The crystal structure of a novel MAX phase is determined using X-ray powder diffraction, spherical aberration corrected transmission electron microscopy, and first-principles calculations. In the new V–Sn–C system, the R 3‾ m space group aligns more closely with the experimental data than the P63/mmc space group. The lattice parameters of the new trigonal V2SnC phase are a = 0.291 nm and c = 2.08 nm. Moreover, the surface of the new phase has a tin-doped carbide face-centered cubic (FCC) structure reconstruction layer. First-principles calculations indicate that the new trigonal V2SnC phase is metastable compared with the hexagonal V2SnC phase. However, the thermal stability of the metastable trigonal V2SnC in air is significantly enhanced owing to the presence of the reconstruction layer.
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