Felsic Schists Research Articles

Redefinition of the Petersburg batholith and implications for crustal inheritance in the Dinwiddie terrane, Virginia, USA

Field relations as well as geochemical and petrologic studies of meta-igneous rocks assigned to the Pennsylvanian–Permian Petersburg batholith identify at least two distinct rock types: foliated metagranitoid gneiss and massive to porphyritic granite. Foliated metagranitoid gneiss of mostly granodioritic composition is geochemically distinct from associated massive and porphyritic granitic rocks. These gneissic rocks yield radiometric ages from ca. 425 Ma to ca. 403 Ma and document that many of the rocks assigned to the late Paleozoic Petersburg batholith are 100 m.y. older than the youngest portions of the composite batholith and are part of an earlier infrastructural terrane. Two samples of massive equigranular granite southwest of Petersburg, Virginia, yield ages of ca. 321 Ma and ca. 317 Ma, which are 15–20 m.y. older than ca. 300 Ma ages for porphyritic granite, massive granite, and monzodiorite near Richmond, Virginia. Geologic mapping shows that the Early Pennsylvanian granite southwest of Petersburg is separated from Late Pennsylvanian to early Permian granite near Richmond by a map-scale septum of Silurian–Devonian foliated metagranitoid gneiss, referred to herein as the informal Pocoshock Creek gneiss. Laser ablation–inductively coupled plasma–mass spectrometry data from one sample of a quartz-muscovite felsic schist xenolith show a peak age mode of ca. 529 Ma that we interpret to be the maximum depositional age. Inherited zircons from foliated metagranitoid gneiss and massive equigranular granite range from ca. 631 Ma to ca. 376 Ma, but many are Cambrian. Neoproterozoic–Cambrian quartz-muscovite felsic schist and amphibolite, Silurian–Devonian Pocoshock Creek gneiss, and Pennsylvanian–Permian granite comprise a fault-bounded terrane referred to herein as the Dinwiddie terrane. Ages of inherited cores in zircon from igneous rocks and limited detrital zircon geochronology suggest the terrane is of peri-Gondwanan affinity. U/Pb ages of healed fractures in zircon grains from foliated metagranitoid gneiss indicate low-grade deformation of the gneiss at ca. 378–376 Ma, while ca. 320–280 Ma rims on many grains record intrusion of late Paleozoic granite. The temperature-time-deformation history of the Dinwiddie terrane is distinct from the adjacent Goochland and Roanoke Rapids terranes. Orogen-scale dextral transpression likely translated the Dinwiddie terrane southward during the Alleghanian orogeny, at which time they were intruded by Pennsylvanian to Permian granite.

Metamorphic evolution of stilpnomelane-bearing felsic schists from the subducted complex of southwestern Tianshan, China

Metamorphic evolution of stilpnomelane-bearing felsic schists from the subducted complex of southwestern Tianshan, China

Petrology of UHP eclogite-facies felsic schist in the Western Tianshan subduction zone, China

Although quartzo-feldspathic metasedimentary rocks are widespread in high pressure-ultrahigh pressure (HP-UHP) metamorphic belts worldwide, their petrogenesis and metamorphic evolution is poorly understood. We discovered an UHP eclogite-facies felsic schist in the Western Tianshan metamorphic belt, China. Petrological observations and phase equilibria modeling both indicate the felsic schist experienced UHP metamorphism in the coesite stability field. In particular, it experienced prograde metamorphism at 21–24 kbar, 445°C–470°C, a pressure peak at 25–28 kbar and 490°C–525°C, and eventually heating with decompression to 20 kbar and 560°C. The obtained clockwise P-T path was consistent with those of other lithologies (eclogite and pelitic schist) from the same belt, which provides new evidence for the coherent exhumation of the UHP unit of the Western Tianshan metamorphic belt. The final uplift of the Western Tianshan oceanic crust to the surface is attributed to fluid activity and late tectonic deformation.

Reduction of iron with no systematic isotope fractionation during continental subduction observed in metamorphic rocks from the Dabie-Sulu orogen, China

• No resolvable Fe isotope fractionation in metabasites during prograde dehydration. • Eclogites have Fe 3+ /∑Fe systematically lower than the other metabasites. • Fe reduction likely occurred during eclogitization with simultaneous S oxidization. In order to better understand the mobility and charge balance of Fe in subducted slabs, here we report precise Fe isotopic data, supplemented by Fe 3+ /∑Fe and C-N-S elemental contents, in a well-characterized suite of metamorphic rocks from the Dabie-Sulu orogen, China, including mafic to felsic greenschists, amphibolites and eclogites. There is no systematic Fe isotopic difference among the mafic schists (δ 56 Fe = 0.08 ± 0.08‰, 2SD, N = 13), amphibolites (δ 56 Fe = 0.09 ± 0.04‰, 2SD, N = 19) and eclogites (δ 56 Fe = 0.07 ± 0.06‰, 2SD, N = 27), implying limited Fe mobility during prograde metamorphic dehydration. The overall δ 56 Fe variation of the metabasites and felsic schists ranging from 0.02 ± 0.03‰ to 0.20 ± 0.03‰ most likely mirrors heterogeneity in their Neoproterozoic magmatic protoliths, and can be interpreted by derivation from diverse sources and isotope fractionation during magma differentiation. In a contrary to limited Fe mobility, a decrease in Fe 3+ /∑Fe ratios has been identified for metabasites during eclogitization (on average 0.43 for greenschists, 0.42 for amphibolites and 0.24 for eclogites respectively). Reduction of Fe could have been compensated by oxidation of S where a concurrent expulsion of sulfate seems to be necessary. This study thus supports the hypothesis that Fe-S redox coupling in subducted slabs promotes transfer of oxidizing agents into the mantle wedge in subduction zones.

