Multiphase combustion is of practical importance in many applications and has received growing interest in the last few decades. However, all the details of the mechanisms involved in this field of research are far from being fully understood. The aim of this work is to bring a new insight to the coupling between vaporization and ignition of a dense cloud of droplets. Therefore, a system of one-dimensional equations including source terms for the vaporization is solved numerically for a spherical cloud of fuel droplets in a hot, oxidizing atmosphere. The different cases investigated show two main ignition modes: internal homogeneous or external diffusion ignition. The analysis of the results proceeds in two steps: first, analytical expressions are derived for the temporal evolution of the cloud before ignition: second, the characteristic time of homogenous and diffusion ignition is estimated continuously during the vaporization process. This decomposition provides useful information about the dynamics of the phenomenon. The coupling between cooling and chenical reaction is explained on the basis of this decomposition. A classification of the ignition modes follows from this analysis, and an ignition diagram is proposed.