Femtosecond Laser Pulses Research Articles

Investigation of laser wavelength effect on the ablation of enamel and dentin using femtosecond laser pulses

We investigated the effect of femtosecond (fs) laser ablation of enamel and dentin for different pulse wavelengths: infrared (1030 nm), green (515 nm), and ultra-violet (343 nm) and for different pulse separations to determine the optimal irradiation conditions for the precise removal of dental hard tissues with the absence of structural and compositional damage. The ablation rates and efficiencies were established for all three laser wavelengths for both enamel and dentin at room temperature without using any irrigation or cooling system, and the surfaces were assessed with optical and scanning electron microscopy, optical profilometry, and Raman spectroscopy. We demonstrated that 515 nm fs irradiation provides the highest rate and efficiency for ablation, followed by infrared. Finally, we explored the temperature variations inside the dental pulp during the laser procedures for all three wavelengths and showed that the maximum increase at the optimum conditions for both infrared and green irradiations was 5.5 °C, within the acceptable limit of temperature increase during conventional dental treatments. Ultra-violet irradiation significantly increased the internal temperature of the teeth, well above the acceptable limit, and caused severe damage to tooth structures. Thus, ultra-violet is not a compatible laser wavelength for femtosecond teeth ablation.

Conical Emission Induced by the Filamentation of Femtosecond Vortex Beams in Water

Conical emission is a typical nonlinear phenomenon that occurs during the filamentation of femtosecond laser pulses in transparent media. In this work, the conical emission induced by two kinds of typical vortex beams (i.e., Laguerre–Gaussian (LG) and Bessel–Gaussian (BG) beams) in water is experimentally studied. By recording the light spots of different spectra components from the supercontinuum induced by the vortex beams, the characteristics of the conical emission induced by femtosecond vortex beams are studied. It is found that the spots of the supercontinuum induced by the two kinds of vortex beams differ greatly from each other. The spots of the supercontinuum induced by the BG beams are a set of concentric rings like a rainbow with a white center, while the white light spots in the case of the LG beams are circular white disks, which are different from the commonly observed white light spots. By measuring the maximum divergence angle, it is observed that the divergence angle increases with a decrease in the wavelength, while it is merely affected by the topological charge, which is explained by the formation mechanism of conical emission in terms of self-phase modulation. Based on the observed results, we discuss the transfer of optical angular momentum during the supercontinuum induced by the filamentation of femtosecond vortex beams. This work may help to better understand the transfer of optical angular momentum in non-optical parametric processes as well as the interaction of high-intensity pulses with matter.

Highly sensitive gas pressure sensor utilizing the harmonic vernier effect in parallel FPIs with femtosecond laser processing

This work proposes and prepares a high-sensitive fiber optic gas pressure sensor based on the first harmonic vernier effect (FHVE). It has two parallel Fabry-Perot interferometers (FPI), each made of a single-mode fiber and a small segment of capillary tube fused as a sensing cavity and a reference cavity, and the end face of the sensing cavity is cut into a thin slice with a femtosecond laser pulse to make it sensitive to gas pressure. When the sensing cavity's (FPI1) and reference cavity's (FPI2) free spectral ranges are close to each other, a traditional vernier effect occurs, and the gas pressure sensitivity approaches 58.49 nm/MPa, which is approximately 14.64 times that of the single sensing cavity (FPI1). When the free spectral range of the sensing cavity (FPI1) is roughly twice that of the reference cavity (FPI3), the first harmonic vernier effect is observed. This leads to a significant increase in gas pressure sensitivity, up to 141.80 nm/MPa, which is about 35.45 times higher than what a single sensing cavity (FPI1) would achieve. Furthermore, testing results reveal that the sensor is temperature insensitive, with a low cross-sensitivity of 3.1 × 10−5 MPa/°C for gas pressure to temperature. This device is made of pure quartz glass, has high mechanical strength, a sealed construction, is easy to fabricate, has a high sensitivity of gas pressure, and may be used to monitor pressure in extreme conditions such as offshore oil or underwater operations.