Zircon and monazite U-Pb ages of the Mashan Complex of the Jiamusi Block of NE China: a link to Gondwana?

ABSTRACT The tectonic affinities of the microcontinents in the eastern Central Asian Orogenic Belt of NE China, particularly the Jiamusi Block, have been hotly debated in the last decade. The Mashan Complex, which is the oldest exposed basement of the Jiamusi Block and consists of khondalitic rocks (felsic granulite, marble, and graphite schist) and orthogneisses, is the key geological unit to look into the tectonic affinity of the Jiamusi Block. In this study, we carried out LA-ICP-MS U-Pb dating on zircon and monazite minerals from the granitic gneisses in the Mashan Complex, to constrain the affinity of the Jiamusi Block. Magmatic zircons from two granitic gneisses yielded weighted mean 206Pb/238U ages of 517 ± 7 Ma and 527 ± 4 Ma, respectively, which are interpreted as the protolith ages. These age data verify a late Pan-African magmatic event in the Jiamusi Block. Metamorphic zircons from one granitic gneiss gave a weighted mean 206Pb/238U age of 510 ± 3 Ma, which constrained the metamorphic time of the Mashan Complex. This metamorphic age is further supported by monazite dating results – the monazites from three granitic gneiss samples yielded weighted mean 206Pb/238U ages of 489 ± 3 Ma, 498 ± 3 Ma, and 500 ± 3 Ma, respectively, which represented the metamorphic recrystallization ages of these monazites. These data consistently indicate a regional metamorphic event immediately after the late Pan-African magmatism in the Jiamusi Block. Our new data, combined with previously published late Pan-African geochronological data from the Jiamusi Block, support that the Jiamusi Block has an affinity to the Gondwana.

Metamorphic rocks from the north-eastern part of the Ereendavaa terrane (Eastern Mongolia) :

In this paper, we have conducted geochronological and geochemical studies on the metamorphic rocks of the Khaychingol and Ereendavaa Formations in the Mogoitiin Gol, Khaychin Gol and Emgentiin Bulag areas from the Ereendavaa terrane and these rocks have been considered to be Precambrian in age. However, new LA–ICP–MS zircon U–Pb dating results indicate that the protolith of the studied metamorphic rocks was formed in two stages: 1) during ~ 296 - 285 Ma, the protolith of mafic, felsic and black schists formed; 2) during ~276 - 271 Ma, the protolith of gneiss and psammitic schists began to deposit. The Early Permian bimodal association composed of low-K basalt and comagmatic high-Na, low-K dacite with high-K calc-alkaline rhyolite, represent protolith of the mafic and felsic schists which were formed in back-arc basin environment. The Middle Permian gneiss, and psammitic schists with sedimentary protolith have geochemical signatures of island arc rocks, such as enrichment of LILE relative to HFSE, and markedly negative Nb, Ta and Ti anomalies, suggesting that they were formed in a continental arc environment. Considering a close spatial relationship of the Ereendavaa terrane with the Mongol-Okhotsk Belt in the north-west, we propose that accompanied with the emplacement of arc magmatic rocks, the arc rifting occurred and formed the Early Permian bimodal volcanic rocks. In the Late Permian, after the formation of the back-arc basin, deposition of the immature deposits as wacke, arkose and litharenite dominated sediments in a continental arc environment started.

Chemostratigraphic constraints on the nature and origin of felsic schist units hosting stratabound and orogenic vein gold on Lone Star Ridge, Klondike Gold District, Yukon

