Abstract White dwarfs play important roles in stellar evolution and help us gauge the age of our galaxy. The white dwarf H1504+65, the hottest known post-asymptotic giant branch star, is peculiar due to its C- and O-rich but He- and H- deficient atmosphere whose composition cannot be well predicted by current stellar evolution models. The analysis of the elemental abundance and the benchmark of stellar atmospheric models depends heavily on spectral data under cosmic conditions, which are currently extremely scarce. We created a well-defined, uniform, relatively large-scale ∼millimeter plasma sample in the laboratory with a temperature and a C/O ratio similar to those of H1504+65’s atmosphere. The emission spectra with high precision in the range of 10–80 nm were obtained and identified according to databases such as NIST and Kelly. A detailed comparison between our emission lines and the Chandra-observed white dwarf H1504+65 atmosphere’s absorption lines was performed. The stongly isolated O VI lines in the range of 10–13 nm are observed in both cases. We observed a wealth of O V lines in the range of 13–14 nm that cannot be well identified or predicted by models due to the weak flux and also probably due to the blending effect of Fe group elements in the Chandra spectrum. Long-wavelength lines ranging from 14 to 80 nm, which are not observed in the Chandra spectrum because of the high interstellar neutral hydrogen column density, show abundant O IV-V, C IV lines, and strong O VI lines. Moreover, the intensities of the lines at 62.973 and 17.216 nm are analyzed to characterize the plasma temperature.