Felsic Research Articles

From an accretionary margin to a sediment-rich collision: Spatiotemporal evolution of the magmatism during the closure of the Mongol-Okhotsk Ocean

The closure of the Mongol-Okhotsk Ocean (MOO) marks the final suturing of the Central Asian Orogenic Belt, one of the largest accretionary orogens on Earth and a region that is considered an archetype for crustal growth during the Phanerozoic. Abundant Permian to Triassic magmatism in Mongolia extended into the Jurassic on the eastern side of the Mongol-Okhotsk Belt (MOB), the orogenic belt produced by the closure of the MOO. Magmatic belts formed north and south of the suture along the MOB provide insight into the dynamics of the subduction system and the magmatic, crustal, and mantle processes pre-, syn- and post- collision within this accretionary margin. One of the main questions regarding the magmatism in the region is: Was the magmatism formed during active subduction or during the collision and closure of the basin? Here we compile geochemical data (major and trace elements, and isotopes) from the Permian to Jurassic magmatic rocks in the MOB and analyze their spatiotemporal characteristics. Our goal is to assess how magmatism changed in time and space during the closure of the Mongol-Okhotsk Ocean and how those changes relate to first-order tectono-magmatic processes right before or during the collisional event that closed the basin. Our results show a general enrichment in fluid mobile elements, LILE, and LREE and depletion in HFSE, and HREE in mafic and felsic rocks, which indicates a mantle metasomatized by subduction-related fluids regardless of crustal contamination. Our analysis supports higher enrichment in sediment melts, especially along its western and older extent, and the assimilation of juvenile crustal components without producing abundant S-type peraluminous magmatism which indicates mantle and crustal contributions. Thus, we conclude that magmatism formed above a sediment-rich retreating margin was able to recycle and stabilize young and compositionally evolved crustal material in the Central Asian Orogenic Belt.

Central Tibetan adakitic rocks archive the critical impact of water on the Nb/Ta variation in deep crustal melts

Nb and Ta are geochemical twins, yet their ratio varies considerably in igneous rocks. It is generally supposed that felsic melts coexisting with residual rutile will have elevated Nb/Ta ratios relative to their basalt precursors, which is pivotal to our understanding of deep crustal melting and continent formation throughout Earth’s history. This study reports petrological, bulk-rock and mineral geochemical, and Sr-Nd-Mo-Hf isotopic data on Eocene adakitic rocks in central Tibet. These rocks can be petrologically and geochemically divided into an amphibole-bearing high-Nb/Ta and an orthopyroxene-bearing low-Nb/Ta group, which were formed by partially molten eclogitized lower crust based on the geochemistry of their early-crystallized minerals. The two groups have similar Sr–Nd–Hf isotope compositions and abundances of strong incompatible elements, suggesting that their source protoliths share identical compositions. Besides, the values of TiO2, Ba, Zr/Sm, and La/Yb are comparable between the two groups of rocks, eliminating the possibility of variations in Nb/Ta-sensitive minerals (e.g., rutile, amphibole, biotite, and titanite) in the source as the cause of their Nb/Ta variation. The contrasting mineral assemblages of the two group rocks, along with the higher Ce/Mo ratios and lower δ98/95Mo values in the low-Nb/Ta group, indicate the source of the low-Nb/Ta contains less water than that of the high-Nb/Ta group. These findings, combined with experimental results and trace element partial melting modeling, lead us to propose that the Drutile Nb/Ta responsible formation of the low-Nb/Ta group is higher than that of the high-Nb/Ta group, due to the decreased water content in the source. Thus, the central Tibetan adakitic rocks provide the first natural example demonstrating that the Nb/Ta ratios in felsic rocks derived from rutile-bearing eclogite depend on the physical conditions of source melting, which are not always higher than the protolith. Our study also highlights the potential of employing Mo isotopes in adakitic rocks to test this hypothesis for those that are not petrologically distinguishable.

Southernmost limit of felsic magmatism along North Almora Thrust in the Himalayan domain

We present significant findings of the Kausani Granite Gneiss within the Inner Lesser Himalayan Sedimentary Zone (iLHSZ) just north of the North Almora Thrust (NAT). The Kausani Granite Gneiss body lies within the quartzite of the Someshwar Formation and has a tectonized contact and a discordant relationship on the north side. Detailed seismic profiling across the body also confirms a similar result. Cathodoluminescence images of zircon from the Kausani body show no inheritance of older cores. The U–Pb ages from the zircon populations separated from the Kausani body give a crystallization age of 1866 ± 3 Ma. Along with the Upalda granite gneiss and Toneta granite gneiss near the Alakhnanda Thrust in the Garhwal Himalaya and the Dungeshwari granite gneiss near the Dailekh Thrust in Nepal, the Kausani Granite Gneiss north of NAT Kumaun Himalaya forms a major terrain boundary. These gneissic bodies mark the southernmost extent of felsic magmatism at NAT, rather than the Main Central Thrust. An about 1.8 billion years‐old magmatic event in the LHSZ suggests that it is a currently active continental margin inside the ‘Greater India’ region, now situated in the Himalayan domain. However, the Pb‐loss modelling of the U–Pb zircon data reveals thermal events during the Himalayan Orogeny (~45 Ma).