Felsic schist units in the Lone Star Ridge area of the northern Klondike Gold District, Yukon, Canada, host both locally gold-bearing orogenic quartz veins and much more extensive zones of disseminated gold mineralization that is stratabound within specific schist units and is interpreted to be syngenetic in origin. Scarcity of outcrop and the difficulty in distinguishing between subtly different schist units has hampered correlation between surface exposures and drill core, and production of a detailed geological map of the area. Lithogeochemistry offers an alternative, unbiased way to map and interpret the various subunits of the felsic schist package that host disseminated gold mineralization and gold-bearing veins in parts of the Klondike, and that can potentially form the basis for correlations between various drill holes, and between drill holes and surface exposures. A detailed investigation of 4590 multi-element geochemical analyses (by 4-acid digestion) from a set of 27 diamond drill holes in the vicinity of the Boulder Lode open cut (Lone Star gold occurrence) on Lone Star Ridge has revealed several lithogeochemical signatures that correlate closely with gold content and to some extent with lithological units distinguished during initial logging of the drill core. Research quality geochemical analyses for a suite of representative rock units selected from the 2005 drill holes have been used to verify the multi-element geochemical analyses, and to determine the petrochemical character of some of the individual rock units. Results of this study demonstrate that it is possible to construct a chemostratigraphic framework for the felsic schist units in the vicinity of the Boulder Lode. Distinctive rock units can be broken out that have very consistent geochemical signatures, and elevated gold values related to the presence of disseminated gold appear to be consistently associated with specific rock units. These chemostratigraphic marker units have been utilized to constrain the geology and structure of the immediate study area, and in particular to define the geometry of the schist units that contain disseminated gold. The same approach has also been applied to a very extensive set of geochemical data (comprising nearly 34,000 individual samples) from chip samples, diamond drill core, reverse circulation drill samples, and conventional soil samples obtained during other historical and more recent exploration programs, to better resolve the geological interpretation of entire Lone Star Ridge area.

Metamorphism and exhumation of basement gneiss domes in the Quadrilátero Ferrífero: Two stage dome-and-keel evolution?

The presence of dome-and-keel provinces in Archean cratons has been connected with the initiation of plate tectonics on Earth as these features are most commonly observed in Archean rocks. The Quadrilátero Ferrífero in Brazil has been identified as a Paleoproterozoic dome-and-keel province for more than three decades. The prevailing model suggests that it formed during the Rhyacian Transamazonian orogeny, making it unique among dome-and-keel provinces. However, a lack of appropriate lithologies, datable minerals and the metamorphic overprint of later orogenesis has resulted in a cryptic metamorphic record for the formation of this dome-and-keel province. A clinopyroxene-bearing migmatite from the core of the Bação dome has peak P–T conditions of 5–7 kbar and 700–750 °C and a published age of ca. 2730 Ma based on U–Pb ages of zircon from leucosomes, suggesting that this age represents the migmatisation event. A fine-grained epidote-albite-titanite assemblage overprints the coarse-grained clinopyroxene and amphibole, giving P–T conditions of 8–9 kbar and 550 °C with an associated titanite age of ca. 2050 Ma. A garnet-bearing amphibolite sample also from the core of the dome has peak P–T conditions of 7–8 kbar and 650–700 °C, and texturally late titanite from this sample produces an age of ca. 2060 Ma. Three additional samples were collected from the edges of the dome. A garnet-gedrite bearing felsic schist produces peak P–T conditions of 8–9 kbar and 650–700 °C on a clockwise P–T evolution. This sample has a U–Pb zircon age of ca. 2775 Ma, which could date metamorphism or be the age of its volcaniclastic protolith. Texturally unconstrained titanite from the sample gives an age of ca. 2040 Ma. A garnet-bearing amphibolite that occurs as a boudin within the felsic schist gives both zircon and titanite ages of ca. 2050 Ma and has peak P–T conditions of 5–6 kbar and 650–700 °C on a near isobaric P–T path. An amphibolite dike, observed to cross-cut the felsic schist produces a zircon U–Pb age of ca. 2760 Ma. Altogether this data suggests that the samples were metamorphosed in the Archean (ca. 2775–2730 Ma) and again during the Transamazonian event. The most plausible explanation for this data is that dome-and-keel formation occurred in the Archean with migmatisation and high-temperature metamorphism occurring at this time. The Paleoproterozoic event is interpreted as a reactivation of the dome-and-keel formation structures, with Paleoproterozoic keels crosscutting Archean keels and producing metamorphic aureoles. The high radiogenic heat production and the presence of dense sedimentary successions in Archean terranes make dome-and-keel provinces a uniquely Archean feature, but they are susceptible to reworking, resulting in an enigmatic record of formation.

VHMS mineralisation at Erayinia in the Eastern Goldfields Superterrane: Geology and geochemistry of the metamorphosed King Zn deposit

