages C2 and C3 display evidence of extensive (carbo)-hydrothermal overprinting that has produced apatite enriched in HREE (<2000 ppm Y) and, in C3, synchysite-(Ce). The final stages comprise HREE-rich apatite fluorite veins and Mn-Fe-rich veins. Widespread brecciation and incorporation of fenite into carbonatite, brittle fracturing, rounded clasts and a fenite carapace at the top of the hill indicate a shallow level of emplacement into the crust. This shallow intrusion level acted as a reservoir for multiple stages of carbonatite-derived fluid and HREE-enriched apatite mineralisation as well as LREE-enriched synchysite-(Ce). The close proximity and similar age of the large Mauze nepheline syenite suggests it may have acted as a heat source driving a hydrothermal system that has differentiated Songwe Hill from other Chilwa carbonatites.

Origins of authigenic minerals and their impacts on reservoir quality of tight sandstones: Upper Triassic Chang-7 Member, Yanchang Formation, Ordos Basin, China

ABSTRACTReservoir quality is critical for sweet-spot evaluation in tight sandstone plays, but few studies have focused on the origin of authigenic minerals in tight sandstones and their impact on reservoir quality. This study integrates petrographic analysis, carbon and oxygen isotopic data and mercury injection capillary pressure data of the Upper Triassic Chang-7 tight sand reservoir samples in the Ordos Basin, China to understand the origin of authigenic minerals and the impact of authigenic minerals on reservoir quality. Carbonate minerals, including calcite, ferroan calcite and dolomite, and kaolinite, are the major authigenic minerals in the Chang-7 sandstone. They were derived from the chemical diagenetic alteration of detrital feldspar and biotite, with the involvement of ions that are believed to be primarily from the connate water in interstitial pore space of the interbedded mudstones. Meteoric water and organic fluids from hydrocarbon generation may also have been involved in the alteration processes of the minerals in the Chang-7 tight sandstone. The origin of kaolinite indicates that the porosity was increased by dissolution of detrital grains, offsetting the porosity loss from burial compaction. Authigenic minerals appear to have a weak correlation with pore structure, suggesting that the pore structure of the Chang-7 tight sandstone is not only controlled by major authigenic minerals but also affected by other geological factors.

Origin and Distribution of Carbonate Cement in Tight Sandstones: The Upper Triassic Yanchang Formation Chang 8 Oil Layer in West Ordos Basin, China

Two generations of carbonate cement as Type I (microcrystalline calcite and dolomite) and Type II (mainly Fe-calcite and Fe-dolomite) are recognized in Chang 8 sandstones, Ordos basin. Carbonate cement in Chang 8 sandstones is closely related to the dissolved carbon from thermal maturation of organic matters. Carbonate cement in the loosely packed framework grains precipitated shortly after deposition, and late-stage ferroan calcite and ferroan dolomite formed with progressive burial. The early diagenetic carbonate cement is partially to completely replaced by late-stage ferroan calcite and ferroan dolomite. Carbonate cement is much more commonly observed in sand bodies adjacent to Chang 7 source rocks. With increasing distance from the Chang 7 oil layers, the carbonate cement content gradually decreases. However, some tight carbonate cemented zones also occur at the sandstone-mudstone interfaces. Dissolution of Ca-feldspars by organic acids-rich fluids, together with clay mineral transformations such as illitization of smectite, would provide Ca2+ and Mg2+ ions for carbonate cementation. Organic acids and CO2 rich fluids would charge into the reservoirs with the hydrocarbons, and when the CO2 and acids were buffered by the framework grain dissolution, carbonate cement would precipitate with a decrease in CO2 concentration.

The first evidence of Permian–Triassic shallow-marine transitional deposits in northern Croatia: Samoborsko Gorje Hills

Permian–Triassic successions occur throughout the world, but well-exposed transitional sequences are relatively rare. In Croatia, only two localities with continuous transition from Permian to Triassic have been described previously from its southern parts, but in northern Croatia the Permian–Triassic boundary remains undocumented. A succession of Permian and Triassic sub- to supratidal deposits is exposed in the Samoborsko Gorje Hills in N Croatia, on the northern margin of the Dinarides towards the Pannonian Basin. Oldest part of the sequence is composed of dolomudstones to dolopackstones containing an Upper Permian (Lopingian) biota: calcareous algae (gymnocodiaceans and dasycladales), gastropods and smaller foraminiferans (e.g. Hemigordius sp., Glomospira sp., Earlandia sp. and Ammodiscus kalhori). The middle part of the succession is characterized by the ‘Transitional breccia’—dolomitic breccia and microbreccia, with ferroan calcite cement, probably deposited during the Late Permian regression. ‘Transitional breccia’ deposits contain only disaster forms (Ammodiscus kalhori and Earlandia sp.) which are often considered as survivors, but can generally be found in both Permian and Triassic deposits, confirming environmental crises in the shallow-marine environments. Gradual recovery of the biota can be traced in the upper part of the succession, with dolomudstones to dolowackestones containing peloids and sparse, smaller foraminiferans. The presence of foraminiferan Meandrospira pusilla, which is identified for the first time in the studied area, indicates a Late Olenekian age for the youngest part of the studied deposits. This study demonstrates that the transition from Permian to Triassic can be indicated even in stressful and/or tectonized areas lacking conodonts, and contributes to the palaeogeographical reconstructions of this part of the Paleo-Tethys.