Understanding the extreme differentiation of granitic magmas through elemental geochemistry and Fe isotope signatures

The petrogenesis of extremely fractionated igneous rocks is closely linked to the evolution of the continental crust and the formation of rare metal mineralization. Extremely fractionated magmas evolve via fractional crystallization, hydrothermal evolution, and volatile-rich fluid–melt interaction, but the specific effects of these magmatic and magmatic–hydrothermal processes remain unclear. To understand the mechanisms by which extremely fractionated granitic magmas evolve, we characterized the geochemical and Fe isotope signatures of a suite of granites and pegmatites from the Baishitouquan (BST) granitic pluton in northwest China. The BST granitic system evolved from a high SiO2 and volatile-poor system to a low SiO2 and volatile-rich system as it transitioned from an evolutionary stage dominated by magmatic processes to one dominated by magmatic–hydrothermal processes. This transition is supported by changes in the degree of melt polymerization (NBO/T) and other geochemical indicators of fluid activity (e.g., TE1,3 (REE tetrad effect), Zr/Hf, Nb/Ta, and F/Cl ratios), suggesting that extremely fractionated granites form as a result of a combination of fractional crystallization and volatile-rich fluid–melt interactions. The bulk-rock samples of the BST pluton exhibit significant Fe isotope variability, with δ56Fe values ranging from 0.40 ± 0.02‰ in the least evolved leucogranite (Zone-a) to 0.65 ± 0.02‰ in the most evolved topaz albite granite (Zone-e). Notably, the increase in bulk-rock δ56Fe values during magma evolution is accompanied by a decrease in SiO2 contents, which is opposite to the general trend during granitic magma evolution. Given the correlations between δ56Fe values and indicators of magmatic differentiation (e.g., Fe2O3T, Rb, (Na + K)/(Mg + Ca), and (La/Lu)N), the variability in bulk-rock Fe isotope composition of granites is likely due to changes in magma composition, with garnet removal being the most likely mechanism fractionating Fe isotopes. Rhyolite-MELTS modeling, coupled with geochemical and petrographic characterization, indicate that the high concentrations of F and H2O in felsic magmas likely play critical roles in structurally modifying granitic melts by dramatically reducing their viscosity and enhancing fluid flow. The distinct geochemical–isotopic features of granites can, therefore, be used as tracers for identifying magmatic–hydrothermal processes and, potentially, rare metal mineralization.

Magma mingling in plagiogranites of the Oman ophiolite suggests an origin by fractional crystallisation

Late-stage plagiogranites in the Oman-UAE ophiolite are frequently associated with layered and massive gabbro bodies, intrusive into the mid-crustal section of the ophiolite. This study reports persuasive field evidence from five different localities for magma-mingling between plagiogranites and melts with a mafic and dioritic composition. It is argued from these relationships that mafic and felsic magmas coexisted in the same magma chamber. On this basis it is suggested that the range of melt compositions is related by a process of fractional crystallisation. The plagiogranites are interpreted as the end-product of this fractionation process and the associated gabbros are thought to be related cumulates. The hypothesis is supported with geochemical evidence which shows from the major element chemistry a continuum of compositions between the most mafic and felsic endmembers (47.6–80.6 wt% SiO2). These compositions ‘capture’ the fractionation process in operation. Modelling these variations using the major and trace element chemistry indicates that the fractionating assemblage comprised olivine-clinopyroxene-plagioclase+/−amphibole and that some plagiogranites contained cumulus plagioclase. The mafic rocks associated with late stage plagiogranite formation are derived from a highly depleted mantle source, which implies melting of an already-depleted mantle. This is consistent with previous models for the origin of the Oman ophiolite and implies a supra-subduction setting for this phase of ocean crust evolution in this ophiolite.