Despite having been a target for volcanic-hosted massive sulfide (VHMS) deposits since the 1960s, few resources have been defined in the Archean Yilgarn Craton of Western Australia. Exploration challenges associated with regolith and deep cover exacerbate the already-difficult task of exploring for small, deformed deposits in stratigraphically complex, metamorphosed volcanic terranes. We present results of drill-core logging, petrography, whole-rock geochemistry and portable X-ray Fluorescence data from the King Zn deposit, to help refine mineralogical and geochemical halos associated with VHMS mineralisation in amphibolite-facies greenstone sequences of the Yilgarn Craton. The King Zn deposit (2.15 Mt at 3.47 wt% Zn) occurs as a 1–7 m-thick stratiform lens dominated by iron sulfides, in an overturned, metamorphosed volcanic rock-dominated sequence located ∼140 km east of Kalgoorlie. The local stratigraphy is characterised by garnet-amphibolite and strongly banded intermediate to felsic schists, with rare horizons of graphitic schist and talc schist. Massive sulfide mineralisation is characterised by stratiform pyrite–pyrrhotite–sphalerite at the contact between quartz–muscovite schists (‘the footwall dacite’), and banded quartz–biotite and amphibole ± garnet schists of the stratigraphic hanging-wall. A zone of pyrite–(sphalerite) and pyrrhotite–pyrite–(chalcopyrite) veining extends throughout the stratigraphic footwall. Footwall garnet-amphibolites are of sub-alkaline basaltic affinity, with a central zone dominated by chlorite ± magnetite interpreted to represent the Cu-bearing feeder zone. SiO2, CaO, Fe2O3T, MgO and Cu concentrations are highly variable, reflecting quartz–epidote ± chlorite ± magnetite ± sulfide alteration. Hydrothermal alteration in stratigraphically overlying intermediate to felsic rocks is characterised by a mineral assemblage of quartz–muscovite ± chlorite ± albite ± carbonate. Cordierite and anthophyllite are locally significant and indicative of zones of Mg-metasomatism prior to metamorphism. Increases in SiO2, Fe2O3T, pathfinder elements (e.g. As, Sb, Tl), and depletions of Na2O, CaO, Sr and MgO occur in quartz–muscovite schists approaching massive sulfide mineralisation. Within all strata (including the immediate hanging-wall), the following pathfinder elements are strongly correlated with Zn: Ag, As, Au, Bi, Cd, Eu/Eu*, Hg, In, Ni, Pb, Sb, Se and Tl. These geochemical halos resemble less metamorphosed VHMS deposits across the Yilgarn Craton and suggest that although metamorphism leads to element mobility and mineral segregation at the thin-section scale, assay samples of ∼20 cm length are sufficient to vector to mineralisation in amphibolite facies greenstone belts. Recognition of minerals such as Mg-chlorite, muscovite, cordierite, anthophyllite, biotite/phlogopite, and abundant garnet are significant, in addition to Al-rich phases (i.e. kyanite, sillimanite, andalusite and/or staurolite) not identified at King. Chemographic diagrams may be used to identify and distinguish different alteration trends, along with several alteration indices (e.g. Alteration Index, Carbonate–Chlorite–Pyrite Index, Silicification Index) and the abundance of normative corundum and quartz.

Triassic rejuvenation of unexposed Archean-Paleoproterozoic deep crust beneath the western Cathaysia block, South China

Jurassic (ca. 150 Ma) Daoxian basalts from the western Cathaysia block (South China) entrained a suite of deep-seated crustal xenoliths, including felsic schist, gneiss and granulite, and mafic two-pyroxene granulite and metagabbro. Zircon U–Pb–Hf isotopic, whole-rock elemental and Sr–Nd–Pb isotopic compositions have been determined for these valuable xenoliths to reveal the poorly-known, unexposed deep crust beneath South China. Detrital zircons from the garnet-biotite schists show several populations of ages at 0.65–0.5 Ga, 1.1–0.75 Ga, 1.6–1.4 Ga, 1.8–1.7 Ga, 2.5–2.4 Ga, ~2.8 Ga, and ~3.5 Ga, representing a multi-sourced, meta-sedimentary origin with deposition time at the early Cambrian. One mafic granulite contains zircons with concordant U–Pb ages of Neoarchean (~2520 Ma), as well as Hf model ages of 2.8–2.6 Ga and positive εHf(t) values (up to 6.3), suggesting an accretion of juvenile crust in Neoarchean, probably as the main framework of the lower crust. Geochemical and geochronological evidence shows the mafic granulite and metagabbro were produced by underplating of magmas derived from the depleted asthenosphere and mixed with EM2-type materials during the Late Triassic (205–196 Ma). This magmatic underplating also resulted in the widespread metamorphism of the mafic lower crust and felsic middle crust (e.g., the felsic granulite and gneiss) at 202–201 Ma. We suggest the existence of a highly evolved Archean-Paleoproterozoic basement beneath the western Cathaysia block, which experienced episodic accretion and reworking and the strong rejuvenation during the Triassic. A three-layered structure of the lower crust could exist beneath the Daoxian area during the Jurassic time: its upper layer is an evolved Archean-Paleoproterozoic basement; the middle hybrid layer represents a mixture of Archean-Paleoproterozoic basement with newly accreted/reworked Proterozoic to Phanerozoic materials; and the deeper layer consists of mafic granulites derived from the intensive magmatic underplating during the Triassic.

