High Temperature Fabrication Research Articles

Fabrication of high temperature chirped FBG by thermal stretching of regenerated FBG

This paper presents an innovative method of high temperature sustainable chirped fiber Bragg grating (FBG) fabrication from the uniform regenerated FBG or their combination written by a single uniform phase mask. A thermal stretching technique is employed that modifies the grating structure of uniform FBGs, resulting in chirped FBGs capable of withstanding high temperatures without compromising their sensing capabilities. Thermal regeneration of uniform FBG was carried out at 850 °C by applying step annealing schedule. Thermal stretching of single regenerated FBG and dual regenerated FBG was carried out for the fabrication of high temperature chirped FBG. For both approaches, the FBG was stretched by applying strain ∼1200 µε along the length of the grating. In the single FBG approach, the chirped grating with reflection intensity 4500 (A.U.) and bandwidth ∼ 7.1 nm was fabricated by applying thermal gradient from 860 °C to 900 °C across the length of strained thermally regenerated FBG. In double grating approach, the chirped FBG with reflection intensity 6000 (A.U.) and bandwidth 12.7 nm was fabricated. The fabricated chirped FBG can sustain temperature upto 900 °C. This innovative method not only extends the operating range of chirped FBGs to high temperatures but also opens up new possibilities for fabricating chirped FBGs of longer length and bandwidth using low-cost uniform FBGs.

Fabrication and development of high temperature resisted bronze composites using 3D printed gate pattern through stir casting route

Fused deposition modeling (Additive manufacturing method) is used for printing the gate pattern by considering Acrylonitrile butadiene styrene (ABS), alumina (Al2O3), and silicon carbide (SiC) as raw material. The three compositions of feedstock filaments are ABS −2% Al2O3 − 0. wt % SiC, ABS −2% Al2O3 − 3. wt % SiC and ABS −2% Al2O3 − 6. wt % SiC, which are produced by using melt flow extruder. The melt flow index of three compositions are determined as 2.413 /10 min, 2.403/10 min and 2.389/10 min which are near to ABS melt flow index of 2.44 / 10 min. The gate pattern is prepared by fusion deposition modeling method by considering parameters such as SiC reinforcement (wt %), raster inclination and infill density and best optimal parameter for producing pattern comprising high tensile strength and high flexural strength using Technique Order Preference Similar to Ideal Solution (TOPSIS). The best set of optimal parameter for printing the gate pattern was found out as ABS −2% Al2O3 −6 wt% SiC, infill density of 50 % and raster inclination 0°. This pattern exhibited average surface roughness of 12.6 µm, tensile strength of 40.5 MPa and flexural strength of 73.1 MPa. The lowest tensile strength of 29.3 MPa was observed for 3 % SiC, 50 % infill density and 30° raster orientation. Using the printed gated pattern via stir casting process, four different compositions of bronze composites are synthesized such as Cu-Sn- 0 wt% B4C, Cu-Sn- 2 wt% B4C, Cu-Sn- 4 wt% B4C and Cu-Sn- 6 wt% B4C. Cu-Sn- 2 wt% B4C composite exhibited maximum hardness, tensile strength and impact strength of 55 HRC, 323 MPa and 279 N/mm2 respectively. The lowest tensile strength, lowest hardness and maximum deviation in dimension of 323 MPa, 38 HRC and 0.144 mm was found out for Cu-Sn-6 wt% B4C. The best optimized pattern: ABS −2% Al2O3 −6 wt% SiC, infill density of 50 % and raster inclination 0° was used as a pattern for producing seven casted cubes (Cu-Sn-2 wt% B4C) which shows average dimension of ± 0.12 mm.

Anchoring groups for ordered and highly stable monomolecular films on naturally oxidized aluminum – phosphonate versus carboxylate

Modification of metal oxide surfaces by self-assembled monolayers (SAMs) is attracting growing attention. Carboxylic (CA) and phosphonic (PA) acids are most popular anchoring groups in this context, applied to create hydrophobic coatings, biosensors, and organic field-effect transistors. The efficiency of these devices is crucially affected by the structural quality and stability of the SAM. In this context, we studied the effect of the preparation procedure (solvent, incubation time, and temperature) on the quality of PA SAMs on naturally oxidized aluminum. We demonstrate formation of PA SAMs matching structural quality of archetypical alkanethiols on gold. Next, we compare their stability with analogous CA SAMs. Our data show that PA SAMs not only exhibit much higher hydrolytic stability but are also capable to protect aluminum substrate from oxidation and degradation. Importantly, even small improvement of the PA SAMs quality, translates into enormous increase of their hydrolytic stability crucial for majority of applications. Finally, we demonstrate that the thermal stability of PA on oxidized aluminum is by ∼250 K higher than CA SAMs, and by ∼200 K higher than for thiols on gold, which makes PA SAMs an excellent candidate for organic electronics, where overheating problems and high-temperature fabrication procedures are common issues.