Evaluation of plume-induced continental crust growth rate in early Earth: Insight from integrated petrological-thermo-mechanical modeling

The origin of Earth’s felsic continental crust remains a mystery. The generation of felsic continental crust requires a two-stage partial melting from original mantle sources. There are two hypotheses for the continental crust generation in the early Earth. One is the subduction-related magmatism, e.g., island arcs, which produces intermediate to felsic magma that constitutes the early buoyant continental crust. The other is the magmatism induced by the mantle plume that creates thick basaltic crust and finally the continental crust. However, there is controversy about the origin of plate tectonics, which is an obstacle for simply applying the subduction-induced model in the early Earth. On the other hand, the efficiency of mantle plume-induced continental crust growth remains unknown. In this study, we develop a new numerical model, integrating the petrological-thermo-mechanical model with melt migration and crystallization, to evaluate the efficiency of continental crust production by mantle plumes in Earth’s history. Our results indicate that mantle plumes are considerably more effective for continental crust generation in the hot early Earth than that in the present Earth. The contribution of plume-induced continental crust growth may be greatly promoted by the possible high frequency of mantle plume generation in the early Earth than the present.

Geochemistry and mineral chemistry of granitic rocks from west Wadi El Gemal area, southern Eastern Desert of Egypt: Indicators for highly fractionated syn- to post-collisional Neoproterozoic felsic magmatism

Geochemistry and mineral chemistry of granitic rocks from west Wadi El Gemal area, southern Eastern Desert of Egypt: Indicators for highly fractionated syn- to post-collisional Neoproterozoic felsic magmatism

Late Devonian felsic magmatism in southern New Brunswick and its association with a large igneous province that may have contributed to the Frasnian-Famennian extinction

Felsic rocks of the Piskahegan Group and coeval plutons form a major part of a Late Paleozoic epicontinental caldera in southwestern New Brunswick, Canada. The caldera forms an elliptical structure with a length of ∼34 km and a width of ∼13 km. It hosts a significant polymetallic deposit of tin, molybdenum, indium and bismuth associated with mid-sequence granitic intrusions. The caldera formed in the aftermath of the late Early to Middle Devonian Acadian Orogeny during the opening of the late Paleozoic Maritimes Basin in the Northern Appalachian Belt. Its surrounding successions are largely composed of bimodal igneous rocks that were derived from two distinct sources: upper mantle-derived mafic magma and lower crust-derived felsic magma. The rocks that marked the beginning of volcanic activity in the caldera are no younger than 374.2 ± 2 Ma, whereas the uppermost dated volcanic unit in the complex yielded an age of 364.6 ± 0.7 Ma. The latter is conformably overlain by a succession of red beds and undated basalts that also overlie penecontemporaneous felsic volcanic rocks adjacent to the caldera. The post-orogenic felsic rocks are fractionated, peraluminous A-2 type rocks with silica contents ranging from ∼70 to ∼79 wt% along with high K2O contents and ɛNd(t) ranging from −0.10 to +1.05. They were generated by the melting of lower crustal basement rocks linked to a lithospheric plate that was metasomatized during the Neoproterozoic. Based on available geochemical, geophysical and structural data on Late Paleozoic rocks of southeastern Canada, the melting may have been triggered by the injection of profuse mafic magma that eventually formed a thick underplating at the base of the crust in association with heat derived from an underlying mantle plume and conveyed by transtensional structures. Basal rocks of the Piskahegan Group (the Intracaldera Sequence) and penecontemporaneous volcanic rocks in Nova Scotia are interpreted as small erosional remnants of a Large Igneous Province (LIP) based on the extensive exposure of large coeval plutons throughout southeastern Canada. The new geochronological data suggests that profuse late Frasnian magmatism in this LIP could have contributed to the environmental deterioration that led to a significant extinction at the Frasnian-Famennian boundary (the Kellwasser Event).

Double-Difference Tomography with a Deep Learning–Based Phase Arrival Weighting Scheme and Its Application to the Anninghe–Xiaojiang Fault Zone

Abstract High-precision seismic phase arrivals are a prerequisite for building reliable velocity models with travel-time tomography. There has recently been a growing use of seismic phase arrival data obtained through deep learning techniques in travel-time tomography research. Nevertheless, a significant challenge that has emerged pertains to the assessment of the quality of these automatic arrivals. In this article, we used PhaseNet, a deep learning method, to automatically detect the arrival times of the P wave and S wave of 3086 seismic events recorded by dense seismic arrays, obtaining 87,553 high-quality arrivals. To evaluate the quality of the arrival times subsequently used for travel-time tomography inversion, we applied a weighting scheme that includes both detection probability value and signal-to-noise ratio. This new weighting scheme can effectively reduce the overall travel-time residual by 7%. The weighted data were then used in the double-difference tomography method to invert for the crustal velocity structure of the Anninghe–Xiaojiang fault zone. The resulting new model exhibits a lateral resolution of up to 0.25° and reveals velocity anomalies that exhibit a strong correlation with major geological features and block boundaries. Notably, the presence of low-VP and low-VS in the middle crust of the Ludian–Qiaojia seismic zone suggests the existence of hot and weak felsic rocks, as well as possible fluid presence beneath the seismogenic layer of this area. This study not only validates the practicality of using deep learning-based phase picking arrivals in travel-time tomography but also proposes a new weighting scheme to refine the tomographic velocity models.