Mesoproterozoic (Grenville-age) granitoids and supracrustal rocks in Kaokoland, northwestern Namibia

We identified and describe rocks of a late Mesoproterozoic Grenville-age igneous province and associated supracrustal sequence in northwestern Kaokoland, Namibia. These rocks are ca. 1176–1534Ma in age and mostly consist of pinkish granitic and trondhjemitic plutons that are unfoliated within the Palaeoproterozoic Epupa Metamorphic Complex but become progressively deformed farther west together with late Neoproterozoic rocks of the Pan-African Kaoko orogen. Furthermore, a supracrustal assemblage of clastic sedimentary rocks and felsic volcanic rocks, known as Okapuka Formation, unconformably overlies the Epupa gneisses and also became deformed in the west during the Kaoko orogeny. A zircon age of ca. 1320Ma for an Okapuka felsic schist is suggested to date volcanism and deposition of sediments in an intracontinental basin that may have extended into southern Angola where similar rocks of the Chela Group are exposed. Some granites have A-type chemical characteristics, and it is likely that granitoid magmatism and Okapuka basin formation in northwestern Kaokoland was related to crustal extension as also documented by emplacement of the 1385±8Ma Kunene Gabbro-Anorthosite Complex.

Metavolcanic host rocks, mineralization, and gossans of the Shaib al Tair and Rabathan volcanogenic massive sulphide deposits of the Wadi Bidah Mineral District, Saudi Arabia

ABSTRACTThe Wadi Bidah Mineral District of Saudi Arabia contains more than 16 small outcropping stratabound volcanogenic Cu–Zn–(Pb) ± Au-bearing massive sulphide deposits and associated zones of hydrothermal alteration. Here, we use major and trace element analyses of massive sulphides, gossans, and hydrothermally altered and least altered metamorphosed host rock (schist) from two of the deposits (Shaib al Tair and Rabathan) to interpret the geochemical and petrological evolution of the host rocks and gossanization of the mineralization. Tectonic interpretations utilize high-field-strength elements, including the rare earth elements (REE), because they are relatively immobile during hydrothermal alteration, low-grade metamorphism, and supergene weathering and therefore are useful in constraining the source, composition, and physicochemical parameters of the primary igneous rocks, the mineralizing hydrothermal fluid and subsequent supergene weathering processes. Positive Eu anomalies in some of the massive sulphide samples are consistent with a high temperature (>250°C) hydrothermal origin, consistent with the Cu contents (up to 2 wt.%) of the massive sulphides. The REE profiles of the gossans are topologically similar to nearby hydrothermally altered felsic schists (light REE (LREE)-enriched to concave-up REE profiles, with or without positive Eu anomalies) suggesting that the REE experienced little fractionation during metamorphism or supergene weathering. Hydrothermally altered rocks (now schists) close to the massive sulphide deposits have high base metals and Ba contents and have concave-up REE patterns, in contrast to the least altered host rocks, consistent with greater mobility of the middle REE compared to the light and heavy REE during hydrothermal alteration. The gossans are interpreted to represent relict massive sulphides that have undergone supergene weathering; ‘chert’ beds within these massive sulphide deposits may be leached wall-rock gossans that experienced silicification and Pb–Ba–Fe enrichment from acidic groundwaters generated during gossan formation.

Lithostratigraphy of the Mesoproterozoic Jannelsepan Formation

The Jannelsepan Formation forms part of the 1.30 to 1.24 Ga Areachap Group. It is a pre-tectonic calc-alkaline volcano-sedimentary unit in the 1.2 to 1.0 Ga Namaqua Sector of the Namaqua-Natal Metamorphic Province. The main rock types are amphibolites with subordinate clinopyroxene or biotite. Although some primary volcanic textures have been identified, primary features are generally poorly preserved. Minor interlayered units include felsic metavolcanic rocks, pelitic schists and calc-silicate rocks which may represent primary marls. Field and geochemical evidence suggests that the Jannelsepan Formation represents metamorphosed basaltic to intermediate lavas and associated sedimentary rocks which formed in a subduction-related arc setting.

Supracrustal suite of the Precambrian crystalline crust in the Ghor Province of Central Afghanistan

The Proterozoic pre-Ediacaran metamorphic basement of the southern Tajik (North Afghanistan) continental block and the adjacent Band-e-Bayan zone is exposed in the Ghor Province of Central Afghanistan. It is predominantly composed of the EW-striking supracrustal succession consisting of interbedded felsic schists and gneisses (metapsammites), amphibolites (metabasalts), calcite and dolomite marbles. The metamorphic facies changes from greenschist in the Band-e-Bayan zone to amphibolite facies in the Tajik block. The supracrustal rocks of the Band-e-Bayan zone and Tajik block possess common features suggesting that the former represents a tectonized part of the latter. The geochemical characteristics of metapsammites indicate derivation of the clastic material from a continental arc and, partly from a passive continental margin, whereas the composition of metabasalts suggests their possible formation in a continental rift basin. The tectonic setting of supracrustal unit could be interpreted as a back-arc type basin. We presume that the Tajik microcontinent split off the Gondwana supercontinent along an ancient rift zone during the late Paleozoic.