Paleosol Diagenesis and Its Deep-Time Paleoenvironmental Implications, Pennsylvanian–Permian Lodève Basin, France

Abstract Sedimentological, petrographic, and geochemical investigations of the Permo-Carboniferous Lodeve Basin, France show complete diagenetic resetting of soil-formed minerals. Carbonate cements include diagenetic end-member phreatic-zone and burial cements in nodules and veins. Cement stratigraphy reveals multiple generations, including low-Mg calcite, ferroan calcite, dolomite, barite, and silica cements that record the burial and exhumation history of the basin. Stable-isotope analysis of calcite nodules yields uncorrected δ13C values of −5.0‰ and −0.7‰, and between 0.4‰ and −3.8‰ for calcite veins; corresponding δ18O values of the calcite nodules are −3.6‰ and 0.2‰, while veins are between −3.1‰ and −11.0‰. Dolomite cements have uncorrected δ13C values of −0.2‰ to −6.7‰ and δ18O values of 2.0‰ to −6.1‰. These values represent micritic calcite as well as mimetic dolomite, dolomite rhombs, microspar calcite, sparry calcite, and ferroan calcite. Isotopic values record multiple fluids of increasing temperature that flowed through the basin from the Triassic through Cenozoic, and are affiliated with the burial of the basin as well as lithospheric thinning during Pangean breakup. Following careful screening of groundwater nodules, veins and paleosols (n = 46), no carbonate retains its primary pedogenic signal or utility for use in quantitative paleoclimate reconstructions. These data document the importance of careful petrographic and geochemical screening for diagenetic alteration of paleosol carbonates before quantitative paleoclimate proxies are applied.

Deep reservoir quality prediction using diagenesis: a case study from Zhanjiaduo Oilfield of Subei Basin, China

Diagenesis study is used to predict deep reservoir quality in Zhanjiaduo Oilfield of Subei Basin. Based on the thin section, scanning electron microscopy, X-ray diffraction, and burial history analysis, it is found that with a significant burial depth, the third Member of Funing Formation shows good reservoir potential, which is believed to be the result of weak compaction. Abnormally high pressures caused by undercompaction lead to the development of intergranular pores in sandstones. Quartz overgrowth and ferroan calcite cementation are inhibited due to relatively high contents of clay, the premature sealing of the diagenesis system, and a short high-temperature experience. Therefore, the reservoir quality is dominated by clay cementation, and compaction is the most important factor to control reservoir physical properties. Under the same conditions of abnormally high pressures, the compaction loss rate of bar sandstones is lower than that of beach sandstones, so the bar sandstones in a high-pressure area are likely to become reservoirs with good quality. Studies over abnormally high pressure, sedimentary facies, and diagenesis reveal that the high-quality bar sandstones exist in the deep sag area. This finding has been validated by recent exploration wells which obtained high industrial oil flow.

Origin of carbonate cements with implications for petroleum reservoir in Eocene sandstones, northern Dongying depression, Bohai Bay basin, China

The Eocene Es4s interval is an important petroleum reservoir of sublacustrine fan dominated at the depths of 2500–4000 m in Dongying depression, Bohai Bay basin. Based on core observation, three types of carbonate-cemented beds have been identified and commonly contain ferroan calcite and ankerite predominantly and less calcite and dolomite. Precipitation temperatures range from 34.6 to 72.8℃ for calcite and dolomite cements, and from 110 to 153℃ for ferroan calcite and ankerite cements. The high δ13CPDB values (−0.65 to +5.59‰) for calcite and dolomite suggest that dissolved inorganic carbon, derived from methanogenic fermentation of organic matter in adjacent mudstones. The low δ13CPDB values (+1.04 to +3.29‰) for ferroan calcite and ankerite probably indicate a mixture of carbon derived from decarboxylation of organic acid as well as from the dissolution of early formed carbonate cements. High plug porosity is mainly developed at the central section of sandstones vertically and the porosity decreases sharply toward the top and base of the sandstones due to extensively carbonate-cemented beds. The carbonate-cemented beds varies from 0.02 to 0.5 m in thickness and might extend from tens to hundreds meters laterally. It could be served as fluid-flow barriers and seals for petroleum, and result in reservoir deterioration and significant heterogeneity.

