Optical high-resolution spectroscopic observations of the emission-line star MWC645 are presented. The spectrum exhibits strong variable double-peaked Balmer emission lines as well as low-excitation emission lines of FeII, [FeII], and [OI] which are signatures of the B[e] phenomenon, while lines of helium have not been found. In addition to the emission lines, for the first time we identified absorption lines of neutral metals (e.g., LiI 6708 A, CaI 6717 A, and a number of FeI and TiI lines) that indicate the presence of a cool component in the system. The heliocentric radial velocity measured in our best spectrum was found to be −65.1±1.0 kms −1 for the emission lines and −23.2±0.4 kms −1 for the absorption lines. Using a combination of photometric and spectroscopic data as well as the Gaia EDR3 distance (D=6.5±0.9 kpc), we disentangled the component contributions and estimated their temperatures and luminosities (∼15000 K and ∼4000 K, log L/L ? = 3.8±0.2 and 2.8±0.2 for the hot and cool component, respectively).
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