Protocrustal evolution of the Nuvvuagittuq Supracrustal Belt as determined by high precision zircon Lu–Hf and U–Pb isotope data

The Nuvvuagittuq Supracrustal Belt (NSB) in northern Quebec, Canada, represents one of the oldest known crustal fragments preserved in the Earth's crust. Its age has, however, been disputed and different authors present crustal formation ages varying from ca. 3.8 Ga to 4.4 Ga (e.g. O'Neil et al., 2012; Guitreau et al., 2013). Here we report new high precision U–Pb geochronological and coupled Lu–Hf isotope data from zircons that reveal the age of the NSB and provide new constraints on the source rocks to this piece of early crust. Two rocks have been analysed, a felsic schist, interpreted to represent a volcanite, and a mylonitic tonalite that is intrusive into the NSB. The felsic schist was emplaced at 3771+5/−3 Ma, dating the formation of the NSB. The Lu–Hf model age indicates that the parental melt to the felsic schist was extracted from the mantle at this age or within a few tens of million years, but no more than 300 m.y., before its extrusion. This mantle extraction age provides an absolute maximum age for the NSB, but the most probable age of its protocrust is ca. 3.8 Ga. The mylonitic tonalite was emplaced at 3667+3/−1 Ma. Its Lu–Hf isotopic composition reveals the presence of an older crustal component than that of the NSB, requiring that its precursor melt formed from a Hadean source that was older than the NSB. Based on recent models for Archean TTG formation, we propose that this source represents re-melted Hadean hydrated crust that must have been translated below the NSB at ca. 3667 Ma.

3806 Ma Isua rhyolites and dacites affected by low temperature Eoarchaean surficial alteration: Earth's earliest weathering

This paper reports evidence for Earth's oldest-recognised low temperature alteration, at ∼3800Ma. Potassic felsic schists with a protolith age of 3806±2Ma form a ∼30km long unit in the amphibolite facies, deformed, Isua supracrustal belt (West Greenland). At a single locality, boudinaged layers (nodules) within the schists are low strain zones: they are fine-grained, weakly feldspar-phyric, contain quartz amygdules and have fiamme-like structures, all supporting a volcanic protolith.The nodules and surrounding schistose matrix contain abundant, 100–50μm, euhedral, oscillatory zoned 3806Ma zircons. The rare earth patterns of the zircons indicate crystallisation was magmatic. Some zircons contain axial lobate voids indicating that they grew at low pressure as the magma exsolved a fluid. Ti-in-zircon thermometry indicates crystallisation temperatures of 750–650°C. Taken together, these zircon features indicates growth at eutectic temperatures in a hypabyssal chamber as the magma was exsolving a fluid phase. The magmatic zircons have ɛHf initial values of ∼0 and δ18OVSMOW of +5.0‰ (Hiess et al., 2009), showing that the source of the volcanic rocks was devoid of assimilated markedly older or weathered crustal material, and probably essentially juvenile. In contrast, the whole rock δ18OVSMOW values are elevated at +14.7 to +16.2‰, indicative of superimposed low-temperature alteration processes.The nodules and matrix schists have non-igneous bulk compositions, exemplified by strong enrichment in K2O and depletion in Na2O. They are depleted in Sr, have no negative Eu anomalies, but have high Rb/Sr, with an Rb–Sr age of 3760±140Ma (Jacobsen and Dymek, 1988). This indicates that the alteration involving strong degradation of plagioclase occurred in the Eoarchaean. Trace element compositions and establishment of alteration vectors suggest the protoliths were likely rhyolitic and dacitic in composition.The strongest-modified matrix schist compositions contain biotite±calcite±dolomite with increase in MgO relative to the nodules, which indicates early magnesian carbonate growth. The whole-rock chemistry, decoupling of the igneous zircon and whole-rock oxygen isotope signatures and the Rb–Sr dating indicate that after eruption, the 3806Ma felsic volcanic rocks underwent Eoarchaean low-temperature potassic alteration with weathering and groundwater circulation the most likely process. The geochemistry of the Isua felsic schists is compared with that of better-preserved volcanic rocks where the alteration conditions are known. This suggests a subaerial environment. The carbonatisation of the Isua felsic schists demonstrates drawdown of atmospheric CO2 into rocks made porous by the weathering.

Paleoproterozoic (ca. 2.1–2.0 Ga) arc magmatism in the Fuping Complex: Implications for the tectonic evolution of the Trans-North China Orogen