Numerical study of ultrafast optical instability causing structured light absorption in metal

We present the first-principle numerical study of nonlinear decay of a femtosecond laser pulse into a pair of surface plasmon polaritons (SPP) during reflection from a rough metallic surface. The ultrafast dynamics of the decay was studied at damaging laser fluences of about 1 J/cm2, and the principal role of the electronic collision rate growth was proved. The resulting strongly inhomogeneous heating of metal is an important stage of laser-induced phenomena like ablation, terahertz radiation generation, and periodic surface structures formation.

Nonlinear photocarrier dynamics in multilayer W S e 2 induced by intense terahertz pulses

Non-equilibrium photocarriers in multilayer WSe2 injected by femtosecond laser pulses exhibit extraordinary nonlinear dynamics in the presence of intense THz fields. The THz absorption in optically excited WSe2 rises rapidly in the low THz field regime and gradually ramps up at high intensities. The strong THz pulses drive the photocarriers into sidebands of higher mobility and release trapped charge carriers, which consequently enhance the transient conductivity of WSe2. The spectrally analyzed conductivity reveals distinctive features, indicating that the photocarriers undergo resonant interactions such as carrier-photon scattering.

Ultrafast nonlinear absorption in MoTe2 and MoTe2/MoS2 nanocomposite films and its application to all-optical logic gates

We present a detailed theoretical analysis of ultrafast saturable absorption (SA) and reverse SA (RSA) in MoTe2 nano-films with femtosecond (fs) laser pulses at 800 nm. A transition from RSA to SA occurs on increasing the thickness from 30 nm to 80 nm at a constant pump intensity of 141 GW cm−2. On the other hand, a transition from SA to RSA occurs upon increasing the pump intensity in an 80 nm thick MoTe2 nano-film. Theoretical results are in good agreement with reported experimental results. The effect of pump pulse intensity, pulse width, nonlinear absorption coefficient and sample thickness has been studied to optimize the SA ↔ RSA transition. The results for low-power and high contrast all-optical switching in MoTe2 nano-films have been used to design all-optical fs NOT, OR, AND, as well as the universal all-optical NOR and NAND logic gates. The SA behavior of MoTe2/MoS2 nanocomposite films has been used to design all-optical AND and OR logic gates. The nanocomposite films of MoTe2/MoS2 possess a larger nonlinear optical response in comparison to MoTe2 and MoS2 nano-films and, therefore, all-optical logic gates designed using nanocomposite films result in a good switching contrast compared to pure MoTe2 nano-films. Ultrafast operation at relatively low pump intensities demonstrates the applicability of MoTe2 and MoTe2/MoS2 nano-films for ultrafast all-optical information processing.

From Multi- to Single-Hollow Trimetallic Nanocrystals by Ultrafast Heating.

Metal nanocrystals (NCs) display unique physicochemical features that are highly dependent on nanoparticle dimensions, anisotropy, structure, and composition. The development of synthesis methodologies that allow us to tune such parameters finely emerges as crucial for the application of metal NCs in catalysis, optical materials, or biomedicine. Here, we describe a synthetic methodology to fabricate hollow multimetallic heterostructures using a combination of seed-mediated growth routes and femtosecond-pulsed laser irradiation. The envisaged methodology relies on the coreduction of Ag and Pd ions on gold nanorods (Au NRs) to form Au@PdAg core-shell nanostructures containing small cavities at the Au-PdAg interface. The excitation of Au@PdAg NRs with low fluence femtosecond pulses was employed to induce the coalescence and growth of large cavities, forming multihollow anisotropic Au@PdAg nanostructures. Moreover, single-hollow alloy AuPdAg could be achieved in high yield by increasing the irradiation energy. Advanced electron microscopy techniques, energy-dispersive X-ray spectroscopy (EDX) tomography, X-ray absorption near-edge structure (XANES) spectroscopy, and finite differences in the time domain (FDTD) simulations allowed us to characterize the morphology, structure, and elemental distribution of the irradiated NCs in detail. The ability of the reported synthesis route to fabricate multimetallic NCs with unprecedented hollow nanostructures offers attractive prospects for the fabrication of tailored high-entropy alloy nanoparticles.

