The present work reports the optical, structural, and electrical properties of cerium-doped Zn0.6Ni0.2Mg0.2Fe2-xCexO4 soft ferrites by green synthesis method that unwrap transformative insights and find technological applications through X-ray diffraction (XRD), UV visible spectroscopy and IV-point probe techniques. Ferrites with different cerium concentrations (x = 0.0, 0.0250, 0.0375) show an enormous difference in the optical, structural, and electrical behavior of the ferrites. The crystallite size increases to 46.9 nm, with a concomitant increase in lattice constants up to 8.550 Å for x = 0.0375. A similar structural shift was noticed in X-ray and bulk densities from 5.031 to 4.982 g/cm³ and 3.83 to 3.97 g/cm³, respectively. The optical explorations revealed a remarkable bandgap reduction from 2.768 eV to 2.758 eV improving the utility of the material substantially in magneto-optic devices. Conversely, the refractive index increases from 2.420 to 2.423, and the imaginary dielectric constant goes up from 10.654 to 10.667, giving a herald of advancement in photonic technologies. Electrically, the study marks a drastic reduction in DC resistivity from 1.95 × 105 to 6.13 × 103 ohm-cm with the Ce doping, which indicates higher conductivity suitable for telecommunication. This extensive work on Ce-doped soft ferrites now opens up newer avenues of applications in electronics and magneto-optics, blending scientific inquiry with practical utility.