The flame stability and combustion characteristics of NH3 is changed by the addition of CH4, including the flammability limits. In this paper, a 5L spherical closed explosive container was constructed to determine the flammability limits of CH4/NH3 mixtures at different CH4/NH3 ratios. The experimental results show that as the NH3 concentration increases, both the upper flammability limits and lower flammability limits of the mixture increase, and the flammable range shifts upwards. A predictive model for the flammability limits of CH4/NH3 mixtures is established based on the limiting laminar burning velocity method, and the predictive model was found to be accurate and reliable by comparing the calculated data with the experimental results. Finally, the effects of CH4 addition, oxygen concentration, and initial temperature on the flammability limits are discussed with the predictive model. The results show that the increase in oxygen concentration significantly increases the upper flammability limits of the mixture and has little effect on the lower flammability limits. An increase in initial temperature raises the upper flammability limits and decreases the lower flammability limits of the mixture, resulting in a wider flammable range.
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