ABSTRACT The availability of simultaneous X-ray and very high energy (VHE) observations of blazars helps to identify the plausible radiative contributors to the VHE emission. Under leptonic scenario, the VHE emission from BL Lacs are attributed to the synchrotron self Compton (SSC) emission. However, many BL Lacerate (BL Lacs) have shown significant hardening at VHE after correction for the extragalactic background light (EBL) attenuation. We study the spectral hardening of two nearby BL Lac objects, Mkn 421 and Mkn 501 having most number of simultaneous X-ray and VHE observations available among all the blazars. These BL Lacs are relatively close and the effect of EBL attenuation is relatively minimal/negligible. We study the scatter plot between the X-ray spectral indices and intrinsic VHE indices to identify the plausible origin of the VHE emission. For Mkn 501, the VHE spectral indices are steeper than X-ray spectra, suggesting the scattering process happening at extreme Klein–Nishina regime. On the other hand, for Mkn 421, the VHE spectra is remarkably harder than the X-ray spectra, which suggests an additional emission mechanism other than the SSC process. We show this hard VHE spectrum of Mkn 421 can be explained by considering the inverse Compton (IC) emission from a broken power-law electron distribution with Maxwellian pileup. The possibility of the hadronic contribution at VHE γ-rays is also explored by modelling the hard spectrum under the photomeson process.