The Fuping Complex is exposed at the central domain of the Trans-North China Orogen (TNCO). Here we report new zircon LA-ICP-MS U–Pb ages, Lu–Hf isotope data, and whole rock geochemistry on a suite of meta-granitoids, amphibolites and metasedimentary rocks from the Fuping Complex. Magmatic zircons from the gneissic granite and syenogranites yield weighted mean 207Pb/206Pb ages of 2050±21Ma and 2077±16Ma, respectively. Those in two amphibolites show weighted mean 207Pb/206Pb ages of 2054±26Ma and 2044±61Ma. Zircons in a felsic schist define two age populations of 2450–2585Ga and 2004–2097Ga, suggesting the Fuping TTG gneisses and Nanying gneissic granites as the provenance. Our data also indicate that the Wanzi supracrustal sequence was deposited between 1.95 and 1.84Ga.The geochemical data suggest that the 2.1–2.0Ga granitic rocks and amphibolites from the Fuping Complex formed in subduction-related arc setting. The granitoids show SiO2 content between 72.53 and 77.67wt.% and classify as high-K shoshonitic, calc-alkalic to alkali granite. The amphibolites are subalkaline basalts in composition. Zircons from the 2.1–2.0Ga granitoids and amphibolites display positive ɛHf(t) values in the range of 0.3–8.5 and Hf crustal model ages (TDMC) from 2124 to 2639Ma. The 2.1–2.0Ga magmatic zircons in the Wanzi supracrustal assemblage show relatively lower ɛHf(t) values (−0.8 to −2.6) and Hf crustal model ages (TDMC) of 2710–2801Ma, suggesting that the magma sources of the 2.1–2.0Ga suite included reworked 2.7–2.8Ga crustal basement together with Neoarchean–Paleoproterozoic juvenile components. Based on the widespread 2.1–2.0Ga magmatism as recorded in different rock types within the TNCO, we propose a tectonic model where we envisage simultaneous subduction and continental rifting process between several micro-blocks (or complexes). During 2.1–2.0Ga, the Wutai Complex and the Fuping Complex were separated by the Longquanguan ocean. The double-sided subduction of the Longquanguan oceanic lithosphere resulted in distinct arc magmatism. Continental rift setting developed in the Hengshan, Huai’an and Zanhuang Complexes coevally. Finally, metamorphism associated with the ∼1.85Ga collision between the Western Block and the Eastern Block along the TNCO overprinted all the lithologies. The Paleoproterozoic continent building recorded in this study correlates with similar events in the crustal fragments of the Columbia supercontinent.

Paleoproterozoic crustal growth in the North China Craton: Evidence from the Lüliang Complex

The building of continental blocks and their assembly into supercontinents are linked to episodic crustal growth through Earth history, where both vertical and horizontal accretions in convergent plate margins play a significant role. Here we investigate the Paleoproterozoic crustal growth in the North China Craton (NCC) from a traverse covering continent-trench-ocean section in the Lüliang Complex within the western margin of the Trans-North China Orogen, a major accretionary belt that sutures the Eastern and Western Blocks in the NCC. We present petrological, geochemical and zircon U–Pb and Lu–Hf data from a suite of samples including meta granitoids and gabbroic diorite that built the continental arc, and metabasalts, felsic tuff, mafic and pelitic schists, and garnet amphibolites that form part of an imbricated package of oceanic and continental material that was accreted onto the eastern margin of the Western Block in the NCC. The salient geochemical features of the magmatic suite such as high Th/Ta and La/Nb ratios, negative Nb–Ta anomalies, and high concentration of LILE as compared to HFSE suggest magma derivation from sub-continental mantle source which has undergone different degree of enrichment with crustal components or material derived from subduction-related older components. In tectonic discrimination diagrams, the granitoids show VAG affinity and all the rocks straddle the field between IAB and MORB reflecting subduction-related arc signature. The majority of zircon grains in all the rock types from the Lüliang Complex show typical magmatic crystallization textures and high Th/U values. Zircons from the meta-granitoids and diorite enclave yield upper intercept or 207Pb/206Pb mean ages in the range of 2250±20 to 2084±69Ma. Those in the mafic schist show a mean age of 2234±9Ma. In the felsic schist group, the mean ages are in the range of 2298±15 to 1933±11Ma. A minor older population of zircons with ages of 2992±28Ma and 2610±80Ma also occurs in these rocks. In the metabasalt, zircon 207Pb/206Pb mean ages are between 2391±40 and 2022±39Ma with rare magmatic xenocrysts showing Mesoarchean age of 3294±21Ma. Zircons in the felsic tuff show mean ages of 2155±25 to 1897±24Ma, with xenocryst populations yielding mean ages of 2528±31Ma and 2710±20Ma. The youngest zircons with 207Pb/206Pb mean age of ca. 1.9Ga from the felsic schist (metasediment) and felsic tuff (volcanic suite) suggest deposition within the trench of an active convergent margin at this time. In the garnet-bearing amphibolite, the zircons yield a limited age range of 1996±17Ma to 1984±12Ma. The Lu–Hf data on zircons from all samples show dominantly positive ɛHf(t) values. In the granitoid–diorite suite, the ɛHf(t) values range up to 7.6 with crustal residence ages (TDMC) of 2371–2729Ma. Zircons in the mafic and felsic schists also possess positive ɛHf(t) values (up to 9.6) with TDMC in the range of 2366–2798Ma. In the metabasalt, both positive and negative ɛHf(t) values are displayed (3.8 to −3.2) with TDMC in the range of 2495–2830Ma. Zircons in the felsic tuff also show prominent positive ɛHf(t) value (up to 7.4) and crustal residence ages range from 2274 to 2607Ma. In the garnet-bearing amphibolite, the ɛHf(t) values lie between 3.3 and 4.8 and TDMC are in the range of 2321–2413Ma. The majority of ɛHf(t) values from all the rock types in the present study are compatible with juvenile magma sources, with limited input from crustal components. Their TDMC values indicate that both Neoarchean and Paleoproterozoic components were involved in the source, attesting to a continental arc setting. The Hf data also suggest the possible presence of Mesoarchean vestiges among the dominantly Neoarchean–Paleoproterozoic basement. Our data demonstrate active plate tectonics and major crustal growth during the Paleoproterozoic history of the NCC, broadly coeval with the making of the global supercontinent Columbia, and provide insights into continent building through subduction–accretion–collision tectonics analogous to those in Phanerozoic orogenic belts.