Design, fabrication and test of high temperature superconducting magnet for heat flux and radio blackout mitigation experiments in plasma wind tunnels

High heat flux and radio blackout are well-known challenges space vehicles have been facing during re-entry into a planet’s atmosphere since the early days of space-flight. Thermal protection systems have been developed to protect spacecraft and astronauts, however, they are often heavy and some have to be replaced after each mission. High temperatures in the compressed gas in the shock wave lead to partial ionization. The dense plasma can cause radio blackout, i.e. attenuation or reflection of radio waves thus blocking data-telemetry and communication with ground stations or satellites. One approach to solve both problems is to influence the plasma with magnetohydrodynamic effects using a strong magnet. In the framework of the European project MEESST (Magnetohydrodynamic Enhanced Entry System for Space Transportation) heat flux mitigation and radio blackout mitigation is investigated by means of modelling and ground experiments in plasma wind tunnels at the Institute of Space Systems (Stuttgart, Germany) and at the Von Karman Institute for Fluid Dynamics (Brussels, Belgium) using an HTS magnet. After a short introduction to the scientific background of the MEESST project, the boundary conditions for the design of the magnet and calculations of field distributions are presented. The pancake coils of the magnet were wound with a robotic winding system. Results from a preliminary test of the conduction-cooled magnet are presented.

Low-temperature aluminum doped and induced polysilicon and its application as partial rear contacts on p-type silicon solar cells

Low-temperature contact techniques offer benefits for various solar cells, including tandem solar cells, which risk degradation from high-temperature contact fabrication for top cell materials, such as in III-V/Si multijunction cells. This paper presents aluminum (Al) doped and induced poly-Si (formed through annealing at 190 °C for 5 min) as localized contacts on p-type silicon absorbers. This approach avoids the high-temperature processes required for poly-Si formation and the toxic gases involved in in-situ doping through chemical vapor deposition. Raman spectroscopy confirms poly-Si formation due to Al-induced recrystallization of a-Si:H(i), with electrochemical capacitance-voltage (ECV) measurements validating Al doping in the newly-formed poly-Si. The contact stack of p-Si/a-Si:H(i)/Al exhibits ohmic behavior after annealing at 190 °C for 5 min, achieving a contact resistivity of ∼13.2 mΩ⋅cm2. Finally, a cell featuring a localized Al-doped poly-Si contact structure is fabricated, realizing a 3% absolute efficiency improvement compared to a full-area Al back contact cell.

Toughening and strengthening of Cu-coated carbon nanotubes reinforced AZ61 magnesium matrix nanocomposites by improving interfacial bonding

Interfacial modification without damaging the structure of carbon nanotubes (CNTs) is urgently needed to improve the performance of CNTs reinforced metal matrix nanocomposites. To fabricate CNTs/AZ61 nanocomposite with strong interfacial bonding, copper-coated CNTs (0.15–2.4 vol%) and AZ61 powder were employed through the process of ball milling mixing, vacuum hot pressing and extrusion. The powder and nanocomposites were characterized by HRTEM, SEM, XRD and compressive test to study the distribution of reinforcements, microstructures, interfacial structure and compression behavior. During the high-temperature fabrication process, in-situ interfacial reactions occurred between Cu particles of CNTs and Mg, Al and Zn elements in AZ61 matrix. As a result, the formation of interfacial reaction phases, such as AlCu3, Al2Cu, Cu2Mg, CuMg2, Cu0.61Zn0.39 and MgAl2C2 phases, and their diffused and/or coherent interface significantly strengthen the interfacial bonding. With only 0.15 vol% CNTs, the work of fracture and compression strength of the composite are 40 % and 20 % higher than those of pure AZ61, respectively. The dominating toughening mechanisms are the load transfer role of scattered CNTs and fine-grain effect. The dominating strengthening mechanisms are thermal mismatch and Orowan strengthening.