Evidence for Low‐Pressure Crustal Anatexis During the Northeast Atlantic Break‐Up

AbstractWhile basaltic volcanism is dominant during rifting and continental breakup, felsic magmatism may be a significant component of some rift margins. During International Ocean Discovery Program (IODP) Expedition 396 on the continental margin of Norway, a graphite‐garnet‐cordierite bearing dacitic unit (the Mimir dacite) was recovered in two holes within early Eocene sediments on Mimir High (Site U1570), a marginal high on the Vøring Transform Margin. Here, we present a comprehensive textural, petrological, and geochemical study of the Mimir dacite in order to assess its origin and discuss the geodynamic implications. The major mineral phases (garnet, cordierite, quartz, plagioclase, alkali feldspar) are hosted in a fresh rhyolitic, vesicular, glassy matrix that is locally mingled with sediments. The major element chemistry of garnet and cordierite, the presence of zircon inclusions with inherited cores, and thermobarometric calculations all support an upper crustal metapelitic origin. While most magma‐rich margin models favor crustal anatexis in the lower crust, thermobarometric calculations performed here show that the Mimir dacite was produced at upper‐crustal depths (<5 kbar, 18 km depth) and high temperature (750–800°C) with up to 3 wt% water content. In situ U‐Pb analyses on zircon inclusions give a magmatic crystallization age of 54.6 ± 1.1 Ma, consistent with emplacement that post‐dates the Paleocene‐Eocene Thermal Maximum. Our results suggest that the opening of the Northeast Atlantic was associated with a phase of low‐pressure, high‐temperature crustal anatexis preceding the main phase of magmatism.

Magmatic degassing and fluid metasomatism promote compositional variation from I-type to peralkaline A-type granite in the late Cretaceous Fuzhou felsic complex, SE China

Abstract A-type granites generally have much lower water, higher temperature, and incompatible element concentrations than I-type granitoids. Yet it remains unclear why I-A-type granitic complexes occur in convergent plate margins. Here we conduct geochemical analyses on apatite and mafic minerals from the late Cretaceous I-A-type granitic complex in Fuzhou area, SE China, aiming to decipher differentiation, fluid metasomatism, and degassing that primarily control the compositional diversity of felsic magmas. Apatites in both rock types are F-rich and show large H2O and δD variations, i.e., 341–3892 ppm H2O and –325 to +336‰ δD in I-type granitoids; 67–1366 ppm H2O and –251 to +1439‰ δD in A-type granites. H2O in apatite is negatively correlated with La/Sm and Sr/Y in the I-type granitoids, whereas it is positively correlated with Ce and total rare earth element (REE) concentrations in the A-type granites. Once H2O increases up to hundreds of ppm, both rock types show a rapid decrease of H2O/Ce, an increase of F/Cl, and extensive H isotope fractionation. Arfvedsonite occurs as a late crystallizing mineral in the A-type granite and has much higher contents of Na2O, K2O, F, and high field strength elements (HFSE) than hornblende in the I-type granitoids, indicating the addition of F-HFSE-rich alkaline fluids during its magmatic evolution. The consumption of arfvedsonite and formation of aegirine further indicate the role of fluid metasomatism and H2 degassing via a reaction of 3Na3Fe5Si8O22(OH)2 + 2H2O = 9NaFeSi2O6 + 2Fe3O4 + 6SiO2+5H2. The combined geochemical data demonstrate that the systematic differences in mineral assemblage, whole-rock composition, magma temperature, H2O content, and δD of apatite between the I- and A-type granites are likely attributed to varying degrees of differentiation, fluid metasomatism and magmatic degassing. The I-type granitoids experienced hornblende, biotite, plagioclase, K-feldspar, and apatite fractionation and close-system degassing. The A-type granite was likely formed from the I-type monzogranitic magma that was metasomatized by the mantle-derived F-HFSE-rich alkaline fluids to produce the peralkaline magma, which further experienced K-feldspar + plagioclase + biotite + apatite fractionation and open-system degassing. Further numerical estimation indicates that the primary magma of Fuzhou granitic complex contained ~3.0 wt% H2O, and the lower water content of A-type granite was likely attributed to strong degassing during its emplacement. Our results indicate that some peralkaline A-type granites can be generated from relatively water-poor I-type granitic magmas by fluid metasomatism and degassing.