Diagenesis and Diagenetic Evolution of Deltaic and Neritic Gas‐Bearing Sandstones in the Lower Mingyuefeng Formation of Paleogene, Lishui Sag, East China Sea Shelf Basin: Implications for Depositional Environments and Sequence Stratigraphy Controls

AbstractGas‐bearing deposits in the Lower Mingyuefeng Formation of Paleogene, Lishui Sag, East China Sea Shelf Basin consist of shoreface sandstones of the highstand systems tract (HST) and transgressive systems tract (TST), and deltaic sandstones of the lowstand systems tract (LST) and falling stage systems tract (FSST). Detailed petrographic observations suggest that the diagenetic features and related evolution of these deposits cannot be simply characterized and demonstrated in the depth domain. However, the occurrence of diagenetic minerals systematically depends on the studied interval within the HST, TST, LST, and FSST; therefore, diagenesis in this region can be better constrained when studied in the context of the depositional environments and sequence stratigraphic framework. The eogenetic processes in such settings include: (1) microcrystalline siderite precipitated as concretions in almost all environments and systems tracts, which inhibited further mechanical compaction; (2) grain dissolution and kaolinitization occurred in shoreface HST sandstones and deltaic LST and FSST sandstones; (3) glaucony was locally observed, which did not clearly reflect the controls of facies or sequence stratigraphy; and (4) cementation by pyrite aggregates occurred in the shoreface HST sandstones and deltaic LST sandstones. The mesogenetic diagenesis includes: (1) partial conversion of kaolinite into dickite in deltaic LST sandstones, and minor chlorite cementation in deltaic FSST sandstones; (2) transformation of kaolinite into illite and quartz cementation in deltaic LST and FSST sandstones; (3) frequent precipitation of ankerite and ferroan calcite in shoreface TST sandstones and early HST sandstones, forming baffles and barriers for fluid flow, with common calcite in shoreface HST sandstones as a late diagenetic cement; and (4) formation of dawsonite in the deltaic LST and FSST sandstones, which is interpreted to be a product of the invasion of a CO2‐rich fluid, and acts as a good indicator of CO2‐bearing reservoirs. This study has thus constructed a reliable conceptual model to describe the spatial and temporal distribution of diagenetic alterations. The results may provide an entirely new conceptual framework and methodology for successful gas exploration in the continental margins of offshore China, thus allowing us to predict and unravel the distribution and quality evolution of clastic reservoirs at a more detailed and reliable scale.

DIAGENESIS OF TIGHT‐GAS SANDSTONES IN THE LOWER CRETACEOUS DENGLOUKU FORMATION, SONGLIAO BASIN, NE CHINA: IMPLICATIONS FOR RESERVOIR QUALITY

Non‐marine tight‐gas sandstones have not been studied intensively in terms of diagenesis and reservoir‐quality evaluation. This paper investigates the sandstones in the Lower Cretaceous Denglouku Formation in the Songliao Basin, NE China, which comprise a tight reservoir for natural gas. Core samples of the sandstones were obtained from eight wells located in two gasfields and were described in terms of lithology and sedimentology with the aid of wireline log interpretation; other data included thin section petrography, and X‐ray diffraction analyses and scanning electron microscopy. The sandstones mainly comprise moderate‐ to well‐sorted, fine‐ to medium‐grained feldspathic litharenites deposited in braided fluvial to braid‐delta settings under warm, arid to semi‐arid climatic conditions. Diagenetic processes which have affected the sandstones include compaction and cementation by calcite, dolomite, ferroan calcite, quartz, chlorite and illite. Porosity characteristics of the sandstones are closely linked to depositional facies, and the sandstones can be divided on the basis of sediment textures and depositional facies into three groups which have distinctive diagenetic features. The best reservoirs are represented by relatively coarse‐grained sandstones deposited in braid‐delta mouth bars and distributary channels and braided fluvial channels; these sandstones have relatively high porosity (up to 5%) and contain large amounts of chlorite and illite pore‐lining cements but relatively minor carbonate cement. A reservoir quality prediction model is proposed and incorporates textural, depositional and diagenetic attributes. The model will help to identify sweet spots in non‐marine tight‐gas sandstones elsewhere, and will contribute to more effective field development.