Ternary cobalt ferrite (CoFeO4)-silver (Ag)-titanium dioxide (TiO2) hybrid nanofluid hydromagnetic nonlinear radiative-convective flow from a rotating disk with viscous dissipation, non-Darcy and non-Fourier effects: Swirl coating simulation

Magnetic nanoparticles are increasingly being deployed in smart coating systems due to their exceptional functionalities and abilities to be tuned for specific environmental conditions. Inspired by the emergence of tri-hybrid magnetic nanofluids which utilize three distinct nanoparticles in a single base fluid coating, the present article examines analytically and computationally the swirl coating of magnetic ternary hybrid nanofluid from a rotating disk, as a simulation of spin coating deposition processes in materials manufacturing. Owing to high temperature fabrication conditions, thermal radiative heat transfer is also considered and a Rossleand flux model deployed. -- hybrid nanoparticles are considered with Ethylene Glycol-Water () base fluid. A filtration medium is also featured (porous medium) adjacent to the disk and the Darcy-Forchheimer model is deployed to simulate both bulk matrix porous drag encountered at lower Reynolds numbers and inertial quadratic drag generated at higher Reynolds numbers. Thermal relaxation of the coating nanofluid is additionally addressed and a non-Fourier Cattaneo-Christov model is therefore implemented in the heat conservation equation. Viscous dissipation is also included in the model. The governing conservation equations for mass, momenta (radial, tangential and axial) and energy with prescribed boundary conditions are rendered into coupled nonlinear ordinary differential boundary layer equations via suitable scaling variables and the Von Karman transformations. The derived reduced boundary value problem is then solved with a Runge-Kutta numerical scheme and shooting scheme in MATLAB. Validation of solutions is included with previous studies. Radial and azimuthal velocities, temperature, radial skin-friction, azimuthal skin friction and local Nusselt number are computed for a range of selected parameters. A comparative assessment of mono nanofluid Hybrid - nanofluid and tri-Hybrid -- nanofluid is conducted. This combination of hybrid nanoparticles has never been examined previously in the literature and constitutes the significant novelty of the present work. Both radial and tangential velocity are depleted with increasing applied magnetic field whereas temperature and thermal boundary layer thickness are increased.

(Bi,Sb)2 Se3 Alloy Thin Film for Short-Wavelength Infrared Photodetector and TFT Monolithic-Integrated Matrix Imaging.

Short-wavelength infrared photodetectors play a significant role in various fields such as autonomous driving, military security, and biological medicine. However, state-of-the-art short-wavelength infrared photodetectors, such as InGaAs, require high-temperature fabrication and heterogenous integration with complementary metal-oxide-semiconductor (CMOS) readout circuits (ROIC), resulting in a high cost and low imaging resolution. Herein, for the first time, a low-cost, high-performance, high-stable, and thin-film transistor (TFT) ROIC monolithic-integrated (Bi,Sb)2 Se3 alloy thin-film short-wavelength infrared photodetector is reported. The (Bi,Sb)2 Se3 alloy thin-film short-wavelength infrared photodetectors demonstrate a high external quantum efficiency (EQE) of 21.1% (light intensity of 0.76µWcm-2 ) and a fast response time (3.24µs). The highest EQE is about two magnitudes than that of the extrinsic photoconduction of Sb2 Se3 (0.051%). In addition, the unpackaged devices demonstrate high electric and thermal stability (almost no attenuation at 120°C for 312h), showing potential for in-vehicle applications that may experient such a high temperature. Finally, both the (Bi,Sb)2 Se3 alloy thin film and n-type CdSe buffer layer are directly deposited on the TFT ROIC (with a 64×64-pixel array) with a low-temperature process and the material identification and imaging applications are presented. This work is a significant breakthrough in ROIC monolithic-integrated short-wavelength infrared imaging chips.

Fabrication of Ultra-Stable and Customized High-Temperature Speckle Patterns Using Air Plasma Spraying and Flexible Speckle Templates.

Reliable and accurate full-field deformation measurements at elevated temperatures using digital image correlation (DIC) require stable and high-contrast high-temperature speckle patterns to be prepared on the sample surface. However, conventional high-temperature speckle patterns fabricated by the existing methods possess several limitations, e.g., easily fail to preserve original pattern features due to the harsh environment and heavily dependent on the operator's experience. In this study, we propose a reliable and reproducible high-temperature speckle fabrication method based on air plasma spraying (APS) and flexible speckle templates. This method involves covering the sample surface with pre-designed speckle templates and then spraying the melted speckle powders onto the specimen surface using an air plasma spray technique to obtain customized speckle patterns. The validity of the proposed method was verified by the speckle fabrication on both planar and curved samples and heating tests with these samples. Experimental results demonstrate that the speckle patterns made by the proposed method adhere well to the sample surface, remain stable during the heating process, and exhibit excellent agreement with the reference values in terms of the thermal expansion coefficients. The proposed method provides a reliable and efficient way to create customized and stable speckle patterns for accurate high-temperature DIC measurements.