Geochemistry of Neoproterozoic arenites from the Murwara area, Katni District, Madhya Pradesh: Implications for provenance, weathering and Tectonic Setting

Geochemical analysis in terms of major, trace and rare earth elements of the Neo-Proterozoic arenites of Rewa and Bhander Groups of the Vindhyan Supergroup from Murwara, Katni district, M.P., has been carried out to determine the provenance, weathering and tectonic setting. The arenites are rich in SiO2 content but less in Na2O, K2O and CaO contents, suggesting the dominance of quartz and less amount of feldspars and rock fragments. Geochemically, these rocks are classified as quartz arenites to sub litharenite to sub-arkose. The CIA (75-98) and PIA values for these arenites and A-CN-K diagram indicates a high intensity of weathering in the source area. High LREE/HREE ratios, negative Eu anomaly and La/Sc, Th/Sc, Th/Co and Cr/Th ratio values suggest felsic source of these arenites. The discriminant diagram for these arenites indicates a quartzose sedimentary provenance. Ni vs TiO2 and Th/Sc vs Sc bivariate plots indicate that the felsic rocks have been the source rock for these arenites. The discrimination diagrams based on log (K2O+Na2O) vs SiO2 and Fe2O3+MgO vs TiO2 contents show a passive margin setting. Whereas the results of new discriminant function multi-dimensional diagram for the high silica arenites reveals a change from collision to continental rift setting

Hydrothermal alteration and its geochemistry of the Xiadian gold deposit, Jiaodong Peninsula, China: Implications for fluid-rock interaction processes and mineral exploration

The interaction between hydrothermal fluids and host rocks, along with associated alteration geochemistry within the Mesozoic Jiaodong gold system, presents significant gaps in our understanding. This study systematically examines the petrographic, mineralogical, and geochemical characteristics of alteration at the Xiadian gold deposit, including comprehensive whole-rock geochemistry analyses, mass balance calculations, and phase equilibria modeling. The alteration history of Xiadian could be divided into four stages. Amid Stage 1, the predominant process involves the replacement of plagioclase by K-feldspar-albite, accompanied by the simultaneous bleaching of amphibolite and associated significant depletion of MgO (ΔCi/CiO = −21.2 %) and Fe2O3 (−27.2 %) owing to the decomposition of mafic minerals. Stage 2a involves sericitization of albite and continued mafic mineral decomposition, resulting in the lowest recorded MgO (avg. 0.23 wt%) and Fe2O3 (avg. 0.92 wt%) contents in all alteration lithologies. Stage 2b is characterized by abundant chlorite vein formation, corresponding to the proximal enrichment of MgO (158.1 %) and Fe2O3 (108.2 %), accompanied by aMg2+/(aH+)2 decreased in the fluid. Stage 3, the main stage of gold mineralization, involves chlorite substitution with sericite during quartz-sericite-pyrite (QSP) alteration, suggesting mild acidification of the ore-forming fluid. Insights from phase equilibrium modeling suggest that sulfidation has contributed to gold precipitation, leading to increased fO2 and reduced fH2S (extending into quartz-carbonate alteration of stage 4). Mass balance calculations indicate gold is enriched compared to protolith at all stages, with the most intense enrichment in stage 3. This suggests that hydrothermal fluids at Xiadian were auriferous throughout their evolution. The process may induce fluid modifications, particularly through the dissolution of mafic minerals, more so in mafic mineral-rich rocks (e.g., amphibolite) than in granite, promoting the incorporation of hydrothermal chlorite into the Au system to contribute to sulfidation. Our results provide insights into lithology controls on gold mineralization at Xiadian, indicating that felsic rocks (Linglong granite and quartz porphyry) with lower initial CaO contents often develop K-metasomatism and Au-bearing QSP alteration, while mafic rocks (amphibolite and lamprophyre) with higher CaO contents develop carbonization. This is likely due to the influence of lower CaO contents on alteration minerals, which promote rock porosity, affecting rock deformation, pore-fluid flow, and reacting with wall rocks. Principal component analysis (PCA) results indicate that elements including Au, Ag, As, Bi, W, and Cu are proxies for Au mineralization, suggesting their mobilization and deposition together during the gold mineralization process. This highlights their significance as a proxy for gold exploration.

