In this work, the stability and synchronization issue of switched singular continuous-time fractional-order systems with nonlinear perturbation are examined. Using the fixed-point principle and S-procedure lemma, a sufficient condition for the existence and uniqueness of the solution to the switched singular fractional-order system is first stated. Next, using the Lyapunov functional method in combination with some techniques related to singular systems and fractional calculus, a switching rule for regularity, impulse-free, and Mittag-Leffler stability is developed based on the formation of a partition of the stability state regions in convex cones. For synchronizing switched fractional singular dynamical systems, we propose a state feedback controller that ensures regularity, impulse-free, and Mittag-Leffler stable in the error closed-loop system. Finally, the ease of use and computational convenience of our proposed methods are illustrated by two numerical examples and a practical example about DC motor controlling an inverted pendulum accompanied by simulation results.