Recommendation of SLM Process Parameters Based on Analytic Hierarchy Process and Weighted Particle Swarm Optimization for High-Temperature Alloys.

Selective laser melting (SLM) of high-temperature alloys involves intricate interdependencies among key process parameters, such as laser power and scanning speed, affecting properties such as density and tensile strength. However, relying solely on experiential knowledge for process parameter design often hampers the precise attainment of target requirements. To address this challenge, we propose an innovative approach that integrates the analytic hierarchy process (AHP) and weighted particle swarm optimization (WPSO) to recommend SLM process parameters for high-temperature alloy fabrication. Our proposed AHP-WPSO model consists of three main steps. First, a comprehensive historical database is established, capturing the process parameters and performance metrics of high-temperature alloy SLM parts. Utilizing an AHP framework, we compute the performance similarity between target and historical cases, applying rational thresholds to identify analogous cases. When suitable analogs are elusive, the model seamlessly transitions to the second step. Here, the WPSO model optimizes and recommends process parameters according to target specifications. Lastly, our experimental validation of the GH4169 high-temperature alloy through SLM experiments corroborates the effectiveness of our AHP-WPSO model in making process parameter recommendations. The outcomes underscore the model's high accuracy, attaining a recommendation precision of 99.81% and 96.32% when historical analogs are present and absent, respectively. This innovative approach offers a robust and reliable solution to the challenges posed in SLM process parameter optimization for high-temperature alloy applications.

Tribological performance for an Mg alloy subjected to sliding at elevated temperatures: A comparison between Al2O3 and MoS2 nano additives in silicone oil-based lubricant

Magnesium (Mg) and its alloys are crucial for energy-efficient vehicles due to their strong and lightweight properties, necessitating high-temperature fabrication and lubrication to reduce oxidation, friction, and wear. This paper investigated the tribological performance of lubricating oil using different particles to a Mg alloy subjected to contact sliding in an open system at high temperatures up to 250 °C. The overall experimental results showed improved tribological performances by using the two types of nanoparticles / nanoparticle-clusters (concentration ≥ 0.5 wt%) compared with the base silicone oil. The mechanisms by which the two types of nano lubricants improved the tribological performance are different. Al2O3 particles provided a more stable Al-rich anti-wear surface at higher temperatures in the range of 200–250 °C, while a tribo-chemical reaction film was formed with MoS2 additives, generating MoO3 and MgSO4. It is generally concluded that Al2O3 has more positive effect in terms of reduced coefficient of friction and wear rate as comparison to MoS2.

Investigation on compaction pressure and sintering temperature suitable for Nimonic 90 superalloy

Fabrication of high strength, high temperature and corrosion resistant materials provide much assistance in aerospace, automotive, chemical and oil industries, as they have to withstand severe operating conditions. Traditionally, superalloys are widely used under these conditions that are prepared by casting method. Nowadays, powder metallurgy technique is gaining importance for preparing superalloys because of its capability of making homogeneous microstructure with near-net-shape. In this significant context, the processing of Nimonic 90 superalloy sample using conventional powder metallurgy route is discussed. Desired amount of metallic powders by weight percent are blended, uni-axially pressed and sintered in tubular vacuum furnace at different sintering temperatures. The influence of compaction pressure and sintering temperature on density, hardness, surface roughness and electrical resistivity is determined. Surface porosity and the effect of sintering temperature on the microstructural features are analyzed noticeably. It is found that the compaction pressure of 700 MPa and the sintering temperature of 1365℃ are the most desirable process parameters, essentially required for synthesizing the Nimonic 90 superalloy. Sample prepared under these conditions has achieved the desired density and hardness, as that of the standard Nimonic 90 alloy. Thus, the study paves the way for future researchers to appropriately identify the conditions suitable for preparing the superalloys as per the application needed.