Integrated approach for geothermal exploration: Case study from Salar area (Afyonkarahisar, Turkey)

The intense investment demand in the geothermal sector in Afyonkarahisar province in recent years has enabled the utilization of geothermal waters such as district heating and greenhouse heating, electricity generation, and spa facilities and accelerated the exploration of new geothermal areas in the region. In this study, the Salar (Afyonkarahisar) region's geothermal potential was investigated using the mineralogy and geochemistry of hydrothermal alteration, hydrogeochemistry, and resistivity models obtained from magnetotelluric data. The Salar region is located within the Afyon-Akşehir Graben (AAG) and 10 km south of Afyonkarahisar province. The most important manifestations of the geothermal system are the geothermal water at temperatures of 25 °C and 31 °C obtained from the boreholes and hydrothermal alteration in Salar. Afyon volcanoclastics are reservoir rocks. Smectite and illite are the most important clay minerals in the hydrothermal alteration zones. The transformation from volcanic glass and alkali feldspar to smectite and illite reflects neutral-alkaline alteration conditions in felsic rocks. The clay minerals' stable isotopes (δD and δ18O) indicate hypogene conditions. Discharge temperature, electrical conductivity and pH of Salar region geothermal waters vary from 25 to 31 °C, 320–357 µs/cm, and 6.8, respectively. The Salar geothermal waters are Ca-(Na)-HCO3 type chemically. The electric resistivity models reveal shallow low resistivity (10 < ρ < 80 Ωm) layer related to the alluvium, Gebeceler formation, and Afyon volcanoclastics and deeper high resistivity (80 <ρ < 200 Ωm and ρ > 200 Ωm) layer based on Deresinek and Değirmendere formation respectively. The difference in electrical resistivity arises from the geothermal waters and hydrothermal alteration zones, influenced by the AAG tectonics.The stable isotopes (δD and δ18O) and alpha cristobalite geothermometer calculations indicate that the condition of the temperature in the active and fossil geothermal systems in the Salar does not change, and the condition of the temperature is between 44 °C and 112 °C.

Evolution of a large-scale phreatoplinian eruption: Constraints from the 40 ka caldera-forming eruption of Kutcharo volcano, eastern Hokkaido, Japan

“Phreatoplinian” is an explosive phreatomagmatic eruption style that is defined by the fragmentation of magma and widespread dispersal of the resulting fine ash and accretionary lapilli. These eruptions pose significant future risks at caldera volcanoes that host lakes and abundant groundwater. There have been no direct observations of a phreatoplinian eruption, therefore, constraining the detailed mechanisms and sequences of such events relies on studying the deposits of previous eruptions. In order to advance our understanding of these hazardous phenomena we conducted a case study of the 40 ka caldera-forming eruption (Kp I) from Kutcharo volcano in eastern Hokkaido, Japan. We subdivided Kp I eruption deposits into 7 units (Units 1 to 7 in ascending order). Units 1 to 6 are air fall deposits consisting of alternating thin pumice and thick silty ash layers with abundant spherical accretionary lapilli. Stratigraphically higher ash fall units are thicker, finer in grain-size, and more widely distributed. The maximum eruption column height and mass-discharge rate were calculated to be 40 km and 1.4 × 109 kg/s, respectively. Unit 7 is a climactic ignimbrite (76 km3), which is distributed widely over the area north of Kutcharo caldera.Unit 6 is the largest air fall unit and can be considered to have been deposited by a phreatoplinian eruption, given its abundant accretionary lapilli, wide dispersion, and high degree of fragmentation. Unit 6 had the highest mass discharge rate (1.4 × 109 kg/s), suggesting the interaction between magma and external water was most intense, and it is thought that a large eruption column covered eastern Hokkaido. In addition, Kp I eruption deposits commonly contain glass shards derived from fragmentation via both magma degassing and Molten Fuel Coolant Interaction (MFCI). To account for this observation, we infer that the conduit penetrated a large aquifer, and the margin of the ascending magma came into contact with this external water source. Due to repeated caldera-forming eruptions, intra-caldera filled deposits (hosting a large aquifer) likely played a key role in supplying external caldera lake water to a level near the fragmentation depth of H2O-saturated felsic magma. The occurrence of these intra-caldera conduit and caldera-lake systems may provide the required conditions for phreatoplinian eruptions at continental arc caldera volcanoes in Japan and globally.

Magmatic sulfide oxidation drives crustal PGE mobilization: Implications for hydrothermal PGE mineralization

