The background PM10 concentration in the Western Macedonia region, a complex terrain area with combined urban and industrial emission sources is investigated in this study. PM10 measurements were collected from a remote agricultural monitoring site situated in the southern part of the region and outside the industrial basin over a 12-year period (2010–2021). The ongoing reduction in lignite production during the last decade resulted in considerable changes in particulate emissions in the area. To take into account the changes in the air quality of the region the whole period was divided into two subperiods of common air pollution characteristics. For each period, Hidden Markov Models clustering was applied to the deseasonalized daily PM10 concentrations and the corresponding diurnal amplitudes to extract groups of similar characteristics (clusters) and define the background pollution. The average background concentration was estimated at 15.9 μg/m3 during the period 2010–2015 followed by a decrease of 3.1 μg/m3 to 12.8 μg/m3 during the second study period (2016–2021). The examination of the long-term changes in the background concentration revealed a statistically significant decreasing annual trend of −0.39 μg/m3 that reflected the air quality improvement of the region during the last decade. Additionally, background concentrations co-existed with favorable meteorological conditions such as higher wind speeds during the cold period (October–March) diminishing the contribution of local anthropogenic emissions (biomass burning for heating purposes) and a less developed mixing layer during the warm period (April–September) impeding the impact of the particulate plumes from the nearby power plants.
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