In response to the problems of small diffusion area, short solidification time, and poor flowability of existing fire extinguishing materials in preventing coal spontaneous combustion in goaf areas of western mining areas, this paper studies a thickened slurry with good flowability and fast diffusion ability. The optimal ratio of thickened slurry was determined through orthogonal experiments, and the rheological properties, impregnation characteristics, and wall hanging characteristics of the material were studied. The results showed that when the water to soil ratio was 8:1, and the concentrations of sodium alginate (SA) and apigenin were 0.6 % and 0.5 %, the flowability and suspension performance of the thickened slurry were the best. When the soaking time is 14 days, the best soaking degree of the material can be achieved, with a soaking depth of 0.93 mm. Through wall hanging tests, it was found that the thickened slurry can naturally air dry on the surface of vertically placed coal pillars with a small sliding distance, which has good adhesion and retention characteristics. Further on-site experiments have shown that by injecting thickened slurry, the CO concentration at the return air corner is significantly reduced, indicating that thickened slurry can cover a large area of residual coal in the goaf, prevent contact between coal and O2, and effectively prevent the composite reaction between coal and oxygen.