Platinum-group elements (PGEs) have a strong affinity for sulfur and tend to accumulate in the deep continental crust, either concentrated within magmatic Cu-Ni-PGE deposits or dispersed throughout disseminated sulfides. However, PGE enrichment in shallow magmatic-hydrothermal systems implies an obscure link to deep sulfide destabilization, which releases PGEs into ore-forming fluids. To bridge this gap, our study investigates the PGE composition of magmatic sulfides with oxidative textures in dacitic rocks from the southwestern Okinawa Trough. We identified three groups of magmatic sulfides, primarily precipitated as Cu-poor monosulfide solid solution (MSS), which formed at distinct stages of magma evolution from deep to shallow crustal levels. Group A sulfides manifest as small-sized inclusions (<30 μm) within most high-Mg olivines, whereas Group B and C sulfides are larger (50–500 μm) and occur within cognate xenoliths of mafic cumulate rocks and the groundmass of host dacites. Group B and C sulfides exhibit distinct oxidative textures and newly-formed mineral assemblages, including magnetite, hematite, goethite, and magnetite ± pyrite, alongside hydrothermal silicate minerals, respectively. We attribute the oxidation process to the infiltration of orthomagmatic fluids exsolved from mafic magma that had underplated the sulfide-bearing felsic magma reservoir, which was nearly solidified. By comparing the chemical compositions between pristine sulfides and their oxidative remnants, we observed extensive mobilization of Pd, Pt, Cu, Ag, Ni, and Co from the altered sulfides of Group B, while Au enrichment occurred as nanoparticles under high oxidation states. In contrast, Au was extracted along with other mobile metals from the altered sulfides of Group C, with Pt remaining in place under more reduced conditions. These distinct scenarios may lead to the formation of PGE-rich and Au-rich fluids, respectively. The formation of deep crustal MSS and subsequent hydrothermal oxidation under varying redox conditions thus provides a viable mechanism for trans-crustal PGE mobilization and inter-element fractionation, typical of PGE-rich magmatic-hydrothermal deposits.

Late Jurassic granitoids in Mufushan complex and their significance for the Mesozoic tectonic evolution of eastern South China

The Mesozoic tectono-thermal evolution of eastern South China plays an important role in forming the abundant magmatic rocks and associated giant polymetallic deposits. The middle-late Mesozoic granitoids in Mufushan and adjacent regions (e.g., Lianyunshan, Wangxiang, Taohuahsan, etc.) represent the western front of the southeast China magmatic province. However, the tectonic regimes and petrogenesis of the magmatic rocks are still elusive. Here, we report zircon UPb ages, geochemistry, and Sr-Nd-Hf-Pb isotopic data for the granitic rocks in the Mufushan region, in combination with data available from the literatures, to discriminate the middle-late Mesozoic tectono–magmatic history of the Mufushan complex in north-central South China Block. New zircon UPb dating suggests that the Mufushan two-mica monzogranites were emplaced at 149–144 Ma, a short time after the 153–151 Ma granodiorites. These late Jurassic felsic magmas share broad similarities in geochemical-isotopic characteristics, with significant enrichment in LREEs and LILEs (e.g., Ba, Rb, Th, and K), depletion in some HFSEs (e.g., Nb, Ta, Ti, and P) and positive Pb anomalies, similar to those of arc-type rocks. The common existence of Neoproterozoic zircons within the magmatic rocks indicates a certain amount of ancient material involved in the genesis of the magma. The two-mica monzogranites have εHf(t) values ranging from −13.4 to +3.5, overlapping with those of the granodiorites (−11.3 to +6.6), but both are lower than contemporaneous diorites (−2.4 to +0.59), suggesting a greater incorporation of enriched materials into the source for the granitoids. The two-mica monzogranites and granodiorites have εNd(t) values ranging from −7.9 to −8.8 and − 10 to −7.9, with corresponding two-stage Nd model ages of 1.7–1.6 Ga and 1.6 Ga, respectively, falling within their two-stage Hf model ages of 2.0–1.4 Ga and 1.8–1.4 Ga, respectively. Compared with the geochemical and isotopic compositions of the coeval magmatic rocks in eastern South China, we favor that the late Jurassic Mufushan granodiorites evolved from variable mixing and differentiation of the diorites and granitoids, accompanied by a continuous magma assimilation. The presence of late Jurassic highly fractionated granites suggests an extensive magma differentiation in eastern South China and the well-developed early Cretaceous A-type granites in eastern South China reflect a dominant extensional tectonic regime induced by slab roll-back of the Izanagi plate. The involvement of subduction-related melts facilitated the underplating of mantle-derived magma and crustal heating, triggering intensive partial melting of the lithosphere and magma enrichment, as well as the polymetallic deposits in eastern South China.