Ultrafast helicity-dependent photocurrents in Weyl Magnet Mn3Sn

Mn3Sn is a material that has attracted a lot of attention lately for its topologically non-trivial band structure, which leads to very promising spintronic properties. In this work we experimentally demonstrate that an epitaxially grown thin film of Mn3Sn acts as a source of THz radiation at room temperature when irradiated by a femtosecond laser pulse. By combining various experimental measurements as a function of pump polarisation, magnetic field, and sample orientation we are able to explain the origin of the THz emission with the photocurrents generated via the photon drag effect. A thorough symmetry analysis combined with electronic band structure calculations using density-functional theory (DFT) are used to support our conclusions and provide a guide towards the important features that lead to photocurrent generation, which is useful for designing ultra-fast current pulses emitters.

Ultrafast dynamics of electrons excited by femtosecond laser pulses: Spin polarization and spin-polarized currents

Ultrafast dynamics of electrons excited by femtosecond laser pulses: Spin polarization and spin-polarized currents

Ultrafast terahertz spin and orbital transport in magnetic/nonmagnetic multilayer heterostructures and a perspective

Ultrafast optically excited ferromagnetic (FM)/nonmagnetic (NM) multilayer heterostructures have been demonstrated recently as efficient, high-power, and broadband sources of terahertz (THz) electromagnetic radiation. Since these spintronic THz emitters exploit the conversion from ultrafast spin to charge current, either in bulk or at the interface, the THz pulses inhere all the characteristics of the involved mechanisms and dynamics associated with spin-charge interconversion processes. Deconvolving the same requires meticulous and careful experimentation and analysis. In this article, we review the current state-of-the-art in this field and provide a perspective on the emerging phenomena, which are prospering as new research avenues and demonstrate application potential for futuristic THz technologies. In the process of developing efficient spintronic THz emitters by optimizing various conditions including those with material parameters and excitation light, it turns out that THz emission spectroscopy itself can be a unique experimental tool for probing microscopic dynamical magnetic and spintronic effects, induced by femtosecond laser pulse excitation, in a noncontact and noninvasive manner. Several breakthroughs can be listed from the literature in this regard from the last decade. Just recently, ultrafast orbitronics is another dimension that is taking shape and will impact the field immensely. A fair account to this topic is also presented in the article.

Magnetic field and gas pressure sensor based on Mach–Zehnder interferometer with micro-groove fabricated by femtosecond laser pulse

A microgroove type Mach–Zehnder interferometer (MZI) for gas pressure and magnetic field measurements was prepared using a femtosecond laser pulse in a single mode fiber. Due to the interference light passing through the microgroove, changing the refractive index (RI) of the medium in the microgroove will change the optical path difference between the two channels, leading to significant drift of the MZI transmission spectrum, thus achieving the measurement of environmental parameters. When the gas pressure inside the microgroove changes, the RI of the air changes, achieving the measurement of environmental gas pressure. When the microgroove is filled with magnetic fluid, changes in the environmental magnetic field will cause changes in the RI of the magnetic fluid, thus achieving measurement of the magnetic field. The experimental results show that the gas pressure sensitivity of the sensor is −5.03 nm/MPa, and the temperature cross-sensitivity is only 1.31 kPa/°C. This sensor achieves a magnetic field sensitivity of −0.3505 nm/mT in the magnetic field range of 6.4–13.6 mT. The sensor is small in size and easy to manufacture, making it a good choice for measuring air pressure and magnetic field.

Photodiode-based time zero determination for ultrafast electron microscopy.

Pump-probe experiments in ultrafast electron microscopy require temporal overlap between the pump and probe pulses. Accurate measurements of the time delay between them allows for the determination of the time zero, the moment in time where both pulses perfectly overlap. In this work, we present the use of a photodiode-based alignment method for these time zero measurements. The cheap and easy-to-use device consists of a photodiode in a sample holder and enables us to temporally align individual, single-electron pulses with femtosecond laser pulses. In a first device, a temporal resolution of 24 ps is obtained, limited by the photodiode design. Future work will utilize a smaller photodiode with a lower capacitance, which will increase the temporal resolution and add spatial resolution as well. This upgrade will bring the method toward the micrometer and picosecond spatiotemporal resolution.

