A double-skin system (double-glazed external wall) is an effective passive system that can be used to decrease solar heat gain into buildings. Detailed information on the thermal distribution of double-skin facades is necessary to design better systems that can provide thermal comfort and conserve energy. In this study, the three-dimensional thermal characteristics of double-skin facades that had the ventilation opening installed partially and were screened partially by the adjacent buildings were investigated by field measurements. To that end, field measurements were carried out on the double-skin exterior wall (9.4 m high and 27.0 m wide) installed in an atrium located in the west of an existing building during cooling period for typical summer conditions. Maximum air change rate of natural ventilation through the bottom opening up to the top opening is about 20–25 [1/h], the reduction ratio of total solar heat gain compared with those of non-natural ventilation is about 25%. The exhaust solar heat gain is about 100 W/m 2 per inner glass surface area of the double-skin facades. Air temperature distribution of air space in the double skin was ranged from 30 °C to 44 °C, and heat gain difference ranged from 50 W/m 2 to 130 W/m 2. The influence of the ventilation openings and the shade conditions on temperature distribution of double skin is found to be significant and the double-skin system was verified to reduce the cooling loads effectively.