Magmatic-hydrothermal evolution and rare metal enrichment of the Huoshibulake B-rich rare metal granite in the Southern Tianshan: Insights from texture, geochemistry, and Hf[sbnd]O isotopes of zircon

Deciphering magmatic-hydrothermal evolution and rare metal mineralization mechanisms in granitic systems is always challenging, particularly when elucidating the intricate details of magmatic-hydrothermal transition, the critical stage when the system changes from melt-driven to fluid-driven with associated metal extraction. Here we present a case study of the Huoshibulake Nb-REE-mineralized alkali pluton in the north margin of the Tarim Carton, China. The pluton exhibits abundant tourmaline-quartz orbicules and tourmaline-quartz veins, which are the products of immiscible B-rich melt exsolved during the magmatic-hydrothermal transition. Three types of zircon crystals with different morphology have been recognized in the pluton: antecrystic, autocrystic and hydrothermal zircons, the latter two representing the melt and fluid parts of the system. LA-ICP-MS UPb dating of autocrystic zircon from granite and orbicule samples (206Pb/238U ages of 274.8 ± 1.5 and 273.6 ± 2.0 Ma, respectively) and cassiterite from the vein sample (lower 206Pb/238U intercept age of 271.4 ± 4.1 Ma) overlap within error. The similar trace-element patterns and near-identical O-isotopic compositions between hydrothermal and autocrystic zircons indicate that the hydrothermal zircons were crystallized from magmatic fluids. Zircon HfO isotopic systematics suggests that the coeval A1-type granites in the Halajun area evolved from a single parental magma chamber which originated from ∼30% of the upper crustal material mixed with ∼70% mantle-derived mafic magma. Whole-rock compositional trends reveal that fractional crystallization of felsic minerals contributed to the rare metal enrichment. The rare metal mineralization in the veins and the close association of rare metal mineralization with fluorite indicate the critical role of F-rich hydrosilicate liquids in rare metal mineralization, which is also recorded by the significant increase of rare metal concentrations from the autocrystic to the hydrothermal zircon grains.

Disputed tectonic setting for the late Silurian–early Carboniferous development of the northern New England Orogen: detrital zircon ages suggest a continental margin arc association

Devonian successions in the Calliope and Yarrol provinces of the northern New England Orogen in central to northern Queensland have a lithological assemblage and depositional environments indicative of a close association with a subduction-related volcanic arc. These rocks have been interpreted as related to island arc and backarc settings based on geochemical characteristics of magmatic rocks. We present new detrital zircon ages from the Devonian to lower Carboniferous successions of the Calliope and Yarrol province successions. Most samples have no or relatively few zircon grains extracted except for samples of quartz-rich sandstone in the Middle Devonian Erebus beds of Hunter Island, located 160 km north-northwest of Rockhampton and another sample in the Rockhampton district. The samples with abundant zircon, and some with less common zircon, have prominent peaks of mid Cambrian to Ordovician ages and are consistent with derivation from the northern Thomson Orogen where igneous rocks of this age are documented in the Charters Towers Province. These data indicate a connection between the Devonian arc-flank deposits of the northern New England Orogen and the Thomson Orogen, which had previously been well established for Carboniferous deep-marine sandstones of the subduction complex (e.g. Shoalwater Formation). These results favour an east-facing continental margin arc setting in the Devonian contra to intra-oceanic island arc settings previously proposed. Detrital zircon age spectra from sampled early Carboniferous units of northern New England Orogen association indicate a pulse of felsic magmatism of that age.

Research on the Diagenetic Facies Division and Pore Structure Characteristics of the Chang 63 Member in the Huaqing Oilfield, Ordos Basin.

In tight sandstone reservoirs, diagenesis has a significant impact on the development of reservoirs and pore structures. To clarify the effect of diagenesis on the pore structure of tight sandstone, 12 samples of the Yanchang Formation in the basin were studied based on experiments such as high-pressure mercury intrusion and low-temperature nitrogen adsorption. The diagenetic facies in the study area are divided into two categories: strong cementation facies of carbonate minerals and strong compaction facies of soft component minerals, which are relatively unfavorable diagenetic facies, and stable facies of felsic minerals and strong dissolution facies of feldspar minerals, which are dominant diagenetic facies. The pore structure of the Chang 63 reservoir in the study area has obvious fractal characteristics, with a fractal dimension D 1 greater than D 2 and a greater heterogeneity of large pore throats. Compared to compaction and cementation, dissolution has a stronger controlling effect on the pore structure of reservoirs. In tight sandstone reservoirs with low porosity and permeability, dissolution has a more important impact on reservoir transformation and development. The intensity of different types of diagenesis in the Chang 63 reservoir affects reservoir heterogeneity, and the level of the reservoir heterogeneity affects the complexity of reservoir pore structure. In tight sandstone reservoirs, cementation has a stronger controlling effect on the structural complexity of large pores, while dissolution has a stronger controlling effect on the structural complexity of small pores. The dissolution has a strong control effect on the physical properties of the reservoir. This study provides insights into the relationships among the diagenetic facies, reservoir quality, and pore structure of tight sandstone reservoirs. This study has reference significance for the exploration and development of tight oil in the research area.