Magnesium isotopic systematics of mafic rocks during continental subduction

Magnesium isotopic compositions of a set of prograde metamorphosed rocks (greenschists, amphibolites, and eclogites) from East China were measured in order to understand the behavior of Mg isotopes during continental subduction. The δ26Mg values of the greenschists vary from −0.269±0.057‰ to −0.133±0.042‰ (2SD), and correlate negatively with the MgO contents and Nb/U ratios, possibly due to the assimilation of isotopicallly heavy felsic schists (δ26Mg up to −0.099‰) during the genesis of MORB-like protoliths. The two subgroups of amphibolites have slightly different Mg isotopic compositions. The group I amphibolites with cumulate origin have δ26Mg values ranging from −0.243±0.061‰ to −0.192±0.050‰, which reflects clinopyroxene accumulation nature of the protolith. The group II amphibolites have relatively light δ26Mg values varying from −0.358±0.061‰ to −0.224±0.056‰, which may result from either source contamination or crustal assimilation of isotopically light components (e.g., carbonates). Eclogitic garnet and clinopyroxene display large inter-mineral Mg isotope fractionations (Δ26MgCpx-Grt=1.097±0.056‰ to 1.645±0.081‰) equilibrated at peak metamorphic temperatures. The δ26Mg values of the eclogites vary from −0.348±0.041‰ to −0.137±0.063‰, overlapping the ranges of greenschists and amphibolites. Such Mg isotopic variations are not related to unrepresentative sampling nor host–eclogite chemical interactions, instead, they reflect the protolith heterogeneities. Collectively, the similarity of Mg isotopic compositions among the greenschists (−0.196±0.044‰), amphibolites (−0.271±0.042‰), and eclogites (−0.226±0.044‰), suggests that Mg isotope fractionation during continental subduction, if any, is limited.

U–Pb and Re–Os geochronology of the Bainaimiao Cu–Mo–Au deposit, on the northern margin of the North China Craton, Central Asia Orogenic Belt: Implications for ore genesis and geodynamic setting

The Bainaimiao Cu–Mo–Au deposit, located at the northern margin of the North China Craton (NCC) in central Inner Mongolia, is a large Cu-dominant deposit. Orebodies are hosted in strongly deformed and metamorphosed granodiorite porphyry intrusions or in EW-trending shear zones in greenschist and sericite felsic schist of the Bainaimiao Group. Mineralization can be divided into early, middle and late stages, characterized by quartz–pyrite, polymetallic quartz–sulfides and carbonate–quartz, respectively. Hydrothermal activity led to pervasive silicification, K-feldspar, biotite and chlorite–epidote–carbonate alteration.Eight samples from Cu–Mo-bearing quartz veins and massive sulfide ores in greenschist were collected from the VIII orebody in the North ore belt and molybdenite separates were selected for Re–Os analyses. The concentrations of Re and 187Os range from 216.6 to 1051ppm and 2302 to 4913ppb, respectively. All samples give Re–Os model ages between 441.2 and 445.9Ma and yielded an isochron age of 445.0±3.4Ma (MSWD=0.26), with an initial 187Os of −4±17ppb. A granodiorite porphyry sample for SHRIMP U–Pb dating was collected from the underground of the XIII orebody of the North ore belt. Spots from 14 zircon grains have 206Pb/238U values between 426.2 and 462.9Ma and form a tight cluster on Concordia yielding a weighted mean 206Pb/238U age of 445±6Ma. This is considered to be the best estimate of crystallization age of the granodiorite porphyry. The Re–Os isochron age of the molybdenite is consistent with the SHRIMP U–Pb age of the granodiorite porphyry, which indicates that the deposit is a porphyry system of Paleozoic age.According to geodynamic setting and geological history of the northern margin of the NCC, the deposit was probably related to magmatic activity of the Middle Paleozoic Ondor Sum subduction–accretion complex-Bainaimiao arc. During the Devonian, the Bainaimiao arc was accreted to the northern margin of the NCC. Collision between the Bainaimiao arc and NCC led to regional metamorphism of the ore-hosting terrane and ore metals were remobilized in this process. Gold mineralization was probably overprinted onto the earlier Cu–Mo mineralization.