In recent decades environmental quality assessment has become a fundamentally important task in the operation of mining enterprises. This assessment becomes an integral part of the strategy for determining maximum permissible loads for mining regions and is aimed at reducing geoecological risk in them. Technological processes of mining and processing plants generate emissions of various pollutants into the atmospheric air, lead to violation of adjacent territories. Monitoring, primarily of atmospheric air and soils, is necessary to ensure the ecological balance of such territories. Lebedinsky Mining and Processing Plant is one of the most significant sources of gas and dust emissions from massive explosions in quarries during ore extraction, which form a large dust and gas cloud, creating a risk of deterioration of the life of the population in the surrounding area. The article examines the main pollutants in soils and in the atmospheric air during mass explosions, and determines the areole of their distribution from the work site. The forecast of an increase in the concentrations of detected harmful substances for the next 50 years is given. A methodology for conducting geoecological monitoring during mining operations is proposed. The research results may be useful in assessing geoecological risks and developing measures to reduce them.