GaN film optical nonlinearity: wavelength dependent refractive index for All-Optical switching application

Gallium Nitride (GaN) is fast becoming a potential replacement for silicon in complex electronic and photonics circuitries and systems. At higher optical intensity, optical effects such as non-linear effects would become non-trivial. To this end, we investigated nonlinear optical properties of metal–organic chemical vapor deposited GaN. Specifically, continuous-wave laser Z-scan techniques were employed to obtain nonlinear refractive index, n2, of a 1-µm thin layer on a c-plane sapphire substrate. FESEM, PL, XRD and EDS analysis confirmed the good quality growth of GaN thin film. We detected a reversal of polarity of the n2 value at 637 nm and 405 nm of CW laser excitation and femtosecond laser pulse at 808 nm. This is substantiated by theoretical calculation of GaN’s n2 showing sign switchover at wavelength shorter than 420 nm. This presents a new all-optical switching scheme based on the switchover of wavelength dependent n2. These findings point to opportunities for GaN-based integrated photonics for nonlinear and quantum photonics applications.

Corrosion behavior of nanostructured ferritic stainless steel by the generation of LIPSS with ultrashort laser pulses

Femtosecond ultra-short laser pulses can induce various micro- and nanostructural changes in the surface of stainless steel, paving the way for new functionalities in the application of these materials. In this work, UV, visible, and IR femtosecond laser pulses have been utilized on ferritic stainless steel under differing conditions of fluence, pulses per spot and hatch distance. These variables resulted in various compositional and micro- and nanostructural changes on the steel surfaces. The texturing processes which originate these changes can be meticulously designed by selecting the appropriate strategy and laser parameters, leading to Laser-Induced Periodic Surface Structures (LIPSS) and other potential morphologies. A significant problem to consider during the laser treatment of stainless-steel surfaces is the effect that these microstructural modifications, induced by the ultra-short pulses, can have on the corrosion behavior and the brightness of the surface. On one hand, a detailed study of the effect that these treatments can have on the corrosion resistance of the stainless steel under investigation has been conducted. The study shows that under specific conditions, treatments with ultra-short laser pulses maintain the corrosion resistance of the surfaces. On the other hand, the study of the surface brightness after laser treatments, as measured by the Light Reflectance Value (LRV), shows that brightness is only slightly decreased (less than 10 %) for samples where Surface Density of Applied Energy (SDAE) is lower than 2 J/cm2. Furthermore, the diffuse LRV is increased in every textured sample due to the presence of ripples.

Effect of femtosecond laser bionic texture on anti-wear properties of medical Ti-6Al-4 V

Ti-6Al-4 V (TC4) is used as a medical implant material. However, its wear resistance is poor, which is not conducive to the use of implants. In this study, three biomimetic textures were designed on the surface of materials by femtosecond pulsed laser processing technology. The wear resistance of the textured surface was studied by rotating dry friction. The results demonstrate that the textured surface effectively reduces and captures the generation of wear particles, leading to enhanced stability of TC4 during wear and reduced surface wear. Compared with the untextured surface, the wear of the textured surface is reduced by 73.68%. These results indicate that bionic texture can improve the wear resistance of TC4.

CuO/ZnO catalysts in chitosan film for CO2 reduction

In this work, ZnO of 1.1 and 10.2 nm sizes, respectively, were synthesized by irradiating femtosecond pulse laser in aqueous Zn ion precursor solutions at pH 5.5 and 10.2 in comparison with ZnO of 18.1 nm size prepared by hydrothermal procedure in an alkaline condition. The 12.8 nm CuO synthesized by precipitation method was physically mixed with ZnO, and the nanocomposites were embedded in chitosan (CS) film. Based on the catalytic activity of CuO/ZnO nanocomposite in CS film, the photocatalysis was performed for CO2 gas adsorbed on amine group in CS acting as a CO2 absorber. On the photocatalytic reaction under UV irradiation, the production of methanol was quantified using a chromogenic reagent, sodium nitroprusside. The highest catalytic activity (5642 μmol/g(catalyst)) for the CO2 conversion was achieved on CuO/ZnO/CS film, where ZnO was synthesized at pH 10.2 by femtosecond laser irradiation. The energy level alignment profile proposed the best hole transition from ZnO to CuO on CuO/ZnO/CS film in consistence with the best catalytic activity. Then the ecofriendly film-type system consisting of CS will be focused as promising biocompatible reactors because of facile production procedure and easy catalytic treatment.

