Solar-thermal conversion can mitigate the inadequate electrochemical performance in extreme cold environment for aqueous electrochromic devices (AEDs). However, the limited intrinsic absorptance of electrochromic materials impedes a satisfying solar-thermal conversion. Herein, bioinspired by the Paradisaeidae’s super black feathers, multiscale hierarchical structure is purposely made to compose of WO3-x nanowires (WNWs) and silver nanowires (AgNWs), where WNWs are grown on AgNWs in different orientations (denoted as WAg). Our ray tracing simulation reveals its underlying absorption mechanism, demonstrating both an increased optical path and a concentrated energy distribution. Comparably, the WAg-AED exhibits much enhanced absorption (87.0 vs. 68.5 % across the entire solar spectrum) and a broader surface temperature change (51.2 vs. 39.7 °C within 8 min) under 1 solar illumination. This leads to a rapid recovery of electrochromic/electrochemical performance even conducted at −20 °C. Notably, upon irradiation for 12 min, the areal capacities of WAg-AED at 0.5mA cm−2 increase by 3.8 and 1.7 times, when compared to the device operating at −20 °C and room temperature, respectively. The WAg-AED establishes a close connection between the photo-thermal conversion and electrochemistry, proving a new pathway in the development of sustainable electronics.
Read full abstract