Nb/a-Si/Nb Josephson junctions for high-density superconducting circuits

We present electrical characterization data of sputtered Nb/a-Si/Nb Josephson junctions (JJs) for high-speed and high-density superconducting circuits. Junctions were studied with critical current densities (Jc) ranging from 0.01 to 3 mA/μm2 at 4 K. For junctions deposited at room temperature and processed to a maximum temperature of 150 °C, the dependence of Jc on barrier thickness d is exponential, Jc∝exp (−d/d0), with d0 constant over the entire range of Jc values studied. Junctions were annealed at temperatures up to 300 °C to study changes in their electrical properties and possible compatibility with high temperature fabrication processes. Current–voltage characteristics, critical current uniformity, critical current modulation with in-plane magnetic field, and sub-gap resistance behavior of these junctions were measured at 4 K and demonstrate that the junction properties do not degrade with annealing. These data indicate that Nb/a-Si/Nb JJs are a potential candidate for higher speed and higher density superconducting circuits.

Cost-effective silicon-photonic biosensors using doped silicon detectors and a broadband source.

We propose and demonstrate a cost-effective, microring-based, silicon photonic sensor that uses doped silicon detectors and a broadband source. Shifts in the sensing microring resonances are electrically tracked by a doped second microring, which acts as both a tracking element and a photodetector. By tracking the power supplied to this second ring, as the sensing ring's resonance shifts, the effective refractive index change caused by the analyte is determined. This design reduces the cost of the system by eliminating high-cost, high-resolution tunable lasers, and is fully compatible with high-temperature fabrication processes. We report a bulk sensitivity of 61.8 nm/RIU and a system limit of detection of 9.8x10-4 RIU.

Arrested tectonic development: Preservation of high-temperature fabrics in the sinistral Caiçara shear zone (Borborema province, northeastern Brazil)

The protracted duration of shearing in large-scale shear zones and/or their reactivation may obscure the metamorphic conditions under which the mylonites initially formed. Here, we describe the case of the high-temperature Caiçara shear zone (Borborema Province, northeastern Brazil), which shows only limited overprint by low temperature fabrics. The NE-trending Caiçara shear zone is ∼35 km long and comprises a 2 to 5 km-wide mylonitic belt. The shear zone was characterized by using kinematic analysis, including field and microstructural observations and measurement of quartz c-axis. The mylonitic foliation is steeply NW-dipping and contains a shallowly SW-plunging stretching lineation. Kinematic criteria (e.g., asymmetric porphyroclasts, S–C fabrics, asymmetric folds, C′-type shear bands) are consistent with sinistral shear. The dominant microstructures (e.g., chessboard extinction in quartz, grain boundary migration and subgrain rotation recrystallization in quartz, and polygonal aggregates of feldspar around porphyroclasts) and application of the opening angle thermometer indicate deformation dominantly at temperatures higher than ∼ 600 °C. In contrast to the common situation in the central Borborema Province, the Caiçara shear zone is unconnected to other shear zones. We attribute preservation of high-T fabrics to cessation of shearing in an early stage of development, preventing continuous fabric development at decreasing temperature conditions.

High-performance self-powered color filter-free blue photodetector based on wide-bandgap halide perovskites

Blue photodetectors (PDs) are attracting great attention for various applications. Commercial blue PDs based on inorganic GaP or InGaN absorbers are limited by their expensive, complex, and high-temperature fabrication techniques. Organic absorber-based blue PDs still have much lower photodetecting properties than inorganic blue PDs. In this study, a high-performance self-powered blue PD is developed using methylammonium lead halide (MAPbX3; X = I, Br, and Cl) perovskites based on the economic and facile solution process at low temperatures. Optimal composition is obtained through halide-composition engineering. Our best-performing device exhibits an average external quantum efficiency and an average detectivity of 42.7% and 8.65 × 1011 Jones, respectively, within the blue region. The peak responsivity of the proposed PD is 0.174 A W−1 at 455 nm, which is comparable to that of commercial gallium phosphide blue PD (0.180 A W−1 at 470 nm). Moreover, the proposed device exhibits excellent environmental stability under ambient air conditions. These findings will act as a basis for next-generation image sensor technologies, such as vertically stacked red/green/blue PDs.

A case study of high-temperature polyetherimide film capacitor fabrication

Capacitors, as the basic building block of power electronics and electrical systems, are the major constraint of the increasingly integrated power systems that require new capable polymer dielectric films operating at higher temperatures >125 °C. Despite tremendous research efforts on the lab scale, there remains a considerable barrier and knowledge basis for converting polymeric films to functioning capacitors desired in actual applications. The authors tackled the polyetherimide (PEI) film scale up issues and developed various engineering processes for film de-wrinkling, optimal metallization, static elimination, and capacitor fabrication improvement. The authors discovered various fabrication challenges such as the electrostatic charge, metallization scheme, winding tension, and end electrode disconnects. To fabricate a high yield of PEI capacitor bobbins, it is necessary to utilize static eliminators (radioactive ionizers), moderately thick aluminum metallization (15–30 Ω/sq), and winding tension (60–100 g). It is also effective to evaluate capacitance, dielectric loss, equivalent series resistance, and thermal cycling stability of capacitors. This work sheds some light on converting PEI films and other polymeric films to capacitors on a scale up fabrication effort. The practical learning from film handling to capacitor fabrication in this work provided the necessary knowledge for manufacturing high-temperature polar film capacitors.

A comparison study of high thermal stable and resistant polyimides

Polyimide thin films with high thermal stability and resistance will contribute to the development of flexible energy devices, which could be compatible with their high temperature fabrication process. Thus, we have prepared poly(amic acid) solutions with bisbenzimidazole and bisbenzoxazole based diamines and finally fabricated polyimide thin films. After comparing with commercial type polyimides, the polyimides containing bisbenzimidazole and bisbenzoxazole segments showed excellent thermal decomposition temperatures (of 581 and 584 °C, respectively), outstanding mechanical properties (with a tensile strength of 218 and 192 MPa, respectively), and relatively low water absorption percentages (of 0.68% and 0.63%, respectively). The superior properties should be ascribed to the rigid molecular chain skeleton, strong inter- and intra-molecular-chain forces, and hydrogen bonds.

Flexible transparent photovoltaics for ultra-UV photodetection and functional UV-shielding based on Ga2O3/Cu2O heterojunction

Ultraviolet (UV) radiation, the harmful portion of the solar spectrum, can have chronic effects on human skin and eyes. Long and periodic exposure to UV radiation can cause skin cancers such as basal and squamous cell carcinoma and visual impairment due to corneal damage. Blocking UV radiation and utilizing the corresponding high energy for energy production can lead to breakthroughs in the medical field and the energy production crisis. Although metal oxide-based photovoltaics are used to harvest UV radiation, their rigid design, high-temperature fabrication, and high weight make them unsuitable for wearable and portable applications. However, developing a lightweight, flexible solar cell based on earth-abundant and nontoxic inorganic materials is still a challenge. In this work, we develop a completely inorganic, lightweight, highly robust, flexible, and transparent Ga2O3/Cu2O heterojunction for photovoltaics and photodetectors. The flexible Ga2O3/Cu2O heterojunction blocked almost 96% of UV light and produced a power of 156 µW/cm2. The device also showed UV-Vis photodetection along with high robustness and durability even after a large number of bending cycles. The device can be easily integrated on sites for UV blocking and energy production and provides a high degree of freedom of installation on windows or surfaces of objects (automobiles, buildings, etc.) to power the Internet of Things (IoT) systems.

Efficient molecular ferroelectric photovoltaic device with high photocurrent via lewis acid–base adduct approach

Traditional inorganic oxide ferroelectric materials usually have band gaps above 3 eV, leading to more than 80% of the solar spectrum unavailable, greatly limiting the current density of their devices just at μA cm−2 level. Therefore, exploring ferroelectric materials with lower band gaps is considered as an effective method to improve the performance of ferroelectric photovoltaic devices. Inorganic ferroelectric materials are often doped with transition metal elements to reduce the band gap, which is a complex doping and high temperature fabrication process. Recently, molecular ferroelectric materials can change the symmetry and specific interactions of crystals at the molecular level by chemically modifying or tailoring cations with high symmetry, enabling rational design and banding of ferroelectricity in the framework of perovskite simultaneously. Therefore, the molecular ferroelectric materials have a great performance for both excellent ferroelectricity and narrow band gap without doping. Here, we report a ferroelectric photovoltaic device employing an organic-inorganic hybrid molecular ferroelectric material with a band gap of 2.3 eV to obtain high current density. While the poor film quality of molecular ferroelectrics still limits it. The Lewis acid–base adduct is found to greatly improve the film quality with lower defect density and higher carrier mobility. Under standard AM 1.5 G illumination, the photocurrents of ∼1.51 mA cm−2 is achieved along with a device efficiency of 0.45%. This work demonstrates new possibilities for the application of molecular ferroelectric films with narrow band gaps in photovoltaic devices, and lays a foundation for Lewis acid–base chemistry to improve the quality of molecular ferroelectric thin films to obtain high current densities and device performance.