Surface texturing, residual stresses and edge treatment of hardmetal tools by means of femtosecond pulsed laser

Laser induced periodic surface structures (LIPSS) have been produced at the surface of a WC-Co turning insert by femtosecond pulsed laser ablation. Wavelengths of approx. 500 nm have been obtained with a 1030 nm incident radiation and with a spot size of 30 μm. No thermal damage is induced by following this procedure, although a slight surface stress relaxation is detected as fluence increases. The higher material removal needed for chamfering operations requires accumulated fluences over 1 kJ/cm2. At lower energy densities, material removal is not completed. If fluence is increased by reducing the laser spot size, material removal is also inefficient since signicant amount of debris is accumulated on the irradiated areas. Best chamfering strategy involves the combination of relatively large spot sizes and fluences. Form factors (Κappa) of the chamfered cutting edges range from 4 to 10 although the laser is oriented at 45° of the rake face. Lower Κ values can be obtained by adjusting the laser focus along the machining process.

Enhancement of plasmonic coupling on Si metallized with intense femtosecond laser pulses

Using a pump–probe technique, the reflectivity of a silicon grating surface irradiated with intense femtosecond (fs) laser pulses was measured as a function of the incidence angle and the delay time between pulses. After irradiating the surface with an intense s-polarized, 400 nm, 300 fs laser pulse, the reflectivity measured with a weak p-polarized, 800 nm, 100 fs laser pulse exhibited an abrupt decrease for an incidence angle of ~ 24°. The depth of the dip was greatest for a delay time of 0.6–10 ps, for which the reflectivity around the dip was highest. The surface was also found to be ablated most strongly for the conditions causing the deepest dip for a delay time of 5–10 ps. Surface plasmon polaritons (SPPs) on silicon metallized by the intense pulse are resonantly excited by the subsequent pulse, and the strong coherent coupling between the subsequent pulse and SPPs excited on the molten Si surface produced by high-density free electrons induces strong surface ablation due to the intense plasmonic near-field. The results clearly show that fs pulses can be used to significantly modulate the nature of nonmetallic materials and could possibly serve as a basic tool for the excitation of SPPs on nonmetallic materials using ultrafast laser–matter interactions.

Reconstruction of Femtosecond Laser Pulses from FROG Traces by Convolutional Neural Networks

We report on the reconstruction of ultrashort laser pulses from computer-simulated and experimental second harmonic generation-frequency resolved optical gating (SHG-FROG) spectrograms. In order to retrieve the spectral amplitude and phase we use a convolutional neural network trained on simulated SHG-FROG spectrograms and the corresponding spectral-domain fields employed as labels for the network, which is a complex field encompassing the full information about the amplitude and phase. Our results show excellent retrieval capabilities of the neural network in case of the simulated pulses. Although trained only on computer generated data, the method shows promising results regarding experimentally measured pulses.

Analytical solution to incident angle quasi-phase-matching engineering for second harmonic generation in a periodic-poled lithium niobate crystal

Phase matching or quasi-phase matching (QPM) is of significant importance to the conversion efficiency of second harmonic generation (SHG) in artificial nonlinear crystals like lithium niobate (LN) crystal or microstructured nonlinear crystals like periodic-poled lithium niobate (PPLN) crystals. In this paper, we propose and show that the incident angle of pump laser light can be harnessed as an alternative versatile tool to engineer QPM for high-efficiency SHG in a PPLN crystal, in addition to conventional means of period adjusting or temperature tuning. A rigorous model is established and analytical solution of the nonlinear conversion efficiency under the small and large signal approximation theory is obtained at different incident angles. The variation of phase mismatching and walk-off length with incident angle or incident wavelength are also explored. Numerical simulations for a PPLN crystal with first order QPM structure are used to confirm our theoretical predictions based on the exact analytical solution of the general large-signal theory. The results show that the narrow-band tunable SHG output covers a range of 532 nm–552.8 nm at the ideal incident angle from 0° to 90°. This theoretical scheme, fully considering the reflection and transmission at the air-crystal interface, would offer an efficient theoretical system to evaluate the nonlinear frequency conversion and help to obtain the maximum SHG conversion efficiency by selecting an optimum incident wavelength and incident angle in a specially designed PPLN crystal, which would be very helpful for the design of tunable narrow-band pulse nanosecond, picosecond, and femtosecond laser devices via PPLN and other